Outline of Material for Exam 2 Chem 101, Summer 2006 Karyn Mlodnosky 1. Chemical Reactions (Ch. 6) Identify chemical changes versus physical changes Balance chemical equations Classify reactions as combination, decomposition, replacement (single or double), combustion and/or redox Given reactants, be able to write products with correct chemical formulas (for simple reactions that follow the patterns of the 4 main reaction types) Identify what is oxidized and what is reduced in redox reactions Identify reactions as exothermic or endothermic Interpret energy diagrams for chemical reactions (be able to label reactants, products, transition state, activation energy and heat of reaction) Identify factors that increase or decrease reaction rate Know LeChâtelier’s Principle and identify factors that shift the equilibrium of a reversible reaction towards products or towards reactants Know (Table 4.8), Table 6.2, Table 6.3, Table 6.4, Table 6.6 and Table 6.7 2. Chemical Quantities (Ch. 7) Know Avogadro’s number and use it to convert between number of particles and number of moles Determine the molar mass of an atom or compound Use molar mass to convert between grams and moles Calculate percent composition by mass of a compound Determine empirical formula from percent composition or masses Use mole ratios from balanced chemical equations to relate moles of reactants and products Use mole ratios and molar masses to calculate grams of product or reactant Given actual yield (in moles or grams) calculate percent yield of a reaction Determine limiting reactant given moles or grams of reactants used Be able to write an equilibrium expression for a reversible reaction Given the equilibrium constant (Keq) determine if the equilibrium favors products or reactants 3. Gases and Gas Laws (Ch. 8) List the 5 main points of the Kinetic Molecular Theory of Gases (p. 245) Know units for the four variables that describe a gas (P, V, T and n) Use Boyle’s Law (P and V), Charles’ Law (T and V) and Gay-Lussac’s Law (T and P) to calculate one variable based on changes in the other variable Use the combined gas law to find new P, V or T based on changes in the other two variables (Can derive any of the first 3 laws from the combined gas law) Use Avogadro’s Law (V and n) and the molar volume of a gas at STP to calculate V or n based on changes in the other variable Use the ideal gas law to calculate P, V, T or n given values for the other three variables Calculate total P from partial P’s for a mixture of gases (or calculate a partial P given the total P and other partial P’s); relate moles of gas to partial pressure Note: you are responsible for knowing the formula for each law, and how to use it, but not for the names of the laws Know Table 8.1, Figure 8.2, Figure 8.3, Figure 8.4, Figure 8.5 and Table 8.6 4. Solutions (Ch. 9; section 9.4 will not be on the exam) Identify solvent and solute in a solution Understand how solutions form (like dissolves like; solvation of ions in water) Know terms homogeneous and heterogeneous Classify solute as strong electrolyte, weak electrolyte or nonelectrolyte Write equations for dissociation of strong and weak electrolytes Use solubility to classify solutions as saturated or unsaturated Calculate amount of solute of solvent in a saturated solution (given solubility) Understand effects of temperature and pressure on solubility Know solubility rules and use them to predict solubility of salts in water Calculate solution concentrations using mass % (m/m), volume % (v/v) and mass/volume % (m/v) and be able to use them as conversion factors Calculate the molarity (M) of a solution and be able to use molarity as a conversion factor (to determine moles of solute or volume of a solution) Classify a mixture as a solution, colloid or suspension and know how to separate them from each other Understand osmosis and osmotic pressure Classify solutions as isotonic, hypotonic or hypertonic and describe what happens to a red blood cell placed in any of these solutions Understand dialysis and use of semipermeable membranes Know Table 9.7, Table 9.12 and Figure 9.7