Significant Digits In science classed you will be making many measurements. We must realize that there is a MAJOR difference between a defined (or exact) number and a number representing a measured quantity (measurements). We know that when we make measurements we must always estimate the last digit in the measurement. Since the last digit is an estimate, there is some uncertainty in all measurements. Defined numbers, such as a dozen eggs, have no uncertainty. There are exactly 12 eggs in a dozen because it is defined as such. The accuracy of your measurements is how close your value is to the actual or accepted value. Accuracy depends on how carefully you make your measurements. Precision, however, depends on the measuring instrument. We can determine the precision of a measurement by the number of significant digits. Rules for identifying significant digits in a written measurement: 1. All non zero digits are significant 2. All zeroes between non zero digits are significant 3. Leading zeroes are never significant 4. Trailing zeroes: -are significant if there is a decimal point (12.300) -are NOT significant if there is no decimal point (12300) We often use our measurements to calculate We often use our measurements to calculate other values. Nothing calculated from measurements can be more precise than the least precise measurement. This is very different from rules you have learned in math class. For example, if we are asked to find the area of a box that is 6 cm by 8 cm. Any decent math student knows that the area would be 48 cm². A science student must look at the problem differently. In science class, a measurement of 6cm has only one significant digit. It means that the length is greater than 5cm and less than 7cm. If the person doing the measurement had measured it more accurately, he/she would have written it as 6.0cm or 6.00cm. Since the lengths are “more or less” 6cm and 8cm, the science student that the area could vary. The maximum are would be 63cm² (7cm · 9 cm) and the minimum area would be 35 cm² (5cm · 7cm). So, how do we write the answer? Since the original measurements are precise to only one significant digit, the answer can have only one significant digit and the answer must be rounded to 50cm²! Since the original measurements were not very precise, we should not expect calculations using imprecise measurements to result in very precise answers. If we measure the volume of a jar to be exactly 900 ml how can we write this number so that all three digits are significant? The easiest way is to use scientific notation and write the number as 9.00 · 10². The rules for significant digits apply to measured numbers. Defined numbers (12 eggs to a dozen, the average of 3 measurements) do not have significant digits and the rules for significant digits do not apply. Rules for Using Significant Digits in Your Calculations 1. When adding and subtracting answers should be rounded to the same precision (Accuracy) as the least accurate tool used. EXAMPLE: 6.28 g + 51.0 g =? Solution: 6.28 g is accurate to the hundredth 51.0 g is accurate to the tenth The sum 57.28 g must be rounded to the same accuracy as the least accurate tool. Therefore the answer is 57.3 g. 4.0000____ 2) Do the following calculations. Round to the correct number of significant digits. 3.44 x 1.256 _____ 2. When multiplying and dividing measured values, answers should have the same number of significant digits as the original number with the fewest number of significant digits. 0.0075 x 3.664 _____ 73.45 / 105 _____ 4.55 / 0.3 _____ EXAMPLE: 750 cm · 0.237 cm =? SOLUTION: 750 2 Significant Digits X 0.0237 3 Significant Digits 17.775 cm² which must be rounded to two significant digits since 2 is the lowest number of significant digits in the original problem. Therefore the answer is 18 cm² FINAL NOTE: If you are doing several mathematical operations on your calculator, leave all the digits on the calculator and do your rounding on the final answer. (22.45 / 1.27) x 0.12 _____ (4500 x 2.44) / 156.0 _____ (4.55 x 104) (7.04 x 105) __________ (5.606 x 109) (4.015 x 106) / (11.18 x 105) ___________ (9.66 x 1011) (3.599 x 104) / (3.91 x 10-3) ___________ (1.1618 x 1015) (4.015 x 106) / (11.18 x 105) 1) How many significant figures are in each of the following? 3) Do the following calculations. Round to the nearest number of significant figures. 0.189 ____ 2.212 + 4.5 = ____ 891.00 ____ 0.88 – 0.2344 = ____ 900____ 5.5 + 0.23 + 3.06 + 8.09 = ____ 190 ____ 3.3 – 11.0 + 15 = ____ 89.00 ____ (12.3 + 6.6) (8.99 – 0.44) = ____ 5400____ (65.4 – 0.3) (3.66 + 18) = ____ 0.0018____ (2.34 – 1.6) (12.9 – 12.7) = ____ 0.0016____ .00001____ 440____ 10,500,000____