LAW OF CONSERVATION OF MASS Anatomy of a Chemical Equation Ingredients are called “reactants” Results are called “products” 2H2 + O2 2H2O coefficient- how many there are of that molecule reacts with “yields” or produces subscript- number of atoms present per molecule LEARNING CHECK How many atoms of each element are in the following molecules? 1. 2. 3. 4. H2SO4 Ca(OH)2 NaCl 3H2O LAW OF CONSERVATION OF MASS Mass cannot be created nor destroyed in a chemical reaction. Mass can be converted from one form to another # of atoms in the reactants = # of atoms in the products mass of reactants = mass of products 2H2 + O2 2H2O VISUALIZING THE LAW OF CONSERVATION OF MASS Reactants mass of reactants Products = mass of products In the procedure shown above, a calcium chloride solution is mixed with a sodium sulfate solution to create the products shown. Which of the following is illustrated by this activity? A. the law of conservation of mass B. the theory of thermal equilibrium C. the law of conservation of momentum D. the theory of covalent bonding TEST QUESTION Which of the following equations correctly shows the conservation of mass? a. HgO ---> Hg + O2 b. BaSO4 + C ---> BaS + CO c. H2SO4 + 2KOH ---> K2SO4 + 2H2O d. NiCl2 + 2NaOH ---> Ni(OH)2 + NaCl According to the law of conservation of mass, how much zinc was present in the zinc carbonate? a. 40 g b. 88 g c. 104 g d. 256 g Accuracy and Precision Accuracy Accuracy is how close a measured value is to the actual (true) value. The bullet holes on this target are accurate but not precise. Precision Precision is how close the measured values are to each other. The bullet holes are precise but not accurate. Examples Practice Look at each target. Determine if the bullet shots are precise, accurate, both or neither. Significant Figures Why are significant figures important? Scientists indicate the precision of measurements by the number of digits they report. A value of 3.92g is more precise than a value of 3.9g. The digits that are reported are called significant figures. Significant figures (sig figs) include all known digits plus one estimated digit. So in the example above: 3.92 there are three sig figs—two known and one estimated. Rules for recognizing significant figures 1. Non-zero numbers are always significant. sig figs 2. Zeros between non-zero numbers are always significant. 3. All final zeros to the right of the decimal place are significant. 4. Zeros that act as placeholders are not significant. (In this case, convert to scientific notation to remove the placeholder zeros.) 5. Counting numbers and defined constants have an infinite number of significant figures. 72.3 = 3 60.5 = 3 sig figs 6.20 = 3 sig figs 0.0253 = 3 4320 = 3 6 molecules 60sec = 1 min. Let’s give it a try! Determine the number of significant figures in the following masses: a. 0.00040230g a. 405000kg a. 508.0L a. 3.1587 x 10-8g How’d you do? a. 0.00040230g five significant figures a. 405000kg three sig figs a. 508.0L four sig figs a. 3.1587 x 10-8g five sig figs Rounding for significant figures If the digit to the right of the last sig. fig. is <5, do not change 2.532 2.53 If the digit to the right of the last sig. fig is >5, round up 2.536 2.54 If the digit to the right of the last sig. fig. is = 5 and followed by a number larger than zero, round up 2.5351 2.54