UNIT 1– Matter What is matter anyway? Matter is ANYTHING that has MASS & takes up SPACE (has VOLUME) Kinetic Molecular Theory KMT=Kinetic Molecular Theory Particles of matter are always in motion. The kinetic energy (speed) of these particles increases as temperature increases. Four States of Matter Solids very low KE (kinetic energy) particles vibrate but can’t move around fixed shape fixed volume Four States of Matter Liquids low KE - particles can move over & around each other but are still close together variable shape fixed volume Four States of Matter Gases high KE - particles have enough energy to separate and move throughout container; so much so that gases are mostly empty space! variable shape variable volume Four States of Matter Plasma Highest KE - particles collide with enough energy to break into charged particles (+/-) gas-like, variable shape & volume stars, fluorescent light bulbs Fluids What is a fluid? a substance that can FLOW & has particles that are able to move around each other. What 2 phases of matter are considered FLUIDS? Liquids & Gases Properties of Fluids What is viscosity? The ability of a liquid to flow or the resistance to flow. (Honey is MORE viscous than water) What is buoyancy? The upward force a fluid exerts on an object. Properties of Fluids What 3 properties allow an object to be “buoyant”? 1. The buoyant force exerted upward on the object is ______________________ than the force downward of the object’s weight. 2. The ___________________ of the object is less than the _____________________ of the fluid. 3. The weight of the water displaced by the object is _________________ than the _____________ of the object. States of Matter…Test YOUR knowledge! Type of Matter Solid Liquid Gas Plasma Kinetic energy Shape Volume States of Matter…Test YOUR knowledge! Type of Matter Kinetic energy Shape Volume Solid Very low Definite/fixed Definite/fixed Liquid Low Indefinite/ not fixed/ variable Definite/fixed Gas High Indefinite/ Not fixed/ variable Indefinite/ Not fixed/ variable Plasma Very high Indefinite/ Not fixed/ variable Indefinite/ Not fixed/ variable Matter Flowchart MATTER yes MIXTURE yes Is the composition uniform? Homogeneous Mixture (solution) PURE SUBSTANCE no Heterogeneous Mixture Colloids no Can it be physically separated? yes Can it be chemically decomposed? Compound C. Johannesson Suspensions no Element Matter Flowchart Test yourself… graphite element pepper hetero. mixture sugar (sucrose) compound paint hetero. mixture soda solution Pure Substances: only TWO types…element OR compound! Element composed of identical atoms Found on the PERIODIC TABLE EX: copper wire, aluminum foil Pure Substances: only TWO types…element OR compound! Compound composed of 2 or more elements in a fixed ratio It has a chemical formula!!! properties differ from those of individual elements EX: table salt (NaCl) Pure Substances Law of Definite Composition A given compound always contains the same, fixed ratio of elements. In other words, water is always H2O with a 2:1 ratio of H to O and hydrogen peroxide is always H2O2 with a 2:2 ratio of H to O. C. Johannesson Pure Substances Law of Multiple Proportions Elements can combine in different ratios to form different compounds. Same as before, ratios matter. You can have the same elements, such as H & O combined in DIFFERENT ratios. H2O (water) and H2O2 (peroxide) are two very different compounds!!! Pure Substances Additional example… Two different compounds, each has a definite composition. A. Matter Flowchart MATTER yes MIXTURE yes Is the composition uniform? Homogeneous Mixture (solution) PURE SUBSTANCE no Heterogeneous Mixture Colloids no Can it be physically separated? yes Can it be chemically decomposed? Compound C. Johannesson Suspensions no Element Mixtures Variable combination of 2 or more pure substances. NOT chemically combined! Heterogeneous Homogeneous Mixtures Homogeneous Mixtures are called Solutions Appear the same throughout very small particles no Tyndall effect (light doesn’t scatter) particles don’t settle; they are dissolved EX: rubbing alcohol Mixtures Heterogeneous Mixtures: Two Types Colloid medium-sized particles Tyndall effect (will scatter light) particles don’t settle (they’re too small) EX: milk Mixtures Suspension large particles Tyndall effect particles settle (because they are so large) EX: fresh-squeezed lemonade; pond water C. Mixtures You try… mayonnaise colloid muddy water suspension fog colloid saltwater solution Italian salad dressing suspension Properties of & Changes in Matter… Density Intensive vs. Extensive Physical vs. Chemical DENSITY Density is the measure of the MASS of a substance to the VOLUME of a substance at a given temperature. Density is expressed in g/mL or kg/L for liquids and g/cm3 for solids. Density of a SUBSTANCE will determine if the substance will SINK or FLOAT in another substance. (recall buoyancy) DENSITY Solving density problems involves using math. Recall the formula Density = MASS VOLUME EX: A gold colored ring has a mass of 18.9 g and a volume of 1.12 mL. Is the ring pure gold (Au)? The density of pure gold is 19.3 g/mL. 18.9g/1.12mL= 16.9 g/mL The ring is NOT pure gold because the density is not the same as pure gold. DENSITY Solving more advanced density problems is easy using a method known as DIMENSIONAL ANALYSIS. Dimensional analysis is known as the “FACTOR-LABEL” Method: A method used to “factor” out (cancel) labels (units) g cm g 3 cm 3 DENSITY Solve the following: What volume would a 0.871 gram sample of air contain if the density of the air is 1.29 g/L? KNOWNS: 0.871 g and 1.29 g/L UNKNOWNS: ? L CALCULATIONS: 0.871 g 1L = 0.68 L 1.29g EXPLANATION: The air occupies a space 0.68L. Significant Figures Figures (values) that indicate precision of a measurement. Recording Sig Figs Sig figs in a measurement include the known digits plus a final estimated digit 2.35 cm Counting Sig Figs Count all numbers EXCEPT: Leading zeros: 0.0025 2 sig figs Trailing zeros without a decimal point: 2,500 2 sig figs Atlantic-Pacific Method Pacific Ocean PRESENT “_________” Atlantic Ocean ABSENT “ _______” Atlantic-Pacific Method: 1. Decimal point is PRESENT: count significant figures from the LEFT (Pacific side) Decimal point is ABSENT: count significant figures from the RIGHT (Atlantic side) 2. Start counting significant figures at the first nonzero number and don’t stop until there are no more digits. Practice Counting Sig Fig 1. 23.50 4 sig figs 2. 402 3 sig figs 3. 5,280 3 sig figs 4. 0.080 2 sig figs 5. 0.006700 4 sig figs Practice Counting Sig Fig Round the number at left to the number of significant figures stated in each column Number 80.405 29,350 4 sig figs 3 sig figs 2 sig figs 1 sig fig 80.4 1 80.4 80. 80 29,00 0 30,00 0 29,35 29,40 0 0 Number vs. Quantity A number without a unit is a “naked” number Quantity - number + unit UNITS MATTER!! EVERY # MUST HAVE A UNIT!!! Extensive vs. Intensive Extensive Property depends on the amount of matter present Can be “extended” or changed Intensive Property depends on the identity of substance, not the amount A. Extensive vs. Intensive Examples: boiling point intensive volume extensive mass extensive density intensive conductivity intensive Accuracy vs. Precision Accuracy - how close a measurement is to the accepted value ACCURATE = CORRECTNESS • Precision - how close a series of measurements are to each other PRECISE = CONSISTENT or REPRODUCIBLE Accurate & Precise Accurate, not Precise Precise, not accurate Neither Accurate nor Precise Example Problem To determine the density of a certain metal alloy, a chemist measures the mass and volume of each of four different samples of the alloy. The chemist obtains the density values shown in the following: Example Problem Sample Density (measured) 1 5.87 g/cm3 2 5.89 g/cm3 3 5.83 g/cm3 4 5.92g/cm 3 Example Problem Later, the chemist learns that the true density of the alloy is 5.62 g/cm3. Describe the chemist’s results in terms of accuracy and precision. a. accurate and precise b. accurate, but not precise c. precise, but not accurate d. neither accurate nor precise Percent Error Indicates accuracy of a measurement % error actual - experiment al What you calculate actual 100 What it should be Small % = more accurate Large % = less accurate Percent Error A student determines the density of a substance to be 1.40 g/mL. Find the % error if the accepted value of the density is 1.36 g/mL. % error 1.40 g/mL 1.36 g/mL 1.36 g/mL % error = 2.9 % 100 Proportions Direct Proportion y X as Y • Inverse Proportion X as Y x y x PHYSICAL CHANGES Physical Change changes the form of a substance without changing its identity EX: cutting, dissolving, grinding PHASE CHANGES Changes of state (phase changes) are physical changes that involve changes of energy. Phase Changes (ARE physical change) sublimation melting SOLID vaporization LIQUID freezing condensation deposition GAS CHEMICAL CHANGES Chemical Change changes the identity of a substance products have different properties EX: tarnishing, burning, corroding Physical vs. Chemical Indicators or Signs of a Chemical Change (*important…you will need to know this for the rest of the year!!!) NEW substance formed Change of color or odor Release or formation of a gas formation of a precipitate (solid that settles…yes, a suspension) change in light or heat Properties of Matter Conservation of mass: The mass of all substances before a chemical change equal the mass of all substances remaining after the change. Exothermic—heat is released Exergonic—energy is released Endothermic—heat is absorbed Endergonic—energy is absorbed EXO- means “out” ENDO- means “in” Physical vs. Chemical CHANGE You try it…(not in notes) rusting iron chemical dissolving in water physical burning a log chemical melting ice physical grinding spices physical Physical vs. Chemical Physical Property can be observed without changing the identity of the substance Chemical Property describes the ability of a substance to undergo changes in identity Physical vs. Chemical PROPERTY You try it… melting point physical flammable chemical density physical magnetic physical tarnishes in air chemical Calculating Rules: Multiplying & Dividing : The # with the fewest sig figs determines the # of sig figs in the answer. (13.91g/cm3)(23.3cm3) = 324.103g 4 SF 3 SF 3 SF 324 g Calculating Rules: Adding & Subtracting: The # with the lowest decimal value determines the place of the last sig fig in the answer. 3.75 mL + 4.1 mL 7.85 mL 7.9 mL 224 g + 130 g 354 g 350 g Significant Figures Practice Problems 1. 2.066 g 2. 85.6 cm 3. 38 g 4. 1.13 g Scientific Notation In science, numbers can be very small & very large (confusing!) Numbers can be expressed in Scientific Notation: Mx n 10 1 ≤ M < 10 +n: large # Scientific Notation To convert into Sci. Notation: Move decimal until there’s 1 digit to its left. (# of places moved = exponent) Large # (>1) positive exponent Small # (<1) negative exponent Only include sig figs. 65,000 kg 6.5 × 104 kg Scientific Notation Practice Problems 1. 2,400,000 mg 2.4 6 10 mg 2. 0.00256 kg 2.56 3. 7 10-5 km 0.00007 km 4. 6.2 104 mm 62,000 mm -3 10 kg Calculating with Scientific Notation (5.44 × 107 g) ÷ (8.1 × 104 mol) = Type on your calculator: 5.44 2nd EE 7 ÷ 8.1 2nd EE 4 ENTER = 671.6049383 = 670 g/mol = 6.7 × 102 g/mol