CHE130--Molecules; CHE130L--Molecules Lab This course will be offered beginning Spring 2001. Its anticipated clients will be 1) Students in the Education Program 2) Students in the Advance program. In order to serve these constituencies, at least one section of the lecture course will be offered on the internet. Whether or not it will be possible to offer some experiments on an “in-the-home” basis is unclear. It is expected that at least some experiments will have to be performed in the lab for safety reasons. We believe that the internet sessions will be particularly attractive to the Advance students, and it should be possible to integrate these with weekend laboratories which will serve each “cohort”. The purpose of the course will be to introduce the basic ideas of chemistry: a set of ideas whose mastery will enable a person to say “I understand chemistry”. The importance for educators of this understanding is almost self-evident. In order to guide our youngest students in the sciences, they must have a clear intuitive knowledge of the explanations of everyday phenomena that the sciences offer. Misconceptions instilled in young students can last a lifetime and can hinder the students intellectual abilities in subsequent academic or non-academic learning environments. The importance of this kind of knowledge to future executives may not be quite so obvious, but a cursory examoination of the business sections of the newspapers or of the world wide web reveals an almost limitless treasury of examples of patent, copyright, technology, and financial issues all grounded in scientific innivation or scientific disputes. But aside from mere utility, understanding the world around us is a delight. We owe it to all our students to, to the extent this is possible, lead them out of Plato’s cave and to help them understand the real thing as opposed to the shadows flickering on the wall. Chemistry has been described by one text book author as the “Central Science” standing as it does between physics and biology. It provides the descriptive narrative that explains the mathematical insights of physics, and is itself, the core around which the biological story of physiology and evolution is constructed. The central concept in chemistry is that of the molecule--the idea that everything, from the color of my cell phone, to the texture of my skin, to the processes of life and evolution...everything that we see, feel, taste, smell or hear is ultimately explainable by an understanding of the interactions of tiny invisible molecules. Indeed, the very processes of hearing, seeing, smelling, touching and tasting are themselves understandable if we understand the molecules from which our sense organs are constructed. We will examine the following chemical ideas, doing so from the perspective of molecules which particularly illustrate each idea. Eight units will take four one-hour classes each, and four others willl last for 2 classes each (forty classes in all). Classroom presentations will in general be accompanied by molecular model building. CHE 130 Lecture 1) atom, molecules, elements What is the difference between a pure substance and a mixture, an element and a compound, an atom and a molecule? Periodic Table Solutions 2) Forces betwen atoms and molecules What kind of forces hold molecules together? Idea of electrical charge. What kinds of forces attract molecules to one another? What do molecules “looklike” (this being determined by the intramolecular forces)? States of matter (solid, liquid, gas, amorphous, liquid crystals), these being determined by the intermolecular forces What kinds of forces operate in solutions 3) Kinds of molecules Atoms Diatomic molecules Ions dimers macromolecular substances polymers isomerism 4) Chemical reactions chemical equations combination decomposition single displacement doube displacement What makes reaactions “go”? 5) Heat--2 classes what is heat? Heat comes from energy stored in chemical bonds 6) Entropy--2 classes Idea of disorder Philosophical implications practical implications for whether a reaction happens or not 7) The idea of equilibrium--2 classes Idea of Dynamic Eq2quilibrium No reaction happens completely How we influence position of equilibrium 8) The idea of rate--2classes What determines speed of reaction Idea of catalysis Enzymes Half life Very Fast and very slow reactions 9) Light What is light? What is color? Color and energy Chemiluminescence (emission of light from a reaction) Absorption of light 10) Acids and Bases What are they? The idea of pH Strong and Weak We eat acids and clean with bases Indicators 11) Electricity Oxidation and reduction Using electricity to split up molecules Tricking natuire into providing us with electricity 12) The molecules of Life Natural Products Sugars Lipids Proteins DNA Biological construction materials CHE 130L Lab 1) Molecules A series of experiments to differentiate atoms, molecules, elements, compounds, pure substaces, mixtures 2) Moleular Shapes Model Building showing 5 basic molecular symmetries and experience with chemicals that possess these structures 3) Kinds of Molecules Model building of ionic and covalent substances examoing variuous tyoes of bonding 4) Chemical reactions Generate a gas Generate a precipitate CopperPlate a nail Decompose peroxide and collect oxygen 5) Heat Observation of Endothermic and exothermic processes, heats of vaporization, supercooling 6) Rate and Equilibrium Cobalt Chloride (invisible Ink) Light Sticcks Catalytic production of hydrogen 7) Light Luminol Light Sticks 8) Acids and Bases Indicators pH meters Household chemicals 9) Electricity Electrolytic decomposition of water Fabrication of a simple battery 10) Life Properties of Lipids, sugars and proteins