X Ray Diagnostics Overview FAC X-TOD Breakout October 12, 2006 October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov LCLS Layout at SLAC Linac-toUndulator (227m e- beam) Undulator Hall (175m e- and g beam) eBeam Dump (40M eand g beam) Near Expt. Hall Far Expt. Hall Linac ebeam (FEE) Front End Enclosure (29m g beam) October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx X-ray Vacuum Transport (250m g beam) Richard M. Bionta bionta1@llnl.gov Raw LCLS Beam Contains FEL and Spontaneous Halo 3 mJ High energy core Eg > 400 keV 2-3 mJ (0.3 W) FEL Pulse duration < 250 fs 20 mJ (2.4 W) Spontaneous 20 mm Spontaneous halo has rich spectral and spatial structure: 0 < E < 10 keV 7.6 < E < 9.0 keV 10 < E < 20 keV 20 < E < 27 keV At midpoint of FEE, FEL tuned to 8261 eV Fundamental, 0.79 nC October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Prioritized List of Desired FEL Measurements (to be measured after finding the FEL) u l1 Dl/l1 x, y x , y f(x,y) s u,s l 1 s x ,s y ,s x ,s y t October 12, 2006 X-TOD Diagnostics Total energy / pulse Photon wavelength Photon wavelength spread Pulse centroid Beam direction Spatial distribution Temporal variation in beam parameters Pulse duration UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Prioritized List of Desired Spontaneous Measurements l1i/l1j Relative 1st harmonic wavelength of undulator i and j f(x,y,l1) Spatial distribution around l1 1st harmonic Photon wavelength 1st harmonic wavelength spread Beam direction Total energy / pulse Temporal variation in beam parameters l1 Dl/l1 x , y u s u,s l 1 October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Codes indicate that damage occurs above melt so choose materials whose doses are a fraction of melt Maximum dose along the beam line for different materials (under normal illumination assuming fully saturated FEL a la M. Xie) Dose (eV/atom) (maximum over 827-8267eV) Shown is the maximum dose (over Ephoton=827 to 8267eV) edump FEE SiC melted Si melted B4C melted Be melted Si - 5/9 melt SiC - 1/9 melt B4C - 1/12 melt Be - 1/50 melt meters from end of undulator October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Candidate detectors pros and cons Element Technology Attenuator Problems Signal reduced, background remains the same Differential pumped N2 gas Space charge, aperture size Low Z solids Damage, scattering CCD Deep depletion Damage, Effect of High E spontaneous, dynamic range CZT imagers Dental X-ray Damage, Effect of High E spontaneous, dynamic range, resolution Phosphor coated imagers Phase plate coupled to CCD Damage, Effect of High E spontaneous, dynamic range, resolution, phosphor saturation Optical coupled Scintillator screen Camera not in beam Damage, dynamic range, saturation Indirect Imager Multilayer mirror reflects fraction of beam into camera Damage, Calibration depends on alignment Photodiodes, PC diamond Damage, Effect of High E spontaneous, spatial resolution Florescence Be doped with high z Damage, contamination and background, signal level Photoelectric Be grid with MCP Calibration, geometry, Effect of High E spontaneous Thermal Energy to heat Damage, sensitivity Ion chamber Count ions sensitivity N2 Photoluminescence Count photons Non-linear space charge, calibration October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov “Direct Imager” x-ray cameras X-ray sensitive CCD or photodiode array X-Ray Beam www.ajat.fi Optical Fiber Scintillator X-Ray Beam Visible Imager X-ray scintilator with fiber coupled imager X-Ray Beam Scintillator Lens Visible Imager X-ray scintilator with lense coupled imager October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov YAG:Ce Light Output Short FEL pulse reveals scintillator saturation FEL energy October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Candidate detectors pros and cons Element Technology Attenuator Problems Signal reduced, background remains the same Differential pumped N2 gas Space charge, aperture size Low Z solids Damage, scattering CCD Deep depletion Damage, Effect of High E spontaneous, dynamic range CZT imagers Dental X-ray Damage, Effect of High E spontaneous, dynamic range, resolution Phosphor coated imagers Phase plate coupled to CCD Damage, Effect of High E spontaneous, dynamic range, resolution, phosphor saturation Optical coupled Scintillator screen Camera not in beam Damage, dynamic range, scintillator saturation Indirect Imager Multilayer mirror reflects fraction of beam into camera Damage, Calibration depends on alignment Photodiodes, PC diamond Damage, Effect of High E spontaneous, spatial resolution Florescence Be doped with high z Damage, contamination and background, signal level Photoelectric Be grid with MCP Calibration, geometry, Effect of High E spontaneous Thermal Energy to heat Damage, sensitivity Ion chamber Count ions sensitivity N2 Photoluminescence Count photons Non-linear space charge, calibration October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Diagnostics Occupy Upstream End of the Front End Enclosure (FEE) Slit Spectrometer Package Solid Attenuators Collimator 1 Total Energy Fixed Mask Gas Detector October 12, 2006 X-TOD Diagnostics Gas Attenuator Gas Detector Direct Imager (Scintillator) UCRL-PRES-xxxxxxx FEL Offset Mirror System Richard M. Bionta bionta1@llnl.gov FEE Schematic 5 mm diameter collimators Windowless Gas Detector Start of Experimental Hutches K Spectrometer Direct Imager Solid Attenuator e- High-Energy Slit Gas Attenuator Muon Shield October 12, 2006 X-TOD Diagnostics NFOV Grating Total Energy Thermal Detector WFOV FEL Offset mirror system Windowless Gas Detector UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Slit and Fixed Mask Define Maximum Beam Spatial Extent Slit Fixed Mask Status: PRD done SCR done PDR done ESD in signature FDR in preparation October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Gas Detector / Attenuator Conceptual Configuration N boil-off 2 (surface) Gas detector Flow restrictor 4.5 meter long, Differential high pressure N2 pumping sections section separated by 3 mm apertures 3 mm diameter Solid holes in Be disks attenuators N2 Gas inlet allow 880 mm (FWHM), 827 eV Status Attenuator: FEL to pass PRD done unobstructed SCR done Prototype done ESD draft PDR in preparation October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Gas detector Green line carries exhaust to surface Richard M. Bionta bionta1@llnl.gov Prototype Gas Attenuator runs well at 0-20 Torr Gas Attenuator prototype pressure control tests October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Gas detectors share differential pumping with the Gas Attenuator Gas Attenuator high pressure section 20 Torr Optical band pass filter Photo diode Gas detector ~1 Torr ~10-3 Torr ~0.1 to 2 Torr N2 ~10-3 Torr ~10-6 Torr ~20 cm inner diameter Single shot, non destructive, measurement of u 2m Photo tube non-specular reflective surface (e.g. treated Al) Optical ND filters LCLS X rays cause N2 molecules to fluoresce in the near UV October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Gas Detector pressure can be adjusted independently of Gas Attenuator pressure October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Schematic of the gas detector from the ESD Data Acquisition System APD Electronics Photodiode Electronics Avalanche Photo Diode Coating Photodiode Bandpass and ND Filters Differential Pumping Section 3 mm apertures along beam path Magnet Coils Magnet Power Supply and Controller October 12, 2006 X-TOD Diagnostics Beam / Gas Interaction Region (~0.1 – 2 Torr N2) Cylindrical Vessel UCRL-PRES-xxxxxxx Gas Feed And Pressure Control Richard M. Bionta bionta1@llnl.gov Overview of physical processes Auger e- photo eH.K. Tseng et al., Phys. Rev. A 17, 1061 (1978) x-rays r N2 gas B q • N2 molecules absorb a fraction of the x-rays by K-shell photoionization, emitting photoelectrons of energy Ex-ray − 0.4 keV • Ionized nitrogen relaxes by Auger decay, emitting Auger electrons of energy ~ 0.4 keV • High-energy electrons deposit their energy into the N2 gas until they are thermalized or reach the detector walls • Excited gas relaxes under the emission of near-UV photons October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Photoluminescence of N2 A.N. Brunner Cornell University (1967). • N2 has strongest lines in the near UV (between 300 and 430 nm) • Backgrounds in the near-UV are difficult to estimate: • Effect of recombination of ions at chamber walls? • Effect of electrons hitting the chamber walls? • We use existing experimental data to estimate the near UV signal: •e.g. measurements made for the Fly’s Eye cosmic ray detector October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov The fluorescence yield per deposited energy depends only weakly on the energy of the exciting electron Fluorescence Yield per deposited energy (a.u.) 1.5 Torr 15 Torr 150 Torr 760 Torr 0.85 MeV 400 eV (F. Arqueros et al., submitted) 8 keV Electron energy (eV) Dependence of the photoluminescence yield on the energy of the incoming electron October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Small magnetic field keeps primary photoelectrons away from walls Electron trajectories and energy deposition in N2 at 8.3 keV B = 250 Gauss without magnetic field 3.0 3.0 2.5 2.5 2.0 2.0 r (cm) 1.5 r (cm) 1.5 1.0 1.0 0.5 0.5 0.0 0 October 12, 2006 X-TOD Diagnostics 5 10 15 z (cm) 20 25 30 UCRL-PRES-xxxxxxx 0.0 0 5 10 15 20 z (cm) 25 Richard M. Bionta bionta1@llnl.gov 30 Expected near-UV signal at FEL saturation 8.3 keV, 2 Torr, 2.3 mJ, 250 Gauss 0.83 keV, 0.1 Torr, 2.3 mJ, 60 Gauss Lambertian Lambertian reflector 8x10 1.2x10 8 Number Number of of specular Photons 4x10 reflector 8 8.0x10 specular Photons reflector reflector 8 absorber 4.0x10 X-TOD Diagnostics 7 absorber 0.0 0 October 12, 2006 7 UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Expected near-UV signal for low intensities 0.83 keV, 0.1 Torr, 0.1 mJ, 60 Gauss 3 6.0x10 Lambertian 4.0x10 Lambertian reflector 4 reflector 3 Number 4.0x10 Number of Photons 8.3 keV, 2 Torr, 1 mJ, 250 Gauss 2.0x10 specular 4 reflector of specular Photons reflector 3 2.0x10 absorber 0.0 absorber 0.0 1 cm recess x-rays 2.5” 30 cm October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Total Energy (Thermal) Sensor Concept Thin low-Z high-G substrate for FEL absorption, thermistor deposited on back side. Temperature rise is proportional to FEL energy, heat flow to cold bath through substrate • Radiation-hard absorber • High E halo transmitted • Sensor protected from beam • Low T operation for high diffusivity ( Speed) and low heat capacity C ( Sensitivity) 0.5 mm Si substrate (sets absorption, C and G) 15 Nd Thermistor (sets operating Top, sensitivity R/T) Resistance [k½] FEL pulse 60 50 Sr 0.67 MnO 0.33 3 sensor on STObufffered Si 10 40 30 5 20 0 10 0 1/R dR/dT [%/K] Cu heat sink (sets Tbath) -5 90 120 150 180 210 240 Temperature [K] Sensor implementation: Nd0.66Sr0.33MnO3 (CMR material) on buffered Si substrate. Cooling in mechanical low-vibration pulse-tube cryocooler October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov t=0 t = 0.1 ms t = 0.25 ms Sensor FEL 0.5mm Si Delta Temperature at Chip [K] FEL induced Temperature pulse quickly diffuses to sensor side, then dissipates 5 Tc200 Tc150 Tc100 4 3 2 1 0 0 0.05 0.1 0.15 0.2 0.25 Time [ms] Peak signals are ~1K per mJ of FEL pulse energy as expected for ~mm3 of Si at ~150K. October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov 0.3 Sensor temperature maintained by Pulse tube cryocooler Considerations: 1) No liquid cryogens in tunnel 2) Low vibrations to reduce microphonic noise and fluctuations in sensor position Low vibrations (SEM compatible) 4 1/2” flange Pulse tube Cold head He gas compressor and rotary valve separated acceleration [µg/rtHz] 103 102 101 100 0 10 20 30 frequency [Hz] VeriCold PT: ~5W cooling power at 80K, low vibrations by separating rotary valve. Sensor position should fluctuate less than ~25 µm beam jitter. October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov 40 Calibration of Total Energy Sensor will be maintained through in situ Laser system Sensor on Si Attenuator: Filter wheel Beam focus Beam splitter on Gimbal mount Minilite pulsed Nd-YAG laser, 532 nm Sources of error (according to specs): Variations in laser output E: Absolute accuracy of laser output: Variations in optical components: Absolute accuracy of pulse meters: Reflection at Si: October 12, 2006 X-TOD Diagnostics Ophir PE-10 Pulse meters: 3% accuracy Incident beam calibration Reflected beam monitoring to assess radiation damage ±1% rms Not calibrated Negligible (below damage threshold) ±5% at 532 nm 37% at 532 nm (flat surface) roughen, calibrate UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Total Energy Error Budget Summary Calibration errors: <5% (limited by accuracy of pulse meter) Electronic noise error: <0.1% at saturation <10% at low energies (depends on excess 1/f noise) Energy loss error: <2% (limited by electron escape) Jitter error: <3% (if jitter is as low as specified) Total error: < 7% at saturation (2 mJ/ pulse) < 7% at 0.2 mJ < 12% at low energies (10 µJ/pulse) Status Total Energy: PRD done SCR done Prototype in preparation ESD in preparation PDR in preparation October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Total Energy Monitor Prototype Vacuum chamber: Based on 6-way cross Refrigeration: Pulse-tube cryocooler To pulse tube and xy-stage Weak link Heater No xy-motion in prototype (yet) XYZ-stage with 5µm steps in z, 3µm in xy Sensor: Nd0.67Sr0.33MnO3 on Si chip Cu chip mount Surface mount resistor as test heat source, laser soon Multiple sensors for different FEL conditions can be operated in final design. Cu-capton-Cu wiring traces Sensor Cu clamps Sensor mount on xy-stage allows ±5 mm field of regard and 40 35 mm2 stay-clear area. October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Thermal Detector and Direct Imager Direct Imager Thermal Detector Calibration Laser Laser Energy Meter October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Wide Field of View Direct Imager Single shot measurement of f(x,y), x, y ,u Camera Scintillators October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Photometrics Cascade:512B The Cascade:512B utilizes a back-illuminated EMCCD with on-chip multiplication gain. This 16-bit microscopy camera’s "e2v CCD97" device features square, 16-µm pixels in a 512 x 512, frame-transfer format. Thermoelectric cooling and state-of-the-art electronics help suppress system noise. Dual amplifiers ensure optimal performance not only for applications that demand the highest available sensitivity (e.g., GFP-based single-molecule fluorescence) but also for those requiring a combination of high quantum efficiency and wide dynamic range (e.g., calcium ratio imaging). The Cascade:512B can be operated at 10 MHz for high-speed image visualization or more slowly for high-precision photometry. Supravideo frame rates are achievable via subregion readout or binning. October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Run027: Low Energy, All undulator modules, Spontaneous Absorbed in 5 um YAG, Maximum ~ 20,000 photoelectrons/pixel Full Well: 200,000 Camera: Photometrics 512B Objective: Navitar Platinum 50 Power: 0.1365 NA: 0.060 October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Run030: Low Energy, All undulator modules, FEL Absorbed in 5 um YAG, Maximum ~ 3.7e+8 photoelectrons/pixel Full Well: 200,000 Camera: Photometrics 512B Objective: Navitar Platinum 50 Power: 0.1365 NA: 0.060 October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Run030: Low Energy, All undulator modules, FEL Absorbed in 5 um YAG, Maximum ~ 3.7e+8 photoelectrons/pixel Full Well: 200,000 Camera: Photometrics 512B Objective: Navitar Platinum 50 Power: 0.1365 Zoomed NA: 0.060 October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Run025: High Energy, All undulator modules, Spontaneous Absorbed in 50 um YAG, Maximum ~ 10,000 photoelectrons/pixel Full Well: 200,000 Camera: Photometrics 512B Objective: Linos/Rodenstock Apo-Rodagon-D Power: 0.8 NA: 0.055 October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Run026: High Energy, All undulator modules FEL Absorbed in 50 um YAG, Maximum ~ 5.0e+7 photoelectrons/pixel Full Well: 200,000 Camera: Photometrics 512B Objective: Linos/Rodenstock Apo-Rodagon-D Power: 0.8 NA: 0.055 Zoomed October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Run036: Low Energy, First undulator module, Spontaneous Absorbed in 1 mm YAG, Maximum ~ 1,800 photoelectrons/pixel Full Well: 200,000 Camera: Photometrics 512B Objective: Navitar Platinum 50 Power: 0.1365 NA: 0.060 October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Experiments Executed at the FLASH VUVFEL to Verify melt Thresholds Linac Undulator Gas Attenuator C Mirror Gas Detector Focusing Mirror Sample Samples: Bulk SiC Bulk B4C Thin Film SiC Thin Film B4C Thin Film a-C Bulk Si Thin Foil Al Diamond FLASH VUV Beamline YAG 15 single shots at each attenuator setting The FLASH photon energy of 39 eV is strongly absorbed in C resulting in extreme energy deposition in small volumes yet multipulse effects in mirrors not yet a problem. October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Measured crater depths scale with measured pulse energy Nomarski picture of ~ 30 micron diameter crater in SiC induced by FEL at 8 x melt Crater depths, if any, were measured by Zygo interferometry October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Statistical analysis shows damage threshold Measured crater depths for 2 low fluence 15 shot series, ordered in increasing depth / pulse 15 shot series shot-to-shot relative pulse energy measurements ordered in increasing energy / pulse 40 closed symbols: SiC open symbols: B4C Enominal = 30 0.010 Peak Depth (nm) GMD e- / E nominal (V/uJ) 0.012 2uJ 0.008 5uJ 0.006 0.004 0.002 0.4uJ 0.8 mJ 20 10 no damage up to 27-33% (0.59-0.66uJ) no damage up to 73-80% (0.43-0.64uJ) 0 0.000 -0.002 0 0.4 mJ 0.8uJ 20 40 60 80 100 0 Cumulative Percentage Data shows that the shot-to-shot pulse energy varies ~linearly between 0 and 200% 20 40 60 80 100 Cumulative Percentage Data shows a consistent damage threshold between 120 and 180 mJ/cm2 •No evidence for surface damage below the melt threshold (~ 90 mJ/cm2 to reach Tmelt, ~130 mJ/cm2 to melt SiC) October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov S. Hau-Reige and D. Rutyov postulate multipulse thermal fatigue thresholds ~ 1/10 of melt Calculate doses for onset of thermal fatigue (D3), to reach melting T (D1), to melt (D2) Doses below melt but above D3will not visibly damage surface in one shot but material may breakdown after an unknown number of repeated shots in the same place. Multipulse exposures with eximer laser was inconclusive for Si but data still under analysis October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Channel-cut Si Monochrometer (KSpectrometer) October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Diagnostics Summary Instrument Name Method Purpose Calibration and Physics risks Direct Imager Scintillator in beam SP f(x,y), look for FEL, measure FEL u, f(x,y), x,y Scintillator linearity, Scintillator damage, Must be used with Attenuator, Attenuator linearity and background Total Energy Energy to Heat FEL u damage Gas Detector N2 Photolumenescence FEL u Signal strength, Nonlinearities Soft x-ray Spectrometer Be Reflection grating FEL l, FEL u Energy Resolution K Spectrometer Channel-cut Si monochrometer Measure undulator relative K Damage, Signal Strength October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov Conclusions Uncertanties constrain detector technology FEL size, shape, and pulse energy Damage thresholds & mechanisms – melted, melt, fatigue Short pulse effects – saturation High energy spontaneous background Avoid placing active detector electronics in beam Single shot damage thresholds at melt verified at FLASH FEL Three technologies chosen for LCLS YAG Scintillator / camera / attenuator – faint FEL Gas photoluminescence – indestructible Thermal – least unknowns October 12, 2006 X-TOD Diagnostics UCRL-PRES-xxxxxxx Richard M. Bionta bionta1@llnl.gov