GLove Kristin Brodie Jeff Colton Colin Galbraith Bushra Makiya Tiffany Santos Objective To create a glove that will generate heat to help keep your hand warm in a cold environment What will this require? Source of heat generation How will they be different? Lightweight Re-usable Smart Temperature Sensor/Switch Reversible Exothermic Material Heat Loss Model Cylindrical Hand Power Lost @ -10C relative to Power Lost @ 25C 2rLq = 2L(T1-T3)/R = 2.5W R = Fabric Resistance + BL Resistance Glove Layers Conduction Convection Overview Battery Powered Rechargeable Non-Rechargeable Uses 2 ‘D’ batteries Checmical Reversible Non-Reversible Lasts 18 hours One time use Battery Operated Glove Wires NiCr Alloys Electrical Resistivity Testing Stainless Steel Mechanical Testing Mechanical Testing Data NiCr Diameter (mm) 0.41 Stress* (ksi) 120 Stress vs Strain for 3 wires Extension (in) 1.95 Stress (lbs/in) 100000 80000 60000 40000 20000 0 0.005 0.01 0.015 Strain NiCrFe FeCrNi NiCr FeCrNi 0.38 0.404 74-130 ~95 2.16 3.5 *Expected Stress 120000 0 NiCrFe 0.02 0.025 Electrical Resistivity Testing Measured Resistances 0.1 Resistance ( W /cm) 0.09 0.08 0.07 0.06 0.05 0.04 0.03 0.02 0.01 0 Expected R Measured R R* Condition NiCr 80:20 All wire diameters are ~40mm *R for wire wrapped around a finger **R for wire after work-hardening NiCrFe 60:16:24 FeCrNi 70:19:11 R** Wire Insulators Teflon Tubing Nextel Braids Teflon PTFE Tubing Property Units Value Resistivity Wcm 1018 Tensile Strength MPa 21-34 Tm C 327 Operating Temp C 260 Water Absorption Thermal Conductivity <0.01% W/mK 0.25 Batteries Amphr Size Durability Recharge ability Serial # 603672 141988 597980 Discharge Capacity (Ah) 0.754 1.364 1.181 Discharge Power (Wh) 2.82 5.10 4.42 Length (mm) 48.9 88.3 65.5 Width (mm) 34.8 54.9 36.2 Height (mm) 5.30 3.03 5.50 Final OCV (V) 3.76 3.74 3.74 Final Impedance 48.8 39.2 30.3 Field Testing My hand feels warm, stop recording At what temperature is your hand comfortable? Test 1 Tested 10 subjects 2 Placed in freezer 3 Dressed in winter clothes Wore gloves with heating element 4 1.7W of power supplied 5 Temp recorded when subject said their hand 6 was warm 7 Conclusion 8 Thermal Switch should turn power off at 9 ~32C 10 AVG Tglove(F) Tenvironment(F) 91.3 -1.1 90.4 -0.7 89.4 -1.3 93.1 -1.8 89.8 -1.2 92.0 -0.4 84.7 0.1 91.7 -1.6 91.6 -1.1 90.9 -0.7 90.5 -1.0 Temperature Sensor/Switch Bimetallic Polymer PICTURE HERE Resistance/Current Testing Before Switch After Switch Expected Temp (C) 32 32 3 Actual Temp (C) Voltage (V) Resistance (W) Current (A) 3.74 0 >106 0.43 0.0012 Fabric Blends of Polyester/Cotton were tested Thermal Testing Input Power = 1.73 W 100cm of wire 3.7V Temperature inside and outside of glove measured 2rLq=2L(T1-T3)/R = 1.73 W L/R = 0.018 W/k Power required using 100P* under same conditions as slide 3: 4.95 W Phase Change Materials Octadecane Tm = 27.2° C Tc = 16.5° C Hc = 283.5 J/g Hydrophobic Soft, waxy material Polyethylene Glycol (PEG) Tm = 26.6° C Tc = 9.8° C Hc = 151.0 J/g Extremely hydrophilic Soft, waxy material Differential Scanning Calorimetery Octadecane Polyethylene Glycol (PEG) PCM Encapsulation To prevent leakage from glove when PCM melts. Ideal Process Microspheres to maximize surface area Polypropylene (PP) /High Density Polyethylene (PE) Can be used to encapsulate microspheres Can be drawn into fibers Extrusion of PEG/PP: phase separation Complications Lack of Encapsulation Facilities Lack of Extrusion Facilities Different thermal properties of PEG and PE Microsphere Fabrication Successfully produced both paraffin and octadecane microspheres. Complications Inefficiency of filtering process Large scale production PCM Encapsulation Octadecane Ground particles embedded in base material. Polydimethyl Siloxane (PDMS) Resin Thermal conductivity = 0.002W/m*K PEG Melting attempts failed. Heat sealed in bags. Low Density Polyethylene (LDPE) Thermal conductivity = 0.33W/m*K -(CH2-CH2)- 5g octadecane in 10ml (~7.5g) PDMS 7g of PEG in ~11g LDPE Comparison of PCMs Octadecane in PDMS PEG in PE Potential Heat: 2.36 J Actual Heat: 1.16 J Potential Heat: 0.66 J Actual Heat: 0.43 J Reduction in Efficiency: 51% Reduction in Efficiency: 35% PCM Conclusions Octadecane is more efficient than PEG. Polyethylene is more efficient than PDMS. Future Recommendations Encapsulate octadecane in polyethylene. Extrusion Power Generated Wire P = V2/R V = 3.74V, R = 8.3W 1.7 W for 156 min Octadecane 5g 1417 J 1.7 W for 12.5 min PEG 7g 1057 J 1.7 W for 9.4 min Field Testing Battery Powered Octadecane PEG Assembly Connect wires to temp switch Connecting wires to battery Mechanical Strengthening of Contacts Discharge battery Encapsulation of PCM Fabrication of Gloves Future Work Improvements Encapsulation process Incorporation of wire into glove Ease of access to recharge battery On/Off switch Insulation of Wire