1. Which of the following statements is correct? a) In this figure, E1 is the bonding orbital b) At energy level E2 the two atomic wave functions ψ1s overlap in phase EE1σ∗ E1s E1s EE2σ H2 H -atom H -atom c) H3 molecule formation is energetically favorable d) sp3 hybridization does not occur in case of H2 molecule formation 2. According to the FermiFermi-Dirac function, which of the following statement is correct? E a) At 0K the probability of finding an electron at an energy (EF+0.32 eV) is less than half but not zero T2 > T 1 T=0 EF b) At room temperature (300K) the probability of finding an electron at Fermi energy is one 0 c) At high temperature (500K), where electrons are not free, the probability of finding an electron at Fermi energy is half T1 1 / 2 1 f(E) d) None of the above is correct 1 3. Consider an intrinsic semiconductor (Si) is at room temperature, which of the following statements is correct? a) the valance band is completely filled and the conduction band is totally empty b) the valance band is completely filled and the conduction band has few electrons c) the valance band is not completely filled and the conduction band is not totally empty 4. Consider a pure Ge crystal is at room temperature, which of the following statements is correct? a) the conductivity is contributed by the free electrons in the conduction band but not by the holes in the valance band b) there is no hole because this is not an extrinsic semiconductor, i.e., no doping c) Thermal energy at room temperature (0.038 eV) is much less than the band gap (0.66 eV) of Ge. But, hole-electron pair generation occurs at room temperature d) There is no charge carrier because it is a semiconductor 2 5. For a p-type semiconductor, which of the following statement is true? a) the Fermi energy level is always close to the conduction band b) the Fermi energy level moves close to the CB, only if temperature is high enough c) the Fermi energy is at equal distance from the bottom of the conduction and from the top of the valance band d) the Fermi energy level is close the valance band 6. Write ‘T’ for true and ‘F’ for false statement You have a small cube of n-type semiconductor. It has plenty of free electrons in its conduction band. But, the cube is electrically neutral 3 7. The following figure shows temperature dependency of the carrier concentration. Which of the following region is termed as ionization slope? ln(n) INTRINSIC slope = -Eg/2k a) region A A b) region B c) region C B ln(Nd) EXTRINSIC IONIZATION Ts C slope = −∆E/2k Ti ni(T) 1/T 8. The Si crystal shown in the figure is first doped with 1012 As atoms. The crystal is further doped with 1015 B atoms. Which of the following statement is true for this Si crystal? 2 cm a) such a doping is not possible R 1 cm fer Si w a 1 mm b) it becomes n-type c) it becomes p-type d) it is neither n-type nor p-type 4 9. Write “T” for true and “F” for false statement Consider, the conduction band of an intrinsic Si semiconductor is empty and the valance band is full. Statement: The valance band is actually consists of many finely separated energy levels, which effectively becomes continuous. Same thing (splitting) happens in the conduction band although there is no electron in the conduction band. Pt (Φ=5.36 eV) Mo (Φ=4.20 eV) 10. Two metals Pt and Mo are in contact. Which of the following is correct? a) electrons tunnel from Pt to Mo b) electrons tunnel from Mo to Pt c) electrons do not tunnel 5