Parent Magma Characteristics of Early Midcontinent Rift Ultramafic Intrusions Jim Miller1, Brian Goldner1,2, Dan Foley1, Pete Hollings3, and Geoff Heggie3,4 1) Department of Geological Sciences, University of Minnesota Duluth 2) Rio Tinto Exploration, Salt Lake City, Utah 3) Department of Geology, Lakehead University 4) Magma Metals, Thunder Bay, Ontario Early Midcontinent Rift Ultramafic Intrusions in Tamarack Hele Disraeli the Western Lake Seagull Kitto Superior Region Kitto Disraeli Hele Seagull Current L. Ontario E Minnesota Tamarack BIC Eagle Talk Outline • Textural and chemical characteristics of chilled margins in Tamarack, BIC, and Seagull Intrusions • Estimation and testing of major/minor element parent magma compositions by subtracting contributions of Ol phenocrysts • Trace element compositions of estimated parent magmas BODY 02L003) Cumulate PHC PHCFO Type Tamarack Intrusion Complete Alteration cOhcp Recharge CHILL- TAIL (03L004) fOhc OCHp Tamarack Basal Chill Basal Chill Zone 5 mm BIC Intrusion Recharge Chill Igneous Stratigraphy of 08BIC-044 Cumulus Min. Pl+Cpx+Ox Cpx+Ox±Ol Cpx+Ol Ol Cpx+Ol Ol Chill Zone Seagull Intrusion Seagull Basal Zone Amphibole-Olivine Pyroxenite Estimation of EUMI Parent Magmas Major-Minor Elements Tamarack Intrusion Intrusion Sample TAMARACK 4-334.2 Ol Correction Fe+2/Fe+3 Set at QFM, 1200oC BIC 4-334.2 4-334.2 20%Fo89 30%Fo89 08BIC-044.660 SEAGULL 08BIC-044.660 WM00-01 710 20%Fo86 WM00-01 710 WM00-01 716 20%Fo86 WM00-01 716 HELE DISRAELI 02TRH091N 03TRH154N 20%Fo86 SiO2 47.5 49.8 51.5 48.1 50.5 48.4 51.0 48.2 50.8 48.8 46.5 TiO2 0.82 1.02 1.17 1.53 1.92 1.27 1.60 1.16 1.47 2.32 1.80 Al2O3 8.7 10.9 12.5 7.8 9.8 7.2 9.0 6.2 7.9 8.4 7.4 Fe2O3 1.20 1.20 1.21 1.35 1.32 1.37 1.39 1.46 1.46 1.22 1.50 Cr2O3 0.49 0.27 0.46 0.20 0.26 0.38 0.47 0.31 0.39 0.10 0.20 FeO 9.7 9.8 9.8 11.0 10.7 11.1 11.2 11.8 11.8 9.9 12.1 MnO 0.17 0.18 0.18 0.18 0.19 0.21 0.23 0.20 0.21 0.18 0.30 MgO 23.2 16.6 12.0 18.4 11.3 19.5 12.6 20.9 14.2 12.0 14.9 CaO 5.63 6.95 7.90 7.88 9.80 5.80 7.23 5.25 6.56 11.67 10.97 Na2O 1.13 1.42 1.63 1.60 2.01 1.99 2.52 2.04 2.58 2.79 1.90 K2O 0.41 0.51 0.58 0.48 0.60 1.12 1.42 1.00 1.27 1.01 0.90 P2O5 0.08 0.10 0.11 0.19 0.24 0.19 0.23 0.16 0.20 0.20 0.22 H2O+ 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Total 100.5 100.3 100.5 100.1 100.1 100.0 100.5 100.3 100.4 100.1 100.2 mg# 80.8 75.1 68.4 74.7 64.9 75.3 66.5 75.8 68.0 68.3 68.4 Q 0 0 1.21 0 0 0 0 0 0 0 0 or 2.34 3 3.47 2.82 3.61 6.53 8.47 5.81 7.54 6.02 5.36 CIPW Norm ab 9.91 12.7 14.82 14.29 18.4 17.64 22.85 18.02 23.29 19.45 13.81 an 16.96 21.75 25.32 12.68 16.35 7.21 9.28 4.76 6.18 7.53 9.19 ne 0 0 0 0 0 0 0 0 0 3.48 2.04 di 7.77 9.56 10.92 19.99 25.31 15.99 20.35 15.87 20.19 39.62 35.4 hy 29.96 38.14 41.08 21.31 28.64 15.22 20.65 14.51 20.06 0 0 ol 29.43 11.97 0 24.98 3.03 33.83 14.19 37.61 18.72 18.93 29.63 mt 2.35 1.25 1.28 1.41 1.42 1.45 1.47 1.5 1.53 1.29 1.58 il 1.11 1.42 1.65 2.12 2.73 1.75 2.25 1.59 2.06 3.26 2.53 ap 0.16 0.21 0.23 0.4 0.51 0.39 0.49 0.33 0.42 0.42 0.46 From Goldner (2011) Estimation of EUMI Parent Magmas Testing with PELE Fractional Crystallization Modeling Ox in Pl in,Ol out Cp/Op in Ol out Ox in Op in Pl in Cp in Ol in Estimation of EUMI Parent Magmas Testing with PELE Fractional Crystallization Modeling Ol out Pl in Ox in Cp in Qualitative Phase Equilibrium of EUMI Parent Magmas DC PM (Al2O3 14-17%) Tamarack PM (Al2O3 9-12%) BIC & Seagull PM (Al2O3 6-9%) Estimation of EUMI Parent Magmas Trace Elements 100.0 1000.00 Early EarlyUltramafic UltramaficIntrusions Intrusions 100.00 OIB EMORB EMORB OIB 10.0 Tamarack Tamarack PM PM BIC BIC PM PM Seagull Seagull PM PM 10.00 1.0 1.00 Nd La Sm Gd Hf Sm Tb EuDyTi Gd Ho Tb Dy Er RbLa Ba Ce U Th PrNb Ta Ce Pr Eu Nd Zr Yb Tm Lu Y Tm Ho Er Yb Lu V Sc * Sun and McDonough (1989), McDonough and Sun (1995) Comparison to Early MCR Volcanics Hele Seagull Disraeli Garnet Lherzolite BIC Tamarack Spinel Lherzolite From Hollings et al., 2007 Comparison to Early MCR Volcanics (mg#>59) 100.0 100.0 Siemens Creek Mamainse Pt Gp 1 Tamarack PM BIC PM Seagull PM 10.0 10.0 1.0 100.0 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 1.0 100.0 Osler Group 10.0 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Mamainse Point Gps 2-7 10.0 1.0 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 1.0 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Comparison to Early MCR Volcanics Disraeli BIC Seagull Hele Tamarack From Hollings et al., 2007 Comparison to Early MCR Volcanics (mg#>59) 1000.0 Siemens Creek 1000.0 Mamainse Pt Gp1 Tamarack PM 100.0 100.0 BIC PM Seagull PM 10.0 1.0 1.0 Rb Ba U Th Nb Ta La Ce Pr Nd Zr Hf Sm Eu Ti Gd Tb Dy Y Ho Er Tm Yb Lu V Sc Rb Ba U Th Nb Ta La Ce Pr Nd Zr Hf Sm Eu Ti Gd Tb Dy Y Ho Er Tm Yb Lu V Sc 10.0 1000.0 1000.0 Mamainse Pt Gps 2-7 Osler Group 100.0 100.0 10.0 10.0 1.0 Rb Ba U Th Nb Ta La Ce Pr Nd Zr Hf Sm Eu Ti Gd Tb Dy Y Ho Er Tm Yb Lu V Sc Rb Ba U Th Nb Ta La Ce Pr Nd Zr Hf Sm Eu Ti Gd Tb Dy Y Ho Er Tm Yb Lu V Sc 1.0 Conclusions • The marginal zones of the Tamarack, BIC and Seagull intrusions represent chilled zones of magmas moderately enriched (20-30%) in olivine phenocyrsts. • Correcting for excess olivine accumulation, marginal compositions reflect reasonable approximations of likely parent magma compositions to these intrusions. • Parent magma compositions for the Seagull and BIC intrusions are similar to OIB except for depletion in Nb and Ta (Magma Type 2 of Nicholson). Seagull is more HREE depleted (=deeper source?) • Parent magma composition of the Tamarack intrusion are more akin to EMORB differs by the other intrusions by being higher in Si and Al, less enriched in IE trace elements, and more depleted in Nb and Ta (= shallow source? Magma Type 1 or 3 of Nicholson). It is noteworthy that Tamarack is one of the youngest UM MCR intrusions. • All magmas were contaminated by S and other volatiles, with Tamarack also contaminated with Si, U, and Th.