行政院國家科學委員會補助專題研究計畫 █ 成 果 報 告 □期中進度報告 對衝水霧流與地板上固體燃料火焰的交互作用 Interaction Between Opposite Water Mist Flow and Flame Over a Solid Fuel on the Floor 計畫類別:█ 個別型計畫 □ 整合型計畫 計畫編號:NSC 94-2212-E-218-015- 執行期間: 94 年 8 月 1 日至 95 年 7 月 31 日 計畫主持人:林宗賢 共同主持人: 計畫參與人員: 成果報告類型(依經費核定清單規定繳交):█精簡報告 □完整報告 本成果報告包括以下應繳交之附件: □赴國外出差或研習心得報告一份 □赴大陸地區出差或研習心得報告一份 □出席國際學術會議心得報告及發表之論文各一份 □國際合作研究計畫國外研究報告書一份 處理方式:除產學合作研究計畫、提升產業技術及人才培育研究計畫、 列管計畫及下列情形者外,得立即公開查詢 □涉及專利或其他智慧財產權,□一年□二年後可公開查詢 執行單位:南台科技大學機械工程系暨研究所 中 華 民 國 95 年 10 月 16 日 中文摘要 large amount of heat from the flame. It was found that, increase the mist concentration 本研究在建立二維的暫態燃燒數值模式,研 究在靜止正常重力狀態下,置於地板上的固 體燃料火焰,受流場中的水霧濃度含量增加 與水霧液滴穿透流場到達燃料表面而冷卻 燃料的影響,使火焰溫度下降而導致熄滅的 熄滅機制,建立數值模式。數值模式中加入 水蒸汽的物種方程式,用以估計水霧吸熱蒸 發後,流場中水蒸汽濃度的變化,由於水蒸 汽濃度的增加不止稀釋了火焰中燃料和氧 的濃度,還吸收了大量的燃燒熱。研究發 results the flame size shrike and the flame temperature decrease. The flame stick on the fuel surface and the flames tip collapse in one as the flame spread rate decrease. Further increase the concentration of the mist, the flame extinction phenomena occurred when the critical mist concentration reaches. 現,在水霧通過火燄時吸收大部分的燃燒 熱,因而使火燄尺寸縮小和溫度降低,隨水 霧濃度的增加,火焰傳播速率減慢,兩火燄 尾端倒塌而結合在一起,火燄縮收而貼緊在 2. Introduction 燃料表面,達臨界水霧濃度時地板上燃燒火 燄發生息滅現象。 關鍵詞:固體燃料、火焰、水霧濃度、熄滅 on downward flame spread over a solid thin fuel surface. In the experimental studies, Olson et al. [1] and Olson [2] used a drop-tower to investigate the forced, opposed flow and quiescent flame spread in microgravity. The rate of flame spread was 1. Abstract Keywords: solid fuel, flame, mist concentration, extinction Intense theoretical and experimental investigations have recently been conducted This study develops a two-dimensional unsteady combustion model for a thin solid fuel burning and extinction on the floor in a quiescent, normal gravity environment. The extinction mechanism is increase the mist concentration and so the penetration amount of the mist reaches the hot fuel surface, the flame temperature decreases which eventually cause the flame extinction. In unsteady combustion model, vapor and oxidizer species measured, and a low velocity-quenching limit was found to exist in low oxygen environments. Quiescent flame spread in microgravity experiments conducted on Space Shuttle facilities were presented by Bhattacharjee et al. [3]. The flame spread rate was determined using a frame-by-frame analysis of the film, and the solid surface temperature was measured. In purely buoyant flow flame spread energy equations were accounted. From these energy equations the variations of concentration of vapor and oxidizer in the flow field are estimated. The vapor and oxidizer in flame not only dilute the fuel and oxygen but also absorbs a lot of combustion heat from the flame. The interaction with hot air induced by the flame will occur continuously when mist flow through the flow field. The evaporation of the mist extracts a experiments, Altenkirch et al. [4] investigated the buoyancy effects on downward spreading flames over thermally thin fuel. The parameter variation was determined by performing flame spread experiments in a closed chamber, which was swung on a centrifuge to generate a gravitational acceleration above that of the Earth. The rates of flame spread were obtained as the 5-cm spacing, divided by the elapsed time, was measured using an electrical clock. They found that an increase in the buoyancy level caused the flame spread rate to drop until no propagation was possible, indicating that 3. MATHEMATICAL MODEL an increasing gravity level tends to increase induced flow intensity such that it retards downward flame spreading. Lin and Chen [5] developed the foundation of the present study, which is a time-dependent combustion model of the ignition of a downward flame. In this work, attention was focused on both the solid and gas phase response at the moments before and after ignition. The ignition mechanism of a two flames initiated at the center of a thin solid fuel sheet and propagate outward from the center in a quiescent gravitational environment. Both the left and right flames are opposite mode because the flame spread and the entrained flow directions are in opposite. Initially, the entrained flow along the fuel surface but it turns to flow upward due to heated in the flame zone, as shown in the figure. In this study the gravity levels were vertical thin solid fuel in a normal gravitational environment, subjected to an external radiant flux as the ignition source, was explored. Although the rate of flame varied above the normal gravity. The ignition and subsequent flame spread behaviors in elevated gravitational field were examined. The mathematical model of the physical spread was predicted, the flame diminished after a short period because the burn out regime (ash) was retained throughout the computation time. This caused a large amount of heat to stay at the flame tail and thus decreased the flame spread rate. By problem described proceed include unsteady gas-phase and solid-phase governing equations which coupled each other. The governing equations are described as follows: assuming that the ash was not retained, a moving boundary condition to account for ash removal was applied in this work. This latter procedure has been found successful for the direct simulation of a propagating downward flame. The main purpose of this work is to predict the rate of flame spread and the extinction limit of a thin fuel at various vapor concentration using an unsteady combustion The gas phase model consist of two-dimensional, time-dependent continuity, complete elliptic Navier-Stokes, energy and species equations. The combustion is described by a one-step overall chemical reaction with finite rate global kinetics. The solid phase is modeled by an unsteady energy and mass conservation equations, which coupled with the gas phase through the energy feed back term from the gas phase. The solid model. For this time-dependent combustion model the spread rate will be obtained directly from the history of the flame front position, and the extinction phenomena at the vapor concentration limit will be depicted. A quantitative comparison between the results obtained from the steady model, developed by Duh and Chen [6] will verify the developed time-dependent model. pyrolysis is described by first-order Arrhenius expression. The nondimensional governing equations for the gas phase are summarized in Table 1. The dimensionless solid-phase governing equations can be expressed as follows for mass conservation: Figure 1 shows schematic diagram of 2.1 Governing Equations ms (1) s E A s s exp( s ). t Ts and for energy conservation: s Ts Ts s msL 1 CTs 1 t x 2 2 T qex . Pr Gr y w (2) 2.2 Boundary and Initial Conditions I. Boundary conditions in dimensionless form are, for gas phase: At x=xmin and x=xmax: u 0, v 0, T 1, YF 0, YO YO , P P . (3) At y=0: YF Pr Le Gr y w (4) mw YOw YO Pr Le Gr y detail computational procedure can be referred to Ref [5]. A non-uniform grid of exponential distribution in the gas phase was used with the grid points being concentrated near the gas-solid interface, where ignition is likely, to capture the significant change in the temperatures and flow field. A grid test has been conducted to ensure that the solutions are independent of grid size. The grid numbers of the entire computational domain were 238 for x, 153 for y direction, the corresponding nondimensional computational domain was u 0, T Ts , m w w v w mw mw YFw and velocity in the full unsteady Navier-Stokes equations in gas phase are solved using the SIMPLE algorithm [7]. The . w 445.36363.21, and dimensional computational area was 61.2450.16 cm2. The nondimensional time step for computation was 13 corresponding 0.0712 s of the physical time. At y=ymax: u v T YF YO 0, P P . x x x x x (5) and for the solid phase: At x=xmin: s 1, Ts 1. (6) At x=xmax: s 1, Ts 1. (7) II. Initial conditions in dimensionless form are, for the gas phase: At t0: u 0, v 0, T 1, YF 0, YO YO , P P . (8) and for the solid phase: At t0: s 1, Ts 1. (9) 2.3 Computational Grid The strong coupling between pressure 3. RESULTS AND DISCUSSION The flames shape, flow velocities vector distributions and temperature contours after 2 s of ignition occurs at various vapor concentration are shown in the Figure 2 and Figure 3, respectively. As shown in the figures, the flame structure in zero vapor concentration is strongest because the flame length and flame temperature are greatest. While the flame structure in 0.3 vapor concentration is weakest because the flame length and temperature are weakest. The weaker of the flame is due to the decrease of the fuel concentration caused by the greater of the vapor concentration. This can be confirmed from the YH 2 O =0.3 plot in Figure 2 in which the buoyant flow velocity vectors are the biggest compare to the other cases. The maximum buoyant flow velocity in YH 2 O =0.3 case within the region show in the plot is about 236 cm/s compare to the that in YH 2 O =0.0 case of 137 cm/s. The extinction The temperature and flame length in zero vapor concentration were greatest indicated that it was the strongest flame. In the case of process in YH 2 O =0.43 case is illustrated in YH 2 O =0.43, the temperature and flame size Figure 4 and Figure 5. Figure 4 shows enlarge view for the sequence of gas-phase fuel reaction rate during the extinction process while Figure 5 shows enlarge view for the sequence of gas-phase temperature. At vapor concentration = 0.43 the vapor is strong enough such that the fuel vapor resident time in the flame is too short for exothermic were lowest indicated that it was the weakest flame. The extinction may occur for flame propagating time greater than 6 s. At chemical reaction completion. Consequently, the vigorous chemical reaction was reduced and the left and right straight flames shrinks into one flat flame after some stagnated times reaction decreases cause the flame temperature drops. The flat flame shrinks and the temperature drops continuously to become a point flame and disappear eventually. as shown in Figure 4 at 4.70 s. Meanwhile, the amount of heat release from the chemical reaction reduced cause the flame temperature drops as shown in Figure 5 at 4.70 s. Finally, the flat flame shrinks and the temperature drops continuously to become a point flame 5. REFERENCES [1] S. L. Olson, P. V. Ferkul and J. S. T’ien, Twenty-Second Symposium (international) on Combustion, pp. 1213-1222, The Combustion Institute, Pittsburgh, 1988. and disappear eventually, as shown at 5.06 s and 5.34 s in Figure 4 and Figure 5, respectively. YH 2 O =0.43 the left and right straight flames shrinks into one flat flame after some stagnated times at 4.70 s. Meanwhile, the amount of heat release from the chemical 4. CONCLUSIONS A numerical study was made for the vapor concentration that is the mist effects on the ignition and subsequent flame spread over a thin solid fuel flatly lay on the floor in various vapor concentration environments. In [2] S. L. Olson, Combust. Sci. Technol., vol. 76, pp. 233-249, 1991. [3] S. Bhattacharjee, R. A. Altenkirch, and K. Sacksteder, Combust. Sci. Technol., vol. 91, pp. 225-242, 1993. [4] K. A. Altenkirch, R. Eichhorn, and P. C. Shang, Combust. Flame, vol. 37, pp. 71-83, 1980. [5] T. H. Lin, and C. H. Chen, Numerical Analysis of Ignition and Transition to this present time-dependent model we can readily simulate the flame extinction behavior over a thin fuel surface. By varying the vapor concentration we conducted five cases of flame spread over a thin solid fuel at 23.3 % oxygen mass concentration. The computational results shows that the flame extinction was predicted at vapor concentration 0.43 on 4.77 s after ignition occurs. Downward Flame Spread Over a Thermally-Thin Solid Fuel, I. J. Trans. Phenomena, vol. 1, pp. 255-275, 1999. [6] F. C. Duh, and C. H. Chen, A theory for Downward Flame Spread over a Thermally Thin Fuel, Combust. Sci. Technol., vol. 77, pp. 291-305, 1991. [7] S. V. Patankar, Numerical Heat Transfer and Fluid Flow, McGraw-Hill, New York, USA, 1980. [8] Nakamura, Y., Yamashita, H., and Takeno, T., Combust. Flame 120:34 (2000). [9] A. C. Fernandez-Pello and T. Hirano, Controlling Mechanisms of Flame Spread, Combust. Sci. Technol., vol. 32, pp. 1-31, 1983. [10] Lin, T. H., Num. Heat Transfer A 40:841 (2001). [11]Hirano, T., Noreikis, S. E., and Waterman, T. E., Combust. Flame 22353 (1974). [12]Chen, C. H., and Chan, S. C. Combust. Sci. Technol., 107:59 (1995). y Gravity Flame Entrained flow Entrained flow x Thin solid fuel sheet Fig. 1. Schematic diagram of two flames propagate outward from the center of a thin solid fuel sheet on the floor in a quiescent gravitational environment. Table 1 Gas Phase Governing Equations u v S t x y x x y y Equation Continuity 1 x-Mom. y-Mom. Energy u v T Fuel YF Oxidizer YO Vapor YH2O 2.5 2.0 YH 2 O =0 1.5 S 0 Gr Pr Gr Pr GrLe Pr GrLe Pr GrLe p Sv y F F q YH 2 O =0.0 y (cm) 1.0 0.5 0.0 p Su x Gr YH 2 O =0.1 0.0 2.5 2.0 YH 2 O =0.2 YH 2 O =0.3 1.5 y (cm) 1.0 0.5 0.0 -1.5 -1.0 -0.5 0.0 x (cm) F f where Su 1 u v 2 v 3 x Gr x y Gr x 3 x Gr y Sv 1 v u 2 u 3 y Gr y x Gr y 3 y Gr x 1.0 1.5 235.8352282 F F f -1.5 -1.0 -0.5 0.0 0.5 0.5 1.0 1.5 Reference Vectors (cm/s) x (cm) Fig. 2. Flames and flow velocity vector distributions at various vapor concentration after 2 s of ignition occur. The flame shapes shown are the fuel reaction rate contour of 10-4 g/cm3/s. 2.5 YH 2 O =0.0 YH 2 O =0.1 2.0 0.6 1.5 Time = 4.70 s y (cm) 0.4 1.0 y (cm) 0.5 0.0 2.5 0.2 YH 2 O =0.2 YH 2 O =0.3 0.0 -0.8 0.6 2.0 1.5 -0.6 -0.4 -0.2 0.0 0.2 0.4 0.6 0.8 0.2 0.4 0.6 0.8 Time = 4.77 s y (cm) 0.4 1.0 y (cm) 0.5 0.2 0.0 -1.5 -1.0 -0.5 0.0 0.5 1.0 1.5 -1.5 -1.0 -0.5 x (cm) 0.0 0.5 1.0 x (cm) Fig. 3. Temperature distributions at various vapor concentration after 2 s of ignition occur. 0.0 -0.8 0.6 0.4 0.4 0.0 -0.8 -0.6 -0.4 -0.2 0.0 0.2 0.4 0.6 Time = 4.77 s -0.6 -0.4 -0.2 0.0 0.2 0.4 0.6 0.8 0.0 0.2 0.4 0.6 0.8 Time = 5.34 s -0.6 -0.4 -0.2 x (cm) process at YH 2 O = 0.43. Shown are the -0.6 -0.4 -0.2 0.0 0.2 0.4 0.6 0.8 0.0 0.2 0.4 0.6 0.8 0.0 0.2 0.4 0.6 0.8 Time = 5.06 s y (cm) 0.2 -4 -0.6 -0.4 -0.2 Time = 5.34 s 0.4 y (cm) 0.2 0.0 -0.8 700 800 900 Fig. 5. Sequence for the extinction 0.2 0.0 -0.8 0.6 Time = 5.06 s 0.8 y (cm) 0.4 0.0 0.2 0.2 0.0 -0.8 0.6 -0.2 y (cm) Time = 4.70 s y (cm) 0.4 -0.4 0.2 0.6 0.0 -0.8 0.6 -0.6 y (cm) 0.0 -0.8 0.6 0.4 1400 1.5 -0.6 -0.4 -0.2 x (cm) Reference Vectors (cm/s) 80 Fig. 4. Sequence for the extinction process at YH 2 O = 0.43. The contours shown are the quantity of take log10. temperature contours.