Number of Protons Atomic Number Number of Protons + Neutrons Mass Number 12 is the mass number. C-12 or carbon-12 Left Superscript = mass number 12C 6 Left Subscript = atomic number 12C 6 35 80Br 35 Atomic Number = ? 20 20Ne 10 Mass Number = ? 238 238U 92 Mass Number = ? 27 27Al 13 Mass Number = ? 20 40Ca 20 Atomic Number = ? 9 19F 9 Atomic Number = ? Mass Number = 235 Atomic Number = 92 (Look up!) U-235 Mass Number? Atomic Number? Mass Number = 14 Atomic Number = 6 (Look up!) Number of neutrons = 14 - 6 = 8 C-14 How many neutrons? Atoms of the same element with a different # of neutrons Isotope Atoms with the same atomic # but different mass # Isotope Charge = +1, mass = 1 amu, location = inside nucleus Characteristics of Proton Charge = 0, mass = 1 amu, location = inside nucleus Characteristics of Neutron Charge = -1, mass = 1/1836 amu or 0.0005 amu, location = outside nucleus Characteristics of Electron An atom that has gained or lost electrons & so carries charge Ion Protons & Neutrons Nucleons Smallest bit of an element that retains the properties of the element. atom Electrically neutral. # of protons = # of electrons. atom # protons - # electrons Charge Mass number – atomic number # of neutrons 8 14C 6 # of neutrons = ? 5 9Be 4 # of neutrons = ? 22 40Ar 18 # of neutrons = ? 8 15N 7 # of neutrons = ? Right superscript = charge 2+ 24Mg 12 10 electrons 2+ 24Mg 12 # of electrons? 36 electrons 86Rb 1+ 37 # of electrons? 53 electrons 127Te 52 1- # of electrons? 18 electrons 32S 16 2- # of electrons? 9 protons, 11 neutrons, 10 electrons 20F 9 - # of protons, neutrons, electrons? Positive ion: atom lost electrons Cation Negative ion: atom gained electrons Anion Weighted avg. of masses of naturally occurring isotopes of an element. Avg. Atomic Mass Avg. atomic mass = .75(35) + .25(37) = 35.5 amu 2 isotopes of Cl: 75% Cl-35 & 25% Cl-37. Calculate avg. atomic mass. Billiard Ball Model Dalton’s Model Plum Pudding Model Thomson’s Model - + + -+ + -+ - Nuclear Model Rutherford’s Model - + - Rutherford’s Experiment Source: http://www.dlt.ncssm.edu/TIGER/chem1.htm#atomic 1) Most of the alpha particles went straight through. Most of the atom is empty space. 2) Some of the alpha particles were deflected back. The nucleus was tiny, but contained most of the mass of the atom. Rutherford’s Experiment: Results Planetary Model Bohr’s Model Modern or Quantum Mechanical Model Schrodinger’s Model Source: http://www.dlt.ncssm.edu/TIGER/chem1.htm #atomic Electron treated as a wave. Never know exactly where it is. Modern Model (Schrodinger or Quantum Mechanical Model) Ground state configurations found in reference tables. Cannot be predicted. Bohr Configuration 2 electrons in energy level 1 8 electrons in energy level 2 1 electron in energy level 3 Bohr Configuration of Na = 2-8-1 +11 Bohr Diagram of Na Electron(s) in outermost orbit or shell Valence Electron(s) Nucleus + all innershell electrons: Everything except the valence electrons Kernel Electrons are restricted to specific orbits or shells or principle energy levels. Each shell holds a specific # of electrons. Each shell has a specific energy & radius. Energy of electron must match energy of shell. Bohr Model Maximum Capacity of Bohr Levels Shell # Max # of electrons 1 2 2 8 3 18 4 32 n 2n2 Bohr model Every electron is in the lowest available orbit. Ground State Ground state configuration of Cl 2-8-7 Ground state configuration of O 2-6 2-8-18-8 Ground state configuration of Kr? Shell # Principle Energy Level? Bohr model An electron has absorbed heat, light, or electrical energy and moved to a higher energy level. Unstable. Returns to ground state quickly by emitting a photon. Excited State An excited state of O 2-5-1 An excited state of Li 2-0-1 Spectrum produced by holding a prism in sunlight. Contains light at every wavelength. Rainbow Continuous Spectrum Visible light produced by electrons in atom returning to ground state: light of only a few wavelengths is present. Each element has a unique bright line spectrum. Used to identify elements. Wavelengths of bright lines correspond to difference between energy levels. Bright Line Spectrum Source: http://www.dlt.ncssm.edu/TIGER/chem1.htm#atomic E3 Excited state E2 h E1 Ground state Absorbtion of Energy h E3 Excited state E2 E1 Ground state Emission of Energy Modern Model Region of space that holds 2 electrons. Has a specific energy. Shapes vary. Orbital Represents an electron dropping to a lower energy level, releasing energy in the process. E2 E1