GEOL 2312 IGNEOUS AND METAMORPHIC PETROLOGY Lecture 14 Origin of Granites From H.H. Read (1955) March 14, 2016 PARTIAL MELTING VS. FRACTIONAL CRYSTALLIZATION THE SONJU LAKE – FINLAND GRANITE CONNECTION Finland Granite The Problem: Even very efficient fractional crystallization will create only ~5% felsic magma PARTIAL MELTING VS. FRACTIONAL CRYSTALLIZATION A few broad generalizations: 1) Most granitoids of significant volume occur in areas where the continental crust has been thickened by orogeny, either continental arc subduction or collision of sialic masses. Many granites, however, may post-date the thickening event by tens of millions of years. 2) Because the crust is solid in its normal state, some thermal disturbance is required to form granitoids 3) Most workers are of the opinion that the majority of granitoids are derived by crustal anatexis, but that the mantle may also be involved. The mantle contribution may range from that of a source of heat for crustal anatexis, or it may be the source of material as well Zoned zircon in a granite with older inherited (restite) core overgrown by new material from the felsic magma ARC PLUTONIC COMPLEXES“GRANITE” BATHOLITHS FEEDER CHAMBERS TO CONTINENTAL ARC VOLCANICS COMPOSITE EMPLACEMENT OF OF “GRANITOID” BATHOLITHS Granitoids – all intermediate to felsic compositions plotting on a QAP(F) diagram Tends toward more granitic compositions over time Epizonal batholiths form mostly by roof collapse (stoping) or downdropping of the chamber floor GEOCHEMISTY OF ARC PLUTONIC COMPLEXES MIMICS VOLCANIC COMPOSITIONS Peruvian Coastal Batholith NON-GENETIC CLASSIFICATIONS OF GRANITOID ROCKS Chemistry-based Mineralogy-based ESSENTIAL MINERALOGY OF GRANITIC ROCKS LINKED TO THE QAP TERNARY EUTECTIC/MINIMUM Felsic Magma Generated from Mafic Magmas Felsic Magma Generated from melting Crust GENETIC CLASSIFICATION OF GRANITIC ROCKS BASED ON SOURCE ROCK/MODE OF ORIGIN Table 18-3. The S-I-A-M Classification of Granitoids SiO2 K2O/Na2O Type M 46-70% low Fe3+/Fe2+ Cr, Ni low 18O < 9‰ low < 9‰ low high > 9‰ var low var Ca, Sr high A/(C+N+K)* low low: metal- moderate uminous to peraluminous I 53-76% low high in mafic rocks S 65-74% high low high low metaluminous A high 77% Na2O high * molar Al2O3/(CaO+Na2O+K2O) low var peralkaline 87 Sr/86Sr Misc Petrogenesis < 0.705 Low Rb, Th, U Subduction zone Low LIL and HFS or ocean-intraplate Mantle-derived < 0.705 high LIL/HFS Subduction zone med. Rb, Th, U Infracrustal hornblende Mafic to intermed. magnetite igneous source > 0.707 variable LIL/HFS Subduction zone high Rb, Th, U biotite, cordierite Supracrustal Als, Grt, Ilmenite sedimentary source var low LIL/HFS Anorogenic high Fe/Mg Stable craton high Ga/Al Rift zone High REE, Zr High F, Cl Data from White and Chappell (1983), Clarke (1992), Whalen (1985) M-TYPE GRANITOIDS Table 18-3. The S-I-A-M Classification of Granitoids DIFFERENTIATES OF MAFIC MAGMAS SiO2 K2O/Na2O Type M 46-70% low Fe3+/Fe2+ Cr, Ni low 18O < 9‰ low < 9‰ low high > 9‰ var low var Ca, Sr high A/(C+N+K)* low low: metal- moderate uminous to peraluminous I 53-76% low high in mafic rocks S 65-74% high low high low metaluminous A high 77% Na2O high * molar Al2O3/(CaO+Na2O+K2O) low var peralkaline 87 Sr/86Sr Misc Petrogenesis < 0.705 Low Rb, Th, U Subduction zone Low LIL and HFS or ocean-intraplate Mantle-derived < 0.705 high LIL/HFS Subduction zone med. Rb, Th, U Infracrustal hornblende Mafic to intermed. magnetite igneous source > 0.707 variable LIL/HFS Subduction zone high Rb, Th, U biotite, cordierite Supracrustal Als, Grt, Ilmenite sedimentary source var low LIL/HFS Anorogenic high Fe/Mg Stable craton high Ga/Al Rift zone High REE, Zr High F, Cl Data from White and Chappell (1983), Clarke (1992), Whalen (1985) Type M Table 18-3. The S-I-A-M Classification of Granitoids I-T YPE GRANITOIDS Sr/ Sr SiO K O/Na O Ca, Sr A/(C+N+K)* Fe /Fe Cr, Ni O Misc Petrogenesis Table 18-3. The S-I-A-MU Classification of Granitoids R EMELTING OF M AFIC NDERPLATED C RUST 46-70% low high low low low < 9‰ < 0.705 Low Rb, Th, U Subduction zone 3+ 2 2 2+ 18 87 86 2 SiO2 K2O/Na2O Type M 46-70% low I 53-76% low Ca, Sr high high in mafic rocks high in mafic low rocks 3+ 2+ A/(C+N+K)* Fe /Fe low low low: metal- moderate uminous to peraluminous low: metal- moderate uminous high to low peraluminous I 53-76% low S 65-74% high S 65-74% high low A high 77% Na2O high low var metaluminous peralkaline var A high 77% Na2O high low var peralkaline var * molar Al2O3/(CaO+Na2O+K2O) * molar Al2O3/(CaO+Na2O+K2O) metaluminous high low Low LIL and HFS or ocean-intraplate Misc Petrogenesis Mantle-derived < 0.705 Low Rb, Th, U Subduction zone < 0.705 high LIL/HFS Subduction zone Low LIL and HFS or ocean-intraplate med. Rb, Th, U Infracrustal Mantle-derived hornblende Mafic to intermed. low < 9‰ < 0.705 high LIL/HFS Subduction zone magnetite igneous source Rb,LIL/HFS Th, U Infracrustal high > 9‰ > 0.707 med. variable Subduction zone hornblende Mafic to intermed. high Rb, Th, U magnetite igneous source biotite, cordierite Supracrustal high > 9‰ > 0.707 variable Subduction source zone Als, Grt, LIL/HFS Ilmenite sedimentary high Th, U low var var low Rb, LIL/HFS Anorogenic biotite, cordierite Supracrustal high Fe/Mg Stable craton Als, Grt, Ilmenite sedimentary source high Ga/Al Rift zone low var var low LIL/HFS Anorogenic High REE, Zr high Stable craton HighFe/Mg F, Cl high Ga/Al Rift(1985) zone Data from White and Chappell (1983), Clarke (1992), Whalen High REE, Zr High F, Cl Cr, Ni low low 18O < 9‰ < 9‰ 87 Sr/86Sr Data from White and Chappell (1983), Clarke (1992), Whalen (1985) Mantle-derived I 53-76% low high in low: metal- moderate low < 9‰ < 0.705 high LIL/HFS Subduction zone mafic uminous to med. Rb, Th, U Infracrustal rocks peraluminous hornblende Mafic to intermed. magnetite igneous source S 65-74% high low high low high > 9‰ > 0.707 variable LIL/HFS Subduction zone Table 18-3. The S-I-A-M Classification of Granitoids high Rb, Th, U metaluminous biotite, cordierite Supracrustal 3+ 2+ 87 18 Sr/86Sr Als, Grt, SiO2 K2O/Na2O Ca, Sr A/(C+N+K)* Fe /Fe Type Cr, Ni O Misc Petrogenesis Ilmenite sedimentary source M 46-70% low high low low low < 9‰ < 0.705 Low Rb, Th, U Subduction zone Na2O A high low var var low var var low LIL/HFS Anorogenic Lowhigh LILFe/Mg and HFS or Stable ocean-intraplate 77% high peralkaline craton Mantle-derived high Ga/Al Rift zone I 53-76% low high in low: metal- moderate low < 9‰ < 0.705 high LIL/HFS Subduction zone High REE, Zr mafic uminous to med.High Rb,F, Th, Infracrustal ClU rocks peraluminous hornblende Mafic to(1985) intermed. * molar Al2O3/(CaO+Na2O+K2O) Data from White and Chappell (1983), Clarke (1992), Whalen magnetite igneous source S 65-74% high low high low high > 9‰ > 0.707 variable LIL/HFS Subduction zone high Rb, Th, U metaluminous biotite, cordierite Supracrustal Als, Grt, Ilmenite sedimentary source Na2O A high low var var low var var low LIL/HFS Anorogenic 77% high peralkaline high Fe/Mg Stable craton high Ga/Al Rift zone High REE, Zr High F, Cl A-TYPE GRANITOIDS ANOROGENIC MELTING OF CONTINENTAL INTERIORS * molar Al2O3/(CaO+Na2O+K2O) Data from White and Chappell (1983), Clarke (1992), Whalen (1985) M-Type M 46-70% low high low low low < 9‰ < 0.705 Low Rb, Th, U Subduction zone Low LIL and HFS or ocean-intraplate Mantle-derived I 53-76% low high in low: metal- moderate low < 9‰ < 0.705 high LIL/HFS Subduction zone Table 18-3. The S-I-A-M Classification of Granitoids mafic uminous to med. Rb, Th, U Infracrustal rocks peraluminous hornblende Mafic to intermed. 3+ 2+ 87 86 18 Fe /Fe Sr/ Sr O SiO K O/Na O Type Ca, Sr A/(C+N+K)* Cr, Ni Misc Petrogenesis 2 2 2 magnetite igneous source M 46-70% low high low low < 9‰ > < 0.707 0.705 variable Low Rb,LIL/HFS Th, U S 65-74% high low high low high > Subduction zone Low and highLIL Rb, Th,HFS U or ocean-intraplate metaluminous biotite, cordierite Supracrustal Mantle-derived Grt, Ilmenite sedimentary I 53-76% low high in low: metal- moderate low < 9‰ < 0.705 Als, high LIL/HFS Subduction source zone Na2O mafic uminous med. Rb, Th, U of Hydrous Infracrustal A high low var to var low varDehydration var lowMelting LIL/HFS Anorogenic rocks peraluminous hornblende Mafic to intermed. 77% high peralkaline high Fe/Mg Stable craton Mineral-bearing Metasedimentary magnetite igneous source high Ga/Al Rift zone Rocks S 65-74% high low high low high > 9‰ > 0.707 variable LIL/HFS Subduction zone High REE, Zr high Rb,F,Th, High Cl U metaluminous biotite,Clarke cordierite Supracrustal * molar Al2O3/(CaO+Na2O+K2O) Data from White and Chappell (1983), (1992), Whalen (1985) Als, Grt, Ilmenite sedimentary source Na2O A high low var var low var var low LIL/HFS Anorogenic 77% high peralkaline high Fe/Mg Stable craton high Ga/Al Rift zone High REE, Zr High F, Cl S-TYPE GRANITOIDS PARTIAL MELTING OF SEDIMENTARY ROCKS * molar Al2O3/(CaO+Na2O+K2O) Data from White and Chappell (1983), Clarke (1992), Whalen (1985) High-grade metasedimentary rocks have little-no free water, so water-saturated melting curve (a-b-c) not as important as hydrous mineral melting curves Melt generation along the 40°C/km geotherm TRACE ELEMENT GEOCHEMISTRY OF SIAM GRANITOIDS Strongly enriched in incompatible trace elements, especially LILE and LREE, U and Th. Negative anomalies in Sr and Ba (follows Ca) and TiNb-Ta (except intraplate granitoids) TRACE ELEMENT TECTONIC DISCRIMINATION DIAGRAMS FOR GRANITOIDS GRANITES CREATED DURING CONTINENT-CONTINENT COLLISION (OROGENESIS) POST- OROGENIC GRANTOIDS EXTENSIONAL COLLAPSE PostPenokean granites