Chemistry 3522 (Spring, 2015)
Farooq A. Khan and Lucille B. Garmon
Welcome to Chemical Thermodynamics, CHEM 3522!
Considerations of energy, entropy, equilibria and rates are central in chemical reactions. In this
course we will revisit these familiar subjects of thermodynamics and chemical kinetics in greater
depth.
Learning Outcomes
The student who successfully completes this course is expected to develop the ability to:

Apply thermodynamic principles in ideal as well as real systems;

Use mathematical concepts such as partial derivatives, exact and inexact functions and to
apply them to chemical systems;

Interpret kinetic data in terms of rate equations and mechanisms; and

Relate principles of thermodynamics and kinetics to chemical and selected biological
problems.
Topics
Ideal gases; fundamental concepts of thermodynamics: Heat, work, internal energy, enthalpy,
and the First Law of Thermodynamics; state functions: Internal energy and enthalpy;
thermochemistry; entropy and the Second and Third Laws of Thermodynamics; Maxwell
relations; chemical equilibrium; real gases; phase diagrams and the relative stability of solids,
liquids, and gases; ideal and real solutions; colligative properties; chemical kinetics: Integrated
rate laws and Arrhenius equation.
1
General Information
Instructor
Farooq A. Khan, Phone (678)839-6027
Office: COSM Dean’s Office (3rd Floor, TLC); email: fkhan@westga.edu
Class time
Tuesdays and Thursdays, 1:00 - 2:20 pm; Workshops: W 1:00-2:20 pm
Textbook
Thermodynamics, Statistical Thermodynamics & Kinetics by Engel &
Reid, 3rd edition
Office Hours
Mondays
1:00 – 2:00 pm
Tuesdays
3:00 – 4:00 pm
Wednesdays
10:00 – 11:00 am
3:00 - 4:00 pm
Additional office hours can be arranged by appointment.
Attendance
Required. A student may be awarded a failing grade in the course if
more than 20% of classes are missed.
A Word about Expectations
It is quite likely that you have heard anecdotal accounts of how tough physical chemistry really
is, and how instructors derive pleasure from deriving equations, one after another. I will not
dispute that! At the same time, I must point out that in nearly two decades of teaching and
research I have found it to be a beautiful subject in which one puts together seemingly diverse
concepts from chemistry, physics and mathematics while examining natural phenomena.
Four words summarize a tried and tested strategy for learning the most in this course. Take your
homework seriously.
Homework assignments will be given regularly during the semester.
Approximately 60 % of questions on the examinations will closely resemble these assignments.
In addition, Wednesdays will be designated for in-class interactive problem solving, or
Workshops.
Let us make a deal.
I will attempt to anticipate any difficulties you may have with the
underlying mathematics. Y’all do your homework and in-class problem solving seriously.
2
Quizzes, Graded Homework and Examinations
Examinations lasting 80 minutes will be given on the following Thursdays in class:
January 29
February 19
March 26
The final examination will be given on Thursday, April 23, 11:00 am -1:30 pm. It consists of
multiple-choice questions, and is prepared by the American Chemical Society.
Please note:
A take-home examination will be administered in mid-April.
A project (based on Livescribe) will be administered starting in mid-January.
Homework will be assigned approximately once a week, but not collected.
No make-up examinations will be given. In case of an illness or a dire emergency, a student
may be excused from one in-class examination, provided the instructor is contacted prior to the
examination. If excused, the score for this examination will be the average of all in-class
examinations.
At the discretion of the instructor, an addendum to an in-class examination may be given in
the form of an announced in-class quiz or a take-home assignment, which must be
completed by a specified date.
Oral Presentation
Working in groups of two, prepare a presentation on any topic in physical chemistry with “reallife” applications. Also, include a biography of a scientist most closely associated with the
subject. Presentations will be held in class on Thursday, April 9.
In-class writing exercises
At the end of each class, the instructor will ask the class to carry out a brief writing exercise.
3
Grades
Your grade will be calculated based on the following components:
In-class examinations (3 @100 points each)
300 points
Take-home examination
100 points
ACS Final
200 points
The final may be curved at the discretion of the instructor.
Workshops
75 points
Oral Presentation
25 points
In-class writing exercises
50 points
Livescribe Project
100 points
TOTAL
850 points
Letter grades
Score
Grade
88% - 100%
A
75% - 87%
B
60% - 74%
C
50% - 59%
D
0% - 49%
F
Policy on cheating
Occurrences of cheating are rare. However, cheating by one individual raises questions about
fairness for the rest of the class, and indeed, endangers the honor code that governs our
examination system. It is after considerable thought and agonizing that I have arrived at the
following formula. If an individual cheats on an examination for the first time, he/she will obtain
a score of zero for that particular examination. If an individual is caught cheating a second time
during the semester, he/she will receive a grade of F for the entire course.
4
11857 CHEM 3522 01 3.00
Chemical
Carrollton Campus
Thermodynamics
APR
TLC JAN 05,
01:00 pm 24, TR
TECHNOLOGY 2105
2015
02:20 pm
2015
LEARN CTR
APR
JAN 05,
24, W
2015
2015
TLC 01:00 pm TECHNOLOGY 3104
02:20 pm
LEARN CTR
Instructor(s):Farooq A. Khan
,Lucille B. Garmon
Open Seats:7 of 15 as
of 01/05/2015
02:47:37
Co-requisites: MATH 2654
Pre-requisites: CHEM 1211 Minimum Grade: C and
CHEM 1212 Minimum Grade: C and MATH 1634
Minimum Grade: C and MATH 2644 Minimum Grade:
C and PHYS 2211 Minimum Grade: C and PHYS 2212
Minimum Grade: C
Additional Information:
Instructional
Method: Technology
enhanced (T)
Tuesday/Thursday
8:00-9:20
Class
classes....................Tuesday,
Periods
Apr
21,
8:00-10:30
am
9:30-10:50
classes..................Thursday,
Apr
23,
8:00-10:30
am
11:00-12:20
classes................Tuesday,
Apr
21,
11:00-1:30
pm
12:30-1:50
classes..................Thursday,
Apr
23,
11:00-1:30
pm
2:00-3:20
classes....................Tuesday,
Apr
21,
2:00-4:30
pm
3:30-4:50 classes....................Thursday, Apr 23, 2:00-4:30 pm
5