Unit 3 Review THE MATH OF CHEMICAL EQUATIONS Limiting Reactant Stoichiometry 1. Use the following equation to answer the following questions. 2 Na + Cl2 ---> 2 NaCl a. Starting with 30.1 g of Na and 22.4 g of Cl2, how many grams of NaCl can be made? Ans ________ b. How many g of excess reactant remain? Ans ________ c. Afterwards, 17.1 grams of NaCl are produced by the reaction. What is the % yield? Ans ________ 2. A molecule is 87.5% N and is 12.5% H. What is its empirical formula? Ans ________ If this molecule's formula weight is 48 g/mol, determine its molecular formula: _____________ CHEMICAL EQUATIONS 3. Which set of coefficients balances the equation for the complete combustion of ethane, C2H6? __C2H6 + __O2 __CO2 + __H2O a) 1,3,2,3 c) 2,6,4,5 b) 1,6,2,6 d) 2,7,4,6 4. When this expression is balanced, 2C3H6 + O2 CO2 + 6H2O what is the coefficient of oxygen, O2? a) 6 c) 12 b) 9 d) 18 5. During a “titration lab,” an acid was neutralized by the following reaction: NaOH + HCl NaCl + H2O This reaction would be classified as… a) synthesis b) decomposition c) double replacement d) single replacement 6. Which reaction below would be classified as a decomposition reaction? a) NaHCO3 NaOH + CO2 b) 2 H2 + O2 2 H2O c) 2 AgNO3 + Cu° Cu(NO3)2 + 2 Ag° d) Ba(OH)2 + H2SO4 BaSO4 + 2 H2O 7. The complete combustion of ethane, C2H6, produces a) C2H5OH b) CH3COOH c) CO2 and H2 d) CO2 and H2O Use the activity series to predict whether the following reactions will occur... If YES, then write the products -- If NO, then write 'N. R.' (no reaction) 8. Al + FeCl2 ---> ___________________ 9. Cu(NO3)2 + Ca ---> _____________________ 10. Zn + NaCl ---> _____________________ Predict the products: 11. CuSO4 + AgCl ---> __________________ 12. C2H6 + O2 ---> ____________________ 13. Suppose you made a Micro-Rocket with butane (C4H10) as the fuel. What is the correct ratio of fuel to O2? 14. What gas is formed when Zn metal is mixed with hydrochloric acid, HCl? a) CO2 c) O2 b) He d) H2 Nomenclature The following random compounds need either names or formulas. Help them discover their identity! 1. Cs3P ___________________ 2. SiCl4 ___________________ 3. platinum (IV) iodate _________ 4. calcium nitrite ________ 5. stannous chloride ___________ 6. HBrO3 ________ 7. sulfur trioxide _______________ 8. Fe(NO3)2 ___________________ 9. (NH4)4C ___________________ 10. hydrochloric acid _________ 11. mercury (II) oxalate ________ 12. CoCO3 _________________ 13. CO ___________ 14. How many electrons were transferred to make AlCl3? _____ MATTER 1. Which property is always conserved during a chemical reaction? a) mass c) pressure b) volume d) solubility 2. Which one of the following is the correct formula for aluminum oxide? a) AlO c) Al2O3 b) Al6O6 d) Al3O2 3. What is the name of the compound CF4? a) b) c) d) 4. fluorocarbonate carbon tetrafluoride tricarbon fluoride carbon difluorate Sodium nitride has the formula Na3N. What is the formula for magnesium nitride? a) Mg2N c) Mg3N2 b) Mg3N d) Mg2N3 5. What is the mass of one mole of aluminum sulfate, Al2(SO4)3? a) 630 g c) 273 g b) 342 g d) 123 g ACIDS, BASES, & SALTS 1. Which of the following is an acid? a) NaOH c) HCl b) NH3 d) H2O 2. The acid, H2S, is correctly named as: a) hydrosulfuric acid b) sulfuric acid c) dihydrogen sulfide d) hydrogen(I) sulfide OXIDATION AND REDUCTION 1. Hydrogen gas was produced according to the following equation: Zn° + 2 HCl ZnCl2 + H2 Which chemical is oxidized? a) Zn° c) ZnCl2 b) HCl d) H2 2. Chemists can make “Trees” by using the reaction: Cu° + 2Ag+ 2 Ag° + Cu2+ Cu°, is _____ electrons and being _____. a) gaining, oxidized b) gaining, reduced c) losing, oxidized d) losing, reduced Bonds that hold everything together Match the following compounds to the three bond types. Each answer may be used once, more than once, or not at all. C) Covalent Bond I) Ionic Bond M) Metallic Bond ___1. KBr ___6. CaCl2 ___11. ZnI2 ___2. Cu ___7. Br2 ___12. Ag ___3. CO2 ___8. Na2O ___13. NaCl ___4. Pb ___9. SiO2 ___14. C(graphite) ___5. CH4 ___10. brass (Cu + Zn) ___15. C3H8 Match the following statements to the three bond types. Each answer may be used once, more than once, or not at all. C) Covalent Bond I) Ionic Bond M) Metallic Bond ___2. conducts electricity as a solid ___6. malleable and ductile ___3. alternating positive and negative particles ___7. conducts electricity when dissolved in water ___4. sharing electrons between two atoms ___8. involves a transfer of electrons ___5. positive ions in a “sea of electrons” ___9. involved in molecules and in network solids ___10. does not usually conduct electricity Exception?: _______________ 11. State whether each molecule below is polar or non-polar. Explain to each other why you made your choice. Write the Lewis dot structures, geometry, and polarity for the following: 12. O2 13. HF 14. BCl3 15. SO3 16. NO31 - 17. CH3OH Classify the bond type as non polar, polar, or ionic by calculating ∆EN: 18. KBr ∆EN = ________ bond type = _________ 19. CO ∆EN = ________ bond type = __________ 20. SiI2 ∆EN = ________ bond type = _________