University of Texas Arlington Department of Electrical Engineering Nanotechnology – Microelectromechanical Systems Ph.D. Diagnostic Examination Spring 2015 To be filled by the student Question # 1 2 3 To be filled by the graders Check to have this question graded. Check only 2. Grade Grade TOTAL: GRADE OUT of 100: 1 Average 1. (50 pts) The newly discovered, mythical semiconductor “utaium” has a cubic crystal symmetry. The E-k relationship is shown in the figure below. The conduction Bands “A” and “B” have the same energy minima Ec. Conduction Band A Ec Conduction Band B Ev Valence Band L [111] [100] X Given the following inverse effective mass tensor data measured by cyclotron resonance at 4 K. Conduction Band A Conduction Band B 0.5 0 0 mo 0 0.5 0 m* 0 0 0.5 0.1 0 0 mo 0 6 0 m* 0 0 6 mo=9.1 x 10-31 kg Assuming parabolic constant energy surfaces at the band minima to: a) Draw the constant energy surface(s) for electrons near the conduction band minima in k-space. b) Determine the effective mass for electrons in each conduction band ( bands A and B) which have minima at the same energy Ec. c) Determine the overall average density of states effective mass for the entire conduction band mn*. 2 Note: Volume of a prolate spheroid is 4 ab where 2a and 2b are the lengths of the major and minor axes 3 respectively of the rotated ellipse. 2 sol 3 2. (50 pts) Given the iso-etch curves for the HNA silicon isotropic etch system below a. Calculate the etch rate for a etchant solution of 60:20:20 HF:HNO3:HC2H3O2. b. Repeat if the diluent is DI water. sol a. 330 µm/min b. 11.5 µm/min 4 3. (50 pts) A one-hour dry oxidation at 1000 °C is followed by a 5-hour wet oxidation at 1100 °C. Calculate the oxide thickness after each step for a <100> wafer. sol 5