Pennium A Yakima WATERS 5E Lesson Pennium Lab Understanding the periodic table is a very important skill for beginning chemists. Atomic mass, number of protons, neutrons, and electrons are the foundation for the structure of the periodic table. For this exercise, students will be using pennies as a model of the element (Pennium). In 1982, the United States changed the composition of the penny changing it from pure copper to a zinc center with copper plating. Because all of the pennies look the same, but have a different weight they make a great model of the chemical isotope. Also, a demonstration will be used at the end of the lab to show the students that the pennies are actually made from different materials. This lab is intended for chemistry students in grades 10-12. Standards Science standards 9-12 APPD -The ability to solve problems is greatly enhanced by use of mathematics and information technologies. 9-11 PS2B - Atoms of the same element have the same number of protons. The number and arrangement of electrons determines how the atom interacts with other atoms to form molecules and ionic crystals. 9-11 PS2J - The number of neutrons in the nucleus of an atom determines the isotope of the element. Radioactive isotopes are unstable and emit particles and/or radiation. Though the timing of a single nuclear decay is unpredictable, a large group of nuclei decay at a predictable rate, making it possible to estimate the age of materials that contain radioactive isotopes. Math standards A1.8.A - Analyze a problem situation and represent it mathematically. A1.8.C - Evaluate a solution for reasonableness, verify its accuracy, and interpret it in the context of the original problem. A1.3B. - Represent a function with a symbolic expression, as a graph, in a table, and using words, and make connections among these representations. A1.8.G - Synthesize information to draw conclusions and evaluate the arguments and conclusions of others. Outcomes Upon completion of this exercise, students should be able to determine number of protons, neutrons, and electrons for a given element. This relationship should then be used to define isotopes and describe how they are formed and list some applications. Students should be able to 1 calculate the average atomic masses of elements. They will also have practiced rounding numbers and analyzing data. Materials and Equipment Students should be placed in groups (2 per group), or could work individually. Each group will need a balance (preferably centigram), a plastic bag with twenty pennies inside, and a calculator. Inside the plastic bags, place twenty pennies of varying dates. It’s important to have about ten pennies from before 1982 and ten pennies from after. Also, you want to make sure the pennies are fairly clean by removing any debris on the surfaces as this will change the weight. For the demonstration done by the instructor: a Bunsen burner, striker, forceps, two pennies (one prior 1982 and one after). Prior Knowledge Students should have prior knowledge of protons, neutrons, and electrons and be able to determine the number for a given element (or atom). Some basic algebra skills are needed; such as rounding, multiplication, division, and some simple manipulation of equations. Safety For this exercise, there aren’t any major safety concerns. The only portion that could potentially be hazardous is done by the instructor. As for minor safety concerns, remind students to wash their hands when finished. Engage (10 min) To engage the students, a question-lead discussion for a couple of minutes on topic of the periodic table serves as a good review. Next a brief demonstration of why two pennies can have different masses. To do this, simply take a penny older than 1982 and a penny that is newer than 1982 and weigh them. It’s best if this can be shown through a document camera on the overhead projector. Then pass the pennies around and ask the students to hypothesize why they think the masses are different. Remind them that they are both pennies! Explore (15 min) Students will get into groups of two, each with their own lab, and be given a station with a balance, bag of twenty pennies, and a calculator (they should provide their own). Once at their lab stations, they will complete the table in the Observations section of the lab. This section requires them to record the date and mass of the pennies. They will also be asked to round the recorded masses from the hundredth place to the tenth place. This step serves as a good review, but is also very important for the correct completion of the lab. The calculations portion of the lab guides the students to understand that there is a different in the masses of pennies. They should mainly see two different mass categories after rounding their numbers; one should be about 3.1g which is from the pre-1982 pennies, and the other will be about 2.5g for the post-1982 pennies. 2 Explain (15 min) The explanation portion of the exercise comes in the application section of the lab. This is where the students read a brief application which helps them relate pennies to isotopes. The goal is to get them to understand that the pennies were being used a model. Then they will be asked to explain the extended knowledge. How many isotopes did they have? How do they know? It is also a good idea to directly (verbally) ask the students what did the pennies symbolizes, especially if they’re not making the connection between the pennies with isotopes. This is a good way to ensure that all the students have made to proper connections; however, you want to do this toward the end. Give the students the opportunity to make the connection on their own. Extend (15 min) Toward the end of the lab, the students are asked to give a couple examples of isotopes and how they are used. During the demonstration, students will need to use the information they have learned to describe what’s taking place. Evaluate (20 min) Students will be evaluated based on their responses from their lab using the following rubric. Also questions on the exam related to calculating average masses and explaining isotopes will be used. Performance Rubric Element Great (5) Good (4) Conceptual Understanding (35%) Application questions: 1,5,6,7, demo Student shows a solid understanding of the content by being able to describe and apply the information covered and be able to connect all the concepts included Student will have a solid understanding of the content, but are having some trouble making all the connections Skill 1 (15%) (simple mathematical skills) PA questions: 1,2 Students were able to properly perform the necessary mathematical equations and calculated them correctly Students were able to properly set up all the necessary equations, some error in calculating 3 In Development (3) Students understand some of the content but were unable to make most of the connections Needs Rethinking (2) Poor (1) Students had little to no understanding of the content and were unable to make valid connections Students had no understanding of the content and did not attempt to make any connections Students made a few errors in setting up mathematical equations, but calculated them correctly Students were unable to set up mathematical equations, but calculated them correctly Students were unable to set up mathematical equations and unable to perform calculations Skill 2 (25%) (Making a table and understanding data) Data table, PA questions:1,2,3 and App question: 3 Skill 3 (25%) (Calculations involving average mass and percent abundance) Application questions: 2,3,4,5 Students were able to properly fill table, and were able to extract data and explain it completely Students made a simple mistake filling in table, but were able to explain their results properly Students made no mistakes filling in table, but had problems explaining their results properly Students made mistakes filling in table and had trouble explaining their results Students could not/would not fill in data table and couldn’t explain Students were able to properly carry out calculations, figure out percent abundance, and explain significance Students made simple errors in calculations, but were able to explain significance Students made simple errors in calculations, and were unable to explain significance completely Students made major errors in calculations, and were unable to explain significance completely Students did not do the calculations, and did not explain significance of them Teacher Background Information Understanding the atomic composition of an element is imperative in composing a solid foundational understanding of chemistry. The number of protons is given in the periodic table (which is the atomic number). The number of electrons can be figured out by subtracting the charge of the given element by the number of protons. An example is P3-: by looking on the periodic table of elements you can figure the number of protons to be 15 (atomic number). To figure out the number of electrons you take 15-(-3) which equals 18 electrons. Neutrons can be factored in when you have the atomic mass given. The average atomic mass subtracting the number of protons will give you the number of neutrons. All the isotopes of an element are factored into the average atomic mass based on their percent abundance. An isotope looks like a normal element (or atom), however, its mass is different because it contains a different number of neutrons. Resources The instructions for the demonstration were obtained from Mr. James Klarich from Davis High School. Using a Bunsen burner, hold a pre-1982 penny with forceps in the flame for a couple minutes. Because the penny is made of pure copper it will glow a hot red color. It’s best if you turn the lights off so the students can see the color better. Then do the same thing with a post-1982 penny. Because the penny is only copper plated, it will melt and the zinc inside will spill out onto the counter. This is best seen with the lights on. http://www.chem4kids.com/files/atom_isotopes.html, www.youtube.com/watch?v=Jdtt3LsodAQ By: John (Eric) Inions, Fall 2011, for Davis High School 4 Pennium Lab Name:____________________ Procedure 1. 2. 3. Each group needs a resealable bag full of pennies. Remove the pennies and count them to make sure that there are 20. Determine and record the combined mass of your 20 pennies. Find the mass of each penny separately. In the Data Table, record the year the penny was minted and its mass to the nearest 0.02 grams. When finished place the 20 pennies in the resealable bag and return the pennies and the laboratory balance to the area designated by your teacher. Return to your seat and finish the pre-application calculations. Observations Penny DATA TABLE Year Mass (g) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 5 20 Pre-application Calculations 1. What is the combined mass (to nearest 0.05 g) of 20 pennies? _____________ 2. Is the mass of 20 pennies equal to 20 times the mass of one penny? Explain. 3. Rounding to the nearest 0.05, how many different weights are there in your data table from above? Application Unless you’re a coin collector, you probably think all the United States pennies are pretty much the same. To the casual observer, all the pennies in circulation do seem to be identical in size, thickness, and composition. But just as elements have one or more isotopes with different masses, the pennies in circulation have different masses. For this application, use the data from before of the pennies with different masses to represent different “isotopes” of an imaginary element called pennium, or Pe. Remember that chemical isotopes are atoms that have the same number of proton, but different number of electrons. Thus, chemical isotopes have nearly identical chemical properties, but some different physical properties. For application purposes, you will determine the relative abundance of the isotopes of pennium and the masses of each isotope. You will then use this information to determine the atomic mass of pennium. Recall that the atomic mass of an element is the weighted average of the masses of the isotopes of the element. This average is based on both the mass and the relative abundance of each isotope as it occurs in nature. Questions 1. Record the number of isotopes of Pe based on your answer in number three from above. 2. Calculate the percentage of each isotope present out of the 20 pennies. This is also called Percent Abundance. (Remember it should add up to 100%) Also record this number as a decimal (divide by 100). 6 3. Calculate the average mass of each of the isotopes. 4. Calculate the average atomic mass of each isotope. Use this equation:[ (atomic weight of isotope from #3) X (% abundance(decimal from question #2))] + [(atomic weight of isotope from #3) X (% abundance(decimal from question #2))] 5. How can you explain the fact that there are different “isotopes” of pennium? 6. List at least three examples of how isotopes are used in the world? 7. Describe what the pennies were used for today? What did they represent? Demo For this portion of the lab, your instructor will conduct a demonstration. Describe what is happening and explain (using words from the chapter of your textbook). 7