The Atom and Radiation Nuclear Radiation and an Introduction to Electromagnetic Radiation Goals: To answer the following questions What is radiation? Where is radiation found? What is radiation used for? Complete the survey on page 410. You should copy each statement in your notebook and indicate whether you feel the statement is true or false. We will revisit these at the end of the unit. The Discovery of Radioactivity The German physicist W.K. Roentgen “accidentally” discovers a mysterious source of radiant energy that can pass through low density shields (like card board). He calls this mysterious energy X-rays. Further research showed that X-rays cannot pass through everything, particularly high density materials like lead and bone. Roentgen takes the first X-rays of his wife’s hand to present to his colleagues. The Discovery of Radioactivity The French physicist Henri Becquerel takes interest in Roentgen's X-rays. He investigated whether certain minerals could emit X-rays. He experiments with Uranium and a photographic plate (develops upon exposure to light). Another accident happens…Becquerel becomes frustrated with his research, wraps the photographic plate in black paper (to prevent light exposure), throws it in his desk drawer with a piece of Uranium on top and closes it up. What do you know??? A few days later, Becquerel discovers that the photographic plate has been exposed while sitting in his dark drawer. The Discovery of Radioactivity What Becquerel inadvertently discovered was radioactivity, the spontaneous emission of nuclear radiation. Soon after, Becquerel's colleagues, Marie Curie and her husband Pierre discover two other radioactive elements: polonium and radium. What is Radioactivity? Radioactivity: the spontaneous emission of nuclear radiation. We now know that there are two categories of radiation: Non-ionizing radiation – low-energy radiation that transfers energy to matter usually only harmful in large amounts Ionizing radiation – high-energy radiation that can eject electrons from atoms/molecules to form highly reactive ions and can cause serious cell damage exposure should be limited. Concerns….. But radiation is all around us…the question is, should we be concerned about our safety?? Are we in danger of serious exposure to radiation? Forms of Radiation Radiation comes in several forms as shown in the electromagnetic spectrum below; but not all forms are represented here Types of Radiation Three main types (from the 2 categories) : 1. Non-ionizing electromagnetic radiation Radio Micro Infrared Visible low energy UV 2. Ionizing electromagnetic radiation High UV X-rays Gamma rays 3. Ionizing atomic particle radiation radioactive elements Why are some elements radioactive? To answer this question, you must understand a little about atomic structure. All matter can be broken down into atoms: 1. 2. 3. An atom is composed of three parts: Protons Neutrons Electrons Parts of the Atom A proton is a positively charged particle that is located in the center of an atom. All atoms of an element have the SAME number of protons A neutron is a particle with no charge and is also located in the center of an atom. An electron is a negatively charged particle that orbits around the protons and neutrons. Parts of the Atom The center of the atom where the protons and neutrons are located is called the nucleus. Name Proton Electron Neutron Location Nucleus Outside Nucleus Nucleus Charge +1 -1 0 • The Number of Protons is the Atomic Number (found on the periodic table) • Mass of an atom is the number of Neutrons plus number of Protons • Mass Atom = Protons + Neutrons • Notation number p + number n number p A E Z Symbol of element E.g. Mass # Atomic # 12 C 6 Symbol of element Element Protons Neutrons Mass # Symbol 39 K 19 20 39 Nitrogen 7 7 14 14 Al 13 14 27 27 He 2 2 4 4 Lithium 3 11 4 12 7 20 Ne 20 10 23 40 10 20 Zinc 30 35 65 S 16 16 32 Sodium Ca 19 7 N Al 13 2 K He 7 Li 3 23 11 40 20 20 10 Na Ca Ne 65 30 32 16 Zn S Isotopes While all atoms of the same element must have the same number of protons, they do not all have to have the same number of neutrons. This makes some atoms of the same element heavier than others. These are referred to as isotopes: Isotope – Atom of the same element (same # protons) but with different Mass Number due to varying numbers of neutrons Element Protons Neutrons Mass # Li 3 4 Symbol 7 7 8 8 3 Li 3 5 C 6 6 12 12 C 6 7 13 13 C 6 8 14 14 B 5 4 9 9 B 5 6 11 11 H 1 0 1 1 H H 1 1 2 2 3 1 3 6 6 6 5 5 1 2 1 3 1 Li Li C C C B B H H H Isotopes (cont.) Some isotopes are stable and others are unstable. This is where radioactivity comes in. A stable isotope is not radioactive, but an unstable isotope is! Ex. 12C is stable 13C is stable 14C is radioactive Radioactive elements will emit radiation until they become a stable isotope. Emitted radiation This emitted radiation can be one of three types: Alpha ( 42 α or 42 He )– heavy particle radiation (easily blocked because its so big). 0 β or 0 e )– particle radiation smaller Beta ( -1 -1 than alpha Gamma ( 0 γ )– high energy radiation 0 Emitted radiation Alpha and Beta cause radioactive elements to change to a new element. Gamma causes no change in the radioactive element. Every Element has Isotopes – the amount of each isotope is fixed Ex. Uranium Mass 238 235 234 Abundance 99.28% 0.71% 0.0054% Which isotope of Uranium is used to make an atomic bomb? Complete the Assignment in your notebook: Pg. 426-427 #2, 4, 17, 18, 21 and 24 Radiation Exposure Naturally occurring radioisotopes provide a constant small dose of radiation Radioactive isotopes constantly decay, releasing alpha, beta and/or gamma radiation. This constant, inescapable radiation is called background radiation. Natural background radiation: - Outer space All forms of electromagnetic radiation - Ground water, rocks, soil contain Uranium and Thorium - Atmosphere contains radon - Food and Environment like C-14 and potassium Manmade background radiation: Fallout (nuclear weapons testing) Airplane flights Released from burning fossil fuels nuclear power plants mining making cement concrete sheet rock Two units are used to measure radiation: Rad measures the absorbed dose of radiation Rem measures the ionizing effect of the radiation Average U.S. individual receives 0.360 rem per year. About 0.300 rem of this is from natural sources U.S. limit for background radiation in a given area is 0.500 rem. U.S. safe exposure in the work environment is 5.000 rem. How much is safe? Ionizing radiation breaks bonds in molecules within the body. At low exposure levels, your body can fix the minimal damage. Higher exposure levels that your body cannot fix will lead to damaged DNA, causing mutations (tumors and birth defects) Copy the dosage chart on page 433 into your notebook Alpha Radioactive isotopes decay until a stable nucleus can be formed. What happens when radioactive isotopes decay? Many elements release alpha radiation: 226 Ra 88 (radium) 4 2 He + (alpha particle) 222 86 Rn (Radon) As these radioactive isotopes decay, an alpha particle is released and a new element is formed. Beta Many elements release beta radiation: 222 86 Rn (radon) As 0 -1 e + (beta particle) 222 87 Fr (Francium) these radioactive isotopes decay, a beta particle is released and a new element is formed. Gamma In addition to releasing a radiation particle (alpha or beta), most radioactive decay is accompanied by the release of gamma radiation too. Remember, gamma radiation is just energy; it is not a particle, so it does not cause the element to change its identity. How do you determine the new element made after radioactive decay? 1. 2. 3. 4. 5. Identify the starting element and write the symbol. Identify the type of radiation released. Subtract the two upper left numbers to find the mass of the new element formed. Subtract the two lower left numbers to find the atomic number of the new element formed. Look up the new atomic number on the periodic table to find the new element made. Radon Produced as Uranium in the soil decays. Uranium decays to produce radon gas: When this gas is inhaled, it further decays in your lungs into Polonium, Bismuth and Lead (these heavy metals cannot be exhaled). The alpha radiation is being released into your body, causing cell damage. Complete the Assignment in your notebook: Pg. 446-447 # 1, 2, 4, 5, 8, 13, 23 and 24 Half-Life Radioactive isotopes change what they are as they decay and release radiation. Scientists call the amount of time it takes for half of a radioactive sample to decay a half life. 14C has a half life of 5,730 6 years. This means that if we started with 100 grams of 146 C, only 50 grams of 146C would remain after 5,730 years have passed. The other 50 grams will have turned into 14 N as a beta particle is 7 released. How long does it take for a radioactive sample to decay? Although it is not possible to predict when any individual isotope will decay, this question can be answered for an entire radioactive sample by the half-life of each radioisotope. The half-life of radioisotopes varies greatly, but is constant for a particular radioisotope. So constant and reliable, it could be used to keep time. How long does it take for a radioactive sample to decay? Why would anyone want to know this? It’ very useful to know how long a radioisotope used in medicine will remain radioactive within the body, to plan how long hazardous nuclear wastes must be stored and to estimate the age of ancient organisms, cavitations or rocks (fossils). Radioisotopes and Medicine 1. Diagnostic: help to understand what is happening inside the body Tracer Studies Study a specific part of the body Radioactive isotopes behave the same way as non-radioactive ones Can be “seen” moving through the body Can “see” where they accumulate Show how body processes that chemical (copy top chart on p 455) Used as Tracers Radioisotopes Half-Life Use Technetium-99 6.01 h Measure Cardiac output; locate strokes, brain and bone tumors. Gallium-67 78.3 h Diagnosis of Hodgkin’s disease Iron-59 44.5 d Determine the rate of red blood cell formation (these contain iron); anemia assessment Chromium-51 27.7 d Determine blood volume and lifespan of red blood cells Hydrogen-3 12.3 y Determine volume of body’s water; assess vitamin D usage in body Thallium-201 72.9 h Cardiac arrest Iodine-123 13.3 h Thyroid function diagnosis 2. Therapeutic: Treats the disease Used for Irradiation Therapy Radioisotopes Half-Life Use 30.1 y Treat shallow tumors (external source) Phosphorus-32 14.3 d Treat leukemia a bone cancer affecting white blood cells (internal source) Iodine-131 8.0 d Treat thyroid cancer (external source) Cobalt-60 5.3 y Treat shallow tumors (external source) Yttrium-90 64.1 h Treat pituitary gland cancer internally with ceramic beads Cesium-137 Suitable or Unsuitable Must have a short half life Cannot emit alpha radiation Cannot be poisonous to the patient Diagnostic Scans 1. X-ray: Wave that’s part of EMS Not an atom/element High energy 2. MRI: uses hydrogen protons and radio waves *NOT RADIOACTIVE!* Scans (cont.) 3. CAT scan: X-ray that produces cross section images of your body that rather than the overlapping images the X-ray unit rotates around your body then a powerful computer creates cross-sectional images, like slices, of the inside of your body. 4. PET scan: uses positions (positively charged antimatter) attached to sugars Collect/gather where cells grow quickly Cancer and Radiation Cancer cells Contain mutated DNA Multiply at abnormally fast rates (tumor formation) Radiation in cancer treatment Ionizing radiation kills all kinds of cells Use to target cancer cells Answer the following questions on pg. 462-463 # 8-11, #13 Nuclear Forces Nuclear fission: The splitting of the atom into smaller atoms, often resulting in the release of tremendous amounts of energy How much??? The fission of Uranium-235 produces 26 million times more energy than the combustion of methane. How does nuclear fission work??? 1n 0 93Kr + 140Ba + 3 1n + ENERGY + 235 U —> 92 36 0 56 Bombarding a uranium atom with one neutron produces two smaller atoms and two more neutrons, free to collide with other uranium atoms. This causes a chain reaction to occur. Animation Animation 2 Since not all of the neutrons produced will hit and split a uranium nucleus, a minimum amount of uranium is necessary. The more uranium present, the more likely the produced neutrons will hit and split another uranium nucleus. This minimum amount of uranium is called its critical mass. It is the minimum amount of fissionable material required to sustain a chain reaction. Uranium Mined from the ground as Uranium Oxide U3O8 Two isotopes 1. Uranium-235 - natural abundance = 0.720% - used for fission in nuclear reactions and weapons 2. Uranium-238 - most abundant = 99.275% Enrichment Must have between 1 to 3% U-235 for fission 2 ways to enrich U-235 1. Change U3O8 into UF6 gas - needs to be done about 1200 times - get 4% u-235 2. Use lasers - excite electrons of lighter isotope (U-235) - collected using magnetic fields - works in 1 try Nuclear Weapons Fission Bomb (a.k.a. Atom Bomb) 1. 2 non-critical masses portions of U-235 are propelled into each other – make 1 critical mass 1 neutron then starts fission, then…BOOM! 2 2. 1 critical mass Usually Plutonium Compressed to get explosion Nuclear Weapons Fusion Bomb (a.k.a. H-Bomb) Uses Lithium Hydride High temperatures create fusion Fusion: 2 different isotopes fuse together Releases more energy (100x) Nuclear Power There are many benefits in using nuclear technology to create electricity, but this must be carefully regulated. If the reactor reaches temperatures that are too high, the danger of a meltdown occurs. A nuclear meltdown can occur when temperatures inside the reactor reach levels that are too high. The materials used to construct the reactor actually melt. If this happens, the chain reaction is no longer contained and dangerous radioactive material can be expelled into the environment. Animation Animation 2 Cooling System How does it work? When the steam from the generator is cooled by water from When the steam from nearby water sources the generator is cooled by water from nearby water sources Cooling Tower Nuclear Power Plants in US Nuclear Power has reached dangerous conditions twice. Three Mile Island Chernobyl 1979, Pennsylvania 1986, Russia the reactor reached dangerous temperatures, but no meltdown occurred the reactor reached temperatures high enough to cause the core to melt caused by both equipment failure and human error caused by both poor plant design and improper operation while some radioactive material was expelled into the atmosphere, no damage sustained by people or environment radiation spewed into the atmosphere and spread over the entire Northern Hemisphere caused government to create stricter regulations over nuclear power plants an estimated 75 million people exposed The Chernobyl incident happened April 26, 1986 in Ukraine. The Chernobyl accident was a result of a flawed reactor design that was operated with inadequately trained personnel and without proper regard for safety. When the operator went to shut down the reactor from it’s unstable condition arising from previous errors, a peculiarity of design caused a dramatic power surge. 3 mile island is located in Harrisburg PA The 3 mile island is a nuclear generating station What Happened? Occurred on 4:00 a.m. March 28, 1979 Problem in secondary, non-nuclear section of the plant The main water pump failed and prevented steam generators from removing heat that the radioactive material was producing The pressure in the primary system (nuclear part of plant) increased What Happened? The relief valve on top of the pressurizer did not close when the pressure decreased Workers reduced the flow of coolant which made the fuel overheat Half of the long metal tubes which held the nuclear fuel pellets ruptured and the pellets started to melt Future Technology… Nuclear Fusion - the joining of two smaller nuclei to create a large nucleus and tremendous energy release. Produces more energy per atom than fission Requires tremendous heat and pressure! Technology does not yet exist that allows more energy to be produced than must be put in. Answer the following questions on pg. 481-482 #1,2,8,9,16,18,19,20