Discussion of the Voigt Profile

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Discussion of the Voigt Profile

The Voigt profile is a mathematical function which accurately represents the absorption cross section per atom,

α

ν

[cm

2

], for conditions under which the only significant operational linebroadening mechanisms are radiation damping (natural line width), collisional damping and thermal Doppler broadening. (With modification of the temperature parameter, T , it can also accommodate the broadening effects of microturbulence.) The Voigt profile is written,

0 a 

  a

2 e

 y

2

( u

 y )

2 dy .

In this expression

0

 e

2 mc f

1

 

D

 g n g n '

A nn '

 2

8

3

2

1

 

D

[ cm

2

] is called the "fictitious absorption coefficient." It corresponds to the central value of the absorption coefficient (

ν

=

ν

0

, u = 0) for the case of zero damping (

Γ

=

δ

= a = 0). Since such a case never occurs, the title is appropriate. The definitions and physical significances of each of the other parameters in the expression for α

ν

are as follows:

 

D

 c

0

2 kT is simply the

M

" Doppler wi dth" as has been previously defined.

 

'

0 v

 c

'

 ν

0 is the Doppler shift of the central frequency for radial velocity v .

δ  Γ /4π = δ r

+ δ c

 Γ r

/4π +  Γ c

/4π is the "damping" half width (a combination of radiation damping and collisional damping). y

 ν'/  ν

D is the ratio of the Doppler shift to the Doppler width, i.e

., the Doppler shift in units of the

Doppler width.

 ν = ν 

ν

0 is the displacement of the frequency under consideration from the line center, u

 

 

D

0 

 

 

D is the displacement of the frequency under consideration from the line center in units of the

Doppler width and

a

 

D is the ratio of the damping half width to the Doppler width, i.e

., the damping half width in units of the Doppler width. Note that a , u and y , all the variables in the explicit definition of the Voigt profile, except α

0

, are dimensionless.

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