Name: Date: Period: The Law of Conservation of Mass Introduction: Chemical reactions result in changes within matter. Often they are accompanied with visible signs of energy release and changes in the appearance of the substances. In this experiment a chemical reaction will be carried out in a closed bottle. As it is conducted, consider the following questions: How are compounds altered and what does their mass relate? Where do the atoms come from and where do they go? Will the total mass of the chemicals change because of the reaction? What is meant by the Law of Conservation of Mass? Purpose: In a brief statement, explain the reason for the experiment . Hypothesis: In this experiment, NaHCO3 (baking soda) will be reacted with HCl (hydrochloric acid) in a closed container. What will happen to the total mass of the chemicals? Using the If–Then–Because format, write a testable hypothesis about the reaction with regard to how the mass of the bottle and its contents will or will not change during the reaction and the reasoning for your prediction. Materials: balance test-tube 100 mL graduated cylinder NaHCO3 (baking soda) weighing paper or weighing boat 2 L pop bottle and cap scoopula 1M HCl (aq) (hydrochloric acid) matches wooden splint Procedure – Follow the procedure below and make careful observations in the data table provided. 1) Rinse out a 2 L pop bottle with cap. Shake as much water out as possible. Make sure the outside is dry. 2) Measure 51.8 mL of 1 M HCl (aq) using a graduated cylinder. Remember to measure to the bottom of the meniscus. Pour the acid into the 2 L pop bottle. 3) Mass 4.35 g of NaHCO3 on creased weighing paper or a weighing boat. 4) Pour the sodium bicarbonate into a test-tube. Use the creased weigh paper to get all the material into the tube. Don’t lose any. Make sure the outside of the test-tube remains clean. 5) Carefully, at an angle, slide the test-tube of sodium bicarbonate into the 2 L pop bottle without letting the acid or baking soda mix. Keep the tube upright so it doesn’t spill. Screw the cap on tightly so no gas can escape during the reaction. 6) Mass the 2 L bottle with everything in it and record. Do not start the reaction yet! 7) Observe the capped bottle carefully. Write down anything you observe including: flexibility of the plastic bottle, chemicals present, color and state of matter of all chemicals, and any other substances in the bottle that may or may not take part in the reaction to come. 8) Now, mix the sodium bicarbonate with the acid. To do this, carefully tip the bottle horizontally, swishing the acid into and out of the test-tube of sodium bicarbonate. Keep swishing back and forth until the reaction seems to be finished and all the white powder is gone. Find and record the mass of the 2 L bottle. In the data table, describe what happens during the reaction. Note any changes, such as color, temperature, and states of matter of the substances and physical characteristics of the bottle when the reaction is complete. What happened to the mass of the bottle? Compare it to your data from procedure 6. 9) Answer questions 1 – 4 in the Question section before continuing. 10) Pour out the “air”. Read this step in its entirety before doing anything: Hold the 2 L bottle upright. Completely loosen the lid but leave it on bottle. Using a match, light a wooden splint and hold the flame near the mouth of the bottle. Open the bottle, tip it down at a slight angle and put the flaming splint into the bottle without getting burned. Do not let go of the splint! Smoke will be produced when the flame goes out. Remove the splint from the bottle and slowly pour out the gas/smoke just as you would a liquid. Watch as it sinks in the air, but don’t let anything else drip or fall out. Now, allow the bottle enough time for the gas inside of it to come to equilibrium with the air in the room. Put the cap back on the bottle, mass it and record. Describe any changes you observed during this procedure. 11) Rinse out the bottle and test-tube. Neatly return and organize your lab materials on your lab table. 12) Answer questions 5-8. Data: Mass (g) Observations Before Reaction After Reaction After Pouring Out the Gas Questions: 1. The baking soda did not dissolve, although that’s what many people think. What do you think happened to the acid and baking soda during the reaction? What is your evidence? 2. Was the mass of the bottle changed significantly after the reaction? Explain why or why not. 3. Since the cap was screwed on tightly, did any mass or matter escape the bottle? How do you explain any discrepancies in mass when comparing the before and after reaction mass data? 4. Name at least two things that can get into and out of the bottle without the cap being opened. (Not necessarily matter…) 5. What gas do you think was poured out? What evidence is there for your answer? (Oxygen is required for combustion, CO2 prevents combustion.) 6. One fundamental property of chemistry is the conservation of mass. Explain what conservation of mass means, using your experimental results as evidence. 7. The complete balanced equation for this reaction is: HCl + NaHCO3 → NaCl + H2O + CO2 Count the number of atoms of each element on each side of the equation (reactants and products). What do you notice? How does your observation above relate to the results from the lab regarding the mass of the bottle? 8. Write a conclusion to this lab with regard to whether or not the written hypothesis was supported by the results. Be sure to include a claim, evidence from the data and the reasoning as to why the evidence supports the claim. M. W. Walker/J.L. Daniel Jul 11, 16