CHEM 121 Today’s outline ◦ ◦ ◦ ◦ ◦ Introductions Learning styles Scientific Method Chemistry Matter and measurement Background in civil and environmental engineering ◦ Researched the removal of metals from the subsurface by using polymers excreted by bacteria ◦ Interested in how science and technology impact society and vise versa Call me Anna About me Let’s get to know each other ◦ ◦ ◦ ◦ ◦ Any nicknames? Why are you taking this course? What’s your educational/career goal? How long have you been at North? Anything you’d like to share? Understanding your learning style allows you to come up with a more successful study plan Some people use one sense more than others while learning ◦ Visual ◦ Auditory ◦ Tactile Focus on what works for you Relate most effectively to written information, notes, diagrams, and pictures Study tips ◦ Take notes even when you have handouts ◦ Look at (don’t just listen) to study materials and directions ◦ Make your own charts/maps/notes/flashcards ◦ Try visualizing words and concepts in your head ◦ Write everything down ◦ Make review sheets that you can refer back to Read your assignments and study materials out loud Record lectures or listen to videos to help you fill in gaps in your notes ◦ Lots of podcasts and videos available online and through publisher that you can listen to Sit up towards the front of a classroom so that you can hear clearly Try typing your notes Use real objects when possible or just act out what you are reading/learning about ◦ Make models ◦ Do practice problems Role-playing helps Plan out and give explanations/ demonstrations on class topics ◦ See me if you’d like to make a presentation on a topic Use the lab portion of the class to help solidify ideas Must be testable ◦ ◦ ◦ ◦ Hypothesis must be testable and falsifiable Experiments and observations must be repeatable Limited by technology of the day Data either supports or falsifies your hypothesis Cannot make value judgments ◦ Cannot determine if something is “bad” or “good” ◦ Humans can use results to advance their causes, but the method itself only generates unbiased data ◦ Discoveries are neither bad nor good – humans and societies decide how to use new information/ideas Very Brief History ◦ 430 BC Democritus proclaims the atom to be the simplest unit of matter/all matter made of atoms ◦ 300 BC Aristotle declares existence of only four elements: fire, air, water and earth All matter is made up of these four elements Matter had four properties: hot, cold, dry and wet ◦ 300 BC alchemists start trying to turn cheap metals into gold In 1520 they start also looking for the elixir of life In 17th century Robert Boyle puts an end to alchemy with The Skeptical Chemist ◦ End of 17th Century -Mid 19th Century Traditional chemistry ◦ Mid 19th Century - Present Modern chemistry Chemistry is the study of matter – its composition, properties, and transformations Matter is anything that has mass and takes up volume (occupies space) ◦ Mass is a measurement of the amount of matter in an object ◦ Can be natural or synthetic (human-made) ◦ Note: Mass and weight are not the same thing Weight is a measurement of how hard gravity is pulling on an object Mass will remain the same wherever an object is Weight will change depending on the force of gravity Solid ◦ Has a definite volume ◦ Maintains its shape regardless of its container ◦ Particles lie close together in a regular pattern Liquid ◦ Has a definite volume ◦ Takes the shape of its container ◦ Particles are close together but can move past one another Gas ◦ Has no definite volume – will fill any available space ◦ Takes the shape of its container – fills container ◦ Particles are very far apart and move around randomly Properties that can be observed or measured without changing the composition of the material ◦ ◦ ◦ ◦ ◦ ◦ ◦ ◦ Boiling point Melting point Solubility Color Odor State of matter Density And many others Properties that determine how a substance can be converted to another substance ◦ Chemical change is the chemical reaction that converts one substance into another Pure Substance ◦ Composed of only a single component (atom or molecule) ◦ Constant composition regardless of size or origin ◦ Cannot be broken down into other pure substances by a physical change ◦ Fixed physical and chemical properties ◦ Examples: Elements – each element is a pure substance that cannot be broken down by a chemical change Compounds- pure substances formed by chemically joining two or more elements Water (H20) Table salt (NaCl) Mixture ◦ Composed of more than one component. ◦ The composition can vary depending on the sample ◦ Can have varying composition (any combination of solid, liquid, and gas) ◦ Can be separated into their components by a physical process ◦ Can be homogenous (maple syrup) or heterogeneous (vinagrette) Why do we take measurements? What kinds of measurements do you take throughout the day? Why do we use standard measurements? Two main systems of measurement ◦ English system Used in the US and a handful of small countries as system of measurement ◦ Metric system Used by most of the world as the system of measurement Used for scientific research Used in the medical field Will be the units used throughout this course The prefix of the unit name indicates if the unit is larger or smaller than the base unit by factors of 10 Example: Length Base unit = meter (m) 1 kilometer (km) = 1,000 meters (m) 1 km = 1,000 m I millimeter (mm) = 0.001 meters (m) 1mm = 0.001 m 1centimeter (cm) = 0.01 meter (m) 1 cm = 0.01 m Example: mass Base unit = gram (g) 1 kilogram (kg) = 1,000 grams (g) 1 kg = 1,000 g I milligram (mg) = 0.001 g (g) 1mg = 0.001 g Example: volume Base unit = liter (L) 1 kiloliter (kL) = 1,000 meters (L) 1 kL = 1,000 L I milliliter (mL) = 0.001 meters (L) 1mL = 0.001 L Volume = length x width x height = cm x cm x cm = cm3 1 mL= I cm3 = 1cc Exact numbers ◦ Results from counting objects or is part of a definition 10 fingers 23 students in a class 1 meter = 100 centimeters Inexact numbers ◦ Results from a measurement or observation and contains some uncertainty 10 cm 23 g 754.5 mL http://www.thetangoboutique.com/wp-content/uploads/2013/05/paulina_heel_measure.jpg All of the digits in a measured number including one estimated digit All nonzero digits are always significant Examples ◦ 39.5 m has 3 significant figures ◦ 9562.5874 m has 8 significant figures Rule 1: A zero counts as a significant figure when it occurs: ◦ Between two nonzero digits 36.054 mL has 5 significant figures 3.004 cm has 4 significant figures ◦ At the end of a number with a decimal place 7.2500 s has 5 significant figures 360. km has 3 significant figures Rule 2: A zero does not count as a significant figure when it occurs ◦ At the beginning of a number 0.00546 mg has 3 significant figures 0.03 cc has 1 significant figure ◦ At the end of number that does not have a decimal place 3560 s has 3 significant figures 2356000 km has 4 significant figures Multiplication and Division ◦ The answer has the same number of significant figures as the original with the fewest figures (you are limited by the least precise number) 4 sig. figures 351.2 miles = 63.854545 miles 5.5 hour hour 2 sig. figures Answer must have 2 sig. figures. to be retained to be dropped 63.854545 miles = 64 miles hour hour first digit to be dropped If the first digit to be dropped is: 2 sig. figures Answer Then: •between 0 and 4 •drop it and all remaining digits •between 5 and 9 •round up the last digit to be retained by adding 1 Addition and Subtraction ◦ The answer has the same number of decimal places as the original number with he fewest decimal places 10.11 kg 2 decimal places 3.6 kg 1 decimal place 6.51 kg answer must have 1 decimal place = 6.5 kg final answer 1 decimal place y x 10x Coefficient: A number between 1 and 10. Exponent: Any positive or negative whole number. If the decimal place is moved to the left x is positive ◦ 280 = 2.8 X 102 If the decimal place is moved to the right x is negative ◦ 0.028 = 2.8 X 10-2 • Conversion factor: A term that converts a quantity in one unit to a quantity in another unit. original quantity x conversion factor desired = quantity • Conversion factors are usually written as equalities. 2.21 lb = 1 kg • To use them, they must be written as fractions. 2.21 lb 1 kg or 1 kg 2.21 lb 37 Factor-label method: Using conversion factors to convert a quantity in one unit to a quantity in another unit. •units are treated like numbers •make sure all unwanted units cancel To convert 130 lb into kilograms: 130 lb x original quantity conversion factor = ? kg desired quantity Can be inverted as needed to have units cancel out 2.21 lb 1 kg 130 lb x or 1 kg 2.21 lb Answer 2 sig. figures = 59 kg Sometimes you’ll have to use multiple conversion factors ◦ Always arrange the factors so that the denominator (bottom) cancels the numerator (top) in the preceding term A measurement of how hot or cold an object is Three common temperature scales ◦ Degrees Fahrenheit (oF) ◦ Degrees Celcius (oC) ◦ Kelvin (K) To convert from oC to oF: oF = 1.8(oC) + 32 To convert from oC to K: K = oC + 273 To convert from oF to oC: oC = oF − 32 1.8 To convert from K to oC: oC = K − 273 A physical property that relates the mass of a substance to its volume density = To convert volume (mL) to mass (g): g mL x = g mL density mass (g) volume (mL or cc) To convert mass (g) to volume (mL): mL g x = mL g inverse of density A quantity that compares the density of a substance with the density of water at the same temperature specific gravity = density of a substance (g/mL) density of water (g/mL) The units cancel out so it is dimensionless If SG > 1 the fluid is more dense than water If SG < 1 the fluid is less dense than water