Supplementary Materials Chemical characteristics of rainwater in Sichuan basin, a case study of Ya’an Yun-Chun Li ▪ Meng Zhang ▪ Man Shu ▪ Steven Sai Hang Ho ▪ Zi-Fang Liu ▪ Xian-Xiang Wang ▪ Xiao-Qing Zhao __________________________________________________ Y.C. Li () College of Science, Sichuan Agricultural University, Ya’an, 625014, China School of Environmental Science and Engineering, Nanjing University of Information Science and Technology, Nanjing, 210044, China e-mail: yunchunli@sicau.edu.cn M. Zhang ▪ M. Shu ▪ X.X. Wang ▪ X.Q. Zhao College of Science, Sichuan Agricultural University, Ya’an, 625014, China Yun-Chun Li and Meng Zhang contributed equally to this work S.S.H. Ho Key Lab of Aerosol Chemistry & Physics, Institute of Earth Environment, Chinese Academy of Sciences, Xi’an, 710075, China Z.F. Liu Environmental Monitoring Station of Ya’an City, Ya’an, 625014, China Table S1. Comparison between the sampling programs in Ya’an Table S2. Correlation coefficients (R2) between ionic species in rainwater in Ya’an Fig. S1 Typical backward trajectories for rain events associated with air masses from the five defined sectors. a: regional; b: south-east; c: north-west; d: south-west wind; e: north-east 1 Table S1. Comparison between the sampling programs in Ya’an 2010-2011 (Zhao et al. 2013) Spring Summer Autumn Winter 1-18 Apr. 2011 3-16 Jun. 17-28 Sep. 2010 31 Dec. 2010-14 Jan. 2011 Number of samples 9 7 6 6 2013-2014 (This study) May 2013, Mar.-May 2014 Jun.-Aug. 2013 Sep.-Nov. 2013 Dec. 2013 Number of samples 16 20 6 4 Table S2. Correlation coefficients (R2) between ionic species in rainwater in Ya’an NH4+ K+ Na+ Mg2+ Ca2+ ClNO3SO42- NH4+ 1 0.72 0.45 0.44 0.32 0.77 0.77 0.85 K+ Na+ Mg2+ Ca2+ Cl- NO3- SO42- 1 0.59 0.53 0.41 0.80 0.77 0.79 1 0.65 0.63 0.73 0.46 0.56 1 0.89 0.68 0.56 0.55 1 0.57 0.41 0.42 1 0.84 0.84 1 0.86 1 a b 2 c d e Fig. S1 Typical backward trajectories for rain events associated with air masses from the five defined sectors. a: regional; b: south-southeast; c: west-northwest; d: southwest; e: north-northeast 3