Chapter 14 - Energy Resources Many of our energy resources originate from geologic processes. Oil, gas, coal, and the fuel for atomic power plants all comes from rocks. Geothermal energy originates in the heat generated by internal Earth processes. Wind and water power involve the movement of wind and water involves cycles in the Earth’s system. There are five fundamental sources of energy in the Earth system: (1) solar energy in the form of electromagnetic radiation, (2) gravitational energy, (3) nuclear fission reactions, (4) stored energy in the Earth’s interior, (5) energy in the form of chemical bonds in compounds Usable energy resources: * solar energy * gravitational energy that drives the tides * energy involving both solar energy and gravity. Wind, which powers wind turbines, is a result of convective air movement as radiation heats the air causing it to rise and gravity causes cooler air to sink. Solar energy evaporates water which then falls as rain and restores surface and subsurface water reservoirs. Moving water can power hydroelectric power plants. * geothermal energy comes from the Earth’s internal energy sources including radioactive decay * energy from nuclear fission - during fission, a tiny amount of mass transforms into a large amount of energy * photosynthetic energy - green plants absorb solar energy which powers the photosynthetic process and the manufacture of food energy * energy from chemical reactions - some inorganic chemical compounds can burn to produce light and energy * fossil fuel energy - oil, gas and coal comes from the stored solar energy captured by organisms that lived long ago The increase in energy usage for the past 150 yrs. Wood was the main energy source in 1850. Hydrocarbons are the main energy source now. Oil and gas are organic chemical hydrocarbons composed of chain-like molecules of carbon and hydrogen. The viscosity and volatility of a hydrocarbon depends on its molecular size. Short-chain molecules tend to be less viscous and more volatile (ex. natural gas). Hydrocarbons, like wood, can burn to release carbon dioxide, water and heat. The primary sources of the organic chemicals in oil and gas come from plankton and algae. When algae and plankton die, they sink to the bottom of a lake or sea and mix with clay particles to create a muddy ooze. Eventually, layer after layer of sediment gets deposited on the lake bed and bcomes lithified to black organic shale. This shale is referred to as a source rock.When the buried shale reaches 100oC, chemical reactions occurring over millions of years transform it into kerogen > then into a mixture of oil, tar, and gas. Hydrocarbon reserves only exist within the top 15-20% of the crust. Shale containing kerogen is called oil shale. At temperatures > 160oC, the oil breaks down to form natural gas and at temperatures > 250oC, the remaining organic matter transforms into graphite. Oil itself only forms within a narrow temperature range called the oil window. An oil field is a region that contains a significant amount of oil. The known supply of oil in an area is known as an oil reserve. The development of an oil reserve requires a source rock, a reservoir rock, and a trap.The largest known oil reserves are in the region surrounding the Persian Gulf. To be a reservoir rock, a rock must have high porosity and permeability. Porosity refers to the amount of open space or pores in a rock. Shale has a porosity of about 10%, sandstone one of 35%. Permeability refers to the way pore spaces connect to one another. In an oil well, oil flows from the permeable reservoir rock into the well and then up to the ground surface, usually assisted by pumping. Oil resides in the source rock. Oil migrates upward to be trapped by the seal rock. Traps and seals Oil and gas must be trapped underground to be available for pumping. An oil trap is a geologic configuration that allows oil and gas to be trapped. A seal rock is a relatively impermeable rock such as shale, salt, or unfractured limestone. The seal rock and the reservoir rock must be arranged in a geometric configuration that allows the oil to be collected in a restricted area. There are different types of oil-trap geometries. An anticline trap An anticline is a fold with an arched shape. If the folded layers include source, reservoir, and seal rocks, than an oil reserve exists. A salt dome trap A salt dome traps oil because it is impermeable A fault trap A fault trap is a fracture where the slip on the fault created an impermeable layer.The oil collects in tilted strata adjacent to the fault. A stratigraphic trap A tilted reservoir rock bed pinches out between two impermeable layers. Oil collects at the pinch-out. Natural gas is a volatile, short-chain hydrocarbon and includes methane, ethane, propane, and butane. Gas occurs above the oil. If temperatures are very high, gas-only fields develop.Gas burns more cleanly than oil (producing CO2 and H2O). Burning oil produces CO2, H2O and complex organic pollutants. Coal is a sedimentary rock that consists of C, organic chemicals, quartz, and clay. Coal forms from plant material that previously grew in vast coal swamps. American’s use about 1 billion tons of coal/year (~23% of the energy supply). Of course, significant coal supplies could not form until vascular land plants appeared during the late Silurian period, about 420 mya. The most extensive deposits of coal were formed during the Carboniferous period (290-360 mya).The extensive coal deposits during this period reflect the environmental conditions of the time when North America, Asia and Europe straddled the equator and sea levels rose. Plate tectonics influenced the climate of ancient coal swamps, allowing the accumulation of enormous masses of plant material that decayed and were buried to form the large coal deposits of today. In order for coal to form, plant material has to be buried anaerobically (without oxygen) and deeply. Transgression and regressions of the sea level allow the accumulation of many sedimentary layers.The deeply buried layers heat up, driving off volatiles. When C is > 70% of the residue, coal is formed. Organic material buried shallowly in an anaerobic environment becomes peat. Peat contains 50% of the world’s C. Coal formation proceeds from peat > lignite coal > bituminous coal > anthracite. The more volatiles are driven off by compaction and heat, the higher the C content and the higher the coal ranking of the coal formed. Coal can’t exist in metamorphic rocks. The high heat and pressures transform it into graphite. The distribution of coal in North America. The distribution of coal by region. Coal occurs in seams or beds because it is a sedimentary material. To be economic to mine, coal has to be >1 m thick. Strip mining, where soil and rock layers are scraped off to get to the coal seam, is the most economic way to mine coal. It can also be the most environmentally destructive method unless steps are taken to revegetate and fill in the damaged land. Deep coal is mined by underground mining where a shaft to the depth of the coal seam is dug and the coal is mined by machine. Underground coal mining is dangerous because of the weaknesses of the sedimentary layers above the coal seam and the accumulation of explosive gases. Miners can also contract black-lung disease from inhaling coal dust. Nuclear power Nuclear power comes from a different process than the burning of fossil fuels. One gram of nuclear reactor fuel = 2.7 barrels of oil. Nuclear power comes from fission, the breaking of the nuclear bonds that hold protons and neutrons together in the nucleus.Some elements, such as uranium, undergo fission naturally. This process is called radioactive decay. In a nucler power plant, uranium 235 is packed into fuel rods. Chain reactions occur when neutrons released during fission strike other atoms, triggering more fission, etc. If enough radioactive atoms are in a small enough space, a critical mass is formed. Problems with nuclear power plants include the possibility of a meltdown where the fission rate proceeds uncontrolled and melts the fuel rods and possibly melts the containment structures to escape into the environment.Chernobyl in 1985 was a near-meltdown when a steam explosion blew the roof off the reactor and 10% of the radioactive material escaped into the atmosphere. Nuclear waste disposal remains a contentious issue. A chain reaction of uranium. Fission of atoms produces lots of heat energy. When a uranium atom undergoes fission, it produces 3 neutrons + barium-141, krypton92, and energy. How a reactor is configured to produce electricity. The control rods are of boron-steel and can be raised or lowered to control the reaction rate. Geothermal energy The heat produced by the Earth’s internal processes can be used as an energy resource. This is common in countries such as Iceland where magma is close to the surface because Iceland is in a rift zone A few hydroelectric power plants use the sea and the tides to generate electricity. Oil reserves are predicted to run out by 2050, only 47 years from now! Other fuel alternatives * * * tar sand solar energy wind energy Problems with extracting and/or implemention of conventional sources of fuel * * * * * nuclear accidents and nuclear waste disposal oil spills acid mine runoff acid rain CO2 and global warming End of Chapter 14