Mathematical Modeling of Convective Heat Transfer: Single Phase through Subcooled Boiling Flows by Matthew P. Wilcox A Thesis Submitted to the Graduate Faculty of Rensselaer Polytechnic Institute in Partial Fulfillment of the Requirements for the degree of MASTER OF SCIENCE Major Subject: MECHANICAL ENGINEERING Approved: _________________________________________ Ernesto Gutierrez-Miravete, Thesis Adviser Rensselaer Polytechnic Institute Hartford, Connecticut April 2013 i © Copyright 2013 By Matthew P. Wilcox All Rights Reserved ii TABLE OF CONTENTS TABLE OF CONTENTS ................................................................................................. iii LIST OF TABLES ............................................................................................................. v LIST OF FIGURES ......................................................................................................... vii ABSTRACT ..................................................................................................................... ix 1. INTRODUCTION ....................................................................................................... 1 1.1 RESEARCH ....................................................................................................... 2 1.2 CONTENT ......................................................................................................... 3 2. HEAT TRANSFER AND FLUID FLOW: THEORY ................................................ 5 2.1 GOVERNING EQUATIONS ............................................................................ 5 2.2 NUMERICAL METHODS................................................................................ 6 2.3 NATURAL CONVECTION .............................................................................. 8 2.4 LAMINAR FLOW ............................................................................................. 9 2.5 TURBULENT FLOW ...................................................................................... 10 2.5.1 2.6 2.7 CALCULATING TURBULENCE PARAMETERS .......................... 13 TWO-PHASE FLOW ...................................................................................... 15 2.6.1 MODELING TWO-PHASE FLOWS .................................................. 17 2.6.2 POPULATION BALANCE MODEL.................................................. 18 BOILING HEAT TRANSFER ........................................................................ 19 3. HEAT TRANSFER AND FLUID FLOW: MODELING ......................................... 21 3.1 NATURAL CONVECTION ............................................................................ 21 3.1.1 HORIZONTAL CYLINDER ............................................................... 21 3.1.2 VERTICAL PLATE ............................................................................ 28 3.2 LAMINAR FLOW ........................................................................................... 34 3.3 TURBULENT FLOW ...................................................................................... 38 3.3.1 TURBULENT FLOW WITHOUT HEAT TRANSFER ..................... 38 3.3.2 TURBULENT FLOW WITH HEAT TRANSFER ............................. 43 iii 3.4 3.5 TWO-PHASE FLOW ...................................................................................... 46 3.4.1 GAS MIXING TANK .......................................................................... 46 3.4.2 BUBBLE COLUMN ............................................................................ 51 3.4.3 BUBBLE COLUMN WITH POPULATION BALANCE MODEL ... 56 BOILING FLOWS ........................................................................................... 60 3.5.1 POOL BOILING .................................................................................. 60 3.5.2 SUBCOOLED Flow BOILING ........................................................... 66 4. DISUSSION AND CONCLUSIONS ........................................................................ 81 REFERENCES ................................................................................................................ 83 iv LIST OF TABLES Table 2.5.1-1: Turbulent Flow Input ............................................................................... 14 Table 2.5.1-2: Turbulence Parameter Calculation ........................................................... 14 Table 3.1.1-1: Horizontal Cylinder Model Input ............................................................. 22 Table 3.1.1-2: Horizontal Cylinder Model Water Density .............................................. 22 Table 3.1.1-3: Mesh Validation for Horizontal Cylinder Model ..................................... 27 Table 3.1.2-1: Vertical Plate Model Input ....................................................................... 29 Table 3.1.2-2: Vertical Plate Model Water Density ........................................................ 29 Table 3.1.2-3: Mesh Validation for Vertical Plate Model ............................................... 33 Table 3.2-1: Laminar Flow Model Input ......................................................................... 35 Table 3.2-2: Laminar Flow Model Water Density .......................................................... 35 Table 3.2-3: Mesh Validation for Laminar Flow Model ................................................. 37 Table 3.3.1-1: Turbulent Flow Without Heat Transfer Model Input ............................... 39 Table 3.3.2-1: Turbulent Flow With Heat Transfer Model Input .................................... 44 Table 3.3.2-2: Turbulent Flow Model Water Density ..................................................... 44 Table 3.3.2-3: Mesh Validation for Turbulence With Heat Transfer Model ................... 46 Table 3.4.1-1: Gas Mixing Tank Model Input ................................................................. 48 Table 3.4.1-2: Mesh Validation for Gas Mixing Tank Model ......................................... 50 Table 3.4.2-1: Bubble Column Model Input ................................................................... 52 Table 3.4.2-2: Mesh Validation for Bubble Column Model ........................................... 56 Table 3.4.3-1: Population Balance Model Input .............................................................. 57 Table 3.4.3-2: Bubble Size Distribution – Surface Tension of 0.072 N/m ..................... 59 Table 3.4.3-3: Bubble Size Distribution – Surface Tension of 0.0072 N/m ................... 60 Table 3.5.1-1: Pool Boiling Model Input......................................................................... 61 Table 3.5.1-2: Pool Boiling Model Water Density .......................................................... 62 Table 3.5.1-3: Mesh Validation for Pool Boiling Model................................................. 65 Table 3.5.2-1: Subcooled Flow Boiling Model Input ...................................................... 69 Table 3.5.2-2: Subcooled Flow Boiling Model Water Properties ................................... 70 Table 3.5.2-3: Boiling Model Study Case Input .............................................................. 71 Table 3.5.2-4: Boiling Model Study Case Results .......................................................... 74 Table 3.5.2-5: Initial Conditions Study Case Input ......................................................... 75 v Table 3.5.2-6: Initial Condition Study Case Results ....................................................... 75 Table 3.5.2-7: Axial Location Liquid Volume Fraction .................................................. 76 Table 3.5.2-8: Absolute Impact on Liquid Volume Fraction .......................................... 78 Table 3.5.2-9: Relative Impact on Liquid Volume Fraction ........................................... 79 Table 3.5.2-10: Mesh Validation for Subcooled Boiling Model ..................................... 80 vi LIST OF FIGURES Figure 2.5-1: Transition from Laminar to Turbulent Flow.............................................. 11 Figure 2.6-1: Flow Regimes ............................................................................................ 15 Figure 2.6-2: Baker Flow Pattern .................................................................................... 16 Figure 2.7-1: Boiling Heat Transfer Regimes ................................................................. 19 Figure 3.1.1-1: Heated Cylinder Schematic .................................................................... 21 Figure 3.1.1-2: Temperature (K) ..................................................................................... 23 Figure 3.1.1-3: Density (kg/m3) ....................................................................................... 23 Figure 3.1.1-4: Velocity Vectors (m/s) ............................................................................ 24 Figure 3.1.1-5: Interference Fringes Around a Heated Horizontal Cylinder (K) ............ 25 Figure 3.1.1-6: Temperature at θ = 30° Vs. Radial Distance .......................................... 26 Figure 3.1.1-7: Temperature at θ = 90° Vs. Radial Distance .......................................... 26 Figure 3.1.1-8: Temperature at θ = 180° Vs. Radial Distance ........................................ 27 Figure 3.1.2-1: Vertical Plate Schematic ......................................................................... 28 Figure 3.1.2-2: Temperature (K) ..................................................................................... 30 Figure 3.1.2-3: Velocity Vectors (m/s) ............................................................................ 30 Figure 3.1.2-4: Interference Fringes Around a Heated Vertical Plate (K) ...................... 31 Figure 3.1.2-5: Dimensionless Temperature as a Function of Prandtl Number .............. 32 Figure 3.1.2-6: Dimensionless Temperature as a Function of Prandtl Number .............. 33 Figure 3.2-1: Laminar Flow Schematic ........................................................................... 34 Figure 3.2-2: Velocity Profile .......................................................................................... 34 Figure 3.2-3: Radial Velocity (m/s) ................................................................................. 36 Figure 3.2-4: Temperature (K) ........................................................................................ 36 Figure 3.2-5: Wall Shear Stress ....................................................................................... 37 Figure 3.3.1-1: Turbulent Flow Without Heat Transfer Schematic................................. 38 Figure 3.3.1-2: Velocity Magnitude ................................................................................ 38 Figure 3.3.1-3: Wall Shear Stress .................................................................................... 40 Figure 3.3.1-4: Radial Velocity (m/s) ............................................................................. 40 Figure 3.3.1-5: dAxial-Velocity/dx ................................................................................. 40 Figure 3.3.1-6: Flow Results for Mass Flow Rate of 0.5 kg/s ......................................... 41 Figure 3.3.1-7: Flow Results for Larger Mass Flow Rate of 1.5 kg/s ............................. 41 vii Figure 3.3.1-8: Turbulent Kinetic Energy (m2/s2) ........................................................... 42 Figure 3.3.1-9: Production of Turbulent Kinetic Energy ................................................ 42 Figure 3.3.2-1: Turbulent Flow With Heat Transfer Schematic ...................................... 43 Figure 3.3.2-2: Temperature (K) ..................................................................................... 43 Figure 3.3.2-3: Radial Velocity (m/s) .............................................................................. 45 Figure 3.3.2-4: Velocity Magnitude ................................................................................ 45 Figure 3.3.2-5: Wall Shear Stress .................................................................................... 45 Figure 3.4.1-1: Gas Mixing Tank Schematic................................................................... 47 Figure 3.4.1-2: Gas Volume Fraction .............................................................................. 49 Figure 3.4.1-3: Liquid Velocity Vectors (m/s) ................................................................ 49 Figure 3.4.1-4: Gas Velocity Vectors (m/s)..................................................................... 50 Figure 3.4.2-1: Bubble Column Schematic ..................................................................... 51 Figure 3.4.2-2: Gas Volume Fraction .............................................................................. 53 Figure 3.4.2-3: Liquid Velocity Vectors (m/s) ................................................................ 54 Figure 3.4.2-4: Gas Velocity Vectors (m/s)..................................................................... 55 Figure 3.4.2-5: Gas Volume Fraction (0.10 m/s)............................................................. 55 Figure 3.4.3-1: Gas Volume Fraction with PBM ............................................................ 57 Figure 3.4.3-2: Liquid Velocity Vectors with PBM (m/s)............................................... 58 Figure 3.4.3-3: Liquid Velocity Vectors with PBM (m/s)............................................... 59 Figure 3.5.1-1: Pool Boiling Schematic .......................................................................... 61 Figure 3.5.1-2: Instantaneous Gas Volume Fraction ....................................................... 63 Figure 3.5.1-3: Liquid Velocity Vectors (m/s) ................................................................ 64 Figure 3.5.1-4: Gas Velocity Vectors (m/s)..................................................................... 64 Figure 3.5.1-5: Volume Fraction of Vapor on Heated Surface ....................................... 65 Figure 3.5.2-1: Subcooled Flow Boiling Model Schematic ............................................ 69 Figure 3.5.2-2: Case 1 - Temperature (K) ....................................................................... 71 Figure 3.5.2-3: Case 1 - Liquid Volume Fraction ........................................................... 71 Figure 3.5.2-4: Case 1 - Mass Transfer Rate (kg/m3-s) ................................................... 72 Figure 3.5.2-5: Liquid Volume Faction for Cases 1-6..................................................... 73 Figure 3.5.2-6: Liquid Volume Faction for Cases 7-12................................................... 77 viii ABSTRACT Various fluid flow and heat transfer regimes were investigated to provide insight into the phenomena that occur during subcooled flow boiling. The theory of each regime was discussed in detail and followed by the development a numerical model. Numerical models to analyze natural convection, laminar flow, turbulent flow with and without heat transfer, two-phase flow, pool boiling and subcooled flow boiling were created. The commercial software Fluent was used to produce the models and analyze the results. Different modeling techniques and numerical solvers were employed depending on the scenario to generate acceptable results. The results of each model were compared to experimental data when available to prove its validity. Although numerous heat transfer and fluid flow phenomena were analyzed, the primary focus of this research was subcooled flow boiling. The impact different boiling model options have on liquid volume fraction was examined. Three bubble departure diameter models and two nucleation site density models were studied using the same initial conditions. The bubble departure diameter models did not show any relationship with liquid volume fraction; however, the Kocamustafaogullari-Ishii nucleation site density model tended to predict a greater liquid volume fraction, meaning less vapor production, than the Lemmert-Chawla nucleation site density model. A second study on how initial conditions impact the liquid volume fraction during subcooled flow boiling was explored. The initial conditions of heat flux, inlet temperature and mass flow rate were increased or decreased relative to a base case value. The difference in liquid volume fraction between scenarios was compared and relationships relating the initial conditions with respect to liquid volume fraction were developed. Overall, the inlet temperature had the greatest impact on liquid volume fraction, the wall heat flux had the second greatest impact and mass flow rate had the smallest impact. ix 1. INTRODUCTION Since the 19th century, the world’s standard of living has greatly increased primarily due to the generation and distribution of electricity. Over 80% of the world’s electricity production is generated by converting thermal energy, from a fuel source into electrical energy. A common energy conversion process known as the Rankine Cycle burns fuel to generate steam which is used to turn a turbine and spin an electric generator. Electricity production involves numerous engineering processes but is primarily based around heat transfer and fluid flow. Coal, oil, natural gas and uranium are some of the different fuel sources available to electrical power plants. The fuel source in focus here will be uranium or nuclear fuel. Nuclear power plants harness energy released during fission to heat water. The energy transfer mechanisms within a nuclear reactor involve all three major forms of heat transfer; conduction, convection and radiation. The fluid flow through the reactor core is complex due to the intense energy transfer and phase change. In Pressurizer Water Reactors, the water surrounding the reactor core is prevented from bulk boiling because it is highly pressurized; however, a small amount of localized boiling does occur. This is known as subcooled flow boiling. This research focuses on the convective heat transfer and fluid flow phenomena that occur during subcooled flow boiling. Specifically, topics on turbulence, two-phase flow and phase change are discussed. Subcooled boiling occurs when an under-saturated fluid comes in contact with a surface that is hotter than its saturation temperature. Small bubbles form on the heated surface in locations called nucleation sites. The number of bubbles that form is heavily dependent on fluid inlet temperature, pressure, mass flow, heat flux and microscopic features of the surface. After the bubbles form on the heated surface, they detach and enter the bulk fluid. When this occurs, saturated steam is dispersed in a subcooled liquid which is where the term subcooled boiling originates. 1 1.1 RESEARCH Subcooled flow boiling is characterized by the combination of convection, turbulence, boiling and two-phase flow. Determining the amount of voiding that occurs during subcooled flow boiling has become a topic of great interest in recent years. A number of mechanistic models for the prediction of wall heat flux and partitioning have been developed. One of the most commonly used mechanistic models for subcooled flow boiling was developed by Del Valle and Kenning. This model accounts for bubble dynamics at the heated wall using concepts developed initially by Graham and Hendricks for wall heat flux partitioning during nucleate pool boiling. Recently, a new approach to the partitioning of the wall heat flux has been proposed by Basu et al. The fundamental idea of this model is that all the energy from the wall is transferred to the liquid adjacent to the heated wall. Then, a fraction of the energy is transferred to vapor bubbles by evaporation while the remainder goes into the bulk liquid. [1] Additionally, focus has been placed on accurately modeling the three most impactful parameters in subcooled flow boiling. These parameters are the active nucleation site density (Na), departing bubble diameter (dbw) and bubble departure frequency (f). The two most common nucleation site density models were developed by Lemmert and Chwala and Kocamustafaogullari and Ishii. Both of these models are available in Fluent. Many correlations have been developed to determine the bubble departure diameter. Tolubinsky and Kostanchuk proposed the most simplistic correlation which evaluates bubble departure diameter as a function of subcooling temperature. Kocamustafaogullari and Ishii improved this model by including the contact angle of the bubble. Finally, Unal produced a comprehensive correlation which includes the effect of subcooling, the convection velocity and the heater wall properties. All three of these bubble departure diameter correlations are available in Fluent. The most common bubble departure frequency correlation for computational fluid dynamics was developed by Cole. It is based on a bubble departure diameter model and a balance between buoyancy and drag forces. The Cole bubble departure frequency model is available in Fluent. Recently, the use of population balance equations (PBEs) has been used to improve the modeling of subcooled flow boiling to better determine how swarms of bubbles 2 interact after detaching from the heated surface. This technique was recommended by Krepper et. al. [2] and investigated by Yeoh and Tu [1]. Population balance equations have been introduced in several branches of modern science, mainly areas with particulate entities such as chemistry and materials. Population balance equations help define how particle size populations develop in specific properties over time. Population balance equations are available in Fluent but not in combination with the boiling model. 1.2 CONTENT This research produced an investigation on subcooled flow boiling using Fluent. Fluent is a widely accepted commercial computational fluid dynamics code that can simulate complex heat transfer and fluid flow regimes. This thesis had three major objectives. The first objective was to gain an understanding of the phenomena that occur during subcooled flow boiling. The second objective was to determine how the boiling model options described in Section 1.1 impact the liquid volume fraction at different axial locations. The third objective was to evaluate how heat flux, inlet temperature and mass flow rate impact the liquid volume fraction at different axial locations. Due to its complexity, development of the subcooled flow boiling model was performed in stages. With the development of each model, a more complicated fluid flow or heat transfer scenario was analyzed. The first and simplest model created was for natural convection. The theory of natural convection is described in Section 2.3 and the analytical modeling results are presented in Section 3.1. Two natural convection geometries were analyzed. The first was a horizontal cylinder suspended in an infinite pool and the second was a vertical plate suspended in an infinite pool. The second model developed was for laminar flow. The theory of laminar flow is described in Section 2.4 and the analytical modeling results are discussed in Section 3.2. The third model developed was for turbulent flow. The theory of turbulent flow is described in Section 2.5 and the analytical modeling results are displayed in Section 3.3. Section 3.3 contains two turbulent flow scenarios; turbulent flow without heat transfer and turbulent flow with heat transfer. The fourth model developed was for two-phase flow with water and air. The theory of two-phase flow is described in Section 2.6 and the analytical 3 modeling results for the scenarios analyzed are shown in Section 3.4. The first scenario is a gas mixing tank and the second scenario is a bubble column. The final and most complex model created includes a phase transformation (vaporization and condensation). The theory of boiling heat transfer is described in Section 2.7 and the analytical modeling results are presented in Section 3.5. Two models were created, the first for pool boiling and the second for subcooled flow boiling. After each model was created, a mesh validation was performed and the results were compared to known experimental data when possible to validate the information generated by Fluent. 4 2. HEAT TRANSFER AND FLUID FLOW: THEORY This section discusses basic theory behind some common heat transfer and fluid flow scenarios. It is meant to provide a brief introduction to the phenomena involved in subcooled flow boiling. 2.1 GOVERNING EQUATIONS Conservation equations are a local form of conservation laws which state that mass, energy and momentum as well as other natural quantities must be conserved. A number of physical phenomena may be described using these equations [3]. In fluid dynamics, the two key conservation equations are the conservation of mass and the conservation of momentum. Conservation of Mass in Vector Form (continuity equation): ππ β β πv + (∇ β)= 0 ππ‘ Conservation of Mass in Cartesian Form: ππ π π π (ππ£π₯ ) + (ππ£π ) + (ππ£π§ ) = 0 + ππ‘ ππ₯ ππ¦ ππ§ Conservation of Momentum in Vector Form: π π·v β β π + π∇ β 2v = −∇ β + ππ π·π‘ Conservation of Momentum in Cartesian Form: ππ£π₯ ππ£π₯ ππ£π₯ ππ£π₯ ππ π 2 π£π₯ π 2 π£π₯ π 2 π£π₯ π( + π£π₯ + π£π¦ + π£π§ )=− +π( 2 + + ) + πππ₯ ππ‘ ππ₯ ππ¦ ππ§ ππ₯ ππ₯ ππ¦ 2 ππ§ 2 π( ππ£π¦ ππ£π¦ ππ£π¦ ππ£π¦ π 2 π£π¦ π 2 π£π¦ π 2 π£π¦ ππ + π£π₯ + π£π¦ + π£π§ )=− +π( 2 + + ) + πππ¦ ππ‘ ππ₯ ππ¦ ππ§ ππ¦ ππ₯ ππ¦ 2 ππ§ 2 ππ£π§ ππ£π§ ππ£π§ ππ£π§ ππ π 2 π£π§ π 2 π£π§ π 2 π£π§ π( + π£π₯ + π£π¦ + π£π§ )=− +π( 2 + + ) + πππ§ ππ‘ ππ₯ ππ¦ ππ§ ππ§ ππ₯ ππ¦ 2 ππ§ 2 5 In subcooled flow boiling, as in many other instances of fluid dynamics, energy is added or removed from the system. In this situation, the conservation of energy equation is important. Conservation of Energy in Vector Form: ππΆΜπ π·π π ln π π·π β β π) − ( = −(∇ ) π·π‘ π ln π π π·π‘ Conservation of Energy in Cartesian Form: ππ ππ ππ ππ πππ₯ πππ¦ πππ§ π ln π π·π ππΆΜπ ( + π£π₯ + π£π¦ + π£π§ ) = − ( + + )−( ) ππ‘ ππ₯ ππ¦ ππ§ ππ₯ ππ¦ ππ§ π ln π π π·π‘ 2.2 NUMERICAL METHODS After the conservation laws governing heat transfer, fluid flow and other related processes are expressed in differential form (Section 2.1), they can solved using numerical methods to determine pressure, temperature, mass flux, etc. for various circumstances and boundary conditions. Each differential equation represents a conservation principle and employs a physical quantity as its dependent variable that is balanced by the factors that influence it. Some examples of differential equations that may be solved through numerical methods are conservation of energy, conservation of momentum and time averaged equation for turbulent flow. [4] The goal of computational fluid dynamics is to calculate the temperature, velocity, pressure, etc. of a fluid at particular locations within a system. Thus, the independent variable in the differential equations is a physical location (and time in the case of unsteady flows). Due to computational limitations, the number of locations (also known as grid points or nodes) must be finite. By only focusing on the solution of the differential equations at discrete locations, the need to find an exact solution to the differential equation is not necessary. The algebraic equations (also known as discretization equations) involving the unknown values of the independent variable at chosen locations (grid points) are derived from the differential equations governing the 6 independent variable. In this derivation, assumptions about the value of the independent variable between grid points must be made. This concept is known as discretization. [4] A discretization equation is an algebraic relationship that connects the values of the dependent variable for a group of grid points within a control volume. This type of equation is derived from the differential equation governing the dependent variable and thus expresses the same physical information as the differential equation. The piecewise nature of the profile (or mesh) is created by the finite number of grid points that participate in a given discretization equation. The value of the dependent variable at a grid point thereby influences the value of the dependent variable in its immediate area. As the number of grid points becomes very large, the solution of the discretization equations is expected to approach the exact solution of the corresponding differential equation. This is true because as the grid points get closer together, the change in value between neighboring grid points becomes small and the actual details of the profile assumption become less important. This is where the term “mesh independent” originates. If there are too few grid points (coarse mesh), the profile assumptions can impact the solution results and the discretization equation solution will not match the differential equation solution. To ensure that the discretization equation results are not dependent on the profile assumptions, the solution should be checked for mesh independence. [4] One of the more common procedures for deriving discretization equations is using a truncated Taylor series. Other methods for deriving discretization equations include variational formulation, method of weighted residuals and control volume formulation. In the iterative process for solving a discretization equation, it is often desirable to speed up or to slow down the changes, from iteration to iteration, in the values of the dependent variable. The process of accelerating the rate of change between iterations is called over-relaxation while the process of slowing down the rate of change between iterations is called under-relaxation. To avoid divergence in the iterative solution of strongly nonlinear equations, under-relaxation is a very useful tool [4]. Fluent allows for manipulation of the relaxation constants for many independent variables to improve convergence ability. It also offers numerous spatial discretization solvers for the various independent variables such as pressure, flow, momentum, 7 turbulence, and energy. Fluent implements the control volume formulation with upwinding which was first proposed by Courant, Isaacson, and Rees in 1952. Other options include QUICK, power law and third-order MUSCL. 2.3 NATURAL CONVECTION Convection is the transport of mass and energy by bulk fluid motion. If the fluid motion is induced by some external force, it is generally referred to as forced convection. Natural convection is a transport mechanism in which the fluid motion is not generated by any external source (like a pump, fan, suction device, etc.) but driven by buoyancy-induced motion resulting from internal body forces produced by density gradients. The density gradients can arise from mass concentration and or temperature gradients in the fluid [5]. For example, in a system where a heated surface is submersed in a cooler fluid, the cooler fluid absorbs energy from the heated surface and becomes less dense. Buoyancy effects due to body forces cause the heated fluid to rise and the surrounding, cooler fluid moves to take its place. The cooler fluid is then heated and the process continues forming a convection current that continuously removes energy from the heated surface. In nature, natural convection cells occur everywhere from oceanic currents to air rising above sunlight-warmed land. Natural convection also takes place in many engineering applications such as home heating radiators and cooling computer chips. The amount of heat transfer that occurs due to natural convection in a system is characterized by the Grashof, Prandtl and Rayleigh numbers. The Grashof number, Gr, is a dimensionless parameter that represents the ratio of buoyancy to viscous forces acting on a fluid; and is defined as: πΊπ = ππ½(ππ − π∞ )πΏ3 (π ⁄π)2 where β is the thermal expansion coefficient: 1 ππ π½=− ( ) π ππ π 8 The Prandtl number, Pr, is a dimensionless parameter that represents the ratio of momentum diffusivity to thermal diffusivity; and is defined as: Pr = Cp μ k The Rayleigh number, Ra, is a dimensionless parameter that represents the ratio of buoyancy and viscosity forces times the ratio of momentum and thermal diffusivities; and is defined as: Ra = GrPr When the Rayleigh number is below a critical value for a particular fluid, heat transfer is primarily in the form of conduction; when it exceeds the critical value, heat transfer is primarily in the form of convection. Like forced convection, natural convection can either be laminar or turbulent. Rayleigh numbers less than 108 indicate a buoyancy-induced laminar flow, with transition to turbulence occurring at about 109. [6] In many situations, convection is mixed meaning that both natural and forced convection occur simultaneously. The importance of buoyancy forces in a mixed convection flow can be measured by the ratio of the Grashof and Reynolds numbers: Gr gβΔTL = Re2 V2 When this number approaches or exceeds unity, there are strong buoyancy contributions to the flow. Conversely, if the ratio is very small, buoyancy forces may be ignored. 2.4 LAMINAR FLOW Fluid flow can be grouped into two categories, laminar or turbulent flow. Laminar flow implies that the fluid moves in sheets that slip relative to each other. Laminar flow occurs at very low velocities where there are only small disturbances and little to no local velocity variations. In laminar flow, the motion of the fluid particles is very orderly and can be characterized by high momentum diffusion and low momentum convection. 9 The Reynolds number is used to characterize the flow regime. The Reynolds number, Re, is a dimensionless number that represents the ratio of inertial forces to viscous forces; and is defined as: Re = ρVA μ The Reynolds number helps to quantify the relative importance of inertial and viscous forces for given flow conditions. For internal flow, such as within a pipe, laminar flow occurs at a Reynolds number less than 2300. The velocity of laminar flow in a pipe is can be calculated by [5]: π’= ππ 2 ππ π2 (− ) (1 − 2 ) 4π ππ₯ ππ Or, in terms of the mean velocity, V: π2 π’ = 2π (1 − 2 ) ππ The above two equations indicate that the velocity for laminar flow is related to the square of the pipe radius and thus the flow profile is parabolic. The energy equation for flow through a circular pipe assuming symmetric heat transfer, fully developed flow and constant fluid properties is [5]: ππ 1π ππ π 2π π’ = πΌ[ (π ) + 2 ] ππ₯ π ππ ππ ππ₯ 2.5 TURBULENT FLOW In fluid dynamics, turbulence is a flow regime characterized by chaotic and stochastic changes. Turbulent flows exist everywhere in nature from the jet stream to the oceanic currents. Turbulent flows are highly irregular and random which makes a deterministic approach to turbulence problems impossible. They have high diffusivity, meaning there is rapid mixing and increased rates of momentum, heat and mass transfer. Because of these properties, turbulent flows are very important to many engineering applications. Turbulent flows involve large Reynolds numbers and contain three10 dimensional vorticity fluctuations. The unsteady vortices appear on many scales and interact with each other generating high levels of mixing. Also, like laminar flows, turbulent flows are dissipative. Because turbulence cannot maintain itself, it depends on its environment to obtain energy. A common source of energy for turbulent velocity fluctuations is shear in the mean flow; other sources, such as buoyancy, exist too. If turbulence arrives in an environment where there is no shear or other maintenance mechanisms, the turbulence will decay and the flow tends to become laminar. [7] In flows that are originally laminar, turbulence arises from instabilities at large Reynolds numbers. For internal flows, such as within a pipe, turbulent flow is characterized by a Reynolds number greater than 4000. For flows with a Reynolds number between 2300 and 4000, both laminar and turbulent flows are possible. This is called transition flow. [7] A common example of the transition from laminar flow to turbulent flow is smoke rising from a cigarette [8]. Figure 2.5-1: Transition from Laminar to Turbulent Flow As the smoke leaves the cigarette, it travels upward in a laminar fashion as shown by the single stream of smoke. At a certain distance, the Reynolds number becomes too large and the flow begins to transition to the turbulent regime. When this 11 happens, the flow of the smoke becomes more random and rapidly mixes with the air causing it to dissipate. Perfect modeling of turbulent flow requires the exact solution of the Continuity and Navier-Stokes equations which can be extremely difficult and time consuming due to the many scales involved. To reduce the complexity, an approximation to the NavierStokes equation was developed by Osborne Reynolds called the Reynolds-averaged Navier–Stokes equations (or RANS equations). This method decomposes the instantaneous fluid flow quantities of the Navier-Stokes equations into mean (timeaveraged) and fluctuating components. The RANS equations can be used with approximations based on knowledge of the turbulent flow to give approximate timeaveraged solutions to the Navier–Stokes equations. [9] For the velocity terms: π’π = π’Μ π + π’π′ where π’Μ π and π’π′ are the mean and fluctuating velocity components respectively. Similarly, for scalar quantities: π = πΜ + π ′ where π denotes a scalar such as energy, pressure, or species concentration. Substituting expressions of this form for the flow variables into the instantaneous continuity and momentum equations and taking a time-average yields the time-averaged continuity and momentum equations [9]. These are written in Cartesian tensor form as: πΏπ πΏ (ππ’Μ π ) = 0 + πΏπ‘ πΏπ₯π πΏ πΏ πΏπ πΏ πΏπ’π πΏπ’π 2 πΏπ’π πΏ ′ ′ Μ Μ Μ Μ Μ Μ (ππ’Μ π ) + (ππ’Μ π π’Μ π ) = − + [π ( + − πππ )] + (−ππ’ π π’π ) πΏπ‘ πΏπ₯π πΏπ₯π πΏπ₯π πΏπ₯π πΏπ₯π 3 πΏπ₯π πΏπ₯π The two above equations are called the RANS equations. They have the same general form as the instantaneous Navier-Stokes equations, with the velocities and other solution variables now representing time-averaged values. The RANS equations can be used with approximations based on knowledge of the turbulent flow to give approximate ′ ′ Μ Μ Μ Μ Μ Μ time-averaged solutions to the Navier–Stokes equations. An additional term,(−ππ’ π π’π ), 12 known as the Reynolds stress appears in the equation as a results of using the RANS method. [9] One way that the Reynolds stress is evaluated in practice is through the k-Ο΅ turbulence model. The k-Ο΅ model was first introduced by Harlow and Nakayama in 1968 [10]. The k-Ο΅ model has become the most widely used model for industrial applications because of its overall accuracy and small computational demand. In the k-Ο΅ model, k represents the turbulent kinetic energy and Ο΅ represents its dissipation rate. Turbulent kinetic energy is the average kinetic energy per unit mass associated with eddies in the turbulent flow while epsilon (Ο΅) is the rate of dissipation of the turbulent energy per unit mass. In the derivation of the k-Ο΅ model, it is assumed that the flow is fully turbulent, and the effects of molecular viscosity are negligible. As the strengths and weaknesses of the standard k-Ο΅ model became known, modifications were introduced to improve its performance. These improvements have helped create many, new, more accurate models, among them, the realizable k-Ο΅ model which differs from the standard k-Ο΅ model in two important ways. First, the realizable model contains an alternative formulation of the turbulent viscosity. Second, a modified transport equation for the dissipation rate, Ο΅, is derived from an exact equation for the transport of the mean-square vorticity fluctuation. The term “realizable” means that the model satisfies certain mathematical constraints on the Reynolds stresses, consistent with the physics of turbulent flows. [9] 2.5.1 CALCULATING TURBULENCE PARAMETERS All of the computational fluid dynamic models discussed in this thesis use the k-Ο΅ turbulence model when applicable. In Fluent, turbulence models require certain parameters to be established prior to initialization to properly set the initial and boundary conditions for the flow. For instance, based on the conditions in Table 2.5.1-1, the equations in Table 2.5.1-2 [9] were used to determine the boundary and initial condition inputs for the turbulent flow models presented in Section 3.3. 13 Table 2.5.1-1: Turbulent Flow Input Input Parameter Mass Flow Rate (πΜ) Pipe Diameter (D) Viscosity (μ) Density (ρ) Turbulence Empirical Constant (Cμ) Numerical Value 1.0 kg/s 0.03 m 0.001003 kg/m-s 998.2 kg/m3 0.09 [9] Table 2.5.1-2: Turbulence Parameter Calculation Variable Hydraulic Diameter (Dh) Flow Area (A) Average Flow Velocity (uavg) Reynolds Number (ReDh) Turbulence Length Scale (l) Equation Numerical Value 4∗π΄ π·β = π π· 2 π ∗ (2 ) = =π· 4∗π∗π· π· 2 π΄ =π∗( ) 2 0.03 π 2 =π∗( ) 2 πΜ π’ππ£π = π∗π΄ 0.5 ππ/π = ππ 998.2 3 ∗ 0.00070686 π2 π πΜπ·β π ππ·β = ππ΄ ππ 0.5 π ∗ 0.03 m = ππ 0.001003 π − π ∗ 0.00070686 π2 π = 0.07 ∗ π·β = 0.07 ∗ 0.03 π − Turbulent Intensity (I) Turbulent Kinetic Energy (k) Dissipation Rate (Ο΅) 0.00070686 m2 1.41726 m/s 42314 0.0021 m 1 πΌ = 0.16 ∗ π ππ· 8 β = 0.03 m 4.22483 % 1 0.16 ∗ 42314−8 3 2 π = (π’ππ£π ∗ πΌ) 2 2 3 π = (1.41726 ∗ 0.0422483) 2 π 3/2 3/4 k ε = Cπ π 0.00537853/2 = 0.093/4 0.0021 14 0.0053785 m2/s2 0.030859 m2/s3 2.6 TWO-PHASE FLOW Fluid flows that contain two or more components are referred to as multiphase flow. The flow components can be of the same chemical substance but in different states of matter such as water and steam, be of different chemical substances but the same state of matter such as water and oil or finally be of different chemical substance and different states of matter such as water and air. This section focuses on two-phase flow involving water and air while Section 2.7 focuses on two-phase flows involving water and steam. Depending on the volume fraction of each component in the two-phase flow, different flow patterns can exist. Understanding the flow pattern of the two-phase flow is important because pressure drops and heat transfer rates are heavily impacted by the flow type. The characteristic flow patterns for two-phase flow, in order of increasing gas volume fraction from liquid to gas, are bubbly flow, plug flow, stratification flow, wavy flow, slug flow, annular flow and spray flow. A schematic representation of each of these flow patterns is shown in Figure 2.6-1 [11]. Figure 2.6-1: Flow Regimes The flow patterns shown in Figure 2.6-1 can be classified into three categories, bubbly flow, slug flow and annular flow. Bubbly flow is when the liquid phase is continuous and the vapor phase is discontinuous such that the vapor phase is distributed 15 in the liquid phase in the form of bubbles. This flow pattern occurs at low gas volume fractions. Subcooled boiling is classified as bubbly flow. Slug flow is when there are relatively large liquid slugs surrounded by vapor. This flow pattern occurs at moderate gas volume fractions and relatively low flow velocities. Annular flow is when the liquid phase is continuous along the wall and the vapor phase is continuous in the core. This flow pattern occurs at high gas volume fractions and high flow velocities. Although not considered to be a flow regime, film boiling is the opposite of annular flow (the vapor phase is continuous along the wall and the liquid phase is continuous in the core). Flow film boiling occurs when the heat flux is relatively large compared to the mass flux. Film boiling is discussed further in Section 2.7. As stated previously, knowing the flow pattern is important to determine the pressure drop and heat transfer rate within a system. The flow pattern changes as a function of gas volume fraction and flow velocity. The flow pattern of a system can be determined using the Baker flow criteria shown in Figure 2.6-2 [11]. Figure 2.6-2: Baker Flow Pattern 16 2.6.1 MODELING TWO-PHASE FLOWS Two-phase flows obey the same basic laws of fluid mechanics that apply to single phase flows; however, the equations are more complicated and more numerous. Two-phase flows are more difficult to solve due to the secondary phase and additional phenomena that must be accounted for such as mass transfer, and phase-interface interactions (slip and drag). Three common multiphase flow models available in Fluent are Volume of Fluid (VOF), Mixture and Eulerian, each with varying strengths and computational demand. The VOF model is the simplest and least computationally expensive of the three multiphase models offered in Fluent. The VOF model can analyze two or more immiscible fluids by solving a single set of momentum equations and tracking the volume fraction of each fluid throughout the domain. All control volumes must be filled with either a single fluid phase or a combination of phases. The VOF model does not allow for void regions where no fluid of any type is present. The VOF method was based on the marker-and-cell method and quickly became popular due to its low computer storage requirements. Typical applications of VOF include stratified or freesurface flows such as the prediction of jet breakup, the motion of large bubbles in a liquid, the motion of liquid after a dam break, and the steady or transient tracking of a liquid-gas interface. [9] The Mixture model is in between the VOF and Eulerian models both in complexity and computational expense. The Mixture multiphase model can analyze multiple phases (fluid or particulate) by solving the momentum, continuity, and energy equations for the mixture, the volume fraction equations for the secondary phases, and algebraic expressions for the relative velocities. Like the VOF model, it uses a singlefluid approach but has two major differences. First, the Mixture model allows for the phases to be interpenetrating and therefore the volume fraction of a fluid in a control volume can be equal to any value between zero and one. Second, the Mixture model allows for the phases to move at different velocities, using the concept of slip velocities. The mixture model is a good substitute for the full Eulerian multiphase model in several cases where a full multiphase model may not be feasible or when the interphase laws are unknown or their reliability can be questioned. 17 Typical applications include sedimentation, cyclone separators, particle-laden flows with low loading, and bubbly flows where the gas volume fraction remains low. [9] The Eulerian model is the most complex and most computationally expensive multiphase model offered in Fluent. It solves momentum and continuity equations for each of the phases, and the equations are coupled through pressure and exchange coefficients. With the Eulerian multiphase model, the number of secondary phases is limited only by memory requirements and convergence behavior. The Eulerian multiphase model allows for the modeling of multiple separate, yet interacting phases. The interacting phases can be liquids, gases, or solids in nearly any combination. Due to its ability to model interacting phases, typical applications of the Eulerian model are bubble columns, risers, particle suspension, fluidized beds and boiling including subcooled boiling. [9] 2.6.2 POPULATION BALANCE MODEL Many industrial fluid flow applications including subcooled boiling involve a secondary phase with a size distribution. The size distribution of particles may include solid particles, bubbles, or droplets that evolve in a multiphase system. Thus, in multiphase flows involving a size distribution, a balance equation is required to describe the changes in the particle size distribution, in addition to momentum, mass, and energy balances. This balance is generally referred to as the population balance. To make use of this modeling concept, a number density function is introduced to account for the different sizes in the particle population. With the aid of particle properties (for example, particle size, porosity, composition, etc.), different particles in the population can be distinguished and their behavior can be described. [9] The link between the population balance and boiling models has not been fully developed in Fluent and is therefore not employed in the subcooled boiling model created in Section 3.5.2. However, the population balance model is utilized in Section 3.4.3 to track bubble size distribution within a bubble column. 18 2.7 BOILING HEAT TRANSFER Boiling is defined as a mode of heat transfer that occurs when saturated liquid changes to saturated vapor due to heat addition. It is normally characterized by a high heat transfer capacity and a low wall temperature which is made possible due to the large amount of energy required to cause a phase change. This is essential for industrial cooling applications, such as nuclear reactors and fossil boilers. Due to its importance in industry, a significant amount of research has been carried out to study the capacity and the mechanism of boiling heat transfer. There are two basic types of boiling, pool boiling and flow boiling. If heat addition causes a phase change in a stagnant fluid then it is pool boiling. If heat addition causes a phase change in a moving fluid then it is flow boiling. Both types of boiling heat transfer can be separated into four regimes which are shown in Figure 2.7-1 [12]. Figure 2.7-1: Boiling Heat Transfer Regimes The first regime of boiling, up to point A, is known as natural convection boiling. During this regime, no bubbles form; instead, heat is transferred from the surface to the 5/4 bulk fluid by natural convection. The heat transfer rate is proportional to π₯ππ ππ‘ [11]. The second regime of boiling, from point A to point C, is called nucleate boiling. During this stage, vapor bubbles are generated at certain preferred locations on the heated surface called nucleation sites. Nucleation sites are often microscopic cavities or cracks in the surface. When the liquid near the wall superheats, it evaporates forming bubbles at the nucleation sites. When the liquid evaporates, a significant amount of 19 energy is removed from the heated surface due to the latent heat of the vaporization. Vaporization also increases the convective heat transfer by mixing the liquid water near the heated surface. There are two subregimes of nucleate boiling. The first subregime is when local boiling occurs in a subcooled liquid (subcooled boiling). In this situation, bubbles form on the heated surface but tend to condense after detaching from it. The second subregime is when local boiling occurs in a saturated liquid. In this case, the bubbles do not condense after detaching from the heated surface since the liquid is the same temperature as the steam. It is possible for both subregimes to take place between points A and C. Nucleate boiling is characterized by a very high heat transfer rate and a small temperature difference between the bulk fluid and the heated surface. For this reason, it is considered to be the most efficient heat transfer boiling regime. [11] As the heated surface increases in temperature, more and more nucleation sites become active. As more bubbles form at the nucleation sites, they begin to merge together and form columns or slugs of gas, thus decreasing the contact area between the bulk fluid and the heated surface. The decrease in contact area causes the slope of the line in Figure 2.7-1 to decrease until a maximum is reached (point C). Point C is referred to as the critical heat flux. When the critical heat flux is reached, the vapor begins to form an insulating blanket around the heated surface which dramatically increases the surface temperature. This is called the boiling crisis or departure from nucleate boiling. [12] As the temperature delta increases past the critical heat flux, the rate of bubble generation exceeds the rate of bubble separation. Bubbles at the different nucleation sites begin to merge together and boiling becomes unstable. The surface is alternately covered with a vapor blanket and a liquid layer, resulting in oscillating surface temperatures. This regime of boiling is known as partial film boiling or transition boiling and takes place between points C and D. [11] If the temperature difference between the surface and the fluid continues to increase, stable film boiling is achieved. During stable film boiling, there is a continuous vapor blanket surrounding the heated surface and phase change occurs at the liquid-vapor interface instead of at the heated surface. During this regime, most heat transfer is carried out by radiation. [12] 20 3. HEAT TRANSFER AND FLUID FLOW: MODELING 3.1 NATURAL CONVECTION Two natural convection scenarios were examined in this section. The first was a heated horizontal cylinder and the second was a heated vertical plate, both were submerged in an infinite pool of liquid. These examples were chosen because of their simplicity, because they are commonly found in nature and because they have been previously studied and results are available for validation of the numerical computations. 3.1.1 HORIZONTAL CYLINDER A cylinder with an elevated constant surface temperature submerged in an infinite pool of liquid was analyzed in this section. Energy passed from the slightly warmer cylinder to the nearby fluid causing its temperature to increase and convection cells to form. Figure 3.1.1-1 shows a schematic representation of the geometry and important boundary conditions used to model the horizontal cylinder. The top and bottom walls of the rectangle represent inlet and outlet pressure boundaries with pressure conditions set such that the fluid is stagnant until heated by the cylinder. The left and right walls of the rectangle are slip walls to more accurately model an infinite pool. See Table 3.1.1-1 for a more detailed list of input parameters used in this section. Figure 3.1.1-1: Heated Cylinder Schematic 21 Table 3.1.1-1: Horizontal Cylinder Model Input Input Geometry Cylinder Diameter Pool Height Pool Width 2D Space Solver Time Time Step Size Type Velocity Formulation Gravity Models Energy Viscous Density Initial Conditions Cylinder Surface Temperature Initial Fluid Temperature Material Properties (Water) Specific Heat Thermal Conductivity Viscosity Density Solution Methods Scheme Gradient Pressure Momentum Energy Transient Formulation Value 0.02 m 0.28 m 0.24 m Planar Transient 0.05 s Pressure Based Relative -9.8 m/s2 (Y-direction) Active Laminar Boussineq 310 K 300 K 4182 J/kg-K 0.6 W/m-K 0.001003 kg/m-s See Table 3.1.1-2 PISO Least Square Cell Based PRESTO! Second Order Upwind Second Order Upwind Second Order Implicit Table 3.1.1-2: Horizontal Cylinder Model Water Density Density (kg/m3) 999.9 994.1 974.9 958.4 Temperature (K) 273 308 348 373 22 Figure 3.1.1-2 shows the liquid temperature field after 20 seconds of heating. As the temperature increases, the fluid begins to rise due to buoyancy forces. Figure 3.1.1-2: Temperature (K) Figure 3.1.1-3 indicates that even the fluid not in direct contact with the heated cylinder experiences a density change. The density gradient which is caused by energy transfer via conduction to the bulk fluid is illustrated by the color transition surrounding the cylinder from least dense (blue) to most dense (red). Figure 3.1.1-3: Density (kg/m3) 23 As the warm fluid rises, it loses energy to the surrounding bulk fluid which causes the buoyancy driving head to diminish and the warm fluid climbs more slowly until it eventually stops. When it reaches its maximum elevation, it is pushed to the left or right by the fluid travelling upwards below it and fluid recently pushed aside begins to sink. This motion creates a small convection cell to the left and to the right of the rising plume about 3 cm above the heated cylinder. This process continues indefinitely as long as there is a temperature gradient between the cylinder and the bulk fluid. If the bulk fluid temperature increases, the buoyancy driving head will be smaller and the convection cells will develop closer to the heated cylinder. Figure 3.1.1-4 is a velocity vector plot that displays how the liquid moves within the control volume. The cycle of energy absorption and replacement around the cylinder and the two convection cells above the cylinder are visible in this figure. Figure 3.1.1-4: Velocity Vectors (m/s) To verify that the model produced realistic results, the solution was compared to experimental data. Figure 3.1.1-5 shows interference fringes surrounding a heated horizontal cylinder in natural convection. Each interference fringe can be interpreted as a band constant temperature. 24 (a) (b) Figure 3.1.1-5: Interference Fringes Around a Heated Horizontal Cylinder (K) (a) From Eckert [13] (b) Isotherms From Fluent The model of a horizontal cylinder submerged in an infinite pool was in qualitative agreement to experimental data. Figure 3.1.1-5 shows that the experimental data and the model solution have isotherms that extend away from the cylinder and grow in distance away from one another as they get farther from the heated surface. Quantitative experimental data from Ingham [14] was compared to the Fluent results to provide model validation. Figure 3.1.1-6, Figure 3.1.1-7 and Figure 3.1.1-8 show a comparison of dimensionless temperature versus dimensionless distance for four dimensionless times at an angle of 30°, 90° and 180°, respectively, from the positive x-axis. Dimensionless temperature is T = (T’ – T0) / (Twall – T0) where T’ is the actual fluid temperature, T0 is the bulk fluid temperature and Twall is the wall temperature. Dimensionless time is t = t’ * (βgΔT/a)1/2 where t’ is real time, ΔT is (Twall – T0), β is the coefficient of thermal expansion and a is the diameter of the cylinder. The heated horizontal cylinder model developed in Fluent showed good agreement compared to experimental data at the three different radial locations. This comparison provided confidence that the information obtained from the Fluent model was accurate. 25 (a) (b) Figure 3.1.1-6: Temperature at θ = 30° Vs. Radial Distance (a) From Ingham [14] and (b) From Fluent (a) (b) Figure 3.1.1-7: Temperature at θ = 90° Vs. Radial Distance (a) From Ingham [14] and (b) From Fluent 26 (a) (b) Figure 3.1.1-8: Temperature at θ = 180° Vs. Radial Distance (a) From Ingham [14] and (b) From Fluent To ensure that the mesh had no significant effect on the results, a mesh validation was performed. The mesh validation compared the results shown in this section (“Analysis Value” in Table 3.1.1-3) to a second case with an increased number of finite volumes (“Mesh Validation” in Table 3.1.1-3). The results from the mesh validation shown in Table 3.1.1-3 prove that the results are mesh independent. Table 3.1.1-3: Mesh Validation for Horizontal Cylinder Model Number of Nodes Number of Elements Max Velocity (m/s) Max Total Temperature (°F) Min Density (kg/m3) Analysis Value 19716 38688 0.01627 309.9239 993.1765 27 Mesh Validation 23636 46400 0.01621 309.9531 993.1625 Difference 19.88 % 19.93 % -0.37 % 0.01 % 0.00 % 3.1.2 VERTICAL PLATE A vertical plate with an elevated constant surface temperature submerged in an infinite pool of liquid was analyzed in this section. Energy passed from the slightly warmer plate to the fluid causing its temperature to increase and the fluid to rise. Figure 3.1.2-1 shows a schematic representation of the geometry and important boundary conditions used to model the vertical plate. Although the top and bottom walls of the rectangle represent inlet and outlet pressure boundaries, the fluid is stagnant until heated by the plate. The left and right walls of the rectangle are slip walls to more accurately model an infinite pool. See Table 3.1.2-1 for a more detailed list of input parameters used in this section. Figure 3.1.2-1: Vertical Plate Schematic Figure 3.1.2-2 presents the liquid temperature field after 20 seconds. When energy is exchanged between the plate and the fluid, a thermal boundary layer is created. Thermodynamic equilibrium demands that the plate, and the fluid in direct contact with it be at the same temperature. The region in which the fluid temperature changes from the plate surface temperature to that of the bulk fluid temperature is known as the thermal boundary layer. The teal color in Figure 3.1.2-2 shows the growth of the thermal boundary layer. The thermal boundary layer is relatively small at the bottom of the plate because there has been little heat addition but it grows (teal color expands away from the plate) as the fluid reaches the top of the plate. 28 Table 3.1.2-1: Vertical Plate Model Input Input Geometry Plate Height Plate Width Pool Height Pool Width 2D Space Solver Time Time Step Size Type Velocity Formulation Gravity Models Energy Viscous Density Initial Conditions Plate Surface Temperature Initial Fluid Temperature Material Properties (Water) Specific Heat Thermal Conductivity Viscosity Density Solution Methods Scheme Gradient Pressure Momentum Energy Transient Formulation Value 0.18 m 0.01 m 0.20 m 0.13 m Planar Transient 0.05 s Pressure Based Relative -9.8 m/s2 (Y-direction) Active Laminar Boussineq 310 K 300 K 4182 J/kg-K 0.6 W/m-K 0.001003 kg/m-s See Table 3.1.2-2 PISO Least Square Cell Based PRESTO! Second Order Upwind Second Order Upwind Second Order Implicit Table 3.1.2-2: Vertical Plate Model Water Density Density (kg/m3) 999.9 994.1 974.9 958.4 Temperature (K) 273 308 348 373 29 Figure 3.1.2-2: Temperature (K) Figure 3.1.2-3 shows the fluid velocity in vector form. The growth of the momentum boundary layer is more visible in this figure (the teal colored arrows expand away from the plate). The figure shows that the velocity is primarily vertical with a magnitude that increases with elevation. The increase in fluid velocity is caused by longer contact time with the heated surface which causes a greater temperature gradient and therefore a larger buoyancy force. Figure 3.1.2-3: Velocity Vectors (m/s) 30 Comparing Figure 3.1.2-3 (vertical plate velocity vectors) with Figure 3.1.1-4 (horizontal cylinder velocity vectors) produces interesting results. Because of the larger heated region, it was expected that the vertical plate would produce a greater maximum fluid velocity compared to the horizontal cylinder. The vertical plate has a maximum fluid velocity of 0.0149 m/s while the horizontal cylinder has a maximum fluid velocity of 0.0177 m/s. Although the difference is small, it is notable. The horizontal cylinder generates a larger maximum velocity because the buoyancy driving force is not impeded by the drag force created by the heated surface. Although the vertical plate continues to heat the fluid as it travels upward, the velocity is limited by friction which causes the plate scenario to have a smaller maximum velocity. To ensure that the model was giving realistic results, the solution was compared to experimental data. Figure 3.1.2-4 shows interference fringes surrounding a heated vertical plate in natural convection. Each interference fringe can be interpreted as a band constant temperature. (a) (b) Figure 3.1.2-4: Interference Fringes Around a Heated Vertical Plate (K) (a) From Eckert [13] and (b) From Fluent 31 The model of a vertical plate submerged in an infinite pool was in qualitative agreement to experimental data. Figure 3.1.2-4 shows that the experimental data and model solution have isotherms that extend away from the plate and grow in distance away from one another as they get farther from the heated surface. Experimental data from Ostrach [15] was compared to the Fluent results to assess the quantitative accuracy of the model. Figure 3.1.2-5 and Figure 3.1.2-6 show a comparison of dimensionless temperature versus dimensionless distance for five different Prandtl numbers. Figure 3.1.2-5a shows theoretical values and Figure 3.1.2-5b compares some of the theoretical values to experimental data. Dimensionless temperature is H(η) = (T – T∞) / (T0 – T∞) where T is the actual fluid temperature, T∞ is the bulk fluid temperature and T0 is the wall temperature. Dimensionless distance is η = (Y / X) * (Grx / 4)1/4 where Grx is the Grashof number, Y is the vertical height and X is the distance from the plate. The information contained in Figure 3.1.2-6 was calculated by Fluent. (a) (b) Figure 3.1.2-5: Dimensionless Temperature as a Function of Prandtl Number (a) Theoretical Values and (b) Experimental Values [15] 32 Figure 3.1.2-6: Dimensionless Temperature as a Function of Prandtl Number The heated vertical plate model developed in Fluent produced similar temperature results to the experimental data for five different Prandtl numbers. This comparison provided confidence that the information obtained from the Fluent model was accurate. To ensure that the mesh had no significant effect on the results, a mesh validation was performed. The mesh validation compared the results shown in this section (“Analysis Value” in Table 3.1.2-3) to a second case with an increased number of finite volumes (“Mesh Validation” in Table 3.1.2-3). The results from the mesh validation shown in Table 3.1.2-3 prove that the results are mesh independent. Table 3.1.2-3: Mesh Validation for Vertical Plate Model Number of Nodes Number of Elements Max Velocity (m/s) Max Total Temperature (°F) Min Density (kg/m3) Analysis Value 12310 23572 0.01376 309.8089 993.2319 33 Mesh Validation 18081 35168 0.01380 309.7991 993.2365 Difference 46.88 % 49.19 % 0.29 % 0.00 % 0.00 % 3.2 LAMINAR FLOW A simple axisymmetric laminar flow model was developed in this section. Figure 3.2-1 shows a schematic representation of the geometry and important boundary conditions used to model laminar flow within a pipe. The bottom line of the rectangle is an axis of rotation which is used to simplify the geometry and represents the pipe centerline. The top line of the rectangle is a no slip wall and after the rotation, becomes the pipe wall. The left and right lines of the rectangle are the inlet and outlet areas respectively, which when revolved, are circular. See Table 3.1.1-1 for a more detailed list of input parameters used in this section. Figure 3.2-1: Laminar Flow Schematic Based upon the selected initial conditions, the Reynolds number is 352, which is well within the laminar regime. A noteworthy characteristics of laminar flow is the parabolic shape of its velocity profile. Figure 3.2-2 displays the velocity magnitude versus position (distance from the pipe centerline) at different lengths from the pipe entrance. Figure 3.2-2: Velocity Profile 34 For example, “line-10cm” is the velocity profile 10 cm from the pipe entrance. Fluid velocity within the pipe slowly decreases as distance from the pipe centerline increases. Also, as the flow develops, the entrance effects dissipate, the velocity profile becomes more parabolic until it reaches a steady state at about 45 cm from the entrance. Table 3.2-1: Laminar Flow Model Input Input Value Geometry Pipe Diameter Pipe Length 2D Space Solver Time Type Velocity Formulation Gravity Models Energy Viscous Material Properties (Water) Specific Heat Thermal Conductivity Viscosity Density Initial Conditions Pipe Wall Surface Temperature Fluid Inlet Temperature Fluid Inlet Velocity Solution Methods Scheme Gradient Pressure Momentum Energy 0.03 m 0.50 m Axisymmetric Steady Pressure Based Relative -9.8 m/s2 (X-direction) Active Laminar 4182 J/kg-K 0.6 W/m-K 0.001003 kg/m-s See Table 3.2-2 305 K 300 K 0.05 m/s Coupled Least Square Cell Based Second Order Second Order Upwind Second Order Upwind Table 3.2-2: Laminar Flow Model Water Density Density (kg/m3) 999.9 994.1 Temperature (K) 273 308 35 Another characteristic of laminar flow is the lack of mixing that occurs within the fluid as it travels through the pipe. The radial velocity within the pipe is basically zero and each fluid molecule or atom remains about the same distance from the centerline as it travels through the pipe. Figure 3.2-3 shows the radial flow velocity. As expected, the radial velocity for most of the pipe is near zero and is less than 10 -3 times the average axial velocity. Radial velocity is at a maximum near the entrance of the pipe due to pipe boundary conditions and entrance effects but these have a negligible impact on system as a whole. Figure 3.2-3: Radial Velocity (m/s) Figure 3.2-4 shows the temperature profile for the laminar flow analyzed. Because there is little to no radial velocity, diffusion and conduction are the primary forms of heat transfer which causes the growth of the thermal boundary layer to be very slow. The growth of the thermal boundary layer is shown in Figure 3.2-4 by the expansion of the teal colored region. Figure 3.2-4: Temperature (K) As in natural convection, laminar flow generates a momentum boundary layer but its development is not visible pictorially. The momentum boundary layer is created by drag, or shear, forces created by the wall. Figure 3.2-5 shows the wall shear stress as a function of distance from the pipe entrance. The wall stress is much larger in the first 10 cm due to entrance effects. Once the entrance effects dissipate, the wall shear stress slowly decreases as the flow reaches a steady state. 36 Figure 3.2-5: Wall Shear Stress To ensure that the mesh had no significant effect on the results, a mesh validation was performed. The mesh validation compared the results shown in this section (“Analysis Value” in Table 3.2-3) to a second case with an increased number of finite volumes (“Mesh Validation” in Table 3.2-3). The results from the mesh validation shown in Table 3.2-3 prove that the results are mesh independent. Table 3.2-3: Mesh Validation for Laminar Flow Model Number of Nodes Number of Elements Max Velocity (m/s) Min Radial Velocity (m/s) Max Dynamic Pressure (Pa) Max Temperature (K) Analysis Value 26320 25353 0.079561 -0.003293 3.15925 304.6503 37 Mesh Validation 31000 29970 0.079507 -0.003528 3.155022 304.6855 Difference 17.78 % 18.21 % -0.07 % 7.12 % -0.13 % 0.01 % 3.3 TURBULENT FLOW 3.3.1 TURBULENT FLOW WITHOUT HEAT TRANSFER A simple axisymmetric turbulent flow model was developed in this section. Figure 3.3.1-1 shows a schematic representation of the geometry and important boundary conditions used to model turbulent flow within a pipe without heat transfer. The bottom line of the rectangle is an axis of rotation which is used to simplify the geometry and represents the pipe centerline. The top line of the rectangle is a no slip wall and after the rotation becomes the pipe wall. The left and right lines of the rectangle are the inlet and outlet areas respectively, which when revolved, are circular. See Table 3.3.1-1 for a more detailed list of input parameters used in this section. Figure 3.3.1-1: Turbulent Flow Without Heat Transfer Schematic Based upon the selected initial conditions, the Reynolds number is 42314, which is well within the turbulent regime. Figure 3.3.1-2 shows the velocity magnitude versus position (distance from the pipe centerline) at different distances from the pipe entrance. Figure 3.3.1-2: Velocity Magnitude 38 The velocity profile of turbulent flow differs significantly in two ways compared to the velocity profile of laminar flow (Section 3.2). First, turbulent flow velocity profiles are much flatter. Therefore, the fluid velocity doesn’t decrease significantly until close to the pipe wall. Second, entrance effects dissipate much quicker in turbulent flow [5] and thus the fluid velocity reaches a steady state velocity profile in a shorter distance. Figure 3.3.1-2 (turbulent flow) shows that flow reached a steady profile about 10 cm from the pipe entrance. Figure 3.2-2 (laminar flow) shows that flow reached a steady profile about 45 cm from the pipe entrance. This qualitatively matches experimental data well. Table 3.3.1-1: Turbulent Flow Without Heat Transfer Model Input Input Value Geometry Pipe Diameter 0.03 m Pipe Length 0.50 m 2D Space Axisymmetric Solver Time Steady Type Pressure Based Velocity Formulation Relative Gravity -9.8 m/s2 (X-direction) Models Energy Inactive Viscous Realizable k-ε Turbulence Model Near Wall Treatment Enhanced Turbulent Intensity 4.22483 % * Initial Conditions Fluid Mass Flow Rate 1.0 kg/s Material Properties (Water) Density 998.2 kg/m3 Viscosity 0.001003 kg/m-s Solution Methods Scheme Coupled Gradient Least Square Cell Based Pressure Second Order Momentum Second Order Upwind Turbulent Kinetic Energy Second Order Upwind Turbulent Dissipation Rate Second Order Upwind * Calculation shown in Table 2.5.1-2. 39 Figure 3.3.1-3 displays the wall shear stress versus distance from the pipe entrance. The shear stress is very large at the pipe entrance and decays to the steady state value after about 10 cm (same location where the velocity profile reaches steady state). The large increase in shear stress at the beginning of the pipe (~1-2 cm from the inlet) is caused by entrance effects. Figure 3.3.1-4 shows that that maximum radial velocity occurs near the pipe entrance. Figure 3.3.1-5 reveals that the greatest reduction in axial velocity occurs near the pipe entrance which is necessary to conserve momentum. Since shear stress is related to change in velocity parallel to the wall (axial velocity), the increase in wall shear stress is reasonable. Figure 3.3.1-3: Wall Shear Stress Figure 3.3.1-4: Radial Velocity (m/s) Figure 3.3.1-5: dAxial-Velocity/dx 40 To further investigate the impact of entrance effects, two additional scenarios were examined using a mass flow rate of 0.5 kg/s (Figure 3.3.1-6) and a mass flow rate of 1.5 kg/s (Figure 3.3.1-7). (a) (b) (c) Figure 3.3.1-6: Flow Results for Mass Flow Rate of 0.5 kg/s (a) Radial Velocity (m/s) (b) Wall Shear Stress (c) dAxial-Velocity/dx (a) (b) (c) Figure 3.3.1-7: Flow Results for Larger Mass Flow Rate of 1.5 kg/s (a) Radial Velocity (m/s) (b) Wall Shear Stress (c) dAxial-Velocity/dx 41 Figures 3.3.1-6 and 3.3.1-7 show that wall shear stress and maximum radial velocity are directly related to mass flow rate. At a certain distance from the pipe entrance, the change in axial velocity as a function of position reaches zero and the wall shear stress reaches a constant value. The pipe length necessary to reach a steady state shear stress is also related to the mass flow rate. A larger mass flow rate requires a greater distance to reach a constant shear stress. Figure 3.3.1-8 and Figure 3.3.1-9 show the turbulent kinetic energy and the production of turbulent kinetic energy as a function of distance, respectively. Figure 3.3.1-8: Turbulent Kinetic Energy (m2/s2) Figure 3.3.1-9: Production of Turbulent Kinetic Energy Most of the turbulent kinetic energy is located near the pipe wall due to shear stress. The trend of Figure 3.3.1-9 is similar to that of Figure 3.3.1-3 because shear stress, created by the wall, produces turbulent kinetic energy. A mesh validation was not performed for this model directly. The mesh accuracy is proven adequate in Section 3.3.2 which utilizes the same model with the addition of energy transfer from the pipe walls to the fluid. 42 3.3.2 TURBULENT FLOW WITH HEAT TRANSFER The turbulent flow model described in Section 3.3.1 was modified to include heat transfer from the pipe wall to the fluid. Figure 3.3.2-1 shows a schematic representation of the geometry and important boundary conditions used to model turbulent flow within a pipe with heat transfer. The bottom line of the rectangle is an axis of rotation which is used to simplify the geometry and represents the pipe centerline. The top line of the rectangle is a no slip wall with a constant heat flux and after the rotation becomes the pipe wall. The left and right lines of the rectangle are the inlet and outlet areas respectively, which when revolved, are circular. See Table 3.3.2-1 for a more detailed list of input parameters used in this section. Figure 3.3.2-1: Turbulent Flow With Heat Transfer Schematic Figure 3.3.2-2 displays the fluid temperature change caused by energy addition from the pipe walls. The radial temperature distribution in Figure 3.3.2-2 is more evenly distributed than the radial temperature distribution in Figure 3.2-4 (laminar flow). Uniform temperature distribution is a characteristic of turbulent flow and made possible by the chaotic nature of the flow regime. Figure 3.3.2-2: Temperature (K) The radial velocity in Figure 3.3.2-3 is very similar to that in Figure 3.3.1-4 which means that the heat addition has a negligible impact on fluid velocity. If the heat transfer rate to the fluid was increased sufficiently such that flow velocity was impacted, then the radial velocity between the two scenarios would also differ. 43 Table 3.3.2-1: Turbulent Flow With Heat Transfer Model Input Input Value Geometry Pipe Diameter 0.03 m Pipe Length 0.50 m 2D Space Axisymmetric Solver Time Steady Type Pressure Based Velocity Formulation Relative Gravity -9.8 m/s2 (X-direction) Models Energy Active Viscous Realizable k-ε Turbulence Model Near Wall Treatment Enhanced Turbulent Intensity 4.22483 % * Initial Conditions Fluid Mass Flow Rate 1.0 kg/s Fluid Inlet Temperature 300 K Wall Heat Flux 450 kW/m2 Material Properties (Water) Specific Heat 4182 J/kg-K Thermal Conductivity 0.6 W/m-K Viscosity 0.001003 kg/m-s Density See Table 3.3.2-2 Solution Methods Scheme Coupled Gradient Least Square Cell Based Pressure Second Order Momentum Second Order Upwind Turbulent Kinetic Energy Second Order Upwind Turbulent Dissipation Rate Second Order Upwind Energy Second Order Upwind * Calculation shown in Table 2.5.1-2. Table 3.3.2-2: Turbulent Flow Model Water Density Density (kg/m3) 999.9 994.1 974.9 Temperature (K) 273 308 348 44 Figure 3.3.2-3: Radial Velocity (m/s) Closely comparing the velocity profiles for the two turbulent flow models (Figure 3.3.1-2 and Figure 3.3.2-4) reveals that the velocity magnitude is slightly larger for the case with heat transfer. The energy addition causes the density of the fluid to decrease and the velocity increases slightly in order to maintain a constant mass flow through the pipe. Figure 3.3.2-4: Velocity Magnitude As expected, the wall shear stress shown in Figure 3.3.2-5 is similar to the wall shear stress shown in Figure 3.3.1-3. Figure 3.3.2-5: Wall Shear Stress 45 Comparing the velocity magnitude, radial velocity and wall shear stress from Section 3.3.1 to Section 3.3.2 proves that the addition of heat transfer has a negligible impact the turbulent flow. This is reasonable since the heat flux is relatively small and does not create any localized phase change. Thus, the relationships developed in Section 3.3.1 (impact mass flow has on shear stress and radial velocity) are applicable to turbulent flows with heat transfer as long as the heat transfer rate is small. To ensure that the mesh had no significant effect on the results, a mesh validation was performed. The mesh validation compared the results shown in this section (“Analysis Value” in Table 3.3.2-3) to a second case with an increased number of finite volumes (“Mesh Validation” in Table 3.3.2-3). The results from the mesh validation shown in Table 3.3.2-3 prove that the results are mesh independent. Table 3.3.2-3: Mesh Validation for Turbulence With Heat Transfer Model Number of Nodes Number of Elements Max Velocity (m/s) Max Temperature (°F) Min Density (kg/m3) Max Dynamic Pressure (Pa) 3.4 TWO-PHASE FLOW 3.4.1 GAS MIXING TANK Analysis Value 31031 31000 1.502045 317.6659 989.4604 1122.853 Mesh Validation 35739 34624 1.500343 318.1447 989.2305 1119.909 Difference 15.17 % 11.69 % -0.11 % 0.15 % -0.02 % -0.26 % In many branches of engineering, gas injection techniques have been extensively utilized to enhance chemical reaction rates, homogenize temperature and chemical compositions, and remove impurities. In the steel industry, the advancements made in mixing have increased the level of control over the steelmaking process which has improved the quality of steel produced. To mix the molten metal, gas is pumped through a porous plug located at the bottom of the mixing tank. The porous plug controls the velocity and bubble diameter of the gas. Buoyancy forces cause the injected gas to move quickly through the molten metal and drag forces causes mixing. Figure 3.4.1-1 46 shows a schematic representation of the geometry and important boundary conditions used to model the gas mixing tank. The top line of the rectangle is a pressure outlet and the left, right and most of the bottom lines of the rectangle represent no slip walls. The red line on the bottom of the rectangle represents a velocity inlet and is where the air jet enters the tank to mix the liquid. See Table 3.4.1-1 for a more detailed list of input parameters used in this section. Figure 3.4.1-1: Gas Mixing Tank Schematic Figure 3.4.1-2 shows the gas volume fraction, Figure 3.4.1-3 shows the liquid vector velocity and Figure 3.4.1-4 shows the gas vector velocity after 5 seconds of gas injection. Midway through the liquid volume in Figure 3.4.1-2, the air jet begins to become wavy. The wavy behavior is explained by Rayleigh instability which states that surface tension tends to minimize surface area between the two phases. Thus, after a certain distance the air jet will transform into air bubbles with the same volume but less surface area. The length required for the jet to breakup is dependent upon the gas velocity and gas / liquid surface tension. The liquid and gas velocities shown in Figure 3.4.1-3 and Figure 3.4.1-4, respectively, are similar in trend and magnitude which indicates that the drag force between the two phases is strong. The maximum gas velocity is much greater than the inlet velocity (0.5 m/s); therefore, buoyancy forces are significant. Figure 3.4.1-3 shows that there is a number of small eddies created by the injected gas which provide a significant amount of mixing within the liquid. 47 Table 3.4.1-1: Gas Mixing Tank Model Input Input Geometry Tank Width Tank Height Porous Plug Width 2D Space Solver Time Time Step Size Type Velocity Formulation Gravity Models Energy Viscous Multiphase Drag Turbulence Model Near Wall Treatment Turbulent Kinetic Energy Turbulent Dissipation Rate Initial Conditions Water Level Gas Velocity Bubble Diameter Material Properties (Water) Density Viscosity Material Properties (Air) Density Viscosity Surface Tension Solution Methods Scheme Gradient Momentum Volume Fraction Turbulent Kinetic Energy Turbulent Dissipation Rate Transient Formulation 48 Value 0.30 m 0.60 m 0.02 m Planar Transient 0.001 s Pressure Based Relative -9.8 m/s2 (Y-direction) Inactive Standard k-ε Eulerian Schiller-Nauman Standard 0 m2/s2 0 m2/s3 0.40 m 0.5 m/s 0.001 m 998.2 kg/m3 0.001003 kg/m-s 1.225 kg/m3 1.7894E-05 kg/m-s 0.072 N/m Phase Coupled SIMPLE Least Square Cell Based Second Order Upwind QUICK Second Order Upwind Second Order Upwind Second Order Implicit Figure 3.4.1-2: Gas Volume Fraction Figure 3.4.1-3: Liquid Velocity Vectors (m/s) 49 Figure 3.4.1-4: Gas Velocity Vectors (m/s) To ensure that the mesh had no significant effect on the results, a mesh validation was performed. The mesh validation compared the results shown in this section (“Analysis Value” in Table 3.4.1-2) to a second case with an increased number of finite volumes (“Mesh Validation” in Table 3.4.1-2). The results from the mesh validation shown in Table 3.4.1-2 prove that the results are mesh independent. Table 3.4.1-2: Mesh Validation for Gas Mixing Tank Model Number of Nodes Number of Elements Max Liquid Velocity (m/s) Max Gas Velocity (m/s) Max Static Pressure (psia) Max Liquid Total Pressure (psia) Max Liquid Volume Fraction Analysis Value 30625 30256 1.539086 2.046923 3925.424 4775.512 1.000000 50 Mesh Validation 36045 35644 1.453488 2.086285 3894.616 4732.633 1.000000 Difference 17.70 % 17.81 % -5.56 % 1.92 % -0.78 % -0.90 % 0.00 % 3.4.2 BUBBLE COLUMN A bubble column reactor is an apparatus primarily used to study gas- liquid reactions. This apparatus is a vertical column of liquid with gas introduced continuously at the bottom through a sparger. The bubble column contains gas dispersed as bubbles in a continuous volume of liquid. Per Section 2.6, the flow is considered to be bubbly. Bubbles form and travel upwards through the column due to the inlet gas velocity and buoyancy. The gas introduced through the sparger provides mixing, similar to the gas mixing tank in Section 3.4.1 but much less intense. This method of mixing is less invasive and requires less energy than mechanical stirring. Bubble column reactors are often used in industry to develop and produce chemicals and fuels for use in chemical, biotechnology, and pharmaceutical processes. Figure 3.4.2-1 shows a schematic representation of the geometry and important boundary conditions used to model the bubble column. The top line of the rectangle is a pressure outlet and the left and right lines of the rectangle represent no slip walls. The bottom line of the rectangle signifies a velocity inlet and is where the air bubbles enter the column. Table 3.4.2-1 for a more detailed list of input parameters used in this section. Figure 3.4.2-1: Bubble Column Schematic 51 See Table 3.4.2-1: Bubble Column Model Input Input Geometry Column Width Column Height 2D Space Solver Time Time Step Size Type Velocity Formulation Gravity Models Energy Viscous Multiphase Drag Turbulence Model Near Wall Treatment Turbulent Kinetic Energy Turbulent Dissipation Rate Initial Conditions Water Level Gas Flow Rate Bubble Diameter Material Properties (Water) Density Viscosity Material Properties (Air) Density Viscosity Surface Tension Solution Methods Scheme Gradient Momentum Volume Fraction Turbulent Kinetic Energy Turbulent Dissipation Rate Transient Formulation 52 Value 0.10 m 0.75 m Planar Transient 0.001 s Pressure Based Relative -9.8 m/s2 (Y-direction) Inactive Standard k-ε Eulerian Schiller-Nauman Standard 0 m2/s2 0 m2/s3 0.50 m 0.05 m/s 0.005 m 998.2 kg/m3 0.001003 kg/m-s 1.225 kg/m3 1.7894E-05 kg/m-s 0.072 N/m Phase Coupled SIMPLE Least Square Cell Based Second Order Upwind QUICK Second Order Upwind Second Order Upwind Second Order Implicit Figure 3.4.2-2 is a comparison between the gas volume fraction 1 second and 5 seconds after gas has begun flowing through the bubble column. At both time points the gas flows in slugs. After 5 seconds, the gas reaches the top of the liquid and caused the surface to change shape. Compared to the initial liquid level, the level after 5 seconds is about 5 cm higher. The level increase is known as gas holdup and is caused by phase drag forces and displacement. Figure 3.4.2-2b reveals that most of the gas travels along the wall in a quasi-annular flow type regime. (a) (b) Figure 3.4.2-2: Gas Volume Fraction After (a) 1 Second and (b) 5 Seconds Figure 3.4.2-3 is a comparison between the liquid velocity vectors 1 second and 5 seconds after the gas has begun flowing through the bubble column. Distinct paths of liquid movement, primarily along the walls, can be seen at both time points. Due to buoyancy and phase drag forces, the largest liquid velocities coincide with the regions of greatest gas volume fraction. 53 (a) (b) Figure 3.4.2-3: Liquid Velocity Vectors (m/s) After (a) 1 Second and (b) 5 Seconds Figure 3.4.2-4 is a comparison between the gas velocity vectors 1 second and 5 seconds after gas has begun flowing through the bubble column. The white region two-thirds up the bubble column in Figure 3.4.2-4a is a region where the gas has not reached. It is noteworthy that the original gas-liquid interface is not flat but consists of two parabolas. The two parabolas are created because most of the gas travels close to the wall (Figure 3.4.2-2). Figure 3.4.2-4b reveals that the greatest gas velocities occur near the walls which are also the areas of greatest gas volume fraction. Higher gas volume fractions lead to greater buoyancy forces which cause greater gas velocities. A second scenario was analyzed to compare the impact that gas inlet velocity has on gas holdup. This case is the same as the case described in Table 3.4.2-1 except that the gas inlet velocity is increased to 0.10 m/s. Figure 3.4.2-5 illustrates the gas volume fraction 1 second and 5 seconds after gas has begun flowing through the bubble column. Figure 3.4.2-5b reveals that the injected gas causes the water level to rise about 15 cm. This is a much larger increase than the gas holdup shown in Figure 3.4.2-2b, which employs a gas inlet velocity of 0.05 m/s and proves that gas holdup is not proportional to inlet velocity. 54 (a) (b) Figure 3.4.2-4: Gas Velocity Vectors (m/s) After (a) 1 Second and (b) 5 Seconds Figure 3.4.2-5: Gas Volume Fraction (0.10 m/s) After (a) 1 Second and (b) 5 Seconds 55 To ensure that the mesh had no significant effect on the results, a mesh validation was performed on the scenario with a gas velocity of 0.05 m/s. The mesh validation compared the results shown in this section (“Analysis Value” in Table 3.4.2-2) to a second case with an increased number of finite volumes (“Mesh Validation” in Table 3.4.2-2). The results from the mesh validation shown in Table 3.4.2-2 prove that the results are mesh independent. Table 3.4.2-2: Mesh Validation for Bubble Column Model Number of Nodes Number of Elements Max Liquid Velocity (m/s) Average Gas Velocity (m/s) Max Liquid Volume Fraction Max Static Pressure (Pa) 3.4.3 Analysis Value 7006 6750 0.625945 0.313947 0.998733 4929.094 Mesh Validation 8785 8500 0.63157 0.308535 1.00000 4920.58 Difference 25.39 % 25.93 % 0.90 % 1.72 % 0.13 % -0.17 % BUBBLE COLUMN WITH POPULATION BALANCE MODEL The bubble column model created in Section 3.4.2 was expanded to include a population balance model (PBM) with three discrete bubble sizes so that bubble swarm could be tracked. In all gas-liquid flows, the bubbles can increase or decrease in size due to coalescence or breakup. Coalescence occurs when two or more bubbles collide and the liquid barrier between them ruptures to form a larger bubble. Bubbles breakup occurs when a bubble collides with a turbulent eddy approximately equal to its size. Table 3.4.3-1 lists the input used to create the PBM implemented in this section. Figure 3.4.3-1 is a comparison between the gas volume fraction at 1 second and 5 seconds after gas has begun flowing through the bubble column. When comparing Figure 3.4.3-1 to Figure 3.4.2-2, there are noticeable differences. One of the obvious differences between the two figures is the distribution of the gas phase at the two time points. With the population balance model implemented (Figure 3.4.3-1), the gas phase distribution is more uniform and does not contain any areas with large gas volume fractions. This is most noticeable at the bottom of the bubble column after 5 seconds. 56 Table 3.4.3-1: Population Balance Model Input Input Method Number of Bins Bin-0 Bin-1 Bin-2 Bin Distribution Bin-0 Bin-1 Bin-2 Aggregation Kernel Model Surface Tension Breakage Kernel Model Surface Tension Formulation Value Discrete 3 0.0075595 m 0.0047622 m 0.0030000 m 25 % 50 % 25 % Luo 0.072 N/m Luo 0.072 N/m Hagesather (a) (b) Figure 3.4.3-1: Gas Volume Fraction with PBM After (a) 1 Second and (b) 5 Seconds 57 Figure 3.4.3-2 is a comparison between the liquid velocity vectors at 1 second and 5 seconds after gas has begun flowing through the bubble column. Figure 3.4.3-2b reveals that the liquid velocity increases as elevation increases. This is less noticeable in Figure 3.4.2-3 which displays a more uniform overall liquid velocity. Table 3.4.3-1 shows that there is an increase in the number of large bubbles at the outlet compared to the inlet in Figure 3.4.3-2b. The larger bubbles attain higher velocities due to greater buoyancy forces which in turn increases the liquid velocity due to drag between the two phases. The velocity gradient in Figure 3.4.2-3 is more uniform because the bubbles do not coalesce and therefore remain at a constant diameter. (a) (b) Figure 3.4.3-2: Liquid Velocity Vectors with PBM (m/s) After (a) 1 Second and (b) 5 Seconds The population balance model calculates the bubble size distribution at each axial height using the Luo breakup and coalescence model. Table 3.4.3-2 shows the bubble size population distribution at the inlet and outlet of the bubble column. This table shows that there is a strong bias for the smaller bubbles to coalesce into larger bubbles; thus, surface tension is a strong driver to reduce surface area and there is very little turbulence within the column to cause the bubbles to break apart. 58 Table 3.4.3-2: Bubble Size Distribution – Surface Tension of 0.072 N/m Inlet (Fraction) 0.250 0.500 0.250 Bin-0 (0.0076 m) Bin-1 (0.0048 m) Bin-2 (0.0030 m) Outlet (Fraction) 0.865 0.117 0.018 Net (Fraction) +0.615 -0.383 -0.232 Figure 3.4.3-3 is a comparison between the gas velocity vectors at 1 second and 5 seconds after gas has begun flowing through the bubble column. Similar to Figure 3.4.2-4, the shape of the gas as it initially climbs the bubble column is made up of two adjacent parabolas; however, it is much more severe in Figure 3.4.3-3a. Figure 3.4.3-3b shows a uniform gas velocity distribution throughout the entire bubble column. This is different from Figure 3.4.2-4b which illustrated large gas velocities along the wall and smaller gas velocities in the center. (a) (b) Figure 3.4.3-3: Liquid Velocity Vectors with PBM (m/s) After (a) 1 Second and (b) 5 Seconds 59 The impact that surface tension has on bubble size distribution was evaluated by reducing the surface tension by a factor of ten to 0.0072 N/m. Table 3.4.3-3 displays the bubble size distribution at the inlet and outlet of the bubble column with the reduced surface tension. The smaller surface tension decreases the driving force for bubbles to coalesce and significantly reduces the average bubble diameter. Table 3.4.3-3: Bubble Size Distribution – Surface Tension of 0.0072 N/m Bin-0 (0.0076 m) Bin-1 (0.0048 m) Bin-2 (0.0030 m) 3.5 BOILING FLOWS 3.5.1 POOL BOILING Inlet (Fraction) 0.250 0.500 0.250 Outlet (Fraction) 0.495 0.335 0.170 Net (Fraction) +0.245 -0.165 -0.080 Pool boiling occurs when a liquid transforms to a vapor due to energy absorption in a fluid that is stagnant. When the surface temperature of the heated surface sufficiently exceeds the saturation temperature of the liquid, vapor bubbles nucleate on the heated surface. The bubbles grow on the surface until they detach and move out into the bulk liquid. While rising is the result of buoyancy, the bubbles either collapse or continue to grow depending upon whether the liquid is locally subcooled or saturated. Pool boiling involves complex fluid motions initiated and maintained by the nucleation, growth, departure and collapse of bubbles, and by natural convection. [11] Figure 3.5.1-1 shows a schematic representation of the geometry and important boundary conditions used to model pool boiling. The top line of the rectangle is a pressure outlet and the bottom wall of the rectangle is the heated surface. The left and right lines of the rectangle represent no slip walls. See Table 3.5.1-1 for a more detailed list of input parameters used in this section. 60 Figure 3.5.1-1: Pool Boiling Schematic Table 3.5.1-1: Pool Boiling Model Input Input Value Geometry Column Width Column Height 2D Space Solver Time Time Step Size Type Velocity Formulation Gravity Models Energy Viscous Multiphase Drag Slip Mass Transfer Initial Conditions Bubble Diameter Initial Fluid Temperature Heater Temperature (Bottom) Backflow Temperature (Top) Backflow Volume Fraction (Top) 61 0.01 m 0.05 m Planar Transient 0.002 s Pressure Based Relative -9.8 m/s2 (Y-direction) Active Laminar Mixture Schiller-Nauman Manninen et al. Evaporation-Condensation 0.0002 m 372 K 383 K 373 K 0 Material Properties (Water) [16] Density Specific Heat Thermal Conductivity Viscosity Heat of Vaporization Material Properties (Vapor) [16] Density Specific Heat Viscosity Thermal Conductivity Surface Tension Solution Methods Scheme Gradient Pressure Momentum Volume Fraction Energy Transient Formulation See Table 3.5.1-2 4182 J/kg-K 0.6 W/m-K 0.001003 kg/m-s 2.418379E+08 J/kgmol 0.5542 kg/m3 2014 J/kg-K 1.34E-05 kg/m-s 0.0261 W/m-K 0.072 N/m PISO Least Square Cell Based Body Force Weighted Second Order Upwind QUICK Second Order Upwind Second Order Implicit Table 3.5.1-2: Pool Boiling Model Water Density Density (kg/m3) 974.9 958.4 Temperature (K) 348 373.15 Figure 3.5.1-2 displays the instantaneous gas volume fraction after 0.9 seconds and 1.7 seconds of heating. The first time point was chosen because it shows steam releasing from the heated surface and entering the bulk fluid which is the driving force behind all fluid motion. The second time point was chosen because it reveals the interaction between the liquid and vapor at a high level. The evolution of the steam generation, upward movement (due to buoyancy) and liquid refill is illustrated in Figure 3.5.1-2 through Figure 3.5.1-4. Figure 3.5.1-2a indicates that the bottom of the control volume is heated and some vapor has formed (two areas of significant steam generation are in green). Figure 3.5.1-2b shows that the vapor has moved upward (teal region) and that the liquid has moved downward to take its place (blue area at the bottom). 62 (a) (b) Figure 3.5.1-2: Instantaneous Gas Volume Fraction After (a) 0.9 Seconds and (b) 1.7 Seconds Figure 3.5.1-3 and Figure 3.5.1-4 display the liquid and gas velocities, respectively, at the two time points. Comparing these two figures indicates that the largest upward liquid and vapor velocities occur in generally the same regions. These regions also coincide with the areas of largest gas volume fraction (Figure 3.5.1-2). As vapor forms on the heated surface, it eventually detaches and enters the liquid above. Due to buoyancy, the vapor travels upward through the liquid. Drag forces between the two phases cause the liquid to also travel upwards but at a slower rate due to slip. Other areas of high liquid velocity occur between the two swells of upward moving vapor and along the walls. The liquid being of greater density flows downward to refill the void created by the steam. 63 (a) (b) Figure 3.5.1-3: Liquid Velocity Vectors (m/s) After (a) 0.9 Seconds and (b) 1.7 Seconds (a) (b) Figure 3.5.1-4: Gas Velocity Vectors (m/s) After (a) 0.9 Seconds and (b) 1.7 Seconds 64 Figure 3.5.1-5 shows the volume fraction of vapor on the heated surface after 2 seconds. The figure illustrates that vapor is produced significantly at two locations (vapor volume fraction is at a maximum), 0.0008 m and 0.0095 m. In this situation 0.00 m is the left wall and 0.01 m is the right wall. The vapor volume fraction is at a minimum at approximately 0.005 m which is where liquid is taking the place of the recently created vapor. Figure 3.5.1-5: Volume Fraction of Vapor on Heated Surface To ensure that the mesh had no significant effect on the results, a mesh validation was performed. The mesh validation compared the results shown in this section (“Analysis Value” in Table 3.5.1-3) to a second case with an increased number of finite volumes (“Mesh Validation” in Table 3.5.1-3). The results from the mesh validation shown in Table 3.5.1-3 prove that the results are mesh independent. Table 3.5.1-3: Mesh Validation for Pool Boiling Model Number of Nodes Number of Elements Min Mixture Density (kg/m3) Max Mixture Velocity (m/s) Min Liquid Volume Fraction Max Static Pressure (Pa) Max Phase Transfer (kg/m3-s) Analysis Value 26645 26208 754.389 0.059396 0.787011 452.2354 2.169675 65 Mesh Validation 32481 32000 742.115 0.062788 0.774197 452.2388 2.190905 Difference 21.90% 22.10% -1.63% 5.71% -1.63% 0.00% 0.98% 3.5.2 SUBCOOLED FLOW BOILING Subcooled flow boiling occurs when a moving, under-saturated fluid comes in contact with a surface that is hotter than its saturation temperature. It involves intense interactions between the liquid and vapor phases and therefore modeling can be a challenge. The Eulerian multiphase model is most appropriate for subcooled boiling because it is capable of modeling multiple separate, yet interacting phases. When modeling subcooled boiling, there are three parameters of great importance. These parameters are active nucleation site density (Na), departing bubble diameter (dbw) and bubble departure frequency (f) [1]. As discussed previously, nucleation sites are preferential locations where vapor tends to form. They are usually cavities or irregularities in a heated surface. However, not all sites are active and the number of nucleation sites per unit area is dependent on fluid and surface conditions. The most common active nucleation site density relationship was developed by Lemmert and Chwala. It is based on the heat flux partitioning data generated by Del Valle and Kenning [1]: ππ = [π(ππ ππ‘ − ππ€ )]π According to Kurul and Podowski, the values of m and n are 210 and 1.805, respectively. Another popular correlation for nucleation site density was created by Kocamustafaogullari and Ishii. They assumed that the active nucleation site density correlation developed for pool boiling could be used in forced convective system if the effective superheat was used rather than the actual wall superheat. This correlation accounts for both the heated surface conditions and the fluid properties and can be written as [1]: ππ = 1 [ −4.4 2πππ ππ‘ 2 πππ€ βππππ ππ βππ ] π(π∗ ) π(π∗ ) = 2.157 ∗ 10−7 ∗ π∗−3.2 ∗ (1 + 0.0049π∗ ) π∗ = ( ππ −ππ 66 ππ ) where dbw is the lift off bubble diameter σ is the surface tension Tsat is the fluid saturation temperature ΔTeff = SΔTw ΔTw = Tsat - Twall S is the suppression factor ρl is the liquid density ρg is the gas density hfg is the latent heat of vaporization The departing bubble diameter is the bubble size when it leaves the heated surface and depends in a complex manner on the amount of subcooling, the flow rate and a balance of surface tension and buoyancy forces. Determining the lift off bubble diameter is crucial because the bubble size influences the interphase heat and mass transfer through the interfacial area and the momentum drag terms. Many correlations have been proposed for this purpose; however, the following three are applicable for low pressure, subcooled flow boiling. The first correlation was proposed by Tolubinsky and Kostanchuk. It establishes the bubble departure diameter as a function of the subcooling temperature [1]: πππ€ = πππ [0.0006 ∗ exp (− ππ π’π 45 ) ; 0.00014] The second correlation was created on the basis of the balance between the buoyancy and surface tension forces at the heated surface. Kocamustafaogullari and Ishii modified an expression by Fritz that involved the contact angle of the bubble [1]: πππ€ = 2.5 ∗ 10−5 ( ππ − ππ π ) π√ ππ π ∗ (ππ − ππ ) A third, more comprehensive correlation was proposed by Unal which includes the effect of subcooling, the convection velocity and the heater wall properties [1]: πππ€ = 2.42 ∗ 10−5 ∗ π0.709 ∗ π √ππ· 67 Where π= (ππ€ − βππ π’π )1/3 ππ 2πΆ 1/3 βππ √πππ ⁄ππ πππ ππ πΆ= √ ππ€ ππ€ πππ€ ππ π’π ;π = ππ ππ πππ 2[1 − (ππ − ππ )] βππ ππ [πππ ⁄(0.013βππ ππ 1.7 )] 3 π √π(π − π ) π π (π’π ) 0.47 πππ π’π ≥ 0.61 π/π Φ = {0.61 1.0 πππ π’π < 0.61 π/π The bubble departure frequency is the rate at which bubbles are generated and detach at an active nucleation site and it is dependent on heat flux and a combination of buoyancy and drag forces. The most common bubble departure frequency correlation for computational fluid dynamics was developed by Cole. It is derived from the bubble departure diameter and a balance between buoyancy and drag forces [1]: π=√ 4π(ππ − ππ ) 3ππ πππ€ The heat transfer rate from the wall to the fluid greatly impacts the number of active nucleation sites, bubble diameter and bubble departure frequency. The amount of energy transferred to the fluid changes based on the amount of vapor on the heated surface. Since the vapor area is constantly changing due to the formation, growth and departure of bubbles, the use of a correlation is necessary. Del Valle and Kenning created a mechanistic model to determine the area of the heated surface influenced by vapor during flow boiling which can be utilized in Fluent. Figure 3.5.2-1 shows a schematic representation of the geometry and important boundary conditions used to model subcooled flow boiling. The bottom line of the rectangle is an axis of rotation which is used to simplify the geometry and represents the pipe centerline. The top line of the rectangle is the heated surface and after the rotation becomes the pipe wall. The left and right lines of the rectangle are the inlet and outlet 68 areas respectively, which when revolved, are circular. See Table 3.5.2-1 for a more detailed list of input parameters used in this section. Figure 3.5.2-1: Subcooled Flow Boiling Model Schematic Table 3.5.2-1: Subcooled Flow Boiling Model Input Input Geometry Pipe Diameter Pipe Length 2D Space Solver Time Type Velocity Formulation Gravity Models Energy Viscous Near Wall Treatment Turbulent Intensity Multiphase Drag Lift Heat Transfer Mass Transfer Correlations Interfacial Area Bubble Diameter Initial Conditions Mass Flow Rate Inlet Fluid Temperature Wall Heat Flux 69 Value 0.03 m 0.50 m Axisymmetric Steady Pressure Based Relative -9.8 m/s2 (X-direction) Active Realizable k-Ο΅ Enhanced 4.2079 % * Eulerian Schiller-Nauman Boiling-Moraga Ranz-Marshall RPI Boiling See Table 3.5.2-3 Ia-Symmetric Sauter-Mean 0.3 kg/s 370 K 90000 W/m2 Material Properties (Water) [16] Density See Table 3.5.2-2 Specific Heat See Table 3.5.2-2 Thermal Conductivity See Table 3.5.2-2 Viscosity See Table 3.5.2-2 Heat of Vaporization See Table 3.5.2-2 Material Properties (Vapor) [16] Density 0.5542 kg/m3 Viscosity 1.34E-05 kg/m-s Thermal Conductivity 0.0261 W/m-K Surface Tension 0.072 N/m Solution Methods Scheme Coupled Gradient Least Square Cell Based Momentum Second Order Upwind Volume Fraction QUICK Turbulent Kinetic Energy Second Order Upwind Turbulent Dissipation Rate Second Order Upwind Energy Second Order Upwind * Calculated using equations from Table 2.5.1-2. Table 3.5.2-2: Subcooled Flow Boiling Model Water Properties 368 K 370 K 373.15 K* Density (kg/m ) 961.99 960.59 958.46 Specific Heat (J/kg-K) 4210.0 4212.1 4215.5 Viscosity (kg/m-s) 0.0002978 0.0002914 0.0002822 Conductivity (W/m-K) 0.6773 0.6780 0.6790 Heat of Vaporization (J/kgmol) N/A N/A 40622346 Surface Tension (N/m) N/A N/A 0.0589 * Saturation temperature at atmospheric pressure (14.7 psia). 3 Boiling Model Study The impact that each boiling model has on liquid volume fraction was investigated by analyzing a set of cases that implemented the inputs listed in Table 3.5.2-1 and Table 3.5.2-3. Based on the modeling options in Fluent, six combinations were possible. The liquid volume fraction at different axial locations and the values of average liquid volume fraction among cases were compared. 70 Table 3.5.2-3: Boiling Model Study Case Input Case Number 1 2 3 4 5 6 Bubble Departure Diameter Model Tolubinski-Kostanchuk KocamustafaogullariIshii Unal Tolubinski-Kostanchuk KocamustafaogullariIshii Unal Nucleation Site Density Model Lemmert-Chawla Lemmert-Chawla Frequency of Bubble Departure Model Cole Cole Lemmert-Chawla KocamustafaogullariIshii KocamustafaogullariIshii KocamustafaogullariIshii Cole Cole Cole Cole Plots of temperature, liquid volume fraction and mass transfer rate for Case 1 are shown in Figures 3.5.2-2, 3.5.2-3 and 3.5.2-4, respectively. Although these figures are specific to Case 1, their trends can be applied to all of the subcooled flow boiling cases analyzed. Figure 3.5.2-2 displays how the liquid temperature increases as the fluid travels down the pipe. The maximum bulk liquid temperature is about 373 K which is also the fluid saturation temperature. Figure 3.5.2-2: Case 1 - Temperature (K) Figure 3.5.2-3 reveals how that the liquid volume fraction decreases as the fluid travels down the pipe. The large reduction in liquid volume fraction is caused by energy transfer from the walls and the small amount of liquid subcooling at the pipe entrance. Figure 3.5.2-3: Case 1 - Liquid Volume Fraction 71 Figure 3.5.2-4 is of particular interest because it shows both the generation and destruction of steam bubbles. The light blue and teal areas next to the heated wall depicts that steam is being generated. After the bubbles grow in size they detach and join the bulk fluid. A small distance towards the pipe centerline away from the heated wall is a dark blue region. In this region, the steam bubbles lose energy to the surrounding subcooled liquid and condense back into liquid. The generation and destruction of steam bubbles is characteristic of subcooled flow boiling. Figure 3.5.2-4: Case 1 - Mass Transfer Rate (kg/m3-s) The volume-weighted average liquid volume fraction of the entire control volume for the six cases described in Table 3.5.2-3 is shown in Table 3.5.2-4. Case 4 predicted the largest liquid volume fraction while Case 2 predicted the smallest liquid volume fraction; however, the difference between the two cases is only about 1.6%. Therefore, the choice of boiling model seems to have only a small impact on the overall liquid volume fraction for the conditions examined. The results also show that the Kocamustafaogullari-Ishii nucleation site density model tends to predict a greater liquid volume fraction, meaning less vapor production, than the Lemmert-Chawla nucleation site density model. Cases 4 through 6 have a smaller liquid volume fraction range (0.9124 to 0.9165) than Cases 1 through 3 (0.9003 to 0.9108). This means that when the Kocamustafaogullari-Ishii nucleation site density model is employed, the choice of the bubble departure diameter model has less of an impact on liquid volume fraction than if the Lemmert-Chawla nucleation site density model is employed. Comparing the results from a bubble departure diameter model perspective reveals that there is no tendency any of the three models examined to predict a larger or smaller liquid volume fraction. Thus, the nucleation site density model has a greater impact on liquid volume fraction than the bubble departure diameter model. 72 (a) Case 1 (b) Case 2 (c) Case 3 (d) Case 4 (e) Case 5 (f) Case 6 Figure 3.5.2-5: Liquid Volume Faction for Cases 1-6 73 Table 3.5.2-4: Boiling Model Study Case Results Case Number 1 2 3 4 5 6 Volume-Weighted Liquid Volume Fraction 0.91078539 0.90031346 0.90856631 0.91649488 0.91612881 0.91241595 Figure 3.5.2-5 shows the liquid volume fraction at nine axial heights as a function of distance from the pipe center for the six cases described in Table 3.5.2-3. The x-axis is position, or distance from the centerline and the pipe wall is located at 0.015 m. Although Table 3.5.2-4 indicates that the models predict similar liquid volume fractions within the entire control volume, Figure 3.5.2-5 illustrates that there are noticeable differences. First, there are significantly higher liquid volume fraction near the pipe inlet (0 to 10 cm) in Cases 4 through 6 compared to Cases 1 through 3. Therefore, vapor formation using the Kocamustafaogullari-Ishii nucleation site density model requires more energy addition. Second, the liquid volume fraction 0.008 m from the pipe centerline is significantly less in Cases 1 through 3 than in Cases 4 through 6. This is due to the smaller vapor production rate at the pipe wall in Cases 1 through 3. Initial Conditions Study A second parametric study using the subcooled boiling model described in Table 3.5.2-1 was used to determine how inlet temperature, mass flow and heat flux impact liquid volume fraction. Six additional cases were analyzed in total as part of this parametric study. For this set of cases, the active nucleation site density is determined using the Lemmert and Chwala correlation, the bubble departure diameter is determined using the Tolubinsky and Kostanchuk correlation and the bubble departure frequency is determined using the Cole correlation. Case 1 from the boiling model study is used as the nominal case to which the other six cases are compared. Cases 7 through 12 increase or decrease the heat flux, the inlet temperature or the mass flow rate relative to the Case 1 value. The input for the cases analyzed is documented in Table 3.5.2-5. 74 Table 3.5.2-5: Initial Conditions Study Case Input Case Number Inlet Temperature (K) 370 370 370 372 368 370 370 1 (base) 7 8 9 10 11 12 Mass Flow (kg/s) 0.30 0.30 0.30 0.30 0.30 0.33 0.27 Heat Flux (kW/m2) 90 100 80 90 90 90 90 The volume-weighted average liquid volume fraction of the entire control volume for the seven cases described in Table 3.5.2-5 is displayed in Table 3.5.2-6. Table 3.5.2-6 shows that the maximum and minimum liquid volume fractions occur in Case 9 and Case 10 (inlet temperature variation cases), respectively. The significant impact that inlet temperature has on liquid volume fraction can be attributed to the large specific heat of water (4212 J/kg-K). If the specific heat was smaller, the difference in liquid volume fraction between these two cases and the base case would be less. The large specific heat value of water is one reason why it is commonly used in energy conversion cycles. Comparing the three cases that cause a decrease in liquid volume fraction from the base case (Cases 7, 9 and 12) to the three cases that cause an increase in liquid volume fraction from the base case (Cases 8, 10 and 11) demonstrates that the liquid volume fraction decreases more than it increases for the same delta change in initial conditions. Changes in initial condition near the saturation point will have a larger impact on liquid volume fraction than changes in initial conditions farther away from the saturation point. Therefore, the initial conditions do not linearly impact liquid volume fraction. Table 3.5.2-6: Initial Condition Study Case Results Case Number 1 7 8 9 10 11 12 Volume-Weighted Liquid Volume Fraction 0.91078539 0.87799626 0.93408281 0.57124303 0.96969908 0.92067945 0.89072032 75 Table 3.5.2-7 shows the liquid volume fraction at nine axial locations for the cases described in Table 3.5.2-5. This table allows for a finer comparison of the liquid volume fraction between the cases. Table 3.5.2-7 does not show any irregular trends in liquid volume fraction and the same relationships between initial conditions and liquid volume fraction developed using Table 3.5.2-6 can be drawn using Table 3.5.2-7. Thus making observations based on overall liquid volume fraction is acceptable. Table 3.5.2-7: Axial Location Liquid Volume Fraction Location* Case 1 Case 7 Case 8 0 cm 1.00000 1.00000 1.00000 5 cm 0.99168 0.98880 0.99397 10 cm 0.97680 0.97050 0.98231 15 cm 0.96151 0.95036 0.97201 20 cm 0.93987 0.92220 0.95598 25 cm 0.91595 0.89812 0.93589 30 cm 0.89784 0.87830 0.91644 35 cm 0.88190 0.85540 0.90250 40 cm 0.85984 0.80840 0.89019 * Distance from the pipe inlet. Case 9 1.00000 0.95129 0.87624 0.80165 0.71266 0.57694 0.42719 0.31823 0.25132 Case 10 1.00000 0.99785 0.99390 0.98885 0.98427 0.97895 0.96784 0.95471 0.93927 Case 11 1.00000 0.99348 0.97938 0.96537 0.94748 0.92264 0.90098 0.88448 0.86812 Case 12 1.00000 0.98907 0.97482 0.95578 0.93222 0.91180 0.89572 0.87680 0.83296 Figure 3.5.2-6 illustrates the liquid volume fraction at different axial locations in Table 3.5.2-6 with respect to distance from the centerline. The x-axis is position, or distance from the centerline and the pipe wall is located at 0.015 m. The impact that inlet temperature (Case 9 and Case 10) has on liquid volume fraction is extremely visible in Figure 3.5.2-6. Case 9 shows significant voiding in the centerline after 25 cm from the pipe inlet due to the high inlet temperature (subcooling of about 1 K). Case 10 reveals the opposite where 40 cm from the pipe inlet there is no voiding even at 0.010 m from the pipe centerline. 76 (a) Case 7 (b) Case 8 (c) Case 9 (d) Case 10 (e) Case 11 (f) Case 12 Figure 3.5.2-6: Liquid Volume Faction for Cases 7-12 77 The liquid volume fraction at the nine axial locations from Cases 7 through 12 were compared to the liquid volume fraction of the base case (Case 1) using the following three equations for heat flux, inlet temperature and mass flow, respectively, where i stands for the axial location. β(ππππ πΉππππ‘πππ) πΆππ π ππππ πΉππππ‘ππππ − π΅ππ π ππππ πΉππππ‘ππππ = β(π»πππ‘ πΉππ’π₯) πΆππ π π»πππ‘ πΉππ’π₯π − π΅ππ π π»πππ‘ πΉππ’π₯π β(ππππ πΉππππ‘πππ) πΆππ π ππππ πΉππππ‘ππππ − π΅ππ π ππππ πΉππππ‘ππππ = β(πΌππππ‘ ππππ. ) πΆππ π πΌππππ‘ ππππ.π − π΅ππ π πΌππππ‘ ππππ.π β(ππππ πΉππππ‘πππ) πΆππ π ππππ πΉππππ‘ππππ − π΅ππ π ππππ πΉππππ‘ππππ = β(πππ π πΉπππ€) πΆππ π πππ π πΉπππ€π − π΅ππ π πππ π πΉπππ€π The results of comparing the values from Table 3.5.2-7 using the three above equations are shown in Table 3.5.2-8. For example, at an axial height of 10 cm, by increasing the heat flux from 90 kW/m2 to 100 kW/m2 (Case 1 to Case 7) the liquid volume fraction decreased by 0.0063 or 0.00063 per kW/m2. Similar calculations were carried out for the remaining axial locations and initial conditions. The change in liquid volume fraction at each axial location was averaged to produce an overall impact that each initial conditions on liquid volume fraction. Table 3.5.2-8: Absolute Impact on Liquid Volume Fraction Height 0 cm 5 cm 10 cm 15 cm 20 cm 25 cm 30 cm 35 cm 40 cm Average Case 7 Case 8 0.00000 0.00000 -0.00029 -0.00023 -0.00063 -0.00055 -0.00112 -0.00105 -0.00177 -0.00161 -0.00178 -0.00199 -0.00195 -0.00186 -0.00265 -0.00206 -0.00514 -0.00304 -0.00154 (kW/m2)-1 Case 9 Case 10 0.00000 0.00000 -0.02020 -0.00309 -0.05028 -0.00855 -0.07993 -0.01367 -0.11361 -0.02220 -0.16951 -0.03150 -0.23533 -0.03500 -0.28184 -0.03641 -0.30426 -0.03972 -0.08028 (K)-1 78 Case 11 Case 12 0.00000 0.00000 0.06000 0.08700 0.08600 0.06600 0.12867 0.19100 0.25367 0.25500 0.22300 0.13833 0.10467 0.07067 0.08600 0.17000 0.27600 0.89600 0.17178 (kg/s)-1 Table 3.5.2-8 reveals the average impact that changing the heat flux, inlet temperature and mass flow rate have on the overall liquid volume fraction. Evaluating which of the three inputs is most impactful on liquid volume fraction is difficult to do in absolute terms (a 1 kg/s increase in mass flow rate is a larger percentage increase than a 10 kW/m2 increase in heat flux). Therefore, the values in Table 3.5.2-8 were compared on a percentage basis to provide further insight. Table 3.5.2-9 shows the liquid volume fraction change expected for a 1% change in each initial condition. The second column of Table 3.5.2-9 repeats the initial conditions used in Case 1 (from Table 3.5.2-1), the third column calculates 1% of the Case 1 input value (for example, 90 kW/m2 * 0.01 = 0.9 kW/m2), the fourth column replicates the results from Table 3.5.2-8, and the fifth column shows the outcome when columns three and four are multiplied together. Table 3.5.2-9: Relative Impact on Liquid Volume Fraction Initial Condition Heat Flux Temperature Mass Flow Case 1 Input 90 kW/m2 370 K 0.3 kg/s 1% of Case 1 Table 3.5.2-8 Input Results 2 0.9 kW/m -0.00154 (kW/m2)-1 3.70 K -0.08028 (K)-1 0.003 kg/s 0.17178 (kg/s)-1 Equivalent Liquid Volume Fraction -0.00139 -0.29704 0.00052 Table 3.5.2-9 illustrates that a 1% increase in heat flux causes the average liquid void fraction to decrease by 0.00139, a 1% increase in temperature causes the average liquid void fraction to decrease by 0.29704 and a 1% increase in mass flow rate causes the average liquid void fraction to increase by 0.00052. It is understood that a 1% increase in the inlet temperature from the Case 1 condition would be greater than the saturation temperature at atmospheric pressure and therefore impossible; however, this exercise was performed to show the impact of the initial conditions in a more revealing manner. Table 3.5.2-9 indicates that inlet temperature has the greatest impact on liquid volume fraction, the wall heat flux has the second greatest impact and mass flow rate has the smallest impact. To ensure that the mesh had no significant effect on the results, a mesh validation was performed. The mesh validation compared the results shown in this section (“Analysis Value” in Table 3.5.2-10) to a second case with an increased number of finite 79 volumes (“Mesh Validation” in Table 3.5.2-10). The results from the mesh validation shown in Table 3.5.2-10 prove that the results are mesh independent. Table 3.5.2-10: Mesh Validation for Subcooled Boiling Model Number of Nodes Number of Elements Max Liquid Velocity (m/s) Max Gas Velocity (m/s) Min Liquid Volume Fraction Max Phase Transfer (kg/m3-s) Analysis Value 25000 23976 0.8181624 0.9972627 0.4876771 24.87638 80 Mesh Validation 31000 29970 0.8199201 0.9982293 0.4853158 26.22442 Difference 24.00 % 25.00 % 0.21 % 0.10 % -0.48 % 5.42 % 4. DISUSSION AND CONCLUSIONS This thesis provided theoretical background and development of computational fluid dynamic models for various fluid flow and heat transfer phenomena including natural convection, laminar flow, turbulent flow with and without heat transfer, twophase flow, pool boiling and subcooled flow boiling. Natural convection models of a heated horizontal cylinder and a heated vertical plate were presented in Section 3.1. These models implemented the Boussineq approximation to calculate temperature induced density gradients and buoyancy forces. The heated horizontal cylinder model predicted a greater maximum velocity compared to the heated vertical plate even though the two models used the same surface and bulk fluid temperatures. The heated vertical plate had a lower maximum velocity due to drag forces invoked by the heated surface. Both natural convection models showed good agreement qualitatively and quantitatively with experimental data. Laminar flow within a pipe was investigated in Section 3.2. The parabolic velocity profile that is characteristic of laminar flow matched well qualitatively with experimental data. Also, the radial velocity for most of the pipe was near zero and was less than 10-3 times the average axial velocity. Two models involving turbulent flow within a pipe were created as part of Section 3.3. As expected, the velocity profiles calculated where flat and the velocity magnitude didn’t decrease until very close to the pipe wall which matched well qualitatively with experimental data. The wall shear stress reached a maximum at a short distance from the pipe inlet due to entrance effects causing a surge in radial velocity which led to a dramatic reduction in axial velocity. The turbulent flow model with the energy equation was compared to the turbulent flow model without energy addition and it was determined that there was a small increase in the fluid velocity magnitude for the scenario with heat addition. The velocity increase was due to the constant mass flow rate boundary condition and the reduction in density caused by energy addition. Two-phase flow involving water and air was examined as part of Section 3.4. The first model was a mixing tank that used an air jet to stir the liquid. Effects of 81 Rayleigh instability were observed. Before the jet broke the surface of the water, it became wavy and surface tension started to transform the jet into bubbles to reduce surface area. The second model created was a bubble column reactor. XXXXXXX was observed to occur. Gas holdup due to phase drag forces and displacement was noted. The amount of gas holdup was found to be related to inlet gas velocity however the relationship was not linear. A population balance model was employed for two bubble column cases. The model predicted that the air bubbles would coalesce and grow in size as they traveled up the bubble column due to surface tension. When the surface tension was reduced, the number of bubbles that grew in size dramatically reduced. Section 3.5 discussed phase transformation due to heat addition in both stagnant and flowing liquids. The pool boiling model showed the progression of vapor formation on the heated surface, detachment and liquid refill. Drag forces between the two phases caused the liquid to travel upwards with the rising vapor but at a slower rate due to slip. The second phase transformation model developed and the focus of this research was a subcooled flow boiling model. The impact that different boiling model options have on liquid volume fraction was investigated. Three bubble departure diameter models and two nucleation site density models were analyzed using the same initial conditions. The bubble departure diameter models did not show any relationship with liquid volume fraction; however, the Kocamustafaogullari-Ishii nucleation site density model tended to predict a greater liquid volume fraction, meaning less vapor production, than the Lemmert-Chawla nucleation site density model. A second study on how initial conditions impact the liquid volume fraction during subcooled flow boiling was explored. The initial conditions of heat flux, inlet temperature and mass flow rate were increased or decreased relative to a base case value. The difference in liquid volume fraction between scenarios was compared and relationships relating the initial conditions with respect to liquid volume fraction were developed. Overall, the inlet temperature had the greatest impact on liquid volume fraction, the wall heat flux had the second greatest impact and mass flow rate had the smallest impact. 82 REFERENCES 1. Yeoh, G. H; Tu, J. Y., “Modelling Subcooled Boiling Flows,” Nova Science Publishers, Inc., 2009. 2. Krepper, E.; Koncar, B.; Egorov, Y., “CFD Modeling of Subcooled Boiling – Concept, Validation and Application to Fuel Assembly Design,” Elsevier B.V., 2006. 3. Bird, R. B., Steward, W. E., Lightfoot, E. N., “Transport Phenomenon,” Wiley & Sons Inc., 2nd Edition, 2007. 4. Patankar, S. V., “Numerical Heat Transfer and Fluid Flow,” Hemisphere Publishing Co., 1st Edition, 1980. 5. Kays, W.; Crawford, M.; Bernhard, W., “Convective Heat and Mass Transfer,” McGraw-Hill, 4th Edition, 2005. 6. Incropera, DeWitt, Bergman, Levine, “Introduction to Heat Transfer,” Wiley & Sons Inc., 5th Edition, 2007. 7. Tennekes, H; Lumley, J. L., “A First Course in Turbulence,” The MIT Press, 1972. 8. McGraw-Hill Encyclopedia of Science and Technology, “Chaos,” The McGrawHill Companies, Inc., 2005. 9. ANSYS, Inc., “ANSYS Fluent 14.0 Theory Guide,” 2012. 10. Harlow, F. H.; Nakayama, P. I., “Transport of Turbulence Energy Decay Rate,” Los Alamos Science Laboratory, LA-3854, 1968. 11. Tong, L. S. “Boiling Heat Transfer and Two-Phase Flow,” Wiley & Sons Inc., 2nd Edition, 1965. 83 12. Faghri, A.; Zhang, Y.; Howell, J., “Advanced Heat and Mass Transfer,” Global Digital Press, 2010. 13. Eckert, E. R. G., “Introduction to the Transfer of Heat and Mass,” 1st Edition, 1950. 14. Ingham, D. B., “Free-Convection Boundary Layer on an Isothermal Horizontal Cylinder,” Journal of Applied Mathematics and Physics, Vol. 29, 1978. 15. Ostrach, S., “An Analysis of Laminar Free-Convection Flow and Heat Transfer About a Flat Plate Parallel to the Direction of the Generating Body Force,” Report 1111 – National Advisory Committee for Aeronautics. 16. NIST/ASME Steam Properties, Database 10, Version 2.11, 1996. 84