HOUSTON COMMUNITY COLLEGE SOUTHWEST COURSE OUTLINE FOR CHEM 1411 GENERAL CHEMISTRY I SPRING 2011 Class Number: 69750 Time and location West Loop Center: 8:00 AM - 11:00 AM: Tue & Th (Lectures: Rm. C220); Th (Labs: Rm. 164). Instructor Dr. Ambrose Okpokpo Office hours: by appointment only E-mail: ambroseokpokpo@hccs.edu Web site: http://learning.swc.hccs.edu/members/ambrose.okpokpo http://swc2.hccs.edu/pahlavan Textbook Laboratory Manual Chemistry, Tenth Edition, by Raymond Chang McGraw Hill Higher Education HCCS SW Chemistry Lab Manual, Custom Laboratory Program for Chemistry 1411 & 1412 Cache House 2010 ISBN: 0077274318 ISBN-13: 9780077274313 ISBN-13: 978-1-59984-186-1 EACH STUDENT MUST HAVE HIS OWN LAB MANUAL. COPIES ARE NOT ACCEPTED. Optional Study Guide Student Solutions Manual to accompany Chemistry, Tenth Edition, prepared by Brandon Cruickshank. McGraw Hill Course Catalog Description Science and Engineering majors study atomic structure, chemical reactions, thermodynamics, electronic configuration, chemical bonding, molecular structure, gases, states of matter, and properties of solutions. The laboratory includes appropriate experiments. Prerequisites: One year of high school chemistry and MATH 1314 (College Algebra). 4 credit (3 lecture, 3 lab). Course Prerequisites These are stated in the course description in the HCC catalog (quoted just above) and they are stressed again here for emphasis. Lack of satisfactory completion of the course prerequisites are one of the main reasons that cause students to do poorly in chemistry. Basic math and problem solving skills at the level of college algebra are essential. If you are not sure if your prior coursework meets these prerequisites, come and talk to me or to the department chair for advice. With the prerequisites satisfactorily completed (preferably with a grade of B or better), you can be confident that you are well-prepared for this course. Course Intent This course is intended for students majoring in one of the physical sciences or life sciences, or for students who are pursuing pre-professional programs in medicine, dentistry, pharmacy, veterinary medicine, or other health programs. The course is also beneficial to students who are preparing themselves for higher level science courses in their respective curricula. Student Learning Outcomes 1 Give names and formulas of elements, ions, and ionic and molecular compounds. 2. Categorize, complete, and balance chemical reactions. 3. Do chemistry calculations involving reaction stoichiometry and energy changes. 4. Relate the properties of electromagnetic radiation (frequency, wavelength, and energy) to each other and to the energy changes atoms undergo which accompany electronic transitions. 5. Identify the parts of the periodic table and the trends in periodic properties of atoms. 6. Relate the properties of gases with the gas laws and extend the application of these relationships to reaction stoichiometry, gas mixtures, and effusion/diffusion of gases. 7. Depict chemical bonding with dot structures and valence bond theory and determine the molecular shapes (geometry) of molecules based on VSEPR and valence bond theory. Course Learning Objectives 1.1. Given the name, identify the formula and charge of positive and negative ions, and vice-versa. 1.2. Given the name, write the formula of ionic compounds, binary molecular compounds, and acids, and given the formulas of these types of compounds, name them. 2.1. Identify given reactions as combination, decomposition, single displacement, and double displacement. 2.2. Starting with the reactants, complete the reaction by writing the reaction products. 2.3. Given the reactants and products, balance the equation for the reaction. 3.1. Convert amounts in units of mass or volume to moles, and vice-versa. 3.2. Given the amount of one substance in a reaction, calculate the amount of the other substances that react and form. 3.3. Identify the limiting reactant and excess reactant in a reaction where more than one reactant amount is given. 3.4. Determine the amount of the excess reactant that remains as unreacted excess. 3.5. Calculate energy changes associated with chemical reactions using Hess's law, standard enthalpies of formation, or calorimetry. 4.1. 4.2. 4.3. 4.4. 4.5. Relate frequency, wavelength, and the speed of electromagnetic radiation. From the frequency or wavelength of electromagnetic radiation, calculate its energy. Relate the energy change in the hydrogen atom to its electronic transitions using the Bohr model. Identify and relate the four quantum numbers that can be associated with electrons. Write the electronic configurations of atoms and ions, including the box diagram method. 5.1. Identify the common regions of the periodic table. Identify by name selected groups of elements in the periodic table. 5.2. Using the periodic table, identify the trend (increasing or decreasing in value) of selected properties of atoms such as atomic radius, ionization energy, and electron affinity. 5.3. Identify reaction similarities of elements within the same group in the periodic table. 6.1. Relate and calculate the pressure, volume, temperature, or amount of gas using Boyle's law, Charles' law, Gay-Lussac's law, Avogadro's law, the combined gas law, and the ideal gas law. 6.2. Perform stoichiometry calculations which involve gaseous substances. 6.3. Use Dalton's law and Graham's law to perform calculations involving gaseous mixtures and effusion and diffusion of gases. 6.4. Explain the assumptions of the kinetic-molecular theory of gases. 7.1. Draw the Lewis dot structure of molecules containing two or more atoms. 7.2. Based on the dot structure of the molecule, determine its electron domain geometry and molecular geometry based on VSEPR theory. 7.3. Given the dot structure, identify the hybridization of and geometry about each atom. Attendance Policy The HCCS attendance policy is stated in the Schedule of Classes: “Students are expected to attend classes regularly. Students are responsible for materials covered during their absences, and it is the student's responsibility to consult with instructors for make-up assignments. Class attendance is checked daily by instructors. Although it is the responsibility of the student to drop a course for non-attendance, the instructor has full authority to drop a student for excessive absences. A student may be dropped from a course for excessive absences after the student has accumulated absences in excess of 12.5% of the hours of instruction (including lecture and laboratory time).” If circumstances significantly prevent you from attending classes, please inform me. I realize that sometimes outside circumstances can interfere with school, and I will try to be as accommodating as possible, but please be aware of the attendance policy. Last Day for Administrative and Student Withdrawals This date is stated in the Schedule of Classes. After the withdrawal date no W can be given, you must receive a regular grade (A-F) in the course. I urge any student who is contemplating withdrawing from the class to see me first! You may be doing better than you think. Either way, I want to be accessible and supportive. I do not believe in "weed out" classes, and I consider you to be much more than just a name or number! If you need assistance, do not hesitate to contact me (my phone number and e-mail address are listed above). I'm here to help. IMPORTANT NOTICE: Students who repeat a course three or more times may soon face significant tuition/fee increases at HCC and other Texas public colleges and universities. If you are considering course withdrawal because you are not earning passing grades, confer with your instructor/counselor as early as possible about your study habits, reading and writing homework, test-taking skills, attendance, course participation, and opportunities for tutoring or other assistance that might be available. Disability Support Services (DSS) HCCS is committed to compliance with the American with Disabilities Act and the Rehabilitation Act of 1973 (section 504) "Any student with a documented disability (e.g. physical, learning, psychiatric, vision, hearing, etc.) who needs to arrange reasonable accommodations must contact the Disability Services Office at the respective college at the beginning of each semester. Faculty are authorized to provide only the accommodations requested by the Disability Support Services Office” If you have any special needs or disabilities which may affect your ability to succeed in college classes or participate in college programs/activities, please contact the office of disability support services at the college. Upon consultation and documentation, you will be provided with reasonable accommodations and/or modifications. Please contact the DSS office as soon as you begin the term. For questions, contact Donna Price at 713 718 5165 or the Disability Counselor at HCC-Southwest: Dr. Becky A. Hauri at 713 718 7909; also see the Schedule of Classes for additional DSS numbers. Also visit the ADA web site at: http://www.hccs.edu/students/disability/index.htm. Faculty Handbook/ Faculty Orientation is also available at http://www.hccs.edu/students/disability/faculty.htm HCCS Sexual Harassment Policy HCC shall provide an educational, employment, and business environment free of sexual harassment. Sexual harassment is a form of sex discrimination that is not tolerated at HCC. Any student who feels that he or she is the victim of sexual harassment has the right to seek redress of the grievance. HCC provides procedures for reviewing and resolving such complaints through its Grievance Policy. Substantiated accusations may result in disciplinary action against the offender, up to and including termination of the employee or suspension of the student. In addition, complainants who make accusations of sexual harassment in bad faith may be subject to equivalent disciplinary action. Academic Honesty Students are responsible for conducting themselves with honor and integrity in fulfilling course requirements. Disciplinary proceedings may be initiated by the college system against a student accused of scholastic dishonesty. Penalties can include a grade of "0" or "F" on the particular assignment, failure in the course, academic probation, or even dismissal from the college. Scholastic dishonesty includes, but is not limited to, cheating on a test, plagiarism, and collusion. Laboratory Policy On the first day of lab a safety video will be shown (about 35 min long) and a safety "quiz" will be given and reviewed. Each student will then sign a statement affirming his or her commitment to following safe procedures in the laboratory, and turn the form in to the instructor. You should be especially aware of the need for adequate eye protection and proper dress in the laboratory. Glasses or goggles must be worn at all times during the laboratory period. Any student not wearing glasses or goggles after the experiment has begun may be given a zero for that experiment! Experiments will be performed in groups of up to two students each. Before you leave the lab, be sure to show me your report so I can review and initial it . Each student should arrive at the lab on time, with his or her lab manual. Laboratory reports are due on or before the next lab experiment. Each report must be done individually, but of course you can work with your lab partners. If you are not sure about a calculation or a particular section, always feel free ask me about it! Each report will be graded on a 100-point basis. Come to lab prepared. Read through the experiment beforehand, and review the pre-lab questions and answer them in the lab manual. You will be much better organized when doing the experiments, and your laboratory experience will be much more rewarding! Exams, Quizzes, and Make-up Policy Examinations will consist of three non-cumulative regular exams (45%) plus a comprehensive final (20%). Make-up exams will not normally be given, so make every effort to take the exams on their scheduled dates. In the event that you must miss one and only one regular exam, the final exam grade may be substituted for the missed exam. Remember that the final exam will be comprehensive and is usually more difficult than the regular exam (meaning that it will cover all of the material from the whole semester, not just the last part). If you do not miss any of the regular exams, I will replace your lowest exam score with your final exam score if the final exam grade is higher. During the semester I will periodically give a short chapter quiz at the beginning of class. I will drop the lowest quiz grade. The remainder will count as a regular exam grade (15%) which cannot be dropped. These quizzes are highly beneficial for learning the material and are intended to help you in this regard. Please note: 1) All students are required to take the final (no student can be exempted), 2) After the withdrawal date, a grade of W cannot be given. Grading The overall score is based on the following: Three Regular Exams Quiz Grade 45% 15% Laboratory 20% Final Exam 20% Overall Score = 0.45(Average of three regular exams) + 0.15(Quiz Grade) + 0.20(Laboratory grade) + 0.20(Final Exam) The course grade is then obtained from the overall score: Final Average Letter Grade 90 - 100 A 80 - 89 B 70 – 79 C 60 – 69 D < 60 F Other Information Free chemistry tutoring is available. A tutoring schedule will be posted in the classroom and lab and will also be placed on my web site and departmental web site. There are many interesting chemistry resources on the Internet. These are interesting and informative, but spending long hours searching for sites or waiting for graphics intensive sites to load, is not beneficial! Your best immediate source of information is your textbook - make thorough use of it. Important Dates: January 18: February 21: March 14-20: April 21: (4:30 pm) Classes Begin Presidents Day Holiday Spring Break Last Day for Administrative/ Student Withdrawals with a grade of “W” April 22-24: May 8: May 12: May 20: Easter Holiday Instruction ends Final Exam ( Thursday at 8:00 a.m.; 2 hours) Grades Available to Students. ”After the withdrawal date no W can be given, you must receive a regular grade (A-F) in the course.” General Suggestions Chemistry is a vast field, ranging from the study of simple inorganic salts to enormously complex molecules such as enzymes and nucleic acids in living organisms. In this course, the major topics we will be covering are Chemical Formulas, Reactions, and Stoichiometry Calculations, Gas Laws, Chemical Thermodynamics, Electron Configuration, Chemical Bonding, and Solutions. As you might suspect, it can be easy to fall behind and, as a result, to not be ready for the exams. Following are some general tips that may be helpful: Learning chemistry takes time. A reasonable guide is to allow yourself two hours of study for each hour of lecture. Heavy work and/or class loads are not compatible with learning chemistry! Attend class regularly (!) and take generous notes during class. Ask questions. When beginning a new chapter, I recommend that you read through it quickly the first time, just to give yourself a good feel for what it is about. I you are really on the job you will have done this before the class lecture on the chapter! You will understand what's going on in class much better if you do this. Next, start tackling the end of chapter problems! Often, working problems facilitates understanding much better than just reading and rereading the chapter itself. Chemistry is a "hands on" course - working problems is essential. However, do not spend an inordinate amount of time on a single problem - skip it for the time being and go on to another. Try working some of the sample exercises. They are worked out in the chapter and are very helpful. Get a good, scientific calculator that has scientific notation ("EE" or "EXP" key), log, ln, x2, , etc. Business calculators usually do not have all of these features. Review basic math operations such as properties of logarithms, if you are rusty. Study groups can be very helpful. Keep the group small though, no more than three or four people. Finally, keep a positive attitude! Chemistry can be hard, but with the right attitude and approach, you will succeed in mastering it! I hope you find chemistry to be an interesting and rewarding subject which will not only be useful in your academic major, but will give you a better insight into the many scientific challenges we are facing today. I look forward to working with you this semester! COURSE SCHEDULE Chapter 1 – Chapter 2 – Chapter 3 – The Study of Change Atoms, Molecules, and Ions Mass Relationships in Chemical Reactions. EXAM #1 ( Chapter 1-3) Chapter 4 Chapter 5 Chapter 6 Chapter 7 – – – – Reactions in Aqueous Solutions Gases Thermochemistry Quantum Theory and the Electronic Structure of Atoms EXAM # 2 ( Chapter 4-7) Chapter 8 – Chapter 9 – Chapter 10 – Chapter 11 – Periodic relationships Among the Elements Chemical Bonding I : Basic Concepts Chemical Bonding II : Molecular Geometry and Hybridization of Atomic Orbitals Intermolecular Forces and liquids and solids EXAM # 3 ( Chapter 8-11) LABS SCHEDULE EXPERIMENT 1 – Measuring Techniques and Calculations EXPERIMENT 2 – Physical Properties - Separation of a Mixture EXPERIMENT 3 – Identification of Substances EXPERIMENT 4 – Empirical formula of an Oxide EXPERIMENT 5 – Formula of a Hydrate and Percentage of Water of Hydration EXPERIMENT 6 – Metathesis Reactions in Aqueous Solutions: Net Ionic Equations EXPERIMENT 7 – Reactivity of Metals - Activity Series EXPERIMENT 8 – Heat of Neutralization EXPERIMENT 9 – Molecular Weight of a Volatile Compound EXPERIMENT 10 –The VSEPR Theory of Molecular Geometry EXAMS SCHEDULE 15* EXAM 1 – Chapters: 1- 3 April 5* EXAM 2 – Chapters: 4 - 7 May 3* EXAM 3 – Chapters: 8 – 11 February May 12 (*) Date may change FINAL EXAM – Chapters: 1 - 11