i EVALUATION AND PERFORMANCE OF GROSS POLLUTANT TRAPS (GPTs) FOR OPEN CHANNEL FLOW NOOR SURAYA BINTI ROMALI A project report submitted in partial fulfilment of the requirement for the award of the degree of Master of Engineering (Civil – Hydrology and Water Resources) Faculty of Civil Engineering Universiti Teknologi Malaysia NOVEMBER, 2008 iii DEDICATION To my beloved mother and father, Fatimah Binti Mohamad and Romali Bin Jusoh, my sisters and brothers, my special friend, not forgotten my supervisors, Assoc. Prof Dr. Norhan Bin Abd Rahman, Pn Noraliani Binti Alias. Thank you for your special supports. iv ACKNOWLEDGEMENT In the name of Allah S.W.T, the Almighty and Merciful, I am so grateful for the chances, strength and patience in me in the accomplishment of this study. My appreciation goes much to my supervisor, Assoc. Prof Dr. Norhan Bin Abd Rahman and my co-supervisor, Pn. Noraliani Binti Alias for their guidance, expertise, knowledge, and opinion that help me to complete this study. My thanks go to Muhammad Fuad Bin Shukor, Irma Norazurah Binti Mohamad, Nur Hanim Binti Abd Ghani and all technicians that are giving full commitment and cooperation during this study. My thanks also dedicated for my friends and lecturers for their helps, advices, and supports. Lastly, a special compliments for the most important person in my life, my parents, family, and my special friend for their supports. Their loves give me strength to accomplish this study. v ABSTRACT Nowadays, water has become a scarce resource due to the water contamination problem. Pollution carried by urban stormwater is considered as one of the significant contributor to the degradation of receiving waters. One way to minimize water pollution is by constructing Gross Pollutant Traps (GPTs) at the point source to treat polluted water prior to being discharged into the river. This study emphasizes on the utilization of GPTs in removing pollutants during dry and wet weather conditions especially during stormwater events in open channel system. The GPTs system is consist of rubbish trap, oil and grease trap, and biofilter which located at Block L50, UTM Skudai. The results indicated that the GPTs system is effective in improving water quality during storm event where the effluent of discharge water of the GPTs system are comply with parameter limit as stated in Standard A and Standard B of Environmental Quality Act (1974). First flush analysis shows that the concentration of pollutants in first flush runoff is found more polluted than the remainder while the values of EMC for TSS, COD, and BOD are higher compared to other pollutants. Despite of functioned for water quality control, the GPTs is also benefit for water quantity control where it provide detention time, storage, and decrease the peak flow of the water flowing through the system. vi ABSTRAK Air telah menjadi satu sumber yang terhad ekoran daripada masalah pencemaran air yang berlaku pada masa kini. Bahan cemar dari air larian permukaan yang dibawa oleh hujan lebat telah dikenalpasti sebagai antara faktor yang merendahkan kualiti air. Satu cara untuk mengurangkan masalah pencemaran air ialah dengan menggunakan Gross Pollutant Traps (GPTs) untuk merawat air dari punca pencemaran sebelum dilepaskan ke sungai. Kajian ini menekankan keberkesanan sistem GPTs menyingkirkan bahan cemar semasa cuaca kering dan basah terutama sewaktu hujan lebat di dalam sistem saluran terbuka. Lokasi kajian terletak di sistem GPTs di Blok L50 UTM, Skudai. Sistem GPTs tersebut merangkumi perangkap sampah, perangkap minyak dan gris, dan penapis air biologi. Keputusan menunjukkan bahawa sistem GPTs ini efektif dalam meningkatkan kualiti air di mana ‘effluent’ dari sistem ini mematuhi had yang ditetapkan oleh Standard A dan Standard B Akta Kualiti Alam Sekitar (1974). Analisis air curahan pertama (first flush) mendapati tahap kepekatan bahan cemar adalah lebih tinggi dalam sampel air curahan pertama berbanding sampel air di akhir aliran air manakala nilai EMC untuk parameter TSS, COD, dan BOD adalah lebih tinggi berbanding parameter lain. Selain berkeupayaan untuk pengawalan kualiti air, GPTs juga berfungsi dalam pengawalan kuantiti air dengan menyediakan waktu tahanan air, penyimpanan air, dan dapat mengurangkan kadar puncak aliran air. vii TABLE OF CONTENTS CONTENTS ABSTRACT ABSTRAK TABLE OF CONTENTS LIST OF TABLES LIST OF FIGURES LIST OF SYMBOLS LIST OF ABBREVIATION LIST OF APPENDIX CHAPTER 1 1.0 INTRODUCTION 1.1 General 1.2 Problem Statement 1.3 Study Objectives 1.4 Scope of Study 1.5 Location of Study 1.6 Significance of Study CHAPTER 2 2.0 LITERATURE REVIEW 2.1 General 2.2 Water Pollution 2.2.1 Stormwater pollutants 2.3 First Flush 2.4 Event Mean Concentration (EMC) 2.5 Gross Pollutant Traps (GPTs) 2.5.1 Design Criteria and Mechanism of GPTs system 2.5.1.1 Rubbish Trap 2.5.1.2 Filtration 2.5.1.2.1 Biofiltration Swale and Vegetated Filter Strip PAGE v vi vii x xii xvi xvii xviii 1 2 3 3 5 7 8 9 10 12 13 19 19 20 22 22 viii 2.6 2.5.1.2.2 Media Filtration 2.5.1.3 Oil Separators 2.5.2 The effectiveness of GPTs as water pollution treatment devices 2.5.2.1 Gross Pollutants Traps 2.5.2.2 Filtration 2.5.2.3 Oil and Grease Traps 2.5.2.4 GPTs system at L50 Block, UTM Skudai Critical Appraisal 23 23 25 25 30 38 40 44 CHAPTER 3 3.0 METHODOLOGY 3.1 Introduction 3.2 Flow Chart of the Study Methodology 3.3 Experimental Site 3.3.1 Catchment Area 3.4 Experimental System 3.4.1 Rubbish Trap 3.4.2 Oil and Grease Trap 3.4.3 Biofilters 3.4.3.1 Modification of Biofilter 3.4.3.2 Filtration Materials 3.5 Data Collection 3.5.1 Rubbish and Sediment Data 3.5.2 Storm Events 3.5.3 Rainfall and Flow Measurement 3.5.3.1 Calibration 3.5.4 Water Sampling 3.5.4.1 Water Quality Sampling 3.5.4.2 Analytical Method 3.5.4.2.1 First Flush Sample 3.5.4.2.2 Water Quality Measurement 3.5.4.3 Data Analysis 3.6 Design Criteria Of GPTs 3.6.1 Rubbish Trap 3.7 Maintenance 45 46 47 49 50 50 51 52 55 55 56 56 57 58 59 61 61 62 62 62 63 64 65 66 CHAPTER 4 4.0 RESULTS AND ANALYSIS 4.1 Introduction 4.2 Performance of GPTs System during Dry Weather 4.3 Rubbish and Sediment Collection 4.3.1 Amount of Rubbish and Sediment 4.3.1.1 Block L50 Rubbish Trap 68 69 69 69 69 ix 4.4 4.5 4.6 4.7 4.8 4.3.1.1.1 Daily Collection 4.3.1.1.2 Three-day Period Collection 4.3.1.2 Block L52 Rubbish Trap 4.3.2 Rainfall Analysis 4.3.3 Classification of Rubbish 4.3.3.1 Daily Collection 4.3.3.2 Three-day Period Collection Water Quality Results 4.4.1 Block L50 GPTs system 4.4.1.1 Water Quality Evaluation 4.3.1.1.1 GPTs Evaluation Results 4.3.1.1.2 Rubbish Trap Evaluation Results 4.3.1.1.3 Biofilter Evaluation Results 4.4.2 Block L52 Rubbish Trap Water Quantity Control First Flush Analysis 4.6.1 Pollutograph Evaluation 4.6.1.1 Event 04/08/2008 4.6.1.2 Event 07/08/2008 4.6.1.3 Event 12/08/2008 4.6.1.4 Event 04/09/2008 4.6.2 Occurrence of First Flush Event Mean Concentration (EMC) Evaluation of Design Criteria 69 72 74 76 78 79 79 81 81 87 87 90 94 97 99 100 101 103 104 105 108 108 109 CHAPTER 5 5.0 CONCLUSION AND RECOMMENDATION 5.1 Conclusion 5.2 Recommendation 112 114 REFERENCES APPENDIX 115 121 x LIST OF TABLES TABLE TITLE PAGE 2.1 General urban runoff EMCs of US EPA, NURP, MOE (Ontario), USGS and NPDES and MASMA 15 2.2 Typical EMCs values of residential land use from various storm water runoff quality studies 17 2.3 Typical EMCs values of commercial land use from various storm water runoff quality studies 18 2.4 Overall Classification of Gross Pollutant Traps 20 2.5 Recommended Treatment Trains 30 2.6 Different types of materials used for modification 40 2.7 Mechanism of development used in oil & grease trap 41 3.1 Different materials used for modifications 55 3.2 Roles of the Filtration Media 56 3.3 Characteristics of monitored storm events at Block L50 57 3.4 Characteristics of monitored events at Block L52 58 3.5 Calibration results for IWK flow meters 60 3.6 Calibration results for TPI flow meter 61 3.7 Analytical Methods for Water Quality Measurement 63 3.8 Description of Water Quality Evaluation 64 4.1 Data Collection Procedure for rubbish trap at Block L50 and 70 xi rubbish trap at Block L52 4.2 Daily rubbish and sediment data collection at Block L50 Rubbish Trap 71 4.3 Three-day period rubbish and sediment data collection at Block L50 Rubbish Trap 73 4.4 Three-day period rubbish and sediment data collection at Block L52 Rubbish Trap 75 4.5 Description of rubbish types 79 4.6 Water Quality Events 82 4.7 Water Quality Results for 21/03/2008 84 4.8 Water Quality Results for 04/08/2008 84 4.9 Water Quality Results for 07/08/2008 85 4.10 Water Quality Results for 12/08/2008 86 4.11 Water Quality Results for Overall GPTs System 87 4.12 Percentages of Removal for GPTs 90 4.13 Evaluation Results for Rubbish Trap 91 4.14 Percentages of Removal for Rubbish Trap 93 4.15 Evaluation Results for Biofilter 94 4.16 Percentages of Removal for Biofilter 94 4.17 Water Quality Results for Block L52 Rubbish Trap 98 4.18 Water Quantity Results of GPTs system 99 4.19 Occurrence of First Flush 108 4.20 Event Mean Concentration (EMC) values 109 4.21 Typical Event Mean Concentration (EMC) values in mg/L 109 4.22 Design Criteria Results 110 xii LIST OF FIGURES FIGURES TITLE PAGE 1.1 Location of study area 5 1.2 Location of study area at UTM Skudai 6 2.1 Continuous Deflective System (CDS) trap 21 2.2 Schematic of API Separator 24 2.3 Schematic of Plate Separator 24 2.4 Schematic Plan View Representation of the CDS System 26 2.5 Isometric Representation of the CDS unit 27 2.6 Summary of Efficiency data used in DSS 27 2.7 Structure of the GPTs decision-support-system (DSS) for evaluating gross Pollutant trapping strategies 29 2.8 Schematic diagram of the experimental facility in St. A and St. B 32 2.9 Relationship reduction ratio of fish flush runoff by soil infiltration and total rainfall amount 33 2.10 Hardwood (HW) and western cedar (WC) media 34 2.11 Cross section of the grass-plate 35 2.12 Hydroponics botanical filter 36 2.13 Recirculating system 36 2.14 Floating system 36 xiii 2.15 Schematic diagram of an upflow packed bioreactor 38 2.16 Comparison results for Biofilter in terms of percentages of removal of TSS, COD and BOD 41 2.17 Comparison results of oil and grease trap in terms of percentages of removal of oil and grease and TSS 42 2.18 Graph of relationship between amounts of rubbish and rainfall for rubbish trap at L50 43 2.19 Suspended solid (SS) at point before and after rubbish trap 44 3.1 Flow chart of the study methodology 46 3.2 Location of Study (L50 UTM Skudai) 47 3.3 Road and Drainage Layout Plan of L50 Block, UTM Skudai 48 3.4 Catchment area for the GPTs system 49 3.5 Arrangement of GPTs system and dimensions in mm 50 3.6 Rubbish Trap located prior the sump and at the beginning of the system 51 3.7 Oil and Grease Trap 52 3.8 Biofilter system 53 3.9 Details of Biofilter system 53 3.10 Flow meter equipment at the inlet point of GPTs system(IWK) 58 3.11 Flow meter equipment at the inlet point of GPTs system(TPI) 59 3.12 Calibration of flow meter 60 3.13 Water Quality and Flow Assessment Sampling Point 62 3.14 Conditions of rubbish trap, oil and grease trap, and biofilter during stormwater event 67 4.1 Relationship between Rubbish and Sediment Amount with Rainfall at Block L50 Rubbish Trap (Daily Collection) 72 4.2 Relationship between Rubbish and Sediment amount with Rainfall at Block L50 Rubbish Trap (Three-day period collection) 74 xiv 4.3 Relationship between Rubbish and Sediment amount with Rainfall at Block L52 Rubbish Trap (Three-day period collection) 76 4.4 Correlation between Rubbish and Sediment amount with Rainfall at Block L50 Rubbish Trap for Daily collection and Three-day period collection 77 4.5 Correlation between Rubbish and Sediment amount with Rainfall at Block L52 Rubbish Trap for three-day period collection 78 4.6 Classification of rubbish according to types for daily collection for total collection and maximum day collection (Block L50 rubbish trap) 80 4.7 Classification of rubbish according to types for three-day period collection for total collection and maximum day collection (Block L50 rubbish trap) 80 4.8 Flow hydrograph and sampling time for event on 04/08/08, 07/08/08, and 12/08/08. 82 4.9 Water Quality Results for GPTs for parameters pH, SS, BOD, COD, AN, and DO 88 4.10 Water Quality Results for Rubbish Trap for parameters pH, SS, BOD, COD, AN, and DO 92 4.11 Water Quality Results for biofilter for parameters pH, SS, BOD, COD, AN, and DO 95 4.12 Water Quality Results for Block L52 during storm event and dry weather 97 4.13 Flow Hydrograph for event 04/08/2008, 07/08/2008, and 12/08/2008 99 4.14 Flow Hydrograph for event 04/09/2008 101 4.15 Pollutograph for event 04/08/2008 for parameters BOD, COD,SS, Cu, Zinc, and AN 102 4.16 Pollutograph for event 07/08/2008 for parameters BOD, COD,SS, Cu, Zinc, and AN 103 4.17 Pollutograph for event 12/08/2008 for parameters BOD, COD,SS, Cu, Zinc, and AN 104 xv 4.18 Pollutograph for event 04/09/2008 for parameters BOD, COD, SS, Cu, Zinc, AN, TP, Pb, Nitrite, and Nitrate 106 xvi LIST OF SYMBOLS m - Meter Q - Flow in Q in out - Flow out s - Second M - Pollutant mass V - Runoff volume t - Time C - Concentration > - Greater than < - Smaller than η - Pollutant removal efficiency xvii LIST OF ABBREVIATION AN Ammonia Nitrogen API American Petroleum Institute BMPs Best Management Practices BOD Biochemical Oxygen Demand CDS Continuous Deflective Separation COD Chemical Oxygen Demand CS Collector System DO Dissolved Oxygen EMC Event Mean Concentration GPTs Gross Pollutant Traps HW Hardwood MASMA Urban Stormwater Management Manual for Malaysia mg/L Milligram per liter mm Millimeter TSS Total Suspended Solid UTM Universiti Teknologi Malaysia WC Western Cedar DID Department of Irrigation and Drainage Malaysia ha Hectare xviii LIST OF APPENDIX APPENDIX A TITLE Average Recurrence Interval (ARI) for existing drainage PAGE 121 system B Invert Level (I.L) – GPTs System 127 C Slope – GPTs System 128 D Details Plan – GPTs System 129 E CALIBRATION FOR FLOW METER 134 F LABORATORY TEST RESULTS FOR EVENT 138 04/09/2008 G FIRST FLUSH CALCULATION 141 H EMC CALCULATION 169 I DESIGN CRITERIA CALCULATION 186 1 CHAPTER 1 INTRODUCTION 1.1 General Water is the basic element of life; without it life would not exist. It is one of the most important resources for man, and yet it is taken for granted because water is everywhere and it flows freely when we turn on the tap. The usage for water increases as population grows until the demand sometimes overshoots the supply or availability. Although the quantity of water on Earth is same all the time, the quality of the water that is available has drastically changed. Every watershed is affected by what takes place on the land. Once used, water flows out as quickly as it comes, down into the drain and into our rivers. The gunk and grease that is flushed down into the drain unthinkingly every day will ultimately find their way to a nearby river. In other words, we are poisoning the very resource that gives us life. Many ways have been practiced to reduce the water pollution. One of the ways is to treat wastewater at the source points. This can be accomplished by constructing Gross Pollutants Traps (GPTs) at the source point to treat water prior to discharge into the river. Generally, GPTs are devices that collect large pollutants from waterways, before they enter wetlands and marine waters. They are used in urban water infrastructure such as stormwater drains, urban wetlands, beach fronts, and airports. They generally collect larger items from the water, such as take away containers, leaves, bottles and plastic bags. Smaller pollutants, such as dirt, chemicals, heavy metals and bacteria are not collected directly by the GPTs; 2 however, some small particles are caught up in the larger items in the trap and thus prevented from reaching the waterway (Hughes, 2004). 1.2 Problem Statement Stormwater pollutants are generated from urban land-use activities and are transported from street surfaces by stormwater runoff before discharging into receiving waters. Community awareness of the environmental effects of urban stormwater pollution and their expectation that urban aquatic ecosystems are protected from environmental degradation has resulted in an increased emphasis on urban stormwater quality. Many local authorities have implemented stormwater management strategies for the protection of receiving waters. These include major public awareness campaigns to encourage environmental sensitivity and structural methods to physically remove pollutants from stormwater. Such initiatives are essentially focused on visible pollutant impacts and concerned with reducing gross pollutants, particularly litter. However, urban stormwater transports a variety of material ranging from large gross pollutants to fine particulates, all of which impact urban receiving waters and therefore require a waste water treatment device that are capable of removing the various types of the pollutants (Walker et. al., 1999). Pollution carried by urban stormwater is considered a significant contributor to the degradation of receiving waters. Urban stormwater pollutants include gross pollutants, trace metals and nutrients that are associated with sediments, and dissolved pollutants (Walker et. al., 1999). The generation and transport of pollution in urban systems during a storm event is multifaceted as it concerns many media, space and time scales (Ahyerre et. al., 1998). During the storm event, the concentration of pollutants in first flush runoff is believed more polluted than the remainder due to the washout of deposited pollutants by rainfall. To preserve the good quality of water resources, it is essential to control the water pollution in river by treating the waste water especially the first flush during 3 storm event which carries with it concentrations of pollutants that have accumulated during the period of dry weather between storms. An effective system of waste water treatment, such as GPTs is important to cater the various types and size of pollutants. 1.3 Study Objectives The objectives of the study are summarized as follows: 1. To evaluate the effectiveness of GPTs system in removing pollutants during storm event and dry weather conditions. 2. To investigate the occurrence and the influence of first flush to the concentration of pollutants entering GPTs system during storm events. 3. To obtain hydrologic data and Event Mean Concentration (EMC) for the purpose of the evaluation of GPTs system. 1.4 Scope of Study This Gross Pollutant Traps (GPTs) system consists of rubbish trap, oil and grease trap, and biofilter. The experimental site will operate at L50 where the stormwater come from nearby catchment area (parking lot and the nearby building). The scopes of this study are; i. An open drainage system at L50 Block, Universiti Teknologi Malaysia, Skudai. ii. To improve the design criteria of the existing GPTs system in order to provide a better quality of surface water runoff for the system. iii. To study about the first flush runoff phenomenon, in terms of its concentration of pollution load compared to normal runoff pollution load. 4 iv. To investigate the capability of the GPTs system in treating the first flush pollution load. v. To determine the relationship between the reductions of the first flush runoff pollution load by the GPTs system and the total rainfall amount. vi. To come out with hydrograph for stormwater events. vii. Determination of water quality parameters such as pH, Suspended Solid (SS), Chemical Oxygen Demand (COD), Biological Oxygen Demand (BOD), Dissolved Oxygen (DO), and Ammonia Nitrogen (AN). viii. The maintenances of the GPTs system to ensure the cleanliness of the experimental site and that there are no overflow of the system occur as the result of any blockage by the rubbish. 5 1.5 Location of study The Gross Pollutant Traps (GPTs) system is located at L50 Block, Universiti Teknologi Malaysia (UTM), Skudai. The compartmentalized GPTs consist of several compartments of Rubbish Trap, Oil and Grease, and Biofiltration. The UTM river in this study is the tributaries of the Sungai Skudai, as shown in Figure 1.1. Figure 1.2(a) and 1.2 (b) illustrated the location of study area at UTM Skudai. Mukim Kulai Seelong Study Area Sg Skudai Kangkar Pulai UTM, Skudai Taman Universiti Figure 1.1: Location of study area Mukim Tebrau 6 K TD I Experimental Site KTC L50 Lingkaran Ilmu KRP (a) (b) Figure 1.2: Location of study area (a) plan and (b) Google Image plan at UTM Skudai 7 1.6 Significance of Study GPTs is a device that has a good potential in removing water pollutants. Nowadays, there are various types of GPTs available in market, such as Baramy Trap, Continuous Deflective Separation (CDS) Trap, HumeCeptor, and Cleansall Trap. However, most of the GPTs systems are only concentrated in removing large pollutants mainly rubbish. There are still lack of GPTs systems that include the function of removing small size pollutants such as oil, grease, and bacteria available in market. Hence, a development of GPTs system that consists of compartments that will function in removing both large and small size of pollutants is essential in order to produce an effective water pollution treatment system. Moreover, most of the available products of GPTs are from overseas, mainly Australia. The study on GPTs in Malaysia is significant in order to produce our local GPTs’ product. 8 CHAPTER 2 LITERATURE REVIEW 2.1 General Water covers over 70% of the Earth's surface and is a very important resource for people and the environment. Water pollution affects drinking water, rivers, lakes and oceans all over the world. This consequently harms human health and the natural environment. Gross Pollutant Traps (GPTs) is a water treatment device that can be used to reduce water pollution by treating the water at point source. The design of GPTs is an important criterion that should be taken into account to obtain an effective result of water treatment. The aims of this study are, thus, to investigate the effectiveness of GPTs as a water pollution treatment device and to evaluate its performance during dry and wet weather condition especially on storm water event. In the following articles the related literature are briefly presented. This chapter is mainly divided into several parts. The first part contains the information about water pollution problems and the others will discuss about GPTs in terms of its types, design criteria and literature of previous studies on the role of GPTs in reducing water pollutions. 9 2.2 Water Pollution Water is one of the most important commodities which Man has exploited than any other resource for sustenance of his life. Most of the water on this planet is stored in oceans and ice caps which is difficult to be recovered for our diverse needs. Most of our demand for water is fulfilled by rain water which gets deposited in surface and ground water resources. The quantity of this utilizable water is very much limited on the earth. Though, water is continuously purified by evaporation and precipitation, yet pollution of water has emerged as one of the most significant environmental problems of the recent times. Not only there is an increasing concern for rapidly deteriorating supply of water but the quantity of utilizable water is also fast diminishing. The causes of such a situation may be many, but gross pollution of water has its origin mainly in urbanization, industrialization, agriculture and increase in human population observed in past one and a half century. The unique properties of water which make it universal solvent and a renewable resource also make it a substance which by virtue of these properties has got a much tendency to get polluted. Water can be regarded polluted when it gets changed in its quality or composition either naturally or as a result of human activities so as to become less suitable for drinking, domestic, agricultural, industrial, recreational, wildlife and other uses for which it would have been otherwise suitable in its natural or unmodified state (Goel, 2006). Water pollution can come from a number of different sources. If the pollution comes from a single source, such as an oil spill, it is called point-source pollution. If the pollution comes from many sources, it is called nonpoint-source pollution. The causes of water pollution include sewage and waste water, industrial waste and oil pollution. Pollution carried by urban stormwater is also considered a significant contributor to the degradation of receiving waters. Stormwater runoff typically contains significant amounts of anthropogenic pollutants as well as naturally occurring materials. 10 2.2.1 Stormwater pollutants Stormwater is a term used to describe water that originates during precipitation events. It may also be used to apply to water that originates with snowmelt or runoff water from overwatering that enters the stormwater system. Stormwater that does not soak into the ground becomes surface runoff, which either flows into surface waterways or is channeled into storm sewers. Stormwater is of concern for two main issues - one related to the volume and timing of runoff water i.e. flood control and water supplies and the other related to potential contaminants that the water is carrying i.e. water pollution. Because impervious surfaces such as parking lots, roads, buildings, compacted soil do not allow rain to infiltrate into the ground, more runoff is generated than in the undeveloped condition. This additional runoff can erode watercourses, as well as will cause flooding when the stormwater collection system is overwhelmed by the additional flow (Wikipedia, 2008). Pollutants’ entering surface waters during precipitation events is termed polluted runoff, and may also be labeled as nonpoint source pollution. Pollutants carried by urban stormwater runoff are considered a significant contributor to the degradation of receiving waters. Urban stormwater pollutants include gross pollutants, trace metals and nutrients that are associated with sediments, and dissolved pollutants. It is well recognized that a significant amount of pollutants are transported by stormwater as sediment-bound contaminants. Results from an investigation by Mann and Hammerschmid (1989) on urban runoff from two Australian catchments in the Hawkesbury/Nepean basin showed high correlations between total suspended solids (TSS) and total phosphorus (TP), total Kjeldahl Nitrogen (TKN) and Chemical Oxygen Demand (COD). Ball et al. (1995) similarly demonstrated a high correlation between TSS and TP. These Australian studies are consistent with numerous overseas studies showing similar correlations and characteristics of road and street runoff. 11 Many investigations have found the concentration of sediment-bound contaminants in street dirt to be associated with the fine particle size fraction. Pitt and Amy (1973), NCDNRCD (1993) and Woodward-Clyde (1994) have all shown that higher concentrations of pollutants such as heavy metals are associated with the smallest particle size fraction of urban dust and dirt. These data indicate that almost half of the heavy metals (represented by copper, lead and zinc) found on street sediments are associated with particles of 60 to 200 µm in size and 75% are associated with particles finer than 500 µm in size. Dempsey et al. (1993) undertook a particle size distribution analysis for urban dust and dirt, and partitioned contaminants into a number of size fractions to determine the concentrations of contaminants in each particle size range. Results show that the highest recorded concentrations of Copper, Zinc and Phosphorous are associated with particles between 74 µm and 250 µm in size. Colwill et al. (1994) found 70% of oil and approximately 85% of polycyclic aromatic hydrocarbon (PAH) to be associated with solids in the stormwater. That study subsequently demonstrated that, over a period of dry weather conditions, increasing concentrations of oil become associated with particulates with the highest oil content found in the sediment range of 200 µm to 400 µm. Coarse sediments transported from urban areas have a physical impact on the receiving aquatic environment by smothering aquatic habitats and silting waterways leading to a reduction in the waterway discharge capacity. Fine suspended particles carried by stormwater flows may not necessarily be considered to have significant physical impacts on the environment. However, they lead to elevated turbidity levels and it is generally understood that the highest concentrations of pollutants (such as nutrients, heavy metals, and organics) are attached to the finer fractions of suspended sediments in urban stormwater (Walker et al., 1999). 12 2.3 First Flush The early runoff in a storm event is often more contaminated than the later part of runoff, which may be due to several factors, including the mobilization of material accumulated during antecedent dry periods, a lack of dilution flow and a disproportionate runoff volume from the impervious surfaces, where pollutants may accumulate. Strong first flushes are usually associated with small impervious catchments such as highways and parking lots (Ma et al., 2002), and specific rainfall patterns (Kang et al., 2006). In general the term first flush has been used to indicate that the mass emission rate is higher during the initial portions of runoff than during the last portion of the runoff. The concept of the first flush phenomenon was first advanced in the early 1970s and it continues to be debated by many researchers. Thornton and Saul (1987) defined the first flush as the initial period of storm water runoff during which the concentration of pollutants is substantially higher than those observed during the later stages of the storm event. Geiger (1987) defined the phenomenon as occurring when the slope of normalized cumulative mass emission plotted against normalized cumulative volume is greater than 45°. Saget et al. (1995) and Bertrand-Krajewski et al. (1998) defined the first flush as occurring when at least 80% of the pollutant mass is discharged in the first 30% of the runoff volume. According to Chapter 30, MASMA (DID, 2000b), for the purpose of stormwater quality monitoring and sampling, the first-flush grab sample should be obtained within the first 30 minutes (min) of discharge. This is generally the most polluted portion of the discharge, because it may contain pollutants that lie on the surface of the drainage area. The existence of a first flush depends on the type of pollutant, size of the catchment as well as the surfaces. Forster (1996) and He et al. (2001) observed a first flush of heavy metals from rooftops surfaces. Fam et al. (1987) and Ma et al. (2002) observed the first flush in oil, grease, TSS, COD and total organic carbon from highways surfaces. Artina et al. (2006) observed the first flush in a commercialindustrial site near Bologna Italy. Barco et al. (2008) examined the pollutant first flush in an urban catchment with area of 12.7 ha and drained by a combined sewer 13 system located in northern Italy. The results show that treating the maximum amount of the early part of the runoff is a better strategy than treating a constant flow rate. Soller et al (2005) had conducted a study on the evaluation of seasonal scale first flush pollutant loading and implications for urban runoff management. From the study they had come out with a conclusion that a first flush phenomenon did not occur consistently for total metals, dissolved metals or anions. There do however seem to be specific combinations of site and storm circumstances that result in a first flush effect of dissolved metals and total mercury. They also indicated that there was no relation between metal concentrations in storm runoff and land use. Deletic (1997) has analyzed the evidence for the existence and nature of the first flush load of pollution input into drainage systems, using data on suspended solid, conductivity, pH, and temperature of storm surface runoff. The study has found out only slight first flush effects for suspended solids and conductivity of storm runoff were observed at the catchments. No flush effects have been detected for pH and temperature. The rainfall and runoff characteristic which influence the first flush phenomenon are different at each catchment studied, although the catchments have a very similar characteristics. The study has concluded that the first flush that strongly present at the end of a drainage system, is not generated by the first flush of pollution input and the regression curves are not very reliable for prediction of the first flush load of pollution input into drainage system. 2.4 Event Mean Concentration (EMC) DID (2000a) in MASMA (Volume 5, Chapter 15) has defined Event Mean Concentration (EMC) as the flow-weighted mean concentration of a pollutant. The EMC is computed as the total storm load (mass) divided by the total runoff volume, although EMC estimates are usually obtained from a flow-weighted composite of concentration samples taken during a storm. Mathematically: 14 EMC = M ∫ C (t )Q(t )dt = V ∫ Q(t )dt (2.1) where C(t) and Q(t) are the time-variable concentration and flow measured during the runoff event, and M and V are pollutant mass and runoff volume. When EMC is multiplied by the runoff volume, an estimate of the event loading to the receiving is obtained. The instantaneous concentration during a storm can be higher or lower than the EMC, but the use of the EMC as an event characterization replaces the actual time variation of C versus t in a storm with a pulse of constant concentration having equal mass and duration as the actual event. This ensures that mass loadings from storms will be correctly represented. Kim et al (2006) have conducted a study on diffusion of pollution loading from urban stormwater runoff in Daejeon city, Korea. In the study, they characterized stormwater runoff from an urban watershed with combined sewer systems to measure the stormwater runoff discharge rates and pollutant concentrations. As the results, they observed the averaged event mean concentrations (EMCs) of combined sewer overflows (CSO) were 536.1mg TSS/L, 467.7 mg TCODcr/L, 142.7 mg TBOD/L, 16.5 mg TN/L, and 13.5 mg TP/L. Chow and Yusop (2008) have conducted a review of the EMC values for urban storm water runoff. From the study, they have come out with several EMCs values from agencies and previous studies. The Nationwide Urban Runoff Program (NURP) study was one of the earliest studies of storm water runoff quality in the United States (Smullen et al. 1999). Ten water quality pollutants were measured at more than 2,300 stations at 81 urban sites in 28 metropolitan areas. The EMCs values for urban runoff in the Unites States which are referenced from US EPA, NURP, and USGS and NPDES sources are shown in Table 2.1. From Table 2.1, it can be seen that the total suspended solids (TSS) of US EPA mean are about 15% higher than that of NURP and approximately 150% higher than that of USGS and NPDES. EMC for biochemical oxygen demand (BODs) is similar among the sources, but chemical oxygen demand (COD) varies among the sources by a factor of 2. 15 Table 2.1: General urban runoff EMCs of US EPA, NURP, MOE (Ontario), USGS and NPDES and MASMA (Chow and Yusop, 2008). Event Mean Concentration (mg/l) Pollutant US EPA(1) NURP(2) USGS and MOE MASMA(5) NPDES(3) (Ontario)(4) TSS 200.0 174.0 78.4 133.0 85 BOD 12.0 10.4 14.1 COD 103.0 66.1 52.8 809 Total P 0.52 0.34 0.32 0.62 0.13 PO4P 0.17 0.10 0.13 TKN 2.40 1.67 1.73 2.84 NO2 & NO3 1.22 0.84 0.66 2.55 (1) United States Environmental Protection Agency (US EPA, 1983) (2) Updated Urban Runoff data from Nationwide Urban Runoff Programs (NURP, 1999) (3) United States Geological Survey (USGS) and National Pollutant Discharge Elimination System (NPDES, 1999) (4) Metropolitan Toronto Waterfront Wet Weather Outfall Study, Phase I (1992) and Phase II (1995), report to Ontario Ministry of the Environment, Toronto, Ontario, Canada. (5) Urban Stormwater Management Manual for Malaysia. One limitation for the EMC values in Table 2.1 is that they do not distinguish between different urban land use types. However, one conclusion of the NURP study was that due to the amount of site-to-site variability, any differences in EMCs between different urban land uses (residential, commercial and mixed) or geographic regions were for the most part not significant. Similar studies were also conducted in Canada, for example, the Toronto Area Watershed Management Strategy Study was conducted by the Ontario Ministry of the Environment to develop a comprehensive water quality management plan for Toronto area watersheds. The EMCs values for urban runoff in Toronto are considerably higher than that of US especially the chemical oxygen demands (COD). While the typical EMC values stated in the urban stormwater management manual for Malaysia (MASMA) which compiled from different sources also shown a vary among the US sources especially the total phosphorus vary among the US data by a factor of 3. Table 2.2 and 2.3 show the EMC values of residential and commercial land use from various storm water runoff quality studies. Each study has different catchment and climate characteristics, therefore a high coefficient of variation is found among the sources. There is questionable as to the applicability of applying 16 event mean concentrations for different land uses developed in one part of the country to another region. As seen in the EMCs values presented in Table 2.2 and Table 2.3, wide variation can exist not only regionally, but on a local scale as well. Furthermore, national mean concentrations obtained by averaging numbers from a variety of geographically disbursed studies can still yield differing results. For example, it can be seen that a large variation exist among the studies from ChongJu, Central and South Florida and Los Angeles Cities, USA for the EMCs of singlefamily and multi-family residential area. These results may indicate that the event mean concentration value is site specific and vary from site to site. EMC of Total suspended Solids (TSS) reported by Nazahiyah (2005) was higher than that among the US sources for residential area while is similar among the US EPA and NURP for commercial land use. The size of catchments also shows that have a significant effect on the event mean concentration of storm water runoff. Study from Brezonik and Stadelmann (2001), at Twin Cities Metropolitan Area, Minnesota, reported that the EMCs for urban residential area ≥ 40 ha is greater than the urban residential area ≤ 40 ha by a factor of 2 (Chow and Yusop, 2008). 17 Table 2.2: Typical EMCs values of residential land use from various storm water runoff quality studies (Chow and Yusop, 2008) Site Line et al. (2002) Upper Neuse River Basin, North Corolina, USA. Baldys et al. (1998) Dallas-Fort Worth Area, Texas,(19921993) USA. Guerard and Weiss (1995) Colorado Springs, Colorado Los Angeles County Stormwater Monitoring Report: 1998-1999 (1999) Los Angeles Cities Harper, H. H. (1998) Central and South Florida, USA. Brezonik and Stadelmann (2001). Twin Cities Metropolitan Area, , USA. Centennial Park Catchment, Australia. Siti Nazahiyah (2005). Skudai, Johor, Malaysia. Choe, J.S., Bang, K.W. and Lee, J.H. (2002) ChongJu, Korea. Event Mean Concentration (mg/l) Land Use TN TKN TP TSS Residential 5.92 0.59 73 NO3-N 0.79 NH3-N 0.55 BOD - Residential 2.1 1.5 0.38 127 - - - Residential a - 3.8 0.75 229 - 0.49 - Residential b Residential c Residential d Residential e Residential f Residential c Residential g Residential h - 2.27 1.5 2.23 0.28 0.13 0.25 81.54 30.90 65.18 - 0.29 0.39 0.46 - 1.77 2.29 2.42 - 0.18 0.30 0.49 19.10 27.00 71.70 - - 4.40 7.40 11.00 0.448.79 0.5219.4 1.2-5.4 1.126.99 0.051.84 0.033.81 16636 31570 0.011.20 0.071.90 - - Residential - - - - - - 20 278 364 - Residential 0.21 0.84 3.0 2.4 - 95 Residential c Residential f - 4.46 6.81 1.21 2.85 145.8 414.1 - - 76.2 125.3 a Actual catchment land use: 79.4% residential, 9.3% commercial, 8.3% public, 3.0% undeveloped. b High Density Residential c Multi-family Residential d mixed Residential e Low-density Residential f Single-family Residential g Urban Residential ≤ 40 ha h Urban Residential ≥ 40 ha 18 Table 2.3: Typical EMCs values of commercial land use from various storm water runoff quality studies (Chow and Yusop, 2008). Site Baldys et al. (1998) Dallas-Fort Worth Area, Texas,(1992-1993) USA. Guerard and Weiss (1995) Colorado Springs, Colorado Los Angeles County Stormwater Monitoring Report: 1998-1999 (1999) Los Angeles Cities Harper, H. H. (1998) Central and South Florida, USA. Brezonik and Stadelmann (2001). Twin Cities Metropolitan Area, Minnesota, USA. Siti Nazahiyah (2005). Skudai, Johor, Malaysia. Choe, J.S., Bang, K.W. and Lee, J.H. (2002) ChongJu, Korea. Z. Yusop (2005) Sg. Pandan Catchment, Johor, Malaysia. Event Mean Concentration (mg/l) Land Use TN TKN TP TSS Commercial 1.5 0.96 0.18 60 NO3-N - NH3-N - BOD - Commercial a - 1.8 0.28 284 - - - Commercial b - 1.67 0.40 48.80 - 0.30 - Commercial c Commercial d Commercial e 1.18 2.83 - 0.15 0.43 81.00 94.30 - - 8.20 7.20 1.80 8.18 1.38 7.39 0.22 0.77 42 418 0.18 0.86 - - Commercial - - - 195 0.001 - 135 Commercial - 107.6 14.4 2111 - - 168.8 Mix land use* - - - 184 0.5 2.27 39 a Actual catchment land use: 61.1% commercial, 23.0% undeveloped, 15.9% residential. b Retail/Commercial c Low-intensity Commercial d High-intensity Commercial e Commercial/Industrial * Mixed land use: 30.3% Residential, 27.3 % Agricultural, 27.9 % Open Space, 8.1 % Industrial, 6.4% Commercial. 19 2.5 Gross Pollutant Traps (GPTs) Gross Pollutants Trap (GPTs) can be used to reduce water pollution at the point source. GPTs remove litter, debris and coarse sediment from stormwater. GPTs may be used as the pretreatment for the polluted water before flow into a pond or wetland to confine the area of deposition of coarse sediments. This facilitates the eventual removal of finer sediments. Traps may also be used to keep coarse sediment out ponds, protecting the vegetation at the head of the pond from the smothering effects of sediment. Traps may also be used to remove coarse sediment before the flows enters an infiltration device or filtration device, which would otherwise clog up prematurely. GPTs may also serve the purpose of capturing floatable oil, provided that they are designed appropriately. Most GPTs will also provide some reduction in other pollutants. For example, instead of trapping coarse sediment, some GPTs may also remove the particulate nutrients, trace metal, oil and grease, bacteria, and reduce the dissolved oxygen demanding substances. All of the above substances can be partly bound to sediments, and will be removed along with the trapped sediment (DID, 2000c). For the purpose of this study, the compartmentalized GPTs consist of several compartments of rubbish trap, oil and grease trap, and biofilters will be adapted. 2.5.1 Design Criteria and Mechanism of GPTs system Drainage and Irrigation Department (DID, 2000c) has listed the guidance of designing GPTs in Chapter 34, Urban Stormwater Management Manual for Malaysia (MASMA). The information of GPTs is including the Planning Considerations, Classification of GPTs, General Considerations, Design of SBTR Traps, and the Maintenances of the GPTs. The hydraulics characteristics is an important criteria that must take into considerations as the GPTs must be designed so as to prevent any additional surcharge or overflow in the stormwater event of partial or complete blockage. For this purpose, Manning’s Equation is recommended to determine the 20 average velocity of the flow. For hydrology purposes, the Rational Method is recommended for the computation of the peak flows. 2.5.1.1 Rubbish Trap There is a very wide range of devices for the treatment of gross solids. Selection of suitable devices depends on many factors including catchment size, pollutant load, the type of drainage system and cost (DID, 2000c). Table 2.4 provides an overall classification of the types of GPTs that could be used in Malaysia, and the range of catchment areas for which they are suitable. Table 2.4: Overall Classification of Gross Pollutant Traps Group Floating Debris Traps (booms) In-pit devices Trash Racks & Litter Control Devices Description and Function Litter capture on permanent waterbodies Litter and sediment capture in existing pit Hard or soft litter capture devices on drains Sediment removal only, Sediment Traps on drains Sediment and litter ‘SBTR’ Traps capture for drains or pipes Proprietary devices Range of devices, mainly for pipes Source: MASMA (Chapter 34), 2000 Catchment Area Range Purpose-built or Proprietary > 200 ha Proprietary 0.1 – 1 ha Proprietary Usually purpose built from modular components 2 – 400 ha > 200 ha Purpose built 5 – 2000 ha Purpose built 2 – 40 ha Propriety Nowadays, there are several proprietary GPTs in the market such as HumeguardTM, CleansallTM Trap, and Continuous Deflective SeparationTM (CDS) (DID, 2000c). The HumeguardTM Trap is marketed by CSR Humes in Australia. It comprises a specially shaped (floating) boom which diverts material entrained in stormwater flows from the separator into an adjacent holding chamber which can be installed in piped drainage systems. The chamber is baffled to ensure that litter and floating debris is retained and not escapes with the outflow from the chamber. While 21 it is particularly suited to retro-fitting within existing piped drainage system, there is limitation on the maximum size of pipe on which the device can be installed. Cleansall TM Trap is installed using pre-cast elements marketed by Rocla Australia. A diversion weir deflects the treatable flow into a circular chamber in which are seated four quadrant baskets. Litter and other debris are captured by the baskets as stormwater flows through the mesh baskets and out a depressed outlet at the base of the chamber. A sediment sump is located immediately downstream of the chamber where the stormwater wells up to re-join the stormwater conduit. Features of this system are that it can be installed underground and in such a way as to minimize head loss in flood flows and that high trapping efficiencies are predicted from laboratory tests. The Continuous Deflective SeparationTM (CDS) trap consists of an on-line stainless steel perforated separation plate placed in a hydraulically balanced chamber. Solid pollutants are retained in a central chamber under a mild vortex action, and drop into a basket for later removal and/or for removal using a grab bucket or using eduction. Features of this system are that it can be installed underground and in such a way as to minimize head loss in flood flows and that high trapping efficiencies are predicted from laboratory tests. An illustration of CDSTM trap is shown in Figure 2.1. STORMWATER DRAIN HIGH FLOWS BYPASS OVER DIVERSION WEIR Figure 2.1: Continuous Deflective System (CDS) trap (Lariyah et al., 2006) 22 2.5.1.2 Filtration There are two types of filtration methods that are implemented in Malaysia. The two Best Management Practices (BMPs) are biofiltration or plant/vegetation based runoff treatment methods while the latter, typically sand, is used to remove pollutants through media retention or adsorption process. In Japan, biofilter technologies have been successfully practiced, based on Shimanto-Gawa system which is introduced to treat rivers and lakes as a result of eutrophication and increased in BOD. Biofilter is one technologies used in the control of water pollution that use microorganisms to treat polluted water before it is being discharged. Biofilter is a filtration method that uses a combination of physio-chemical adsorption and in-situ bioremediation in the filtration process. Biofiltration is a pollution control technique using living material to capture and biologically degrade the pollutants process. Common uses include processing waste water, capturing harmful chemicals or silt from surface runoff, and microbiotic oxidation of contaminants in air. Natural materials are used in the biologically active filter (BAF) as its filtering media which consists of granular activated carbon, granite, zeolite, lime stones, coarse and fine sand, fiber sponges, leaves and peanut shells. The filtering material functioned as a media which enable the adsorption of organic matters and pollutant onto its surface (Norhan et al., 2008). 2.5.1.2.1 Biofiltration Swale and Vegetated Filter Strip Biofiltration swales and vegetated filter strips are two practices, which have been used for some years in most developed countries. Only fairly recently they have been studied to determine their effectiveness at treating pollution from stormwater runoff and to assess their abilities to reduce on site peak flow rates. At this time these two practices are assumed to provide runoff quality treatment only (DID, 2000b). Biofiltration swale is a vegetated channel that is sloped like a standard storm drain channel; stormwater enters at one end and exits at the other with treatment provided as the runoff passes through the channel. With the vegetated filter strips, the flow is distributed broadly along the width of the vegetated area, and the treatment is 23 provided as runoff travel (as sheet flow) through the vegetation. Methods to be used are depend on the drainage patterns of the site. 2.5.1.2.2 Media Filtration Sand filtration basins are open impoundments, which filter runoff through a layer of sand into an underdrain system. Sand filtration provides runoff treatment, but not quantity control and these basins are to be located off-line from the primary conveyance/detention system. While effective at treating conventional pollutants, sand infiltration is not effective at removing nutrients. Its use for treating oil is being allowed on an interim basis and sand infiltration may substitute for oil/water separators. 2.5.1.3 Oil Separators Oil separation devices are applicable for stormwater runoff from areas where hydrocarbon products are handled or where small spills routinely fall on paved surface exposed to rain. The objective of the oil separators is to treat most of the flow (90 to 95%) from a potentially contaminated catchment to an acceptable degree (10 20 mg/l oil and grease) and to remove free floating oil. In addition to collecting oil, which rises to the surface, separators collect sediment, which falls to the bottom of the devices. In fact, the sediment is likely to contain petroleum products, which are attached to fine sediments. Oil in general urban stormwater runoff is likely to be in the form of an emulsion, which is intimately mixed with the water. Such oil will not readily float out, so oil separators are not used for treatment of general urban runoff. Oil separators need to treat only the stormwater runoff from oily areas or areas which may become oily. General stormwater runoff from other areas should be routed away from the separator and treated for sediment removal in the usual fashion. Treatment should be as close to the source of the oil-generating activities as possible. 24 Two types of more efficient oil separators are API tanks and plate separators. API tanks were originally designed by the American Petroleum Institute (API) for use in refinery applications, but modifications of the design can be used for stormwater treatment. Figure 2.2 shows the schematic of API Separator. Plate separators (as shown in Figure 2.3) contain packs of plates, typically spaced at 10 mm to 20mm centers. The plates increase the effective surface of the device. The close spacing of the plates reduces the height that an oil droplet must rise before it reaches a collecting surface (DID, 2000b). Figure 2.2: Schematic of API Separator (DID, 2000b) Figure 2.3: Schematic of Plate Separator (Meyers, 1980) 25 2.5.2 The effectiveness of GPTs as water pollution treatment devices A number of previous studies had proved the capability of GPTs in reducing water pollution problems. The following literature reviews below briefly describe the design criteria, the mechanism of the trap system and their findings. 2.5.2.1 Gross Pollutants Traps Walker et al., (1999) have conducted a study to investigate the efficiency of CDS Gross Pollutants Traps in removal of suspended solids and associated pollutants. The performance of a continuous deflective separation (CDS) unit in removing suspended particles, particularly sediment and associated contaminants from a suburban catchment in Coburg, Melbourne was assessed during stormwater runoff events and dry weather flow conditions. The results indicate that the CDS unit can remove nearly all gross pollutants and a significant proportion of finer pollutants, particularly during storms. An annual removal efficiency of 65% and 21% for TSS and TP respectively were estimated by assuming typical pollutant concentrations during different flow conditions and using removal efficiencies estimated using data collected in the study. The mechanism of the CDS used is illustrated in Figure 2.4. The CDS separates and retains gross pollutants by first, diverting the flow and associated pollutants in a stormwater drainage system away from the main flow stream of the pipe or channel into a pollutant separation chamber. The separation chamber consists of a containment sump in the lower section and an upper separation section as shown in Figure 2.5. Gross pollutants are retained within the chamber by a perforated plate that allows water to pass through to the outlet pipe. The water and associated pollutants contained within the separation chamber are kept in continuous motion by the energy generated by the incoming flow. This has the effect of preventing the separation plate from becoming blocked by the gross solids retained from the inflow. Heavier solids settle into the containment sump and much of the neutrally buoyant material eventually sinks while floating material accumulates at the water surface. 26 Diverting stormwater and associated pollutants into a separation chamber overcomes problems associated with the direct filtration systems used in conventional gross pollutant traps. The diversion weir is designed to divert all flows below the crest level of the diversion weir. During above-design flow conditions, when water levels exceed the crest of the diversion weir, some flow would by-pass the CDS system carrying pollutants downstream. The selection of the design crest level of the diversion weir can vary for different installations depending on site conditions and the capacity of the CDS unit. The by-pass system is designed to minimize upstream flood afflux for above design flow conditions. If the unit discharges directly to a watercourse, some type of outlet scour protection will be appropriate, such as gabions or riprap. DETAILS OF SEPARATION CHAMBER FROM INLET TO OUTLET Figure 2.4: Schematic Plan View Representation of the CDS System (Walker et al., 1999) The solid separation system consists of a perforated stainless steel partition, which acts as a filter screen with a perimeter volute outlet passage. The perforations in the separation screen are typically elongated in shape and are aligned with the longer axis in the vertical direction. The size of the elliptical perforations can be specified according to performance requirements and typical perforation size for use in urban stormwater systems is 4.7 mm by 10 mm however finer screens have been used. The separation screen is installed with the leading edge of each perforation extending into the flow. 27 Separation Chamber Containment Sump Figure 2.5: Isometric Representation of the CDS unit (CDS Technologies, 1998) A research by Cooperative Research Centre for CATCHMENT HYDROLOGY on ‘Decision Support System for Determining Effective Trapping Strategies for Gross Pollutants’ found that CDS is the most effective devices in removing litter and pollutants. Figure 2.6 shows the percentages of efficiencies for litters and total load for different types of trapping system, where CDS give the highest results for both litter and total load efficiencies. 120 SUMMARY OF EFFIENCY DATA USED IN DSS 100 % 80 Efficiencies for Litter (%) 60 40 Efficiencies for Total Load (%) 20 0 Side entry Trash Litter CDS GPTs Floating pit traps racks Control devices debris trap devices Figure 2.6: Summary of Efficiency data used in DSS (Allison, et al, 1999) 28 Rawson et al, (2002) were designed a study to examine the impact of the structure on physico-chemical and nutrient variables. A GPT system was installed on Brookvale Creek, just downstream of the Warringah Mall shopping centre as part of the Brookvale Creek rehabilitation Program in 2000. It was found that the GPT does change some quality parameters of the waters in Brookvale Ck. In dry weather periods, there was an increase in the turbidity and suspended solids of the waters within the GPT. There was a general increase in temperature, which was correlated with a decrease in dissolved oxygen between sites above and below the GPT. The GPT had an insignificant effect on conductivity and pH. Of the chemical variables, ammonia-N, nitrate-N and phosphorus all decreased slightly, although not significantly. In wet weather conditions, the water quality variables that were strongly affected include conductivity, suspended solids, turbidity, nitrate-N and phosphorus. As part of the Brookvale Creek Rehabilitation Program wetlands were constructed along the creek below the GPT. These wetlands appeared to significantly affect pH, temperature, dissolved oxygen and suspended solids which all decreased between the GPT and the sites downstream. In general, while the pollutant trap appears to affect the water quality, it is not to such a level as to necessitate further remediation. Lariyah, et al (2006) have conducted a study on developing a Decision Support System (DSS) for GPTs that can be used to assist engineers and authorities to select and design an appropriate gross pollutants system for particular urban area. The software developed takes into account the urban drainage layout, trapping locations, the predominant land-use type and funding limitations in assessing the benefits and costs of proposed strategy. The developed software was based on results obtained from a gross pollutant field monitoring study (gross pollutant movement and trapping), as well as a review of GPTs devices commonly used in Malaysia. The structure of the DSS is shown in Figure 2.7, showing the steps involved from the model inputs to the range of outputs. As the result, the study has indicated that a tremendous reduction in the maintenance cost and gross pollution of urban drainage systems and rivers can be achieved, and the gross pollutant trap will not only perform as a device to recover hydraulic efficiency of drainage facilities, but also enhance the environment. 29 Catchment’s Characteristic Rainfall Street Cleanings Typical load Inputs Actual load Conventional & Proprietary Clean-up Technique Trapped Load Installation & Maintenance Outputs Computation Design of GPTs Receiving Water Figure 2.7: Structure of the GPTs decision-support-system (DSS) for evaluating gross pollutant trapping strategies (Lariyah, et al, 2006) Water Sensitive Urban Design (WSUD) is a new philosophy of water management being developed within Australia that embraces sustainability principles to reduce the impacts of development on the total water cycle. a number of WSUD systems have been installed in Australia that integrate various controls into “treatment train systems”. Some of these WSUD systems have been very successful. However, many have been poorly designed, primarily due to the lack of an integrated approach in their design, operation and management and a failure to identify the expected pollutants and site constraints at the beginning of the process. Extensive studies have been undertaken to better understand these treatment systems and the situations in which they are most effective. In both New South Wales and South Australia rainwater tanks, stormwater infiltration systems, and wetlands have been studied extensively (Coombes, 2002, Beecham, 2001, and Argue, 2001). In Victoria, the Cooperative Research Centre for Catchment Hydrology has been researching bioretention systems, swales, wetlands and ponds (Lloyd, 2002, Fletcher, 2002, and Wong, 2000). Dallmer Roach and Beecham (2004) have documented effective treatment trains using pre-filtering and other good design practices based on these 30 and other case studies. They have come out with the suggested treatment trains that can be applied for certain controls and end users, as shown in Table 2.5. Table 2.5: Recommended Treatment Trains (Dallmer Roach and Beecham, 2004) Control and Use RAINWATER TANKS Outdoor, Toilet and Hot Water Indoor (excluding drinking water) Drinking Water INFILTRATION TRENCHES Rainwater from Roofs Stormwater Runoff VELOCITY REDUCTION Residential Conveyance DISCHARGE REDUCTION Urban Development Treatment Train First Flush Filter + Rainwater Tank Screened Roof Gutter + First Flush Filter + Rainwater Tank Screened Roof Gutter + First Flush Filter + Rainwater Tank + Point of Use Filter (UV or micro filter) First Flush Filter + Infiltration Trench Grass Filter Strip or Pre-filter Pit + Infiltration Trench First Flush Filter + Rainwater Tank + Grass Swale Grass Swale + Detention Basin + Pre-filtering Pit + Infiltration Basin Limited Pervious Area Porous Pavement + Bio-filtration Trench HIGH QUALITY DISCHARGE Natural System Replication or Litter Rack or Boom + Sediment Trap + Wetland Open Channel Urban Development Grass Swale + Bio-filtration Trench + Sedimentation Pond + Wetland Reuse Litter Baskets or GPT or Pre-filter Pit + Detention + Sand Filter FINE PARTICULATE REMOVAL Residential Areas Grass Swale + Bio-retention Trench Commercial Areas Pre-filter Pit + Bio-retention Trench 2.5.2.2 Filtration A filtration method based on soil infiltration has been developed in Lake Biwa, Japan as a way to reduce pollutant loading of organic matter and nutrients from non-point sources in urban areas (Wada and Fujii, 2007). Two kinds of pilot plants were installed in roadside, and their performance was examined in several rainfall events. These plants were designed to remove pollutants in the first flush, which corresponded to the cumulative runoff volume of 2mm of stormwater, by percolating the water through soil layer. There are two experimental sites involved in this study. One is the Kunobe over the bridge of the Otsu-Notogawa-Nagahama Line 31 in Shiga prefecture (St. A: catchment area is 285 m2). The other is the RittoShinanaka Line (St. B: catchment area is 72 m2). Figure 2.8(a) and 2.8(b) show the schematic diagram of the experimental facility in St. A and St.B. Stormwater runoff from the road is transferred from the drainage area to this facility under the bridge. This facility is designed to selectively collect the first flush runoff (cumulative runoff volume: 2.8 mm∼3.9 mm) and to percolate it through soil, based on the foregoing and other study results (Wada and Fujii, 2006). This soil is made up of decomposed granite that is low cost and has a good capability of water purification (Tomioka et al., 1998). The treated flow rate is controlled o.4 L/m as the retention time is 24 hours (Wada et al., 2001b). This study investigated the removal characteristic by soil infiltration in terms of the concentration of each water item, the relationship between the first flush runoff pollution load and treated effluent load, and the relationship (reduction ratio) of the first flush runoff pollution load by soil infiltration and total rainfall amount. As the result, it was found out that the plants were able to remove COD (77%), TOC(78%), T-N (51%), and T-P (89%). However, the rate of reduction varies from different configurations between particle substances and dissolved substances, that of the particle was more than 90% and of the dissolved substance was approximately 40%. In terms of the reduction effect by soil infiltration, it was found that the treated effluent load is proportional to influent load. Figure 2.9 shows the relationship reduction ratio of the first flush runoff pollution load by soil infiltration and total rainfall amount. The reduction ratio showed a decreasing tendency in particular PCOD, POC, and P-TP amount, with an increase in the total rainfall amount. That suggests the possibility that particle substances are affected by the total rainfall amount and rainfall intensity. 32 (a) 60cm Soil Area: 75cm(L) x 75cm(W) x 25cm(D) Retention Time: 24 hour 40cm Street Sidewalk 75cm 12cm 25cm First Flush runoff: Cumulative runoff volume: 2mm 15cm Treated Effluent JP patent No.3768186 (b) Figure 2.8: Schematic diagram of the experimental facility in (a)St. A and (b)St. B (Wada and Fujii, 2007) As a way to reduce unpleasant odors, biofiltration has been used as a versatile odor and gas treatment technology and has gained much acceptance in agriculture. Several research studies using compost-based biofilters have been conducted with significant reductions in odor and specific gases reported. Nicolai and Janni (1997) reported a compost/bean straw biofilter that achieved average odor and H2S removal efficiencies of 75% to 90%, respectively. Sun et al. (2000) observed an average H2S removal efficiency between 92.8% and 94.2%, and an average NH3 removal efficiency between 90.3% and 75.8% with 50% media moisture content and 20 s gas 33 retention time. Martinec et al. (2001) also found from several biofilter research experiments on odor reduction efficiency up to 95%. The mixture of wood chips and compost (70:30% to 50:50% by weight) has been recommended as biofilter media (Nicolai and Janni, 2001a). (a) (b) (c) (d) Figure 2.9: Relationship reduction ratio of first flush runoff by soil infiltration and total rainfall amount for (a) COD, (b) POC, (c) TN, and (d) TP (Wada and Fujii, 2007) Chen et al. (2008) have developed a pilot-scale mobile biofilter, where two types of wood chips; western cedar and 2 in. hardwood (as shown in Figure 2.10) were examined to treat odor emissions from a deep-pit swine finishing facility in central Iowa. The biofilters were operated continuously for 13 weeks at different air flow rates resulting in a variable empty bed residence time (EBRT) from 1.6 to 7.3 s. During this test period, solid-phase microextraction (SPME) PDMS/DVB 65 lm fibers were used to extract volatile organic compounds (VOCs) from both the control plenum and biofilter treatments. Analyses of VOCs were carried out using a multidimentional gas chromatography–mass spectrometry–olfactometry (MDGC– MS–O) system. Results indicated that both types of chips achieved significant reductions in p-cresol, phenol, indole and skatole which represent some of the most 34 odorous and odor-defining compounds known for swine facilities. The results also showed that maintaining proper moisture content is critical to the success of woodchip based biofilters and that this factor is more important than media depth and residence time. Figure 2.10: Hardwood (HW) and western cedar (WC) media (Chen et al., 2008) Nduwimana Andr´e et al. (2007) have designed a model system for farm aquaculture water treatment using Lolium perenne Lam as plant biofilter for improving wastewater quality prior to use for irrigation and the removal of TAN (total ammonia nitrogen) from the discharge water. The L. perenne was chose because of its tolerance to a wide range of physiological stress conditions. Additionally, this grass has an extensive and deep root system that would help maintain the hydraulic conductivity and contribute to oxygen transport into the bed. In the study, two aquaculture wastewater treatment systems; recirculation system and a floating plant bed system were designed to improve the quality of irrigation water in local communities with low income. In both systems the grass species Lolium perenne Lam was used as a plant biofilter while vegetable specie Amaranthus viridis was used to evaluate the performance of the system and the suitability of the phyto-treated water for irrigation. It was found that the harmful material removal rate for recirculating system was 88.9% for TAN (total ammonia nitrogen), 90% for NO2--N, 64.8% for NO3--N while for floating plant bed system 82.7% for TAN, 82% for NO2--N and 60.5% for NO3--N. Comparative analysis of the efficiency of waste element removal between the two systems revealed that both 35 systems performed well, however, plant growth was not robust for floating plant bed system while recirculating system is energy consuming. They conducted a laboratory test where seedlings were cultured (5 g/plate) on plates with 30% of their bottom perforated, laid on four layers of moist unwoven fabrics for 60 d (Figure 2.11). Unwoven fabric was used as a growing medium. During the culture period, a commercial solution was used as nutrient solution. Each concrete trough consist of 40 plates arranged horizontally (Figure 2.12). The grass was clipped at 10 cm height before each series of experiments. The first pilot experiment was designed to compare the efficiency of L. perenne to remove nutrients in recirculating and in the floating system. In the recirculating system, six plates (60 days after sow: DAS) were placed on a bench elevated to a gentle slope (5%) that allows the flow of wastewater from a closed turtle pond regularly pumped from a large container (80 L). The flow rate was 128 ml/s. The system was equipped with a timer set at 15 s On and 5 min Off. This regime helped to maintain a high oxygen level in the root zone and as well allows assimilation of pollutants and back to the large container (Figure 2.13). The setting of the floating system consisted of a series of concrete trough compartments in which the same volume (80 L) of the turtle aquaculture farm discharge was put. Six grass plates were then made to float on the surface during the trial (Figure 2.14). Each experimental unit was replicated three times, the duration of each trial was 15 days, and the wastewater was replaced between trials. Figure 2.11: Cross section of the grass-plate. (1) grass leaves and stems; (2) unwoven fabric layer(s); (3) hollowed plate bottom; (4) grass roots (Nduwimana Andr´e et al, 2007). 36 7 1 2 8 3 a 4 4 b 3 7 1 2 8 Figure 2.12: Hydroponics botanical filter (a) top view (b) cross section view. (1) trough; (2) hydroponics grass-plate; (3) wastewater tank; (4) inlet pipe; (5) pump; (6) timer; (7) tap; (8) discharge pipe (Nduwimana Andr´e et al, 2007). Figure 2.13: Recirculating system (Nduwimana Andr´e et al, 2007). Fig. 2.14: Floating system (Nduwimana Andr´e et al, 2007). Saliling et al. (2007) have conducted a study evaluated wood chips and wheat straw as inexpensive and readily available alternatives to more expensive plastic media for denitrification processes in treating aquaculture wastewaters or other high nitrate waters. Nine 3.8-L laboratory scale reactors (40 cm packed height × 10 cm diameter) were used to compare the performance of wood chips, wheat straw, and Kaldnes plastic media in the removal of nitrate from synthetic aquaculture wastewater. The upflow bioreactors were loaded at a constant flow rate and three influent NO3–N concentrations of 50, 120, and 200 mg/L each for at least 4 weeks, in sequence. 37 The experiments showed that both wood chips and wheat straw produced comparable denitrification rates to the Kaldnes plastic media. As much as 99% of nitrate was removed from the wastewater of 200 mg NO3–N/L influent concentration. Pseudo-steady state denitrification rates for 200 mg NO3–N/L influent concentrations averaged (1360 ± 40) g N/(m3 d) for wood chips, (1360 ± 80) g N/(m3 d) for wheat straw, and (1330 ± 70) g N/(m3 d) for Kaldnes media. These values were not the maximum potential of the reactors as nitrate profiles up through the reactors indicated that nitrate reductions in the lower half of the reactors were more than double the averages for the whole reactor. COD consumption per unit of NO3–N removed was highest with the Kaldnes media (3.41–3.95) compared to wood chips (3.34–3.64) and wheat straw (3.26–3.46). Effluent ammonia concentrations were near zero while nitrites were around 2.0 mg NO2–N/L for all reactor types and loading rates. During the denitrification process, alkalinity and pH increased while the oxidation–reduction potential decreased with nitrate removal. The laboratory set up is shown in Figure 2.15 where nine 3.8-L bench-scale upflow biofilters were fed with wastewater synthesized from a formula based on the chemical characterization of recirculating aquaculture systems. Three biofilters each were packed with one of the three types of media; hard wood chips, wheat straw, and Kaldnes plastic media (Kaldnes Miljøteknologi AS, Tønsberg, Norway). Kaldnes media is made of high-density polyethylene with an average diameter of 10 mm and height of 7 mm and an approximate effective specific surface area (SSA) of 500 m2/m3 (Ødegaard et al., 2000). The dimensions of the wood chips particles were approximately 8–50 mm on a side and 2–15 mm in thickness while the wheat straws were chopped to lengths of approximately 20–35 mm. The 3.8-L packed column reactors were made of clear 10.16 cm (4 in. i.d.) diameter PVC pipe and were 40 cm in length. The ends of the PVC column were covered with plastic screens to hold the biofilter media and were fitted with 10.16 cm × 2.54 cm (4 in. × 1 in., insert) PVC reducer tees. The 2.54 cm outlets of the reducer tees were fitted with 2.54 cm × 0.635 cm (1 in. × 1/4 in., insert by barbed) reducer fittings. These reducer fittings coupled with clear vinyl tubing delivered influent to and effluent from the reactors. Three holes were bored along the 38 column at different heights (10, 20, and 30 cm) and 0.635 cm (1/4 in. barbed by NPT) adapters were threaded into these holes. These openings were used to extract liquid samples from these locations. 10cm 10cm 10cm 10cm Figure 2.15: Schematic diagram of an upflow packed bioreactor used (Saliling et al., 2007). 2.5.2.3 Oil and Grease Traps Grease traps are widely used by most restaurants and food processing industries in Hong Kong to reduce oil and grease to an acceptable level before it can be discharged to public sewers. To meet demanding effluent standards in the future, it is necessary to polish the effluent by upgrading the conventional trap design. Chu and Ng (2000) have conducted a study to evaluate the possibility of upgrading traditional grease traps by installing tube settlers inside the trap. Cooking oil made from peanuts was used to make up the synthetic wastewater in all experiments. The pilot plant used consists of three chambers and was made from 1-cm-thick acrylic plates. The first chamber served as an equalization tank to mix and store raw wastewater. Here, a motor-driven peddler with a long span 39 was provided to agitate the mixture so that the interface of oil and water could be broken. the second chamber was the main grease trap, where the tube settler could be installed or removed. The tube settler module was made by polypropylene (PP) with many 45 mm × 60 mm openings on the top and bottom of the module; the dimension of each module was 600 mm (L) × 250 mm (W) × 325 mm (H). the third chamber was used to collect treated effluent and was marked at the 20 L, 40 L, and 60 L levels so that the hydraulic detention time could be determined. A Rio-1700 water pump (maximum rate 1820 L/hr) was used for pumping the wastewater from the chamber one to chamber two. A plug valve was installed in the pipeline to adjust the flow rate, so that suitable detention times could be reached. The efficiency of the grease trap in removing chemical oxygen demand (COD) and oil/grease was examined to justify the performance. It was found that installing a tube settler is a feasible and cheap way to upgrade the conventional grease trap since it improved oil/grease removal efficiency by 8-10% compared to the conventional design. In addition, a remarkable improvement in COD removal was observed following a very short hydraulic detention time after the installation of tube settlers. This ensured acceptable effluent quality under peak flow rates. Fast-food restaurants generate grease-containing wastewaters for which there is, currently, no acceptable treatment technology. The development of microbial cultures for use in a bioreactor could, therefore, provide effective treatment of these wastewaters. Wakelin and Forster, (1997) have performed an investigation into microbial removal of fats, oils and grease by examined the growth of a range of pure and mixed cultures by using vegetable oils, lard and 'grease' from a fast-food restaurant grease-trap. The pure cultures were Acinetobacter sp., Rhodococcus rubra, Nocardia amarae and Microthrix parvicella and these were compared with a mixed culture isolated from a greasetrap, MC1, and with activated sludge. The effectiveness of these cultures was assessed in terms of their grease removal efficiency, the biomass production and yield coefficients. The results found out that Acinetobacter was the most effective of the pure cultures, typically removing 60-65% of the fatty material whose initial concentration had been 8 g/l. The effectiveness of the mixed culture, MC1, was variable, with the removal efficiency ranging from 29% for rapeseed oil to 73% for the restaurant grease. The activated sludge gave a more 40 consistent removal, which was generally better than 90%. However, there was a lag phase of about 1 day in every case. Acclimatised activated-sludge did not exhibit a lag phase and also achieved a high (> 90%) removal efficiency. The absence of a lag phase resulted in faster growth and fat removal. 2.5.2.4 GPTs system at L50 Block, UTM Skudai The study of the GPTs system at L50 Block, UTM Skudai has been conducted since 2005 until present. The GPTs system consists of rubbish trap, biofilter, and oil and grease trap. Since 2005, a few modifications have been made to biofilter and oil and grease traps to improve their performance in removing pollutants (as shown in Table 2.6 and 2.7). Previous studies from Faradiella (2006), Nur Eezani (2007), and Muhammad Ashraff (2008) show that the biofilter system is capable in removing pollutants in water and the most significant parameters in determining biofilter efficiency were SS, BOD and COD. The various filtration media contained in the biofilters were proven effective in removing pollutants in water. The comparisons of the results are shown in Figure 2.16(a) to 2.16(c) where the latest modification in year 2008 gives the most effective results for the Total Suspended Solid (TSS) and Chemical Oxygen Demand removal in terms of percentages. While for Biochemical Oxygen Demand parameters, modification in year 2006 gives the best results. Table 2.6: Different types of materials used for modification (Muhammad Ashraff, 2008) 2006 • Coir • Sand • Gravel • Charcoal • Sponge 2007 • Oil Palm Fiber • Coir • Gravel • Bioball • Charcoal • Sponge 2008 • Oil Palm Fiber • Gravel • Bioball • EBB • Charcoal 41 Table 2.7: Mechanism of development used in oil & grease trap (Munzir, 2008) 2005 2006 2008 Detention Time Detention Time + Baffles Detention Time + Baffles + Banana treetrunks Fibre Lim (2005), Norizan (2006), and Munzir (2008) have studied the effectiveness of oil and grease trap and the results are presented in Figure 2.17(a) and 2.17(b) where the modification in 2006 give the best results of oil and grease and TSS removal. COMPARISON OF PERCENTAGES OF REMOVAL FOR TSS 75.20 80.00 % 60.00 40.00 54.15 28.00 31.76 43.75 37.50 2006 36.17 20.00 22.20 20.00 2007 2008 0.00 Average Maximum Minimum (a) % COMPARISON OF PERCENTAGES OF REMOVAL FOR COD 70.00 60.00 50.00 40.00 30.00 20.00 10.00 0.00 56.36 36.48 32.88 25.53 Average 58.06 2006 27.80 Maximum 24.30 9.68 13.16 2007 2008 Minimum (b) Figure 2.16: Comparison results for Biofilter in terms of percentages of removal of (a) TSS and (b) COD 42 (Continued Figure 2.16) % COMPARISON OF PERCENTAGES OF REMOVAL FOR BOD 70.00 60.00 50.00 40.00 30.00 20.00 10.00 0.00 58.69 56.30 50.28 49.97 52.94 41.94 44.90 29.38 2007 12.34 Average 2006 Maximum 2008 Minimum (c) Figure 2.16: Comparison results for Biofilter in terms of percentages of removal of (c) BOD COMPARISON OF PERCENTAGES OF OIL & GREASE REMOVAL 120 98.82 98.85 100 % 80 71.63 2005 60 2006 40 2008 20 0 1 (a) COMPARISON OF PERCENTAGES OF TSS REMOVAL 120 98.02 100 2005 % 80 60 87.30 2006 45.67 2008 40 20 0 1 (b) Figure 2.17: Comparison results of oil and grease trap in terms of percentages of removal of (a) oil and grease and (b) TSS 43 A study to determine the efficiency of rubbish trap in terms of the trapping rubbish and water quality improvement was conducted by Sarizah (2006) in L50 Block, UTM Skudai. The relationship between amount of rubbish and total rainfall was investigated. From Figure 2.18 it was found out that the amount of rubbish that flow into the trap is influenced by the total of rainfall for 10 days observation. Flowing water in channel will bring along rubbish that present in the channel into the trap. The faster water flow causing the amount of rubbish that trapped will increase. During wet season, the amount of rubbish in the trap is between 5 to 18 kg per day. 0 20 30 40 Rainfall (m m ) 10 Rainfall Rubbish 50 60 24 /1 25 2 /2 /1 00 26 2 /2 5 /1 00 27 2 /2 5 /1 00 28 2 /2 5 /1 00 29 2 /2 5 /1 00 30 2 /2 5 /1 00 31 2 /2 5 /1 005 2/ 2 1/ 0 0 1/ 5 2 2/ 00 1/ 6 20 06 Rubbish (kg/day) 40 35 30 25 20 15 10 5 0 Date Figure 2.18: Graph of relationship between amounts of rubbish and rainfall for rubbish trap at L50 (Sarizah, 2006) Figure 2.19 shows the amount of suspended solid between the point before and after the trap. Four set of samples was taken and each set shows decreasing of suspended solid (SS) except for final samples where the amount of suspended solid is not achieving either Standard A or Standard B. The present of oil in large quantity had caused this result where the oil will cover the small particles to form large particles. These large particles will float at surface of water causing the increasing in amount of suspended solid in water. 44 Suspended Solid (mg/L) 700 600 500 SS (before) 400 SS (after) 300 Standard A Standard B 200 100 0 9/9/2005 28/12/2005 11/1/2006 2/2/2006 Date Figure 2.19: Suspended solid (SS) at point before and after rubbish trap (Sarizah, 2006) 2.6 Critical Appraisal It appears from the review of the literatures that a significant volume of experimental works and research have been done on GPTs by previous people. From the studies, it can be concluded that GPTs has the potential to be an effective water pollution treatment device. As such, a study on GPTs, mainly on the design criteria is very essential in order to produce GPTs with better performances that are capable to overcome the water pollution problems. 45 CHAPTER 3 METHODOLOGY 3.1 Introduction This study is conducted for the purpose of observing the compatibility of Gross Pollutants Traps (GPTs) as a wastewater treatment system for surface runoff in open channel flow. With aim to investigate the feasibility of the GPTs system, a few methodologies as shown in flow chart (Figure 3.1) have been practiced; • Observation at the study site to identify any problems arises • Maintenance will be perform in order to ensure the cleanliness of the site and no channel is being blocked with rubbish or sediments • Redesign the existing GPTs system to increase the effectiveness of the system • Field experiments will be conducted with the intention of looking at the first flush pollutants in the stormwater runoff from catchment areas’ surface • Water samples will be taken and will be tested with a few parameters such as; COD, BOD, SS, AN, DO, and pH for water quality checking 46 3.2 Flow Chart of the Study Methodology Objectives and Scope of Study Observation • to identify any problems arises Maintenances • Removal of rubbish & sediment • On frequent basis & when necessary (after stormwater event) Conclusion & Recommendation Modification of GPTs system • To improve the system’s performance • Only on biofilter and rubbish trap Data Collection • Rubbish & Sediment data collection -L50: Daily (20/06/08-01/08/08) 3-day period (04/08/08-26/09/08) -L52: 3-day period (08/08/08-26/09/08) • Water Quality L50: -4 Stormwater Events (Influent&Effluent)17 samples (21/03/08 & 4, 8, 12/08/08) - First Flush-EMC (10 samples) (04/09/08) L52: -1 Stormwater Event (19/08/08) (2 samples) -1 dry day (20/8/08) (2 samples) • Hydrological Data: -Flow, rainfall (June-September 2008)-Daily Collection Results and Analysis • Rubbish and Sediment Collection Results • Water Quality: -Improvement in quality of water • Water Quantity: -Provide storage and detention time Data Analysis • Flow hydrograph • Water Quality Analysis : - pH, DO, BOD,COD,TSS,AN(Standard A & B) • EMC (MASMA) Figure 3.1: Flow chart of the study methodology 47 The methodologies of this study can be viewed from Figure 3.1 where it started with the identification of objectives and scopes of study as elaborated in Section 1.3 and Section 1.4 respectively. The next stage is observation, maintenances, and modification of the GPTs system as mention in Section 3.1. Data collection are divided into 3 parts i.e. rubbish and sediment collection, water quality, and hydrological data such as flow and rainfall data. The results then are analyzed to come out with discussion, conclusion and recommendation. 3.3 Experimental Site This study is conducted at Block L50, Universiti Teknologi Malaysia, Skudai for the purpose of observing the effectiveness of GPTs system. Figure 3.2 show the experimental site investigated in this study where the system is located near a lecture hall building, L50 parking lot and Co-Curriculum Centre. The detail of the drainage system is shown in Road and Drainage Plan in Figure 3.3. GPTs Co-Curriculum Centre Building Parking Lot Experimental Site Figure 3.2: Location of Study (L50 UTM Skudai) Lingkaran Ilmu 48 I.L 19.80 Building I.L 31.6 I.L 31.3 I.L 31.55 I.L 31.54 I.L 31.6 Parking Lot I.L 31.1 I.L 31.6 Jalan Cengal I.L 31.0 Figure 3.3: Road and Drainage Layout Plan of L50 Block, UTM Skuda 49 3.3.1 Catchment Area The catchment area of the system is determined from the drainage and layout plan of L50 Block, UTM Skudai as shown in Figure 3.4. The catchment area covers 0.16 ha with 90% of the catchments are impervious area, with 70% of it is consist of parking lot and the rest is the lecture building. The peak flow and the Average Recurrence Interval (ARI) for existing drainage system are calculated as 0.212 m3/s and 10 years respectively. The GPTs is design for 10 years ARI and three (3) months ARI for flow and water quality respectively. (Refer Appendix A for the details of calculation) GPTs SYSTEM CATCHMENTS AREA Figure 3.4: Catchment area for the GPTs system 50 3.4 Experimental System The compartmentalized GPTs consist of several compartments of rubbish trap, oil and grease trap, and biofilter as shown in Figure 3.5. (Refer Appendix B and C for the Invert Level and slope of the GPTs system respectively). 1500 1700 1470 1270 2000 1550 2500 1700 2760 750 4400 1500 2950 800 Figure 3.5: Arrangement of GPTs system and dimensions in mm 3.4.1 Rubbish Trap Rubbish trap will control pollution by preventing large pollutants items and rubbish from being carried into rivers or lakes. The type of rubbish trap used in this system is Trash Rack. There are two rubbish trap installed at the system; one prior the sump, and one at the beginning of the system (as shown in Figure 3.6(a) and 3.6(b) respectively). However, in this study the first one have been removed leaving only one rubbish trap that will operated in this system. 51 (a) (b) Figure 3.6: Rubbish Trap located (a) prior the sump (b) at the beginning of the GPTs system (used in this study) 3.4.2 Oil and Grease Trap Oil and grease trap accumulates oil and increases the quality of effluent before discharge into the environment. Base on the previous study by Lim (2005), the oil and grease trap is potentially decreased the oil pollution in the experimental site during 2005, 52 since there was a cafeteria operated at the L50 Block. However, the cafeteria is now closed and there are no oil pollutants that are contributing to the river anymore. Hence, this study will not including the oil and grease system in the evaluation of the performance of the GPTs system. Figure 3.7: Oil and Grease Trap 3.4.3 Biofilter Biofilter is one of the technologies used in the control of water pollution that use microorganisms to treat polluted water before it is being discharged. Biofilter is a filtration method that uses a combination of physio-chemical adsorption and in-situ bioremediation in the filtration process. Biofiltration is a pollution control technique using living material to capture and biologically degrade the pollutants process. Common uses include processing waste water, capturing harmful chemicals or silt from surface runoff, and microbiotic oxidation of contaminants in air. Natural materials are used in the biologically active filter (BAF) as its filtering media which consists of granular activated carbon, granite, zeolite, lime stones, coarse and fine sand, fiber sponges, leaves and peanut shells. The filtering material functioned as a media which 53 enable the adsorption of organic matters and pollutant onto its surface. Biofilter system in this study is described in Figure 3.8 and 3.9. Figure 3.8: Biofilter system. Oil Palm Fibre EBB Activated Carbon Charcoal (a) Figure 3.9: Details of Biofilter System: (a) Arrangement of the Biofilter system 54 (Continued Figure 3.9) 800 300 900 300 650 153 Charcoal Oil Palm Fibre Inlet EBB Activated Carbon 300 X Outlet X (b) 800 300 900 300 650 60 74 80 300 (c) Figure 3.9: Details of Biofilter System: (b) Plan view of Biofilter (in mm) and (c) Details of section X-X (in mm). 55 3.4.3.1 Modification of Biofilter In order to improve the effectiveness of the biofilter system, a few modification on its filtration materials have been made since 2006 as shown in Table 3.1. From the previous study it can be seen that different filtration materials are suitable for different pollutants removal. For this study, activated carbon has been added to replace bioball. The activated carbon is produced from coconut shell where the coconut shell is burn until producing a fine porous material. 3.4.3.2 Filtration Materials Natural materials are used in the biofilter system as the materials can be found naturally, easy to obtain and are relatively cheap. Table 3.2 shows the role of each material in treated the polluted water. The mechanisms of oil palm fibre and activated carbon are by absorbing the pollutants into their surface while charcoal works by absorbing gas and liquids. EBB (Eco Bio Blocks) is functioned by treating the wastewater with “fermented-soybeans bacillus” microorganism that exist in the block. The details of the filtration materials’ mechanisms and functions are shown in Table 3.2. Table 3.1: Different materials used for modifications 2006 2007 2008 • Coir • Oil Palm Fiber • Oil Palm Fiber • Oil Palm Fiber • Sand • Coir • Gravel • Gravel • Gravel • Gravel • Bioball • Activated Carbon • Charcoal • Bioball • EBB • EBB • Sponge • Charcoal • Charcoal • Charcoal • Sponge July (2008) 56 Table 3.2: Roles of the Filtration Media Filtering Materials Oil Palm Fiber Mechanism Function Pollutant will adsorb onto its surface during the treatment Capable of removing suspended matter contained in water turbidity Improve turbidity Gravel Provides for maximum entrapment Activated The porous material will absorb the Carbon contaminants. The pollutants will mix (from with the activated carbon particles and coconut shell) removed later by filtration. Eco BioThe “fermented-soybeans bacillus” Block (EBB) microorganism in the block will treat the wastewater by the decomposition of organic/inorganic process Charcoal 3.5 The porosity of activated charcoal is functioned to adsorb gases and liquids. Remove hydrocarbons, oils, phenols, and low concentrations of metals Capable in reducing BOD,COD, ammonia (NH3), Suspended Solid (SS), turbidity level in polluted water Removing unpleasant odour in treated water Data Collection The data collection for this study involved the collection of rubbish and sediment amount, water quality sampling, and flow and rainfall data measurement. The observation and data collection is conducted during dry and wet weather condition. 3.5.1 Rubbish and Sediment Data Daily data collection for Block L50 rubbish trap was performed for 39 days from 20/06/2008 until 01/08/2008. Because of the small amount of daily rubbish and sediment 57 collection, the daily collection has been change to a three-day period collection started from 04/08/2008 until 26/09/08. For the purpose of the comparison of the performance, the three-day period collection also has been started at Block L52 rubbish trap since 10/08/2008 until 26/09/08. 3.5.2 Storm Events A total of 11 storm events and one event during dry weather condition are sampled from March 2008 to September 2008. The characteristics of the events are shown in Table 3.3 and Table 3.4 for Block L50 and Block L52 respectively. The hydrologic and water quality data are used to produce hydrograph, pollutograph, observing the concentration of water quality parameters, and for the purpose of detention time and storage determination. Table 3.3: Characteristics of monitored storm events at Block L50 Storm Date Event 1 21/03/08 2 03/07/08 3 19/07/08 4 21/07/08 5 25/07/08 6 04/08/08 7 07/08/08 12/08/08 8 9 16/08/08 10 04/09/08 Rainfall Rainfall Rainfall Depth Duration Intensity (mm) (hr) (mm/hr) NA 28.6 16.6 24.6 20.2 8.2 45.2 57.2 11.4 12.2 NA 0.42 1 1.75 1.08 1.33 2 1.75 1.58 1 NA 68.1 16.6 14.05 18.7 6.2 22.6 32.7 7.2 12.2 Flow (l/s) NA 27 2.3 115 0.41 0.7 0.9 0.1 7.6 34.4 Water Storage Quality EMC (m3) Sample X √ NA NA X X NA X X NA X X NA X X 0.525 √ √ √ √ 0.638 NA √ √ 8.19 X X NA √ √ 58 Table 3.4: Characteristics of monitored events at Block L52 Event Date 1 19/08/08 2 20/08/08 3.5.3 Condition Storm Event Dry Weather Rainfall Depth (mm) 9.4 0.0 Flow (l/s) 382.5 0.54 Water Quality Sample EMC X √ X √ Rainfall and Flow Measurement Rain Gauge ISCO, 0.1 mm TIP has been installed at Meteorology Park, UTM for the purpose of rainfall data collection. While for flow data collection, two flow meters have been used, both from ISCO brand but labeled as IWK and TPI respectively. IWK is installed at the inlet point (Figure 3.10) and TPI is located at the outlet point of the GPTs system (Figure 3.11). (a) (b) Figure 3.10: Flow meter equipment at the inlet point of GPTs system with (a) IWK flow meter (b) Plat detector in the rectangular channel 59 (a) (b) Figure 3.11: Flow meter equipment at the outlet point of GPTs system with (a) TPI flow meter (b) Plat detector in the rectangular channel 3.5.3.1 Calibration of Flow Meter Calibration has been performed at Hydraulics Laboratory, Faculty of Civil Engineering, UTM Skudai to the flow meters that have been used in this study to measure the discharge (Q) of the water that flow in and out of the GPTs system. The height (H), velocity (V), and flow (Q) of the water are measured in laboratory test in rectangular channel equipment as shown in Figure 3.12(a). The height of water is measured by ruler. In determining the velocity and flow, a small paper is released to the flowing water in the rectangular channel (Figure 3.12(b)), and then the time taken by the paper to travel for a distance of 1 m is taken. The velocity and flow are calculated using the following formulas: Velocity (V) = Dis tan ce(m) Time( s) (3.1) 60 Flow (Q) = Heigth × Width × Dis tan ce(m3 ) Time( s) (a) (3.2) (b) Figure 3.12: Calibration (a) rectangular channel equipment (b) determining velocity and flow The results then are compared with the results obtained from the flow meter equipment. The results and the percentages of error of the equipments are shown in Table 3.5 and Table 3.6. The details of the calculation are shown in Appendix E. Table 3.5: Calibration results for IWK flow meters LABORATORY TEST Reading Height (m) 1 0.090 2 0.080 3 0.070 4 0.050 5 0.030 Flow (m3/s) 0.0263 0.0247 0.0208 0.0136 0.0064 Velocity (m2/s) 0.97 1.03 0.99 0.91 0.71 AUTOMATIC FLOW METER Height Flow Velocity (m) (m3/s) (m2/s) 0.0906 0.0275 1.00 0.0876 0.0269 0.99 0.0759 0.0218 0.97 0.0525 0.0129 0.83 0.0358 0.0068 0.61 PERCENTAGES OF ERRORS Height Flow Velocity (%) (%) (%) 0.67 4.57 2.67 9.50 9.09 3.64 8.43 4.85 2.03 5.00 5.40 8.70 19.33 5.78 14.60 61 Table 3.6: Calibration results for TPI flow meter LABORATORY TEST Reading Height (m) 1 0.090 2 0.080 3 0.070 4 0.055 5 0.045 3.5.4 Flow (m3/s) 0.0268 0.0232 0.0201 0.0145 0.0117 Velocity (m2/s) 0.99 0.96 0.96 0.88 0.87 AUTOMATIC FLOW METER Height Flow Velocity (m) (m3/s) (m2/s) 0.0928 0.0284 1.03 0.0877 0.0267 1.01 0.0765 0.0213 0.93 0.0598 0.0154 0.85 0.0501 0.0117 0.84 PERCENTAGES OF ERRORS Height Flow Velocity (%) (%) (%) 3.11 5.89 3.69 9.63 15.33 4.70 9.29 6.16 2.66 8.73 6.40 3.10 11.33 0.00 3.40 Water Sampling 3.5.4.1 Water Quality Sampling The aim of this study is to evaluate the effectiveness of the GPTs system during dry and wet weather condition. However, there is no flow in the drainage system during dry weather as the GPTs system is design to functioned only during wet weather (during stormwater event) and furthermore, the cafeteria at Block L50 which is predicted to contribute oil waste to the drainage system has stopped its operation since 2006. Hence, the water sampling only conducted during stormwater event. Figure 3.13 shows the water quality and flow assessment sampling point for this study where sampling points 1, 2, and 3 represent the influent, after rubbish trap and the effluent of the GPTs system respectively. 62 1 2 3 Water Quality Sampling Point Flow Assessment Figure 3.13: Water Quality and Flow Assessment Sampling Point 3.5.4.2 Analytical Method 3.5.4.2.1 First Flush Sample With the aim to investigate the occurrence and the influences of first flush to the concentration of pollutants entering GPTs system during storm event, the first-flush grab sample method are applied where the water samples are obtained within the first 30 minutes of the discharge (DID, 2000a). 3.5.4.2.2 Water Quality Measurement The testing was conducted by Spectrum Laboratories (Johore) Sdn. Bhd. The water quality checked are according to Standard A and Standard B of Environmental Quality Act (1974) parameters, that are pH, BOD, COD, Lead, Manganese, Zinc, Phenol, Boron, Suspended Solid, Mercury, Cadmium, Tri-Chromium, Nickel, Oil and Grease, Free Chlorine, Ammonia Nitrogen, Hexa-Chromium, Arsenic, Cyanide, Copper, Tin, Iron, and Sulphide. 63 For Event Mean Concentration (EMC) samples, the testing has been conducted at Environmental Laboratory, Faculty of Civil Engineering, UTM Skudai. The following water quality parameters are chose based on Urban Stormwater Management Manual for Malaysia (MASMA), Chapter 15, Volume 5; Suspended Solid, BOD, COD, Lead, Copper, Zinc, Oil and Grease, Nitrate, Nitrite, Total Phosphorus, and Ammonia Nitrogen (DID, 2000a). The analytical method used is shown in Table 3.7 for both water quality and EMC determination. Table 3.7: Analytical Methods for Water Quality Measurement pH ANALYTICAL METHODS APHA 4500-H+B NICKEL ANALYTICAL METHOD APHA 3030-E,3111-B BOD*5 days APHA 5210-B TIN APHA 3114-C COD SUSPENDED SOLID MERCURY CADMIUM HEXA-CHROMIUM ARSENIC CYANIDE LEAD TRI-CHROMIUM COPPER MANGANESE APHA 5220-C APHA 2540-D APHA 3112-B APHA 3111-B APHA 3500-Cr D APHA3114-C OSRMA P-456 APHA3111-B APHA3500-Cr D APHA 3030-E,3111-B APHA 3030-E,3111-B ZINC BORON IRON PHENOL FREE CHLORINE SULPHIDE OIL&GREASE AMMONIA NITROGEN TOTAL PHOSPHORUS NITRITE NITRATE APHA 3030-E,3111-B APHA 4500-B C APHA 3030-E,3111-B APHA 5530-B C APHA 4500-Cl F APHA 4500-S2- F APAHA 5520-B APHA 4500 NH3 B C APHA 4500-P B APHA 4500-NO2 B APHA 4500-NO3 B PARAMETERS PARAMETERS 3.5.4.3 Data Analysis Data obtained from the experiment will be analyzed based on their performance. The effluent discharge is checked with concentration limits stated in Standard A and Standard B in Third Schedule, Environmental Quality (Sewage and Industrial Effluents), Regulation 1978, Environmental Quality Act 1974. The source of water located at the upstream of water supply intake must be compliance with standard A as it is used as a drinking water. On the other hand, any kind of effluents must be in compliance with Standard B to ensure safe water for aquatic life. 64 The evaluation is categorized into three stages; that are evaluation for overall GPTs system, for rubbish trap, and for biofilter. The evaluation is performed by comparing the concentration of influent and effluent of the discharge as presented in Table 3.8. Six parameters i.e. pH, Suspended Solid (SS), Biological Oxygen Demand (BOD), Chemical Oxygen Demand (COD), Ammonia Nitrogen (AN), and Dissolved Oxygen (DO) have been selected for the evaluation purpose and the effectiveness is expressed in terms of percentages of removal efficiency. The formula of the percentages of removal efficiency: Percentages of removal efficiency (%) = Influent − Effluent × 100 Influent (3.3) Table 3.8: Description of Water Quality Evaluation Sampling Point 3.6 No. Types of Evaluation Influent Effluent 1 Overall GPTs System 1 3 2 Rubbish Trap 1 2 3 Biofilter 2 3 Design Criteria of GPTs Design criteria of GPTs are checked according to MASMA, Chapter 34, Volume 13. For hydrology purposes, peak inflows are computed using the Rational Method; y C . I t. A Qy = 360 (3.4) where Qy = y year ARI peak flow (m3/s), C = dimensionless runoff coefficient, yIt = y year ARI average rainfall intensity over time of concentration, tc,(mm/hr), and A = drainage area (ha) (DID, 2000c). 65 The GPT must be designed so as to prevent any additional surcharge in the stormwater system in the event of partial or complete blockage. The time stormwater takes to flow along an open channel may be determined by dividing the length of the channel by the average velocity of the flow. The average velocity of the flow is calculated using the hydraulic characteristics of the open channel. The Manning’s Equation is recommended for this purpose: 1 2/ 3 1/ 2 V= R S n (3.5) where V = average velocity (m/s), n = Manning’s roughness coefficient, R = hydraulic radius (m), and S = friction slope (m/m) (DID, 2000a). 3.6.1 Rubbish Trap For the purpose of this study, the selected type of rubbish trap that will be used is ‘Trash Rack’. For the sizing of trash rack, the height is determined based on the rack not being overtopped in the water quality design storm when the rack is 50% blocked. The presence of a downstream hydraulic control can lead to the downstream submergence of the trash rack and an increase in the pool level upstream of the trash rack. Under these conditions the trash rack height should be sized by a hydraulic analysis of the site and the trash rack. The sizing method for a standard vertical-bar trash rack is as follows (Willing & Partners, 1992): Under unsubmerged conditions, the required height of the trash rack [Hr] is twice the depth at critical flow [yc] through the unblocked trash rack. 66 H r = 2 yc 1/ 3 ⎛ Q0.25 2 ⎞ ⎟ = 2⎜⎜ 2 ⎟ g . L e ⎠ ⎝ (3.6) where Hr= required height of trash rack (m), Q0.25 = the design flow (m3/s), g = gravitational acceleration = 9.8 m/s2 , and Le = the effective length of flow through an unblocked trash rack (m). Using a standard design of vertical 10mm galvanized flat steel bars at 60 mm centers and a coefficient [Cc]of 0.8 to account for contraction of flow through the trash rack, gives: ⎛Q ⎞ Hr = 1.22⎜⎜ 0.25 ⎟⎟ ⎝ Lr ⎠ (3.7) where Hr= required height of trash rack (m), Q0.25 = the design flow (m3/s), and Lr = actual length of the trash rack (m). 3.7 Maintenance Maintenance must be conducted to ensure the cleanliness of the experimental site and to ensure that there will be no overflow occur on the system due to any blockage. Figure 3.14 (a) to 3.14 (d) show the conditions of the GPTs’ system during stormwater event where the rubbish trap are blocked by the rubbish, mainly dry leaves. This rubbish should be removed to avoid any blockage for the water to flow. The maintenance should be conducted at least twice a week and especially after stormwater event. 67 (a) (b) (c) (d) Figure 3.14: Conditions of (a) rubbish trap, (b) rubbish trap, (c) oil and grease trap and (d) biofilter during stormwater event. 68 CHAPTER 4 RESULTS AND ANALYSIS 4.1 Introduction The performance of the GPTs system is evaluated in the following aspects; water quality, water quantity, first flush analysis, and the determination of EMC values. For water quality, the effectiveness of GPTs in improving the quality of water is investigated by observing the amount of rubbish trapped by the rubbish trap before entering water bodies, the concentration of suspended solid after rubbish trap, the capability of the biofilter’s filtering materials in removing pollutants and the effluent of discharge water from the whole GPTs system must comply with parameter limit as stated in to Standard A and Standard B of Environmental Quality Act (1974). Despite of functioned for water quality control, the GPTs is also functioned for water quantity control which it can be a detention basin to provide sufficient detention time for the sedimentation of pollutant loads. The Event Mean Concentration (EMC) values and the first flush analysis are appropriate for the purpose of the evaluation of the GPTs system. All data are well analyzed and are presented in respective figures and tables. 69 4.2 Performance of GPTs System during Dry Weather The results of this study shows that the GPTs system is not working during dry weather. No data collection was recorded during dry weather and no flow is detected for water quality sampling. There is no flow entering the drainage system during dry weather as the cafeteria at the nearby building had been closed and was not operated. Hence, the sources of water for the drainage and GPTs system are mainly from surface runoff. 4.3 Rubbish and Sediment Collection Results and data analysis for rubbish trap are presented in two parts. The first part is for rubbish trap located at Block L50. In order to evaluate its performance, the results then will be compared with the results obtained from rubbish trap located at Block L52. The details of data collection procedure for rubbish trap at Block L50 and rubbish trap at Block L52 are shown in Table 4.1. 4.3.1 Amount of Rubbish and Sediment 4.3.1.1 Block L50 Rubbish Trap The daily rubbish and sediment collection for L50 rubbish trap has been started from 20/06/2008 until 01/08/2008. Because of the small amount of daily rubbish and sediment collection, the daily collection has been change to a three-day period collection started from 04/08/2008 until 24/09/08. 4.3.1.1.1 Daily Collection Daily rubbish and sediment collection had been performed for 39 days from 20th June 2008 until 1st August 2008. However, there was no data collection from 4th 70 July until 7th July because of unavoidable cause. From the result shown in Table 4.2, it can be seen that the rubbish data are only available during wet weather and no rubbish collected during dry weather. The wet leaves collected during rainy days were dried to obtain the dry weight of the rubbish. The relationship between the weather condition and amount of rubbish and sediment collected are shown in Figure 4.1. The amount of rubbish collected was high during wet weather while during dry weather there was no rubbish data recorded. However, the highest amount of rubbish i.e. 19.2 kg/day was recorded during dry weather on 20/6/2008 which was the start of the measurement. The rubbish trap was not cleaned and maintained for almost 2 months, thus generated the high amount of rubbish. The same trend of result is followed by sediment where the amount of sediment was only recorded during wet weather condition and the amount of sediment recorded at the start of the measurement was also very high i.e. 13.9 kg/day. Table 4.1: Data Collection Procedure for rubbish trap at Block L50 and rubbish trap at Block L52 Types of Data 1. Rubbish and Sediment Amount 2. Flow and Velocity 3. Rainfall 4. Water Quality Site L50 L52 Frequency Daily (From 20/6/2008 until 1/8/2008) 3 days time (From 4/8/2008 until 26/9/2008) Weekly (From 20/7/2008 until 29/7//2008) 3 days time (From 4/8/2008 until 26/9/2008) L50 Daily (Starting June 2008) L50 Daily (Starting June 2008) L52 Daily (Starting June 2008) L50 Four (4) storm water events L52 One (1) each for dry and rainy day 71 Table 4.2: Daily rubbish and sediment data collection at Block L50 Rubbish Trap Amount (kg) Date 20/6/2008 21/6/2008 22/6/2008 23/6/2008 24/6/2008 25/6/2008 26/6/2008 27/6/2008 28/6/2008 29/6/2008 30/6/2008 1/7/2008 2/7/2008 3/7/2008 8/7/2008 9/7/2008 10/7/2008 11/7/2008 12/7/2008 13/7/2008 14/7/2008 15/7/2008 16/7/2008 17/7/2008 18/7/2008 19/7/2008 20/7/2008 21/7/2008 22/7/2008 23/7/2008 24/7/2008 25/7/2008 26/7/2008 27/7/2008 28/7/2008 29/7/2008 30/7/2008 31/7/2008 1/8/2008 Vegetative Wet Dry 0 19.1 0 0 0 0 0 1.2 0 0.3 0 0 0 0 0 0 1 0.7 16.9 15.2 0 0 0 0 0 0 2.9 2 4 2.8 0 0 8.5 7 5.5 4.2 3.4 2.8 4.8 3.4 1.6 1.1 0 0 0 0 0 0 0.7 0.4 4 3.6 1.9 1.8 3.3 2.9 0 0 0.15 0.1 0 0 1 0.7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Plastic Paper Metal 0.1 0 0 0 0 0 0 0 0 0.1 0 0 0 0 0.1 0 0.5 0.3 0 0 0 0 0 0 0 0.2 0.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.1 0 0 0 0.1 0 0 0 0.2 0.2 0 0.1 0 0 0 0 0 0.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.005 0 0.001 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Total Rubbish 19.2 0 0 1.2 0.3 0 0 0 1 17.1 0 0 0 3 4.105 0 9.001 6 3.6 4.8 1.7 0 0 0 0.7 4.2 2.1 3.3 0 0.15 0 1 0 0 0 0 0 0 0 Sediment 13.9 0 0 8 0 0 0 0 0 10.2 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.2 0 0 0 0 0 0 0 0 0 Weather Dry Dry Dry Dry Dry Dry Dry Dry Wet Wet Dry Dry Dry Wet Wet Dry Wet Wet Wet Wet Wet Dry Dry Dry Wet Wet Wet Wet Dry Wet Dry Wet Dry Dry Dry Dry Dry Dry Dry Rainfall Depth (mm) 0 0 0 0 0 0 0 0 0.4 63.8 0 0 0 28.6 13 0 16 0.4 0.2 0.2 2 0 0 0 0.2 16.6 3.8 24.6 0 4.6 0 17.6 0 0 0 0 0 0 0 72 Figure 4.1: Relationship between Rubbish and Sediment Amount with Rainfall at Block L50 Rubbish Trap (Daily Collection) 4.3.1.1.2 Three-days Period Collection Three-day period collection had been started from 4/8/2008 until 24/09/2008 and the results are presented in Table 4.3. The relationship between the weather condition and amount of rubbish and sediment collected are illustrated in Figure 4.2 which shown that the amount of rubbish collected was high during wet weather while during dry weather there was almost no rubbish and sediment collected. The maximum rubbish and sediment collection was 12.9kg/3days and 7.5/3 days respectively. 73 Table 4.3: Three-day period rubbish and sediment data collection at Block L50 Rubbish Trap Date 3/8/2008 4/8/2008 5/8/2008 6/8/2008 7/8/2008 8/8/2008 9/8/2008 10/8/2008 11/8/2008 12/8/2008 13/8/2008 14/8/2008 15/8/2008 16/8/2008 17/8/2008 18/8/2008 19/8/2008 20/8/2008 21/8/2008 22/8/2008 23/8/2008 24/8/2008 25/8/2008 26/8/2008 27/8/2008 28/8/2008 29/8/2008 30/8/2008 31/8/2008 1/9/2008 2/9/2008 3/9/2008 4/9/2008 5/9/2008 6/9/2008 7/9/2008 8/9/2008 9/9/2008 10/9/2008 11/9/2008 12/9/2008 13/9/2008 14/9/2008 Vegetative Wet Dry Plastic Amount (kg/3 days) Total Paper Metal Rubbish Sediment 9 6.3 0 0 1.7 10.7 3.7 3.8 3 0 0 0.2 4 3.8 1.9 1 0 0 0 1.9 1 1.4 1.0 0 0 0 1.4 1.2 2.5 2 0 0 0 2.5 3.2 6 4.1 0 0 0.2 6.2 5.3 4 3.5 0 0 0 4 3.4 12.5 11 0 0 0.2 12.7 4 12.7 10 0 0 0.2 12.9 7.5 5.2 3 0 0 0 5.2 1.4 12 8 0 0 0 12 3 5.5 4.3 0 0 0.4 5.9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Weather Dry dry wet Dry Dry Wet Wet Wet Wet Dry Wet Dry Dry Dry Wet Wet Dry Wet Dry Dry Wet Wet Wet Wet Wet Wet Dry Dry Wet Wet Wet Wet Wet Wet Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Rainfall Depth (mm) 0 0 12.4 0 0 45.2 0.8 7.2 1.2 0 57.2 0 0 0 11.4 5.6 0 9.4 0 0 1.6 0 0 85 0 30 0 0 5.2 1.3 10.2 37.2 34.1 12.2 0 0 0 0 0 0 0 0 0 0 74 (Continued Table 4.3) Date 15/9/2008 16/9/2008 17/9/2008 18/9/2008 19/9/2008 20/9/2008 21/9/2008 22/9/2008 23/9/2008 24/9/2008 Vegetative Wet Dry 0.7 0.4 Plastic 0 Amount (kg/3 days) Total Paper Metal Rubbish 0 0 0.7 Sediment 0.3 0.5 0.3 0 0 0 0.5 0.2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Weather Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Rainfall Depth (mm) 0 0 0 0 0 0 0 0 0 0 Figure 4.2: Relationship between Rubbish and Sediment amount with Rainfall at Block L50 Rubbish Trap (Three-day period collection) 4.3.1.2 Block L52 Rubbish Trap For the purpose of the performance comparison, the three-day period rubbish and sediment collection also has been conducted at Block L52 rubbish trap since 10/08/2008 until 24/09/08. The results from Table 4.4 show that the data are available during dry and wet weather condition. The rubbish trap is functioned during both weather conditions as the catchments area is consist of food stalls which produce daily waste water, food and oil to the drainage system. The relationship of 75 amount of rubbish and sediment collected illustrated in Figure 4.3 shows the amount of collection was high during rainy days. Table 4.4: Three-day period rubbish and sediment data collection at Block L52 Rubbish Trap Date Amount (kg/3 days) Rubbish 8/8/2008 9/8/2008 10/8/2008 11/8/2008 12/8/2008 13/8/2008 14/8/2008 15/8/2008 16/8/2008 17/8/2008 18/8/2008 19/8/2008 20/8/2008 21/8/2008 22/8/2008 23/8/2008 24/8/2008 25/8/2008 26/8/2008 27/8/2008 28/8/2008 29/8/2008 30/8/2008 31/8/2008 1/9/2008 2/9/2008 3/9/2008 4/9/2008 5/9/2008 6/9/2008 7/9/2008 8/9/2008 9/9/2008 10/9/2008 11/9/2008 12/9/2008 13/9/2008 14/9/2008 Sediment 17 60 18.1 76.4 39 11.2 49.1 14 47 11.5 80 17 28 37.5 12.3 21 24.4 30 2 2 35 0 40 0 Weather Wet Wet Wet Dry Wet Dry Dry Dry Wet Wet Dry Wet Dry Dry Wet Wet Wet Wet Wet Wet Dry Dry Wet Wet Wet Wet Wet Wet Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Rainfall Depth (mm) 0.8 7.2 1.2 0 57.2 0 0 0 11.4 5.6 0 9.4 0 0 1.6 0 0 85 0 30 0 0 5.2 1.3 10.2 37.2 34.1 12.2 0 0 0 0 0 0 0 0 0 0 76 (Continued Table 4.4) Date 15/9/2008 16/9/2008 17/9/2008 18/9/2008 19/9/2008 20/9/2008 21/9/2008 22/9/2008 23/9/2008 24/9/2008 Amount (kg/3 days) Rubbish Sediment Weather 45 0 Dry Rainfall Depth (mm) 0 Dry Dry Dry Dry Dry Dry Dry Dry Dry 0 0 0 0 0 0 0 0 0 39 0 21 0 30 0 Figure 4.3: Relationship between Rubbish and Sediment amount with Rainfall at Block L52 Rubbish Trap (Three-day period collection) 4.3.2 Rainfall Analysis The relationship between rainfall and rubbish and sediment amount can be illustrated from Figure 4.1, Figure 4.2 and Figure 4.3. The relationship shows that for both collection at Block L50 and Block L52, the amount of rubbish and sediment collected are high when the rainfall value is high. 77 (a) (b) Figure 4.4: Correlation between Rubbish and Sediment amount with Rainfall at Block L50 Rubbish Trap for (a) Daily collection and (b) Three-day period collection The correlation between rainfall and rubbish and sediment amount for Block L50 rubbish trap are shown in Figure 4.4(a) and 4.4(b) for daily and three-day period collection respectively. The amount of rubbish and sediment collected is increase with the increasing rainfall amount. The same trend of correlation is observed for rubbish and sediment collection at Block L52 rubbish trap where the collection is high when the rainfall amount is high (Figure 4.5). These results indicate that rain influences the amount of rubbish and sediment trapped and the rubbish trap proved its efficiency in preventing large pollutants from reaching water bodies during storm event. 78 Figure 4.5: Correlation between Rubbish and Sediment amount with Rainfall at Block L52 Rubbish Trap for three-day period collection 4.3.3 Classification of Rubbish The rubbish collected at Block L50 is categorized into plastic, paper, metal, and vegetative. The categories are selected from the observation made to the rubbish trap system from the previous studies and the analysis of the catchments area. Previous study by Sarizah (2006) found that the trapped rubbish at Block L50 was only from leaf type. Siti Norazela (2007) reported that the rubbish trapped by Continuous Deflective Separation (CDS) system was classified as plastic, paper, metal, vegetative and others. The catchment area of Block L50 is consists of parking lots, a lecture building and co-curriculum centre which may contribute to the plastic and cans litter by public. There are also a few trees nearby that may falls dry leaves that will move to the drainage system by wind and runoff. The descriptions of each category are explained in Table 4.5. 79 Table 4.5: Description of rubbish types No Types Description 1 Plastic From Personal : Food wrapper, cigarettes, polystyrene wrapper 2 Paper From Personal : Food wrapper, newspaper, writing paper, tissue 3 Metal From Personal : Drinks can, food can 4 Vegetative From Nature : Leaf, small wood (from trees) 4.3.3.1 Daily Collection Figure 4.6(a) and Figure 4.6(b) illustrate the classification of rubbish according to types for daily data collection from 20/06/08 until 01/08/08. The total rubbish collected is 82.456 kg for 39 days collection with average of 2.11kg/day. The highest rubbish type is from vegetative (97.32%), 1.7% from plastic, 0.97% from paper, and 0.01% from metal types (Figure 4.6(a)). The maximum rubbish collection was recorded on 20/06/2008, i.e. 19.2kg/day. Figure 4.6(b) illustrated that almost all the rubbish is from vegetative type with only 0.52% is from plastic. None of the rubbish is paper or metal. The result is reasonable as the catchment area is covered with trees. The dry leaves may drop during dry day and will be swept away to the drainage system during storm events. 4.3.3.2 Three-day Period Collection A total of 80.6 kg rubbish had been collected during three-day period collection from 10/08/2008 until 24/09/2008 with average 1.49 kg/day. From the amount, 96.4% is from vegetative types and 3.6% is metal types. None of plastic and paper types were collected (Figure 4.7(a)). Maximum rubbish collection i.e. 12.9 kg/3 days was collected on 28/08/2008. Figure 4.7(b) shows that almost 100% of the collection is from vegetative type. 80 (a) (b) Figure 4.6: Classification of rubbish according to types for daily collection for (a) total collection and (b) maximum day collection (Block L50 rubbish trap) (a) Figure 4.7: Classification of rubbish according to types for three-day period collection for (a) total collection (Block L50 rubbish trap) 81 (Continued Figure 4.7) (b) Figure 4.7: Classification of rubbish according to types for three-day period collection for (b) maximum day collection (Block L50 rubbish trap) 4.4 Water Quality Results 4.4.1 Block L50 GPTs system A total of six events had been monitored at Block L50 GPTs system as shown in Table 4.6. Figures 4.8(a) to Figure 4.8(c) are the flow hydrographs for event 04/08/2008, 07/08/2008 and 12/08/2008. The figures show that for all events, the first sample is taken during the first 30 minutes of the discharge which are considered as first flush samples. The later samples are taken at the end of the discharge for the purpose of first flush evaluation. The water quality results are displayed in Table 4.7, 4.8, 4.9, and 4.10 for event on 21/03/2008, 04/08/2008, 07/08/2008, and 12/08/2008 respectively. Table 4.7 shows that all effluent is comply with Standard A and Standard B of Environmental Quality Act 1974 for event 23/03/2008. 82 Table 4.6: Water Quality Events Event Date 1 21/03/2008 2 04/08/2008 3 07/08/2008 (First Flush) 4 07/08/2008 (End of Storm) 5 12/08/2008 (First Flush) 6 12/08/2008 (End of Storm) (a) (b) Figure 4.8: Flow hydrograph and sampling time for event on (a) 04/08/08 and (b) 07/08/08 83 (Continued Figure 4.8) (c) Figure 4.8: Flow hydrograph and sampling time for event on, and (c) 12/08/08. For event on 21/03/2008, all effluent is fulfill Standard A while for Standard B requirement, all effluent is fulfill Standard B except for Ammonia Nitrogen (Table 4.7). For event on 04/08/2008, all effluent is fulfill Standard A except for COD, Hg, Phenol, and Oil and Grease. While for Standard B requirement, all effluent is fulfill Standard B except for Oil and Grease, and Ammonia Nitrogen (Table 4.8). From the 07/08/2008 results in Table 4.9, all the effluent of first flush samples is fulfill Standard A. For the samples taken at the end of the storm, all effluent fulfill standard A except for Cu and Phenol. While for Standard B requirement, both samples for first flush and end storm effluent are fulfill Standard B except for Ammonia Nitrogen. The water quality result of 12/08/2008 is shown in Table 4.10 where all the effluent of first flush samples is fulfill Standard A except for Hg and Zinc. For the samples taken after 1 hour storm, all effluent fulfills standard A except for Hg and Phenol. While for Standard B requirement, both samples are fulfill Standard B except for Ammonia Nitrogen. 84 Table 4.7: Water Quality Results for 21/03/2008 Standard Parameters Units Influent Effluent A pH 6.4 6.7 6.0-9.0 BOD*5 days at 20⁰C mg/L 20 5 4 COD mg/L 17 7 50 Suspended solid mg/L 10 15 50 Mercury as Hg mg/L <0.001 <0.001 0.005 Cadmium as Cd mg/L <0.004 <0.004 0.01 Hexa-Chromium as 0.05 Cr6+ mg/L 0.03 <0.02 Arsenic as As mg/L <0.001 <0.001 0.05 Cyanide as CN mg/L <0.02 <0.02 0.05 Lead as Pb mg/L <0.02 <0.02 0.1 Tri-Chromium as 0.20 Cr3+ mg/L <0.02 <0.02 Copper as Cu mg/L <0.01 <0.01 0.20 Manganese as Mn mg/L <0.004 <0.004 0.20 Nickel as Ni mg/L <0.02 <0.02 0.20 Tin as Sn mg/L <0.01 <0.01 0.20 Zinc as Zn mg/L 0.06 0.09 1 Boron mg/L 0.57 <0.01 1 Iron as Fe mg/L 0.17 0.09 1 Phenol mg/L <0.001 0.003 0.001 Free Chlorine as Cl2 mg/L <0.02 <0.02 1 Sulphide as S2mg/L 0.23 0.23 0.50 Not Oil&Grease mg/L <10 <10 detectable Ammonia Nitrogen as N mg/L 1.5 1.7 Standard B 5.5-9.0 50 100 100 0.05 0.02 0.05 0.100 0.10 0.50 1.00 1.00 1.00 1.00 1.00 2.00 4.00 5.00 1.00 2.00 0.50 10 0.07 Table 4.8: Water Quality Results for 04/08/2008 Results Standard Standard Parameters Units Point 1 Point 2 Point 3 A B pH 5.9 5.6 5.7 6.0-9.0 5.5-9.0 BOD*5 days at 20⁰C 20 mg/L 10 11 17 50 COD mg/L 38 66 75 50 100 Suspended solid mg/L 44 21 38 50 100 Mercury as Hg mg/L <0.001 0.022 0.022 0.005 0.05 0.01 Cadmium as Cd mg/L <0.004 <0.004 <0.004 0.02 Hexa-Chromium as 0.05 Cr6+ mg/L <0.02 <0.02 <0.02 0.05 Arsenic as As mg/L <0.01 <0.01 <0.01 0.05 0.100 Cyanide as CN mg/L <0.02 <0.02 <0.02 0.05 0.10 Lead as Pb mg/L <0.02 <0.02 <0.02 0.1 0.50 85 (Continued Table 4.8) Results Parameters Tri-Chromium as Cr3+ Copper as Cu Manganese as Mn Nickel as Ni Tin as Sn Zinc as Zn Boron Iron as Fe Phenol Free Chlorine as Cl2 Sulphide as S2- Units Point 1 Point 2 Point 3 mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L 0.02 0.1 <0.004 0.02 <0.01 0.55 0.12 0.04 0.001 <0.02 0.19 <0.02 0.09 0.01 <0.02 <0.01 0.98 0.30 0.42 0.034 <0.02 0.31 <0.02 0.06 <0.004 0.03 <0.01 0.91 0.32 0.06 0.059 <0.02 <0.05 Oil&Grease Ammonia Nitrogen as N mg/L <10(2) <10(DA) 13 mg/L 1.5 0.9 0.8 Standard Standard A B 0.20 1.00 1.00 1.00 1.00 1.00 2.00 4.00 5.00 1.00 2.00 0.50 0.20 0.20 0.20 0.20 1 1 1 0.001 1 0.50 Not detectable 10 - 0.07 Table 4.9: Water Quality Results for 07/08/2008 FIRST FLUSH Parameters Units pH BOD*5 days at 20⁰C mg/L COD mg/L Suspended solid mg/L Mercury as Hg mg/L Cadmium as Cd mg/L Hexa-Chromium as Cr6+ mg/L Arsenic as As mg/L Cyanide as CN mg/L Lead as Pb mg/L Tri-Chromium as Cr3+ mg/L Copper as Cu mg/L Manganese as Mn mg/L Nickel as Ni mg/L Tin as Sn mg/L Zinc as Zn mg/L Boron mg/L Iron as Fe mg/L Phenol mg/L Free Chlorine Cl2 mg/L END OF STORM Point 1 5.7 Point 2 6 Point 3 5.9 Point 1 5.9 Point 2 5.8 Point 3 6.1 4 17 12 0.001 <0.004 4 20 2 0.06 <0.004 5 20 15 0.002 <0.004 6 20 9 0.002 <0.004 4 23 14 0.003 <0.004 4 20 9 0.003 <0.004 <0.02 <0.01 0.03 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.01 0.07 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 0.81 0.04 <0.02 <0.01 0.42 0.28 0.26 0.072 <0.02 <0.02 0.69 0.03 <0.02 <0.01 0.40 0.35 0.27 <0.001 <0.02 0.03 0.08 0.03 <0.02 <0.01 0.34 0.63 0.12 <0.001 <0.02 <0.02 0.07 0.03 <0.02 <0.01 0.19 0.42 0.15 <0.001 <0.02 <0.02 0.03 0.01 <0.02 <0.01 0.40 0.63 0.20 <0.001 <0.02 <0.02 0.52 0.02 <0.02 <0.01 0.35 1.23 0.23 0.002 <0.02 Standard A 6.0-9.0 20 50 50 0.005 0.01 0.05 0.05 0.05 0.1 0.20 0.20 0.20 0.20 0.20 1 1 1 0.001 1 Standard B 5.5-9.0 50 100 100 0.05 0.02 0.05 0.100 0.10 0.50 1.00 1.00 1.00 1.00 1.00 2.00 4.00 5.00 1.00 2.00 86 (Continued Table 4.9) Table 4.9: Water Quality Results for 07/08/2008 FIRST FLUSH END OF STORM Parameters Sulphide as S2- Units mg/L Point 1 <0.05 Point 2 0.07 Point 3 <0.05 Point 1 <0.05 Point 2 0.07 Point 3 <0.05 Oil&Grease Ammonia Nitrogen as N mg/L <10 <10 <10 <10 <10 <10 mg/L 0.9 1.4 0.9 0.5 0.5 0.4 Standard Standard A B 0.50 0.50 Not detectable 10 - 0.07 Table 4.10: Water Quality Results for 12/08/2008 FIRST FLUSH END OF STORM Standard A 6.0-9.0 Standard B 5.5-9.0 Parameters pH BOD*5 days at 20⁰C COD Suspended solid Mercury as Hg Cadmium as Cd HexaChromium Cr6+ Arsenic as As Cyanide as CN Lead as Pb Tri-Chromium as Cr3+ Copper as Cu Manganese as Mn Nickel as Ni Tin as Sn Zinc as Zn Boron Iron as Fe Phenol Free Chlorine as Cl2 Sulphide as S2- Units Point 1 6.1 Point 2 6.1 Point 3 6 Point 1 6.4 Point 2 7 Point 3 6.6 mg/L mg/L 7 33 8 39 7 39 5 16 4 10 5 16 mg/L mg/L 23 0.008 62 0.011 29 0.01 9 0.008 4 0.012 9 0.008 0.005 100 0.05 mg/L <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 0.01 0.02 mg/L mg/L mg/L mg/L 0.03 <0.001 0.03 <0.02 <0.02 <0.001 <0.02 <0.02 <0.02 <0.001 <0.02 <0.02 <0.02 <0.001 0.05 <0.02 <0.02 <0.001 <0.02 <0.02 0.02 <0.001 <0.02 <0.02 0.05 0.05 0.05 0.1 0.05 0.100 0.10 0.50 mg/L mg/L <0.02 0.04 0.02 0.04 0.03 0.03 <0.02 0.04 0.06 0.03 0.08 0.04 mg/L mg/L mg/L mg/L mg/L mg/L mg/L 0.04 <0.02 <0.01 2.29 <0.01 0.14 <0.001 0.06 <0.02 <0.01 1.15 0.03 0.31 0.002 0.04 <0.02 <0.01 1.14 <0.01 0.18 <0.001 0.01 <0.02 <0.01 0.42 0.17 0.17 0.008 0.02 <0.02 <0.01 0.32 <0.01 0.19 0.01 0.02 <0.02 <0.01 0.27 0.25 0.15 0.007 mg/L mg/L <0.02 <0.05 <0.02 <0.05 <0.02 <0.05 <0.02 <0.05 <0.02 0.07 <0.02 <0.05 Oil&Grease Ammonia Nitrogen as N mg/L <10 <10 <10 <10 <10 <10 mg/L 0.6 0.9 2.1 0.8 0.8 0.6 20 50 50 0.20 0.20 0.20 0.20 0.20 1 1 1 0.001 1 0.50 Not detectable - 50 100 1.00 1.00 1.00 1.00 1.00 2.00 4.00 5.00 1.00 2.00 0.50 10 0.07 87 4.4.1.1 Water Quality Evaluation The water quality evaluation involved three types of evaluations; evaluation of overall GPTs system, Rubbish Trap evaluation, and the evaluation of Biofilter as described in Section 3.5.2.3. 4.4.1.1.1 GPTs Evaluation Results Table 4.11 presented the overall results for GPTs system evaluation. The results can best be illustrated by Figure 4.9(a) to 4.9(f) for pH, SS, BOD, COD, AN, and DO respectively. Table 4.11: Water Quality Results for Overall GPTs System pH SS (mg/L) BOD (mg/L) Event Influent Effluent Influent Effluent Influent Effluent 6.4 6.7 10 15 5 4 1 5.9 5.7 44 38 10 17 2 5.7 5.9 12 15 4 5 3 5.9 6.1 9 9 6 4 4 6.1 6 23 29 7 7 5 6.4 6.6 9 9 5 5 6 COD (mg/L) AN (mg/L) DO (mg/L) Event Influent Effluent Influent Effluent Influent Effluent 17 7 1.5 1.7 1 38 75 1.5 0.8 7.4 7.57 2 3 17 20 0.9 0.9 7.57 7.7 20 20 0.5 0.4 7.8 7.4 4 33 39 0.6 2.1 8.8 7.6 5 16 16 0.8 0.6 9 7.8 6 From Figure 4.9(a), it can be noticed that the pH values for all event are in the range 5.5 to 9 which under the limit of Standard A and Standard B, of Environmental Quality Act 1974. The improvement of SS concentration is only detected in Event 2 with 13.64% of removal (Figure 4.9(b)). The percentages of removal for BOD are detected in Event 1 and Event 4 with 20% and 33.33% removal respectively. The removal for COD is only detected in Event 1 by 59%. AN shows a good water quality improvement with 46.67%, 20%, and 25% removal in Event 2, Event 4, and Event 6 respectively. The concentration of DO is increased for all 88 events with the highest improvement is in Event 6 with 13.33% concentration increment. The summary of the percentages of removal efficiency are displayed in Table 4.12. (a) (b) Figure 4.9: Water Quality Results for GPTs for parameters (a) pH and (b) SS 89 (Continued Figure 4.9) (c) (d) (e) Figure 4.9: Water Quality Results for GPTs for parameters (c) BOD, (d) COD and (e) AN 90 (Continued Figure 4.9) (f) Figure 4.9: Water Quality Results for GPTs for parameters (f) DO Table 4.12: Percentages of Removal for GPTs Percentages of Removal (%) Event SS BOD COD AN DO 20.00 58.82 2.30 1 13.64 46.67 1.72 2 3 33.33 20.00 4 5 4.4.1.1.2 Rubbish Trap Evaluation Results The evaluation results for rubbish trap are shown in Table 4.13 and the results are also depicted in Figure 4.10(a) to 4.10(f) for pH, SS, BOD, COD, AN, and DO respectively. 91 Event 2 3 4 5 6 Event 2 3 4 5 6 Table 4.13: Evaluation Results for Rubbish Trap pH SS (mg/L) BOD (mg/L) Influent Effluent Influent Effluent Influent Effluent 5.9 5.6 44 21 10 11 5.7 6 12 2 4 4 5.9 5.8 9 14 6 4 6.1 6.1 23 62 7 8 6.4 7 9 4 5 4 COD (mg/L) AN (mg/L) DO (mg/L) Influent Effluent Influent Effluent Influent Effluent 38 66 1.5 0.9 7.4 7.4 17 20 0.9 1.4 7.57 7.8 20 23 0.5 0.5 7.8 7.5 33 39 0.6 0.9 8.8 9.0 16 10 0.8 0.8 9.0 8.6 From Figure 4.10(a), it can be seen that pH values are in a good range of 5.5 to 7 while the percentages of SS removal are in the range of 52% to 83% (Figure 4.10(b). The low performance results can be observed from other parameters; COD,BOD, and AN where the improvement were detected in only one event. The poor performance was also detected in DO with percentages of improvement less than 3%. For overall, it can be concluded that the rubbish trap is very effective in improving SS concentration compared to other parameters. The percentages of removal efficiency results are summarized in Table 4.14. (a) Figure 4.10: Water Quality Results for Rubbish Trap for parameters (a) pH 92 (Continued Figure 4.10) (b) (c) (d) Figure 4.10: Water Quality Results for Rubbish Trap for parameters (b) SS, (c) BOD, and (d) COD 93 (Continued Figure 4.10) (e) (f) Figure 4.10: Water Quality Results for Rubbish Trap for parameters (e) AN and (f) DO Table 4.14: Percentages of Removal for Rubbish Trap Percentages of Removal (%) Event SS BOD COD AN DO 2 52.27 40.00 83.33 3.04 3 33.33 4 37.50 2.27 5 94 4.4.1.1.3 Biofilter Evaluation Results Table 4.15 illustrated the overall results for biofilter system evaluation. The comparison of concentration values between the events are displayed in Figure 4.11(a) to 4.11(f) for pH, SS, BOD, COD, AN, and DO respectively. The summary of the percentages of removal efficiency results for biofilter are shown in Table 4.16. Event 2 3 4 5 6 Event 2 3 4 5 6 Table 4.15: Evaluation Results for Biofilter pH SS (mg/L) BOD (mg/L) Influent Effluent Influent Effluent Influent Effluent 5.6 5.7 21 38 11 17 6 5.9 2 15 4 5 5.8 6.1 14 9 4 4 6.1 6 62 29 8 7 7 6.6 4 9 4 5 COD (mg/L) AN (mg/L) DO (mg/L) Influent Effluent Influent Effluent Influent Effluent 66 75 0.9 0.8 7.4 7.4 20 20 1.4 0.9 7.57 7.8 23 20 0.5 0.4 7.8 7.5 39 39 0.9 2.1 8.8 9.0 10 16 0.8 0.6 9.0 8.6 Table 4.16: Percentages of Removal for Biofilter Percentages of Removal (%) SS BOD COD AN DO Event 11.11 2 35.71 3.04 3 35.71 13.04 20.00 4 53.23 12.50 2.27 5 It can be seen in Figure 4.11(a) that the pH value was only improved in Event 4 from 5.8 to 6.1. In Event 4, the concentration of SS decreases by 35.71% removal and increases by 53.23% removal in Event 5 (Figure 4.11(b)). The improvement of BOD can only be seen in Event 5 with 12.5% removal (Figure 4.11(c)). The concentration of DO increase for all events in the range 1% to maximum value of 10% improvement while AN improve for all Events except event 5 with percentages of removal from 11% to 35%. From the results, it can be concluded that the biofilter is very effective in improving AN and DO. 95 (a) (b) (c) Figure 4.11: Water Quality Results for Biofilter for parameters (a) pH, (b) SS, and (c) BOD 96 (Continued Figure 4.11) (d) (e) (f) Figure 4.11: Water Quality Results for Biofilter for parameters (d) COD, (e) AN, and (f) DO 97 4.4.2 Block L52 Rubbish Trap The water quality at Block L52 rubbish trap is checked to compare with the water quality results of Block L50. The influent and effluent samples are taken on two events, i.e., stormwater event on 19/08/2008 and dry weather on 20/08/2008. The results are presented in Table 4.17 where it shows that all the effluent for storm event samples are complies with Standard A and Standard B. The effluent for samples taken during dry weather are complies with Standard A and Standard B except for SS, BOD, and COD. Figure 4.12(a) and 4.12(b) presented the comparison of concentration for six parameters; pH, Biological Oxygen Demand (BOD), Chemical Oxygen Demand (COD), Suspended Solid (SS), and Ammonia Nitrogen (AN). The effluent samples taken during dry weather show the excellent improvement with almost 100% removal for BOD, COD, and SS. During storm event, the percentages of removal for COD, BOD, and SS are only 35.3%, 56%, and 31.5% respectively. This result indicates that this L52 rubbish trap is capable in improving water quality in both dry and wet weather, and more effective during dry day. (a) Figure 4.12: Water Quality Results for Block L52 during (a) storm event 98 (Continued Figure 4.12) (b) Figure 4.12: Water Quality Results for Block L52 during (b) dry weather Table 4.17: Water Quality Results for Block L52 Rubbish Trap Parameters pH BOD*5 days at 20⁰C COD Suspended solid Mercury as Hg Cadmium as Cd Hexa-Chromium as Cr6+ Arsenic as As Cyanide as CN Lead as Pb Tri-Chromium as Cr3+ Copper as Cu Manganese as Mn Nickel as Ni Tin as Sn Zinc as Zn Boron Iron as Fe Phenol Free Chlorine as Cl2 Sulphide as S 2- Oil&Grease Ammonia Nitrogen as N Units mg/L mg/L mg/L mg/L mg/L Storm Event Influent Effluent 6 6 17 11 75 33 54 37 <0.001 <0.001 <0.004 <0.004 Dry Weather Influent Effluent 5.2 6 381 99 1077 255 1937 72 <0.001 <0.001 <0.004 <0.004 Standard A 6.0-9.0 20 50 50 0.005 0.01 0.05 Standard B 5.5-9.0 50 100 100 0.05 0.02 mg/L mg/L mg/L mg/L 0.04 <0.001 <0.02 <0.02 <0.02 <0.001 <0.02 <0.02 0.03 0.006 0.17 <0.02 <0.02 0.005 <0.02 <0.02 mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L <0.02 <0.01 0.09 <0.02 <0.01 0.04 1.58 0.29 0.014 <0.02 <0.01 0.07 <0.02 <0.01 0.05 0.27 0.65 0.006 0.02 <0.01 0.1 <0.02 <0.01 0.08 0.49 1.87 0.024 <0.02 <0.01 0.1 <0.02 <0.01 0.05 1.01 2.44 0.021 mg/L <0.02 <0.02 <0.02 <0.02 0.20 0.20 0.20 0.20 1 1 1 0.001 1 <0.05 1.58 1.34 0.50 0.50 Not detectable 10 mg/L 0.23 mg/L 17 <10 48 <10 mg/L <0.07 0.8 10.1 8.6 0.05 0.05 0.1 0.20 - 0.05 0.100 0.10 0.50 1.00 1.00 1.00 1.00 1.00 2.00 4.00 5.00 1.00 2.00 0.07 99 4.5 Water Quantity Control Despite functioned for water quality improvement, the GPTs system can also benefit for the purpose of water quantity control. Figures 4.13(a) to 4.13(c) are the flow hydrograph for event 04/08/2008, 07/08/2008, and 12/08/2008 respectively. From the figures, it can be seen that the values of peak flow out is lower than the peak flow in. That means that the GPTs system is capable in reducing the peak flow of the discharge entering the water bodies, thus preventing overflows occurs to the system. The GPTs also provide storage and detention time for the sedimentation of pollutant loads in the system. Table 4.18 below shows the detention time, storage capacity, and the values of peak flow in and out of the GPTs system of three stormwater events; 04/08/2008, 07/08/2008, and 16/08/2008. Table 4.18: Water Quantity Results of GPTs system Qpeak Storm Detention Storage Qpeak in out Event Time (m3) (l/s) (l/s) (min) 04/08/08* 10 0.525 0.7 0.7 07/08/08 10 0.638 0.9 0.7 16/08/08 10 8.190 7.6 4.6 *Notes: Problem occurs to flow meter during sampling (a) Figure 4.13: Flow Hydrograph for event (a) 04/08/2008 100 (Continued Figure 4.13) (b) (c) Figure 4.13: Flow Hydrograph for event (b) 07/08/2008, and (c) 12/08/2008 4.6 First Flush Analysis First flush analysis results are presented in two parts. In first part, the pollutograph for four monitored events (04/08/2008, 07/08/2008, 12/08/2008, and 04/09/2008) are depicted to investigate the influences of first flush to the concentration of pollutants entering the GPTs system. The samples are then checked for the occurrence of first flush and the results are explained in Section 4.6.2. Flow hydrographs and sampling time for event 04/08/2008, 07/08/2008, and 12/08/2008 101 are shown in Figure 4.8(a) to 4.8(c) respectively and hydrograph and sampling time for event 04/09/2008 is displayed in Figure 4.14. Figure 4.14: Flow Hydrograph for event 04/09/2008 4.6.1 Pollutograph Evaluation 4.6.1.1 Event 04/08/2008 The relationship between the concentration of pollutants with time can be observed from Figure 4.15(a) to 4.15(f) which represent the pollutograph for BOD, COD, SS, Cu, Zinc, and AN respectively for event 04/08/2008. From the results, it can be seen that the concentration of BOD, COD, and Zn is increasing within 20 minutes of the discharge to the end of the discharge. For SS, Zinc, and AN, the concentration of pollutants is high at the early discharge and low at the end of the discharge. 102 (a) (b) (c) (d) (e) (f) Figure 4.15: Pollutograph for event 04/08/2008 for parameters (a) BOD, (b) COD, (c)SS, (d)Cu, (e)Zinc, and (f) AN 103 4.6.1.2 Event 07/08/2008 The pollutograph for event 07/08/2008 are illustrated in Figure 4.16(a) to 4.16(f) for BOD, COD, SS, Cu, Zinc, and AN respectively. Figure 4.15(a) to 4.15(c) show that the concentration of BOD, COD, and SS is low at the early of the discharge, become higher at the middle, and the concentration is decreased at the end of the discharge. For Cu, Zinc, and AN, the concentration of pollutants is high at the early discharge and low at the end of the discharge. (a) (b) (c) (d) Figure 4.16: Pollutograph for event 07/08/2008 for parameters (a) BOD, (b) COD, (c)SS, and (d)Cu 104 (Continued Figure 4.16) (e) (f) Figure 4.16: Pollutograph for event 07/08/2008 for parameters (e)Zinc, and (f) AN 4.6.1.3 Event 12/08/2008 The pollutograph for event 12/08/2008 are depicted in Figure 4.17(a) to 4.17(f) for BOD, COD, SS, Cu, Zinc, and AN respectively. All the pollutograph show that the concentration of the six parameters is high at the early of the discharge, then decrease at the end of the discharge. (a) (b) Figure 4.17: Pollutograph for event 12/08/2008 for parameters (a) BOD and (b) COD 105 (Continued Figure 4.17) (c) (d) (e) (f) Figure 4.17: Pollutograph for event 12/08/2008 for parameters (a) BOD, (b) COD, (c)SS, (d)Cu, (e)Zinc, and (f) AN 4.6.1.4 Event 04/09/2008 The pollutograph for event 04/09/2008 are depicted in Figure 4.18(a) to 4.18(j) for BOD, COD, SS, Cu, Zinc, AN, TP, Pb, Nitrite, and Nitrate respectively. From the results obtained, it can be noticed that the concentration of the pollutants is higher at first sample which was taken at the early of the storm event compared to the samples taken at time 10 minutes discharge until the end of discharge. The trend is observed for all the ten parameters. (Refer to Appendix F for laboratory test result) 106 (a) (b) (c) (d) (e) (f) Figure 4.18: Pollutograph for event 04/09/2008 for parameters (a) BOD, (b) COD, (c)SS, (d)Cu, (e)Zinc, and (f) AN 107 (Continued Figure 4.18) (g) (h) (i) (j) Figure 4.18: Pollutograph for event 04/09/2008 for parameters (g) TP, (h) Pb, (i) Nitrite, and (j) Nitrate For overall, the observation from all the four events have found out that the concentration of pollutants for most event is high at the beginning of the discharge, i.e. within the 30 minutes of the discharge then decrease throughout the time until at the end of the discharge. It shows that the concentration of pollutants in first flush runoff is more polluted than the remainder due to the washout of deposited pollutants by rainfall. 108 4.6.2 Occurrence of First Flush The dimensionless normalized mass and flow volumes are used to characterize the occurrence of first flush. A first flush is exist if the dimensionless cumulative pollutant mass M exceeds the dimensionless cumulative runoff volume V at all instances during the storm events or falls above the 45 line when plotting M versus V graph. The results of first flush analysis for all storm events 04/08/2008, 07/08/2008, 12/08/2008, and 04/09/2008 are presented in Table 4.19. The occurrence of first flush is only detected for TSS and COD, showing that only the two pollutants occur in the stormwater runoff for every storm event. The details of first flush occurrence calculation and determination can be view at Appendix G. Table 4.19: Occurrence of First Flush Event TSS 4/8/08 7/8/08 12/8/08 4/9/08 YES YES YES YES 4.7 BOD5 COD NO NO NO NO YES YES YES YES Cu Pb Zn O&G NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NH3N NO NO NO NO NO3N NA NA NA NO NO2N NA NA NA NO Event Mean Concentration (EMC) Event Mean Concentration (EMC) is the flow-weighted mean concentration of a pollutant. EMC is one of the numbers of empirical approaches available for determining pollutant load. This pollutant load is essential for GPTs design purpose. EMC values for the four events (04/08/2008, 07/08/2008, 12/08/2008, and 04/09/2008) have been calculated and the results are displayed in Table 4.20. The detail of the EMC calculation is shown in Appendix H. PO4 NA NA NA NO 109 Table 4.20: Event Mean Concentration (EMC) values Date TSS BOD5 COD Cu Pb Zn O&G 4/8/08 7/8/08 12/8/08 4/9/08 31.03 10.91 19.98 3.90 12.22 5.10 6.00 3.65 0.09 0.20 0.04 0.06 <0.02 <0.02 <0.02 0.04 0.85 0.30 0.79 0.24 9.98 <10 <10 0.00 61.08 19.98 27.18 10.98 NH3N 1.30 0.79 1.38 0.09 NO3N NA NA NA 0.11 NO2N NA NA NA 0.003 PO4 NA NA NA 0.52 By comparing the results with the typical EMC values for urban area abstracted from (DID, 2000) in Table 4.21, it was found that all the parameters value are below the typical EMC limit except for PO4 and Cu. For event 4/9/08, the concentration of PO4 is 0.52 mg/L which exceeding the limit of 0.13 mg/L while the value of 0.20 mg/L Cu concentration is also exceeding the limit of 0.03-0.09 mg/L (for event 7/8/08). Table 4.21: Typical Event Mean Concentration (EMC) values in mg/L (DID, 2000) Landuse Pollutants Sediment 50 to 200 Urban 4.8 SS 85 TN 1.2 TP Ammonia 0.13 0.01 to 9.8 Faecal Coliforms 4,000200,000 Cu 0.030.09 Pb 0.20.5 Evaluation of Design Criteria The sizing of the rubbish trap is checked according to Urban Stormwater Management Manual for Malaysia (MASMA). The determination of design criteria for the rubbish trap is based on general design parameters stated in Section 34.5.2, Chapter 34, MASMA (DID, 2000c). The design criteria checking for rubbish trap is considering the following criterion; trap area, trap rack size (height), velocity, and bar spacing. The summarized of design criteria results are presented in Table 4.22. Zn 0.271.1 110 Table 4.22: Design Criteria Results Criteria Requirement Actual Value Check Trap Area, At Minimum requirement 5.1225 m2 = 0.036 m2 Actual > Min Req. -OK! Trap Rack height Minimum requirement 50cm = 26.5cm Actual > Min Req. -OK! Flow Velocity, V V should not exceed 1.0 m/s 0.25m/s Actual < 1.0m/s -OK! Bar Spacing Maximum clear spacing 50mm 30mm bar spacing Actual < Max Req. -OK! The actual value of the trap area is calculated as 5.1225 m2 while the minimum requirement of trap area obtained from Design Chart 34.A1, Chapter 34 MASMA is 0.036 m2. As the trash rack area is larger than the minimum requirement values, hence the size adopted is appropriate. Same goes for the trap rack height where the actual value 50 cm exceeding the minimum requirement of 26.5 cm. The bar spacing i.e. 30 cm is under the limit of maximum requirement of 50 mm clear spacing. From observation at site, the 30 cm clear spacing between bars of the trash rack is found capable in retaining small bottle and aluminum can. In order to minimize re-suspension, the flow velocity through the track must not exceed 1 m/s. the results show that the checking for velocity is appropriate where the calculated velocity for the track rack is 0.25 m/s. The details of the design criteria calculation can be viewed in Appendix I. Annual sediment data is required to calculate the average annual pollutant retention value for the purpose of sediment trap depth calculation. However, the sediment data collection in this study is only available for three months (data collection from 2006/2008 until 26/09/2008). The Event Mean Concentration (EMC) 111 values obtained from this study are also limited where the data are only available for four stormwater events. Annual EMC values are needed to calculate the average annual load. From the average annual load and annual volumetric runoff values, the Annual Mean Concentration (AMC) can be determined. Then, the pollutant removal efficiency, η of the rubbish trap can be determined from Equation 4.1: ⎛ AMC ⎞ ⎝ ⎠ proposed ⎟ η = ⎜⎜ AMCexisting ⎟ where AMC = annual mean concentration. (4.1) 112 CHAPTER 5 CONCLUSION AND RECOMMENDATION 5.1 Conclusion In the present study, an attempt has been made to evaluate and investigate the performance of GPTs system for surface runoff in open channel flow. The collection of rubbish and sediment amount, hydrologic data collection, water quality assessment, first flush analysis and EMC values determination have been performed for the purpose of achieving the study objectives. A few conclusions have been made from the series of field work and laboratory investigation carried out. In terms of the efficiency of GPTs system in removing pollutants during storm and dry weather condition, the following conclusions can be made: i. The GPTs system is effective in removing pollutants during wet weather condition. However, the system is not working during dry weather as there is no flow entering the system during that time. ii. For overall, it can be concluded that the GPTs system is effective in improving water quality during storm event where the effluent of discharge water of the GPTs system are comply with parameter limit as stated in Standard A and Standard B of Environmental Quality Act (1974). However in terms of the pollutant removal efficiency, the results are not encouraging 113 where the percentages of pollutants removal for most water quality parameters are low. iii. The performance of rubbish trap is excellent where it manage to decrease the concentration of Suspended Solid in the range of 52% to 83% removal efficiency and is capable in preventing as high as 19.2kg rubbish and 13.9kg sediment from entering water bodies. Rainfall influence the amount of rubbish and sediment collected, where the rubbish and sediment amount increase with the increasing rainfall value. iv. Despite of functioned for water quality control, the GPTs is also benefit for water quantity control where it provide detention time, storage, and decrease the peak flow of the water flowing through the system. The investigation of first flush analysis on the water samples and the determination of EMC values from the hydrologic data have come out with the conclusions stated that: v. For first flush analysis, the concentration of pollutants in first flush runoff within the early 30 minutes of the runoff is found more polluted than the remainder. Analysis for occurrence of first flush shows that only TSS and COD occur in the stormwater runoff for every storm event. vi. The values of EMC for all the monitored storm event are higher for TSS, COD, and BOD compared to other pollutants, i.e. Cu, Pb, Zn, Oil and Grease, NH3-N, NO3-N, and PO4. 114 5.2 Recommendation There are some recommendations suggested in order to improve the performance of the GPTs system; i. It is recommended that the maintenance for the GPTs system is conducted for three-day period to avoid overflows occurred to the system. Maintenance work is also suggested during storm events to ensure large pollutants that block the rubbish trap can be removed to avoid overflows. ii. The backwater and overflow problems during storm event are affecting the results of water quality. Thus, providing solution for this problem will enhance a better water quality results. iii. A lot of improvement need to be done to the design criteria of the GPTs to suit the weather condition in Malaysia as the design implemented before is based on MASMA which are adopted from the Australia weather conditions. iv. New effective filtration materials should be suggested to improve the workability of the biofilter system. The materials should be economical, durable, and the most important criteria is it has a good mechanism in improving the quality of water. v. 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Woodward–Clyde, (1994), San Jose Street Sweeping Equipment Evaluation, report prepared for City of San Jose, California, October. 121 APPENDIX A Average Recurrence Interval (ARI) for existing drainage system 35 cm A1 10 cm A2 40 cm 1 0.3125 15 cm 50 cm Manning’s Equation (for Composite drain Section): Q = 1 m ⎛ Ai 5 / 3 ⎞ 1 / 2 ⎟S ∑ ⎜ n * i = 1 ⎜⎝ Pi 2 / 3 ⎟⎠ (1) Where; Area,A15/3 = (b × y)5/3 = (0.35 m × 0.50 m)5/3 = 0.055 Area,A2 5/3 = ((b+zy)y)5/3 = ((0.15+0.3125×0.40)0.40)5/3 = 0.025 Wetted Perimeter, P12/3 = (2y+b)2/3 = ((2×0.35)+0.50)2/3 = 1.129 Wetted Perimeter, P2 2/3 = (b+2y√(1+z2))2/3 = (0.15+2*0.40*√(1+0.31252))2/3 = 0.992 122 n, Manning’s roughness = 0.011 (From Table 14.3, MASMA (Chapter 14, for coefficient Concrete/Asphalt)) n*, Manning’s roughness = coefficient m ni Ai i =1 Pi ∑ m 5/3 2/3 A5 / 3 ∑P i =1 i 2/3 i = (0.011 × 0.055 / 1.129) + (0.011 × 0.025 / 0.992) (0.055 / 1.129) + (0.025 / 0.992) = 0.011 S, friction slope = 1:1000 or 0.001 (recommended) From Equation (1): ∴Flow, Q = 1 × ((0.055 / 1.129) + (0.025 / 0.992)) × 0.0011 / 2 0.011 = 0.212 m 3 /s = 212 l/s Assume : QManning ' s From Rational Method, = Q = 0.212m 3 /s = QRationalMe thod C×I ×A 360 (2) C×I × A 360 Where; C, Dimensionless Runoff Coefficient = 0.9 (From Design Chart 14.3, MASMA) A, Drainage Area = 1600m 2 or 0.16 ha From Equation (2): ∴ y It = 0.212m3 / s × 360 0.9 × 0.16ha = 531 mm/hr Where; y It = y year ARI average rainfall intensity over time of concentration, tc , (mm/hr) 123 From Equation 13.2 (MASMA Chapter 13); ln( RI t ) = a + b ln(t ) + c (ln(t )) 2 + d (ln(t ))3 Try with t=10 mins ln(532.5) = a + b ln(10) + c (ln(10)) 2 + d (ln(10))3 6.28 = a + 2.3025b + 5.302c + 12.21d From Table 13.A1, for Johor Bharu, (Try ARI 5 years) a = 4.3251 b = 1.0147 c = -0.3308 d = 0.0205 From Equation (3): 6.28 = a + 2.3025b + 5.302c + 12.21d 6.28 = 4.3251 + (2.3025 × 1.0147) + (5.302 × −0.3308) + (12.21 × 0.0205) 6.28 ≠ 5.16 (Try ARI 10 years) a = 4.4896 b = 0.9971 c = -0.3279 d = 0.0205 From Equation (3): 6.28 = a + 2.3025b + 5.302c + 12.21d 6.28 = 4.4896 + (2.3025 × 0.9971) + (5.302 × −0.3279) + (12.21 × 0.0205) 6.28 ≈ 5.30 ∴ARI for the drainage system = 10 years (3) 124 Average Recurrence Interval (ARI) for GPTs system 60cm 30cm b = 0.30 m y = 0.60 m From Manning’s Equation : Q = AR 2 / 3 S 1 / 2 n (1) Where; A, cross-sectional area = by = 0.30m × 0.60m = 0.180m 2 R, Hydraulic Radius = by b + 2y = 0.180m2 0.30m + (2 × 0.60m) = 0.120m S, friction slope = 1:1000 or 0.001 (recommended) n, Manning’s roughness = 0.011 (From Table 14.3, MASMA (Chapter 14, for coefficient Concrete/Asphalt)) From Equation (1): 2 ∴Flow, Q = 1 0.180m 2 × 0.120m 3 × 0.0012 0.011 = 0.126 m 3 /s = 126 l/s 125 Assume : = QManning ' s From Rational Method, QRationalMe thod C×I × A 360 Q = 0.126m 3 /s = (2) C×I × A 360 Where; C, Dimensionless Runoff Coefficient = 0.9 (From Design Chart 14.3, MASMA) A, Drainage Area = 1600m 2 or 0.16 ha From Equation (2): ∴ y It = 0.126m3 / s × 360 0.9 × 0.16ha = 315 mm/hr Where; y It = y year ARI average rainfall intensity over time of concentration, tc , (mm/hr) From Equation 13.2 (MASMA Chapter 13); ln( RI t ) = a + b ln(t ) + c (ln(t )) 2 + d (ln(t ))3 Try with t=10 mins ln(315) = a + b ln(10) + c(ln(10)) 2 + d (ln(10))3 5.75 = a + 2.3025b + 5.302c + 12.21d From Table 13.A1, for Johor Bharu, (Try ARI 5 years) a = 4.3251 b = 1.0147 c = -0.3308 d = 0.0205 (3) 126 From Equation (3): 5.75 = a + 2.3025b + 5.302c + 12.21d 5.75 = 4.3251 + (2.3025 × 1.0147) + (5.302 × −0.3308) + (12.21 × 0.0205) 5.75 ≠ 5.16 Try ARI 10 years) a = 4.4896 b = 0.9971 c = -0.3279 d = 0.0205 From Equation (3): 5.75 = a + 2.3025b + 5.302c + 12.21d 5.75 = 4.4896 + (2.3025 × 0.9971) + (5.302 × −0.3279) + (12.21 × 0.0205) 5.75 ≈ 5.30 ∴ARI for the GPTs system = 10 years 127 APPENDIX B Invert Level (I.L) – GPTs System Rubbish Trap 3 I.L 29.519 Existing Invert Level: 29.700 2 I.L 29.70 4 5 I.L 28.176 I.L 28.013 I.L 27.532 Oil & Grease Trap Biofilter I.L 29.70 1 Sump 6 Drainage 7 I.L 25.342 8 I.L 26.514 To UTM River Point 1 2 3 4 5 6 7 8 Different Height (m) 0.000 0.000 -0.181 -1.343 -0.163 -0.481 -1.018 -1.172 I.L 29.700 29.700 29.519 28.176 28.013 27.532 26.514 25.342 128 APPENDIX C Slope – GPTs System Rubbish Trap Oil & Grease Trap 1 Biofilter 1:4 2 Point 1 2 Horizontal Distance (m) 0 15.168 Different Heigth (m) 0 -3.849 Slope 1:4 129 APPENDIX D Details Plan – GPTs System C 1470 A 2760 Drainage 800 Plan view of the GPTs system (in mm) Biofilter 2500 Oil & Grease Trap 4400 750 Sump D 1450 1050 1100 65 1500 1830 Rubbish Trap 2000 950 B 1550 1700 1270 1700 A 1500 2950 To UTM River 130 Details of Section A-A (in mm) 950 1050 Details of Section B (Rubbish Trap) (in mm) 50 2100 131 Details of Section C (Oil and Grease Trap) 125 1300 125 Inlet 1130 X X 150 250 300 1270 Y 1130 Y 250 1470 Y Y Outlet Plan view of Oil & Grease Trap (in mm) 132 1300 250 1380 1120 250 250 1550 250 Details of section X-X (in mm) 560 1380 270 φ270 250 1550 Details of section Y-Y (in mm) 250 133 Details of Section D (Biofilter) 800 300 900 300 650 153 Charcoal Oil Palm Fibre EBB Inlet Activated Carbon 300 X X Plan view of Biofilter (in mm) 800 300 900 300 650 Details of section X-X (in mm) 60 74 300 80 Outlet 134 APPENDIX E CALIBRATION FOR FLOW METER (IWK) LABORATORY TEST Reading 1 2 3 4 5 Velocity Height (m) 0.090 0.080 0.070 0.050 0.030 Width (m) 0.30 0.30 0.30 0.30 0.30 Area (m2) 0.027 0.024 0.021 0.015 0.009 Distance(m) Time(s) 3.00 3.00 3.00 3.00 3.00 3.08 2.92 3.03 3.30 4.20 V (m/s) 0.97 1.03 0.99 0.91 0.71 Flow Q (m3/s) 0.0263 0.0247 0.0208 0.0136 0.0064 EFFICIENCY HEIGHT Reading 1 2 3 4 5 0.001 0.008 0.006 0.003 0.006 Average / / / / / Percentages of Error = 0.090 = 0.080 = 0.070 = 0.050 = 0.030 = 0.67 9.50 8.43 5.00 19.33 8.59 % % % % % % AUTOMATIC FLOWMETER Velocity Flow Height Q (m3/s) (m) V (m2/s) 0.0906 1.00 0.0275 0.0876 0.99 0.0269 0.0759 0.97 0.0218 0.0525 0.83 0.0129 0.0358 0.61 0.0068 135 FLOW Reading 1 2 3 4 5 0.0012 0.0022 0.0010 0.0007 0.0004 Average / / / / / Efficiency 0.0263 0.0247 0.0208 0.0136 0.0064 0.03 0.04 0.02 0.08 0.10 Average / / / / / Efficiency 0.97 1.03 0.99 0.91 0.71 = = = = = = 4.57 9.09 4.85 5.40 5.78 5.94 % % % % % % = = = = = = 2.67 3.64 2.03 8.70 14.60 6.33 % % % % % % VELOCITY Reading 1 2 3 4 5 136 CALIBRATION FOR FLOW METER (TPI) LABORATORY TEST Reading 1 2 3 4 5 Velocity Height (m) 0.090 0.080 0.070 0.055 0.045 Width (m) 0.30 0.30 0.30 0.30 0.30 Area (m2) 0.0270 0.0240 0.0210 0.0165 0.0135 Distance(m) Time(s) 3.00 3.00 3.00 3.00 3.00 3.02 3.11 3.14 3.42 3.45 V (m/s) 0.99 0.96 0.96 0.88 0.87 = = = = = = 3.11 9.63 9.29 8.73 11.33 8.42 Flow Q (m3/s) 0.0268 0.0232 0.0201 0.0145 0.0117 EFFICIENCY HEIGHT Reading 1 2 3 4 5 0.003 0.008 0.006 0.005 0.005 Average / / / / / Efficiency 0.090 0.080 0.070 0.055 0.045 % % % % % % AUTOMATIC FLOWMETER Velocity Flow Height Q (m3/s) (m) V (m2/s) 0.0928 1.03 0.0284 0.0877 1.01 0.0267 0.0765 0.93 0.0213 0.0598 0.85 0.0154 0.0501 0.84 0.0117 137 FLOW Reading 1 2 3 4 5 0.0016 0.0035 0.0012 0.0009 0.0000 Average / / / / / Efficiency 0.0268 0.0232 0.0201 0.0145 0.0117 0.04 0.05 0.03 0.03 0.03 Average / / / / / Efficiency 0.99 0.96 0.96 0.88 0.87 = = = = = = 5.89 15.33 6.16 6.40 0.00 6.76 % % % % % % = = = = = = 3.69 4.70 2.66 3.10 3.40 3.51 % % % % % % VELOCITY Reading 1 2 3 4 5 138 APPENDIX F LABORATORY TEST RESULTS FOR EVENT 04/09/2008 (EMC) SS Sample 1 2 3 4 5 6 7 8 9 10 Wt. of Filter Wt. of Filter Vol. of SS SS Paper (mg) 84.21 83.64 84.32 84.41 84.37 84.1 84.31 84.02 84.18 84.06 Paper+SS (mg) 90.22 83.77 84.69 84.67 84.50 84.27 84.62 84.05 84.40 84.06 sample (ml) 100 100 100 100 100 100 100 100 100 100 (mg/ml) 0.0601 0.0013 0.0037 0.0026 0.0013 0.0017 0.0031 0.0003 0.0022 0 (mg/L) 60 1 4 3 1 2 3 0 2 0 Time (min) 0 10 15 20 25 30 40 45 55 65 BOD Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 DO1(ppm) DO5(ppm) 14.95 5.60 7.98 6.16 8.22 6.06 7.18 5.74 8.5 6.17 9.25 5.90 8.18 5.88 9.43 6.30 7.93 6.20 8.44 6.80 Nutrient Water (ml) 175 175 175 175 175 175 175 175 175 175 Sample(ml) 125 125 125 125 125 125 125 125 125 125 BOD5(mg/L) 13 3 3 2 3 5 3 4 2 2 139 COD Sample 1 2 3 4 5 6 7 8 9 10 NH3-N Time (min) 0 10 15 20 25 30 40 45 55 65 COD (mg/L) 128 0 14 15 1 15 0 0 0 0 Cu Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 NH3-N (mg/L) 0.39 0.25 0.17 0.06 0.04 0.03 0.03 0.2 0.19 0.07 Time (min) 0 10 15 20 25 30 40 45 55 65 NITRATE (mg/L) 0.22 0.04 0.08 0.11 0.1 0.13 0.11 0.13 0.13 0.09 Time (min) 0 10 15 20 25 30 40 45 55 65 NITRITE (mg/L) 0.008 0.001 0.003 0.004 0.002 0.003 0.003 0.002 0.001 0 NO3-N Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Cu (mg/L) 0.16 0 0 0.08 0 0.05 0.13 0.11 0.13 0 Pb Sample 1 2 3 4 5 6 7 8 9 10 NO2-N Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Pb (mg/L) 0.061 0.057 0.054 0.04 0.046 0.036 0.04 0.04 0.038 0.032 Sample 1 2 3 4 5 6 7 8 9 10 140 PO4 Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 PO4 (mg/L) 0.58 0.22 0 0.22 0.09 1.58 0.11 0.33 1.72 0.02 Oil & Grease Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Wt. of Beaker + beaker (g) 49.1874 87.7020 55.5878 86.1999 56.4375 52.3234 47.8652 61.4478 55.6800 54.4224 O&G (g) 49.1774 87.6872 55.5811 86.1986 56.4320 52.3188 47.8588 61.4471 55.6776 54.4177 Vol. of sample (ml) 350 350 350 350 350 350 350 350 350 350 O&G (mg/L) 0 0 0 0 0 0 0 0 0 0 141 APPENDIX G FIRST FLUSH CALCULATION FOR EVENT 04/08/2008 SS Time Sample (min) 1 0 2 2 3 5 ΣQ = Q (m3/s) 0.0007 0.0007 0.0002 0.0250 Zn (mg/L) 44 21 38 Cum Normalized ∆t(min) Time Time 0 0 0.00 2 2 0.40 3 5 1.00 Σ Cum T 5 OCCURRENCE OF FIRST FLUSH: YES Avg Q (m3/s) 0.0000 0.0007 0.00045 Avg V (m2) 0 0.084 0.081 Σ Avg V 0.165 Avg Conc Cum Cum/ΣV (mg/L) V 0 0.00 0 0.084 0.51 32.5 0.165 1.00 29.5 Σ Mass = Mass (mg) 0 2730 2389.5 5119.5 Cum Cum/ Mass ΣMass 0 0.00 2730 1.35 5119.5 2.54 142 BOD Sample 1 2 3 Time (min) 0 2 5 Q (m3/s) 0.0007 0.0007 0.0002 ΣQ= 0.0250 Zn (mg/L) 10 11 17 ∆t(min) 0 2 3 Σ Cum T OCCURRENCE OF FIRST FLUSH: NO Cum Time 0 2 5 5 Normalized Avg Q Time (m3/s) 0.00 0.0000 0.40 0.0007 1.00 0.00045 Σ Avg V Avg V (m2) 0 0.084 0.081 0.165 Avg Conc Cum V Cum/ΣV (mg/L) 0 0.00 0 0.084 0.51 10.5 0.165 1.00 14 Σ Mass = Mass (mg) 0 882 1134 2016 Cum Mass 0 882 2016 Cum/ ΣMass 0.00 0.44 1.00 143 COD Sample 1 2 3 Time (min) 0 2 5 ΣQ = Q (m3/s) 0.0007 0.0007 0.0002 0.0250 Zn (mg/L) 38 66 75 ∆t Cum Normalized Avg Q (min) Time Time (m3/s) 0 0 0.00 0.0000 2 2 0.40 0.0007 3 5 1.00 0.00045 Σ Cum Σ Avg T 5 V OCCURRENCE OF FIRST FLUSH: YES Avg V (m2) 0 0.084 0.081 0.165 Cum V 0 0.084 0.165 Avg Cum/ Conc Mass Cum Cum/ΣV (mg/L) (mg) Mass ΣMass 0.00 0 0 0 0.00 0.51 52 4368 4368 2.17 1.00 70.5 5710.5 10078.5 5.00 Σ Mass = 10078.5 144 CU Sample 1 2 3 Time (min) 0 2 5 Q Zn (m3/s) (mg/L) 0.0007 0.1 0.0007 0.09 0.0002 0.06 ΣQ= 0.0250 ∆t (min) 0 2 3 Σ Cum T OCCURRENCE OF FIRST FLUSH: NO Cum Time 0 2 5 5 Normalized Avg Q Time (m3/s) 0.00 0.0000 0.40 0.0007 1.00 0.00045 Σ Avg V Avg V (m2) 0 0.084 0.081 0.165 Avg Conc Cum V Cum/ΣV (mg/L) 0 0.00 0 0.084 0.51 0.095 0.165 1.00 0.075 Σ Mass = Mass (mg) 0 7.98 6.075 14.055 Cum Mass 0 7.98 14.055 Cum/ ΣMass 0.00 0.00 0.01 145 ZINC Time Sample (min) 1 0 2 2 3 5 ΣQ = Q Zn (m3/s) (mg/L) 0.0007 0.55 0.0007 0.98 0.0002 0.91 0.0250 ∆t (min) 0 2 3 Σ Cum T OCCURRENCE OF FIRST FLUSH: NO Cum Normalized Avg Q Avg V (m2) Time Time (m3/s) 0 0.00 0.0000 0 2 0.40 0.0007 0.084 5 1.00 0.00045 0.081 Σ Avg 5 V 0.165 Cum V 0 0.084 0.165 Cum/ΣV 0.00 0.51 1.00 Avg Conc (mg/L) 0 0.765 0.945 Mass (mg) 0 64.26 76.545 Σ Mass = 140.805 Cum/ Cum Mass ΣMass 0 0.00 64.26 0.03 140.805 0.07 146 OIL & GREASE Time Sample (min) 1 0 2 2 3 5 ΣQ = Q Zn 3 (m /s) (mg/L) 0.0007 9 0.0007 9 0.0002 13 0.0250 ∆t (min) 0 2 3 Σ Cum T OCCURRENCE OF FIRST FLUSH: NO Cum Time 0 2 5 5 Normalized Avg Q Time (m3/s) 0.00 0.0000 0.40 0.0007 1.00 0.00045 Σ Avg V Avg V (m2) 0 0.084 0.081 0.165 Avg Conc Mass Cum V Cum/ΣV (mg/L) (mg) 0 0.00 0 0 0.084 0.51 0.095 9 0.165 1.00 0.075 11 Σ Mass = 20 Cum Mass 0 756 891 Cum/ ΣMass 0.00 0.38 0.44 147 NH3-N Sample 1 2 3 Time (min) 0 2 5 Q Zn (m3/s) (mg/L) 0.0007 1.5 0.0007 0.9 0.0002 0.8 ΣQ= 0.0250 ∆t (min) 0 2 3 Σ Cum T Cum Time 0 2 5 5 Normalized Avg Q Time (m3/s) 0.00 0.0097 0.40 0.0007 1.00 0.00045 Σ Avg V Avg V (m2) 0 0.084 0.081 0.165 Avg Conc Cum V Cum/ΣV (mg/L) 0 0.00 0 0.084 0.51 32.5 0.165 1.00 29.5 Σ Mass = Mass (mg) 0 1.2 0.85 Cum Mass 0 100.8 68.85 Cum/ ΣMass 0.00 0.05 0.03 2.05 OCCURRENCE OF FIRST FLUSH: NO *NOTE: No first flush calculation is performed for Pb, NO3-N, NO2-N, and PO4 as no or very small amount of the pollutant is water sample. detected in the 148 FIRST FLUSH CALCULATION FOR EVENT 07/08/2008 SS Time Q Zn Sample (min) (m3/s) (mg/L) 0.0009 12 1 0 2 0.00085 2 2 5 0.0008 15 3 25 0.0003 9 4 27 0.0003 14 5 30 0.0003 9 6 ΣQ = 0.0035 ∆t (min) 0 2 3 20 2 3 Σ Cum T Cum Time 0 2 5 25 27 30 30 Normalized Avg Q Time (m3/s) 0.00 0.0000 0.07 0.000875 0.17 0.000825 0.83 0.00055 0.90 0.0003 1.00 0.0003 Avg V (m2) 0 0.105 0.1485 0.66 0.036 0.054 Σ Avg V 1.0035 Avg Cum/ Conc Mass Cum ΣMass (mg) Mass Cum V Cum/ΣV (mg/L) 0.00 0.00 0 0 0 0.00 0.11 0.10 7 735 735 0.14 0.25 0.25 8.5 1262.25 1997.25 0.39 0.91 0.91 12 7920 9917.25 1.94 0.95 0.95 11.5 414 10331.25 2.02 1.00 1.00 11.5 621 10952.25 2.14 Σ Mass = 10952.25 OCCURRENCE OF FIRST FLUSH: YES 149 BOD Sample 1 2 3 4 5 6 Time (min) 0 2 5 25 27 30 Q Zn (m3/s) (mg/L) 0.0009 4 0.00085 4 0.0008 5 0.0003 6 0.0003 4 0.0003 4 ΣQ= 0.0035 ∆t (min) 0 2 3 20 2 3 Σ Cum T Cum Time 0 2 5 25 27 30 30 Normalized Avg Q Time (m3/s) 0.00 0.0000 0.07 0.000875 0.17 0.000825 0.83 0.00055 0.90 0.0003 1.00 0.0003 Avg V (m2) 0 0.105 0.1485 0.66 0.036 0.054 Σ Avg V 1.0035 Avg Conc Mass (mg) Cum V Cum/ΣV (mg/L) 0.00 0.00 0 0 0.11 0.10 4 420 0.25 0.25 4.5 668.25 0.91 0.91 5.5 3630 0.95 0.95 5 180 1.00 1.00 4 216 Σ Mass = 5114.25 OCCURRENCE OF FIRST FLUSH: NO Cum Mass 0 420 1088.25 4718.25 4898.25 5114.25 Cum/ ΣMass 0.00 0.08 0.21 0.92 0.96 1.00 150 COD Time Q Sample (min) (m3/s) 0.0009 1 0 2 0.00085 2 5 0.0008 3 25 0.0003 4 27 0.0003 5 30 0.0003 6 ΣQ = 0.0035 Zn (mg/L) 17 20 20 20 23 20 ∆t (min) 0 2 3 20 2 3 Σ Cum T Cum Time 0 2 5 25 27 30 30 Normalized Avg Q Avg V (m2) Time (m3/s) 0.00 0.0000 0 0.07 0.000875 0.105 0.17 0.000825 0.1485 0.83 0.00055 0.66 0.90 0.0003 0.036 1.00 0.0003 0.054 Σ Avg V 1.0035 Cum V 0.00 0.11 0.25 0.91 0.95 1.00 Avg Conc Cum/ΣV (mg/L) 0.00 0 0.10 18.5 0.25 20 0.91 20 0.95 21.5 1.00 21.5 Σ Mass = OCCURRENCE OF FIRST FLUSH: YES Mass (mg) 0 1942.5 2970 13200 774 1161 20047.5 Cum/ Cum Mass ΣMass 0 0.00 1942.5 0.38 4912.5 0.96 18112.5 3.54 18886.5 3.69 20047.5 3.92 151 CU Sample 1 2 3 4 5 6 Time (min) 0 2 5 25 27 30 Q Zn (m3/s) (mg/L) 0.0009 0.81 0.00085 0.69 0.0008 0.08 0.0003 0.07 0.0003 0.03 0.0003 0.52 ΣQ= 0.0035 ∆t (min) 0 2 3 20 2 3 Σ Cum T Cum Time 0 2 5 25 27 30 30 Normalized Avg Q Time (m3/s) 0.00 0.0000 0.07 0.000875 0.17 0.000825 0.83 0.00055 0.90 0.0003 1.00 0.0003 Avg V (m2) 0 0.105 0.1485 0.66 0.036 0.054 Σ Avg V 1.0035 Avg Conc Mass (mg) Cum V Cum/ΣV (mg/L) 0.00 0.00 0 0 0.11 0.10 0.75 78.75 0.25 0.25 0.385 57.1725 0.91 0.91 0.075 49.5 0.95 0.95 0.05 1.8 1.00 1.00 0.275 14.85 Σ Mass = 202.0725 OCCURRENCE OF FIRST FLUSH: NO Cum Mass 0 78.75 135.9225 185.4225 187.2225 202.0725 Cum/ ΣMass 0.00 0.02 0.03 0.04 0.04 0.04 152 Zn Sample 1 2 3 4 5 6 Time (min) 0 2 5 25 27 30 Q Zn (m3/s) (mg/L) 0.0009 0.42 0.00085 0.4 0.0008 0.34 0.0003 0.19 0.0003 0.4 0.0003 0.35 ΣQ= 0.0035 ∆t (min) 0 2 3 20 2 3 Σ Cum T Cum Time 0 2 5 25 27 30 30 Normalized Avg Q Time (m3/s) 0.00 0.0000 0.07 0.000875 0.17 0.000825 0.83 0.00055 0.90 0.0003 1.00 0.0003 Avg V (m2) 0 0.105 0.1485 0.66 0.036 0.054 Σ Avg V 1.0035 Avg Conc Mass Cum (mg) Mass Cum V Cum/ΣV (mg/L) 0.00 0.00 0 0 0 0.11 0.10 0.41 43.05 43.05 0.25 0.25 0.37 54.945 97.995 0.91 0.91 0.265 174.9 272.895 0.95 0.95 0.295 10.62 283.515 1.00 1.00 0.375 20.25 303.765 Σ Mass = 303.765 OCCURRENCE OF FIRST FLUSH: NO Cum/ ΣMass 0.00 0.01 0.02 0.05 0.06 0.06 153 NH3-N Sample 1 2 3 4 5 6 Time (min) 0 2 5 25 27 30 Q Zn (m3/s) (mg/L) 0.0009 0.9 0.00085 1.4 0.0008 0.9 0.0003 0.5 0.0003 0.5 0.0003 0.4 ΣQ= 0.0035 ∆t (min) 0 2 3 20 2 3 Σ Cum T Cum Time 0 2 5 25 27 30 30 Normalized Avg Q Time (m3/s) 0.00 0.0000 0.07 0.000875 0.17 0.000825 0.83 0.00055 0.90 0.0003 1.00 0.0003 Avg V (m2) 0 0.105 0.1485 0.66 0.036 0.054 Σ Avg V 1.0035 Avg Conc Mass Cum (mg) Mass Cum V Cum/ΣV (mg/L) 0.00 0.00 0 0 0 0.11 0.10 1.15 120.75 120.75 0.25 0.25 1.15 170.775 291.525 0.91 0.91 0.7 462 753.525 0.95 0.95 0.5 18 771.525 1.00 1.00 0.45 24.3 795.825 Σ Mass = 795.825 Cum/ ΣMass 0.00 0.02 0.06 0.15 0.15 0.16 OCCURRENCE OF FIRST FLUSH: NO *NOTE: No first flush calculation is performed for Pb, Oil and Grease, NO3-N, NO2-N, and PO4 as no or very small amount of the pollutant is detected in the water sample. 154 FIRST FLUSH CALCULATION FOR EVENT 12/08/2008 SS Sample 1 2 3 4 5 6 Time (min) 0 2 5 60 62 65 Q (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 ΣQ= 0.6000 Zn (mg/L) 23 62 29 9 4 9 ∆t (min) 0 2 3 55 2 3 Σ Cum T Cum Time 0 2 5 60 62 65 65 Normalized Time 0.00 0.03 0.08 0.92 0.95 1.00 Avg Q (m3/s) 0.0000 0.1 0.1 0.1 0.1 0.1 Σ Avg V Avg V (m2) 0 12 18 330 12 18 390 Avg Conc Mass Cum (mg) Mass Cum V Cum/ΣV (mg/L) 0.00 0.00 0 0 0 12.00 0.03 42.5 510000 510000 30.00 0.08 45.5 819000 1329000 360.00 0.92 19 6270000 7599000 372.00 0.95 6.5 78000 7677000 390.00 1.00 6.5 117000 7794000 Σ Mass = 7794000 OCCURRENCE OF FIRST FLUSH: YES Cum/ ΣMass 0.00 0.22 0.57 3.25 3.28 3.33 155 BOD Sample 1 2 3 4 5 6 Time (min) 0 2 5 60 62 65 Q (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 ΣQ= 0.6000 Zn (mg/L) 7 8 7 5 4 5 ∆t (min) 0 2 3 55 2 3 Σ Cum T Cum Time 0 2 5 60 62 65 65 Normalized Time 0.00 0.03 0.08 0.92 0.95 1.00 Avg Q (m3/s) 0.0000 0.1 0.1 0.1 0.1 0.1 Σ Avg V Avg V (m2) 0 12 18 330 12 18 390 Avg Conc Mass Cum (mg) Mass Cum V Cum/ΣV (mg/L) 0.00 0.00 0 0 0 12.00 0.03 7.5 90000 90000 30.00 0.08 7.5 135000 225000 360.00 0.92 6 1980000 2205000 372.00 0.95 4.5 54000 2259000 390.00 1.00 4.5 81000 2340000 Σ Mass = 2340000 OCCURRENCE OF FIRST FLUSH: NO Cum/ ΣMass 0.00 0.04 0.10 0.94 0.97 1.00 156 COD Sample 1 2 3 4 5 6 Time (min) 0 2 5 60 62 65 Q (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 ΣQ= 0.6000 Zn (mg/L) 33 39 39 16 10 16 ∆t (min) 0 2 3 55 2 3 Σ Cum T Cum Time 0 2 5 60 62 65 65 Normalized Time 0.00 0.03 0.08 0.92 0.95 1.00 Avg Q (m3/s) 0.0000 0.1 0.1 0.1 0.1 0.1 Σ Avg V Avg V (m2) 0 12 18 330 12 18 390 Avg Conc Mass Cum (mg) Mass Cum V Cum/ΣV (mg/L) 0.00 0.00 0 0 0 12.00 0.03 36 432000 432000 30.00 0.08 39 702000 1134000 360.00 0.92 27.5 9075000 10209000 372.00 0.95 13 156000 10365000 390.00 1.00 13 234000 10599000 Σ Mass = 10599000 OCCURRENCE OF FIRST FLUSH: YES Cum/ ΣMass 0.00 0.18 0.48 4.36 4.43 4.53 157 Cu Sample 1 2 3 4 5 6 Time (min) 0 2 5 60 62 65 Q (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 ΣQ= 0.6000 Zn (mg/L) 0.04 0.04 0.03 0.04 0.03 0.04 ∆t (min) 0 2 3 55 2 3 Σ Cum T Cum Time 0 2 5 60 62 65 65 Normalized Time 0.00 0.03 0.08 0.92 0.95 1.00 Avg Q (m3/s) 0.0000 0.1 0.1 0.1 0.1 0.1 Σ Avg V Avg V (m2) 0 12 18 330 12 18 390 Avg Conc Cum V Cum/ΣV (mg/L) 0.00 0.00 0 12.00 0.03 0.04 30.00 0.08 0.035 360.00 0.92 0.035 372.00 0.95 0.035 390.00 1.00 0.035 Σ Mass = OCCURRENCE OF FIRST FLUSH: NO Mass (mg) 0 480 630 11550 420 630 13710 Cum Mass 0 480 1110 12660 13080 13710 Cum/ ΣMass 0.00 0.00 0.00 0.01 0.01 0.01 158 Zn Sample 1 2 3 4 5 6 Time (min) 0 2 5 60 62 65 ΣQ= Q (m3/s) Zn ∆t(min) (mg/L) 0.1 2.29 0 0.1 1.15 2 0.1 1.14 3 0.1 0.42 55 0.1 0.32 2 0.1 0.27 3 Σ Cum 0.6000 T Cum Time 0 2 5 60 62 65 65 Normalized Time 0.00 0.03 0.08 0.92 0.95 1.00 Avg Q (m3/s) 0.0000 0.1 0.1 0.1 0.1 0.1 Σ Avg V Avg V (m2) 0 12 18 330 12 18 390 Avg Conc Cum V Cum/ΣV (mg/L) 0.00 0.00 0 12.00 0.03 1.72 30.00 0.08 1.145 360.00 0.92 0.78 372.00 0.95 0.37 390.00 1.00 0.295 Σ Mass = OCCURRENCE OF FIRST FLUSH: NO Mass Cum (mg) Mass Cum/ΣMass 0 0 0.00 20640 20640 0.01 20610 41250 0.02 257400 298650 0.13 4440 303090 0.13 5310 308400 0.13 308400 159 NH3-N Sample Time (min) Sample 1 2 3 4 5 6 (min) 0 2 5 60 62 65 ΣQ= Q (m3/s) (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 0.6000 Zn (mg/L) (mg/L) 0.6 0.9 2.1 0.8 0.8 0.6 ∆t (min) ∆t(min) 0 2 3 55 2 3 Σ Cum T Cum Time Normalized Time Avg Q (m3/s) Avg V (m2) Time 0 2 5 60 62 65 Time 0.00 0.03 0.08 0.92 0.95 1.00 (m3/s) 0.0000 0.1 0.1 0.1 0.1 0.1 Σ Avg V (m2) 0 12 18 330 12 18 65 390 Avg Conc Cum V Cum/ΣV (mg/L) Cum V Cum/ΣV (mg/L) 0.00 0.00 0 12.00 0.03 0.75 30.00 0.08 1.5 360.00 0.92 1.45 372.00 0.95 0.8 390.00 1.00 0.7 Σ Mass = Mass (mg) Cum Mass (mg) Mass 0 0 9000 9000 27000 36000 478500 514500 9600 524100 12600 536700 Cum/ ΣMass ΣMass 0.00 0.00 0.02 0.22 0.22 0.23 536700 OCCURRENCE OF FIRST FLUSH: NO *NOTE: No first flush calculation is performed for Pb, Oil and Grease, NO3-N, NO2-N, and PO4 as no or very small amount of the pollutant is detected in the water sample. 160 FIRST FLUSH CALCULATION FOR EVENT 04/09/2008 Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 ΣQ= Q Zn (m3/s) (mg/L) 0.0000 60 0.0097 1 0.0153 4 0.0200 3 0.0344 1 0.0227 2 0.0149 3 0.0061 0 0.0020 2 0.0003 0 0.1254 ∆t (min) 0 10 5 5 5 5 10 5 10 10 Σ Cum T Cum Time 0 10 15 20 25 30 40 45 55 65 65 Normalized Time 0.00 0.15 0.23 0.31 0.38 0.46 0.62 0.69 0.85 1.00 Avg Q (m3/s) 0.0000 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Σ Avg V Avg V (m2) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 46.23 Avg Conc Cum V Cum/ΣV (mg/L) 0 0.00 0 2.91 0.06 30.7 6.66 0.14 2.5 11.955 0.26 3.15 20.115 0.44 1.95 28.68 0.62 1.5 39.96 0.86 2.4 43.11 0.93 1.7 45.54 0.99 1.25 46.23 1.00 1.1 Σ Mass = OCCURRENCE OF FIRST FLUSH: YES Mass (mg) 0 89337 9375 16679.25 15912 12847.5 27072 5355 3037.5 759 180374.3 Cum Mass 0 89337 98712 115391.3 131303.3 144150.8 171222.8 176577.8 179615.3 180374.3 Cum/ ΣMass 0.00 0.53 0.59 0.68 0.78 0.85 1.02 1.05 1.07 1.07 161 BOD Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Q (m3/s) 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 ΣQ= 0.1254 Zn (mg/L) 13 3 3 2 3 5 3 4 2 2 ∆t (min) 0 10 5 5 5 5 10 5 10 10 Σ Cum T Cum Time 0 10 15 20 25 30 40 45 55 65 65 Normalized Time 0.00 0.15 0.23 0.31 0.38 0.46 0.62 0.69 0.85 1.00 Avg Q (m3/s) 0.0000 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Σ Avg V Avg V (m2) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 46.23 Cum V 0 2.91 6.66 11.955 20.115 28.68 39.96 43.11 45.54 46.23 Cum/ΣV 0.00 0.06 0.14 0.26 0.44 0.62 0.86 0.93 0.99 1.00 Avg Conc (mg/L) 0 7.819 2.786 2.52 2.639 3.976 3.955 3.801 3.402 2.359 Σ Mass = OCCURRENCE OF FIRST FLUSH: NO Mass (mg) 0 22753 10448 13343 21534 34054 44612 11973 8267 1628 168613 Cum Mass 0 22753.29 33200.79 46544.19 68078.43 102132.9 146745.3 158718.4 166985.3 168613 Cum/ ΣMass 0.00 0.13 0.20 0.28 0.40 0.61 0.87 0.94 0.99 1.00 162 COD Time Sample (min) 1 0 2 10 3 15 4 20 5 25 6 30 7 40 8 45 9 55 10 65 ΣQ = Q COD (m3/s) (mg/L) 0.0000 128 0.0097 0 0.0153 14 0.0200 15 0.0344 1 0.0227 15 0.0149 0 0.0061 0 0.0020 0 0.0003 0 ∆t(min) 0 10 5 5 5 5 10 5 10 10 0.1254 Σ Cum T Cum Normalized Avg Q Time Time (m3/s) 0 0.00 0.0000 10 0.15 0.00485 15 0.23 0.0125 20 0.31 0.01765 25 0.38 0.0272 30 0.46 0.02855 40 0.62 0.0188 45 0.69 0.0105 55 0.85 0.00405 65 1.00 0.00115 Σ Avg 65 V Avg V (m2) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 46.23 Cum V 0 2.91 6.66 11.955 20.115 28.68 39.96 43.11 45.54 46.23 Cum/ΣV 0.00 0.06 0.14 0.26 0.44 0.62 0.86 0.93 0.99 1.00 Avg Conc (mg/L) 0 64 7 14.5 8 8 7.5 0 0 0 Mass (mg) 0 186240 26250 76777.5 65280 68520 84600 0 0 0 ΣM 507667.5 OCCURRENCE OF FIRST FLUSH: YES Cum Cum/ ΣMass Mass 0 0.00 186240 1.10 212490 1.26 289267.5 1.72 354547.5 2.10 423067.5 2.51 507667.5 3.01 507667.5 3.01 507667.5 3.01 507667.5 3.01 163 Cu Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Q Zn (m3/s) (mg/L) 0.0000 0.16 0.0097 0 0.0153 0 0.0200 0.08 0.0344 0 0.0227 0.05 0.0149 0.13 0.0061 0.11 0.0020 0.13 0.0003 0 ∆t (min) 0 10 5 5 5 5 10 5 10 10 Cum Time 0 10 15 20 25 30 40 45 55 65 Normalized Time 0.00 0.15 0.23 0.31 0.38 0.46 0.62 0.69 0.85 1.00 Avg Q (m3/s) 0.0000 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Avg V (m2) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Avg Conc Cum V Cum/ΣV (mg/L) 0 0.00 0 2.91 0.06 0.08 6.66 0.14 0 11.955 0.26 0.04 20.115 0.44 0.04 28.68 0.62 0.025 39.96 0.86 0.09 43.11 0.93 0.12 45.54 0.99 0.12 46.23 1.00 0.065 OCCURRENCE OF FIRST FLUSH: NO Mass (mg) 0 232.8 0 211.8 326.4 214.125 1015.2 378 291.6 44.85 Cum Mass 0 232.8 232.8 444.6 771 985.125 2000.325 2378.325 2669.925 2714.775 Cum/ ΣMass 0.00 0.00 0.00 0.00 0.00 0.01 0.01 0.01 0.02 0.02 164 Pb Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Q Zn (m3/s) (mg/L) 0.0000 0.061 0.0097 0.057 0.0153 0.054 0.0200 0.04 0.0344 0.046 0.0227 0.036 0.0149 0.04 0.0061 0.04 0.0020 0.038 0.0003 0.032 ΣQ= 0.1254 ∆t (min) 0 10 5 5 5 5 10 5 10 10 Σ Cum T Cum Time 0 10 15 20 25 30 40 45 55 65 65 Normalized Time 0.00 0.15 0.23 0.31 0.38 0.46 0.62 0.69 0.85 1.00 Avg Q (m3/s) 0.0000 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Σ Avg V Avg V (m2) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 46.23 Avg Conc Cum V Cum/ΣV (mg/L) 0 0.00 0 2.91 0.06 0.059 6.66 0.14 0.0555 11.955 0.26 0.047 20.115 0.44 0.043 28.68 0.62 0.041 39.96 0.86 0.038 43.11 0.93 0.04 45.54 0.99 0.039 46.23 1.00 0.035 ΣM OCCURRENCE OF FIRST FLUSH: NO Mass (mg) 0 171.69 208.125 248.865 350.88 351.165 428.64 126 94.77 24.15 2004.285 Cum Mass 0 171.69 379.815 628.68 979.56 1330.725 1759.365 1885.365 1980.135 2004.285 Cum/ ΣMass 0.00 0.00 0.00 0.00 0.01 0.01 0.01 0.01 0.01 0.01 165 Zn Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 ΣQ= Q Zn (m3/s) (mg/L) 0.0000 1.34 0.0097 0.21 0.0153 0.2 0.0200 0.2 0.0344 0.21 0.0227 0.16 0.0149 0.26 0.0061 0.21 0.0020 0.26 0.0003 0.25 0.1254 ∆t (min) 0 10 5 5 5 5 10 5 10 10 Σ Cum T Cum Time 0 10 15 20 25 30 40 45 55 65 65 Normalized Time 0.00 0.15 0.23 0.31 0.38 0.46 0.62 0.69 0.85 1.00 Avg Q (m3/s) 0.0000 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Σ Avg V Avg V (m2) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Avg Conc Cum V Cum/ΣV (mg/L) 0 0.00 0 2.91 0.06 0.775 6.66 0.14 0.205 11.955 0.26 0.2 20.115 0.44 0.205 28.68 0.62 0.185 39.96 0.86 0.21 43.11 0.93 0.235 45.54 0.99 0.235 46.23 1.00 0.255 46.23 OCCURRENCE OF FIRST FLUSH: NO ΣM Mass (mg) 0 2255.25 768.75 1059 1672.8 1584.525 2368.8 740.25 571.05 175.95 11196.38 Cum Mass 0 2255.25 3024 4083 5755.8 7340.325 9709.125 10449.38 11020.43 11196.38 Cum/ ΣMass 0.00 0.01 0.02 0.02 0.03 0.04 0.06 0.06 0.07 0.07 166 NH3-N Time Sample (min) 1 0 2 10 3 15 4 20 5 25 6 30 7 40 8 45 9 55 10 65 ΣQ = Q Zn (m3/s) (mg/L) 0.0000 0.39 0.0097 0.25 0.0153 0.17 0.0200 0.06 0.0344 0.04 0.0227 0.03 0.0149 0.03 0.0061 0.2 0.0020 0.19 0.0003 0.07 0.1254 ∆t (min) 0 10 5 5 5 5 10 5 10 10 Σ Cum T Cum Normalized Time Time 0 0.00 10 0.15 15 0.23 20 0.31 25 0.38 30 0.46 40 0.62 45 0.69 55 0.85 65 1.00 65 Avg Q (m3/s) 0.0000 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Σ Avg V Avg Avg Conc Mass Cum V Cum Cum/ΣV (mg/L) (mg) Mass (m2) V 0 0 0.00 0 0 0 2.91 2.91 0.06 0.32 931.2 931.2 3.75 6.66 0.14 0.21 787.5 1718.7 5.295 11.955 0.26 0.115 608.925 2327.625 8.16 20.115 0.44 0.05 408 2735.625 8.565 28.68 0.62 0.035 299.775 3035.4 11.28 39.96 0.86 0.03 338.4 3373.8 3.15 43.11 0.93 0.115 362.25 3736.05 2.43 45.54 0.99 0.195 473.85 4209.9 0.69 46.23 1.00 0.13 89.7 4299.6 Σ Mass 46.23 = 4299.6 OCCURRENCE OF FIRST FLUSH: NO Cum/ ΣMass 0.00 0.01 0.01 0.01 0.02 0.02 0.02 0.02 0.02 0.03 167 Tp Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 ΣQ= Q Zn (m3/s) (mg/L) 0.0000 0.58 0.0097 0.22 0.0153 0 0.0200 0.22 0.0344 0.09 0.0227 1.58 0.0149 0.11 0.0061 0.33 0.0020 1.72 0.0003 0.02 0.1254 ∆t (min) 0 10 5 5 5 5 10 5 10 10 Σ Cum T Cum Time 0 10 15 20 25 30 40 45 55 65 65 Normalized Time 0.00 0.15 0.23 0.31 0.38 0.46 0.62 0.69 0.85 1.00 Avg Q (m3/s) 0.0000 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Σ Avg V Avg V (m2) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 46.23 Avg Conc Cum V Cum/ΣV (mg/L) 0 0.00 0 2.91 0.06 0.4 6.66 0.14 0.11 11.955 0.26 0.11 20.115 0.44 0.155 28.68 0.62 0.835 39.96 0.86 0.845 43.11 0.93 0.22 45.54 0.99 1.025 46.23 1.00 0.87 ΣM OCCURRENCE OF FIRST FLUSH: NO Mass (mg) 0 1164 412.5 582.45 1264.8 7151.775 9531.6 693 2490.75 600.3 23891.18 Cum/ Cum ΣMass Mass 0 0.00 1164 0.01 1576.5 0.01 2158.95 0.01 3423.75 0.02 10575.53 0.06 20107.13 0.12 20800.13 0.12 23290.88 0.14 23891.18 0.14 168 NO3-N Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 ΣQ= Q NO3-N (m3/s) (mg/L) ∆t(min) 0.0000 0.22 0 0.0097 0.04 10 0.0153 0.08 5 0.0200 0.11 5 0.0344 0.1 5 0.0227 0.13 5 0.0149 0.11 10 0.0061 0.13 5 0.0020 0.13 10 0.0003 0.09 10 Σ Cum 0.1254 T Cum Time 0 10 15 20 25 30 40 45 55 65 65 Normalized Time 0.00 0.15 0.23 0.31 0.38 0.46 0.62 0.69 0.85 1.00 Avg Q (m3/s) 0.0000 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Σ Avg V Avg V (m2) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Avg Conc Cum V Cum/ΣV (mg/L) 0 0.00 0 2.91 0.06 0.13 6.66 0.14 0.06 11.955 0.26 0.095 20.115 0.44 0.105 28.68 0.62 0.115 39.96 0.86 0.12 43.11 0.93 0.12 45.54 0.99 0.13 46.23 1.00 0.11 46.23 ΣM Mass (mg) 0 378.3 225 503.025 856.8 984.975 1353.6 378 315.9 75.9 Cum Mass 0 378.3 603.3 1106.325 1963.125 2948.1 4301.7 4679.7 4995.6 5071.5 23891.18 OCCURRENCE OF FIRST FLUSH: NO *NOTE: No first flush calculation is performed for Oil and Grease and NO2-N as no amount of the pollutant is detected in the water sample. Cum/ ΣMass 0.00 0.00 0.00 0.01 0.01 0.02 0.03 0.03 0.03 0.03 169 APPENDIX H EMC CALCULATION FOR EVENT 04/08/2008 Suspended Solid (SS) No Time Q (m3/s) SS ∆t(min) Avg Q(m3/s) 1 2 3 12:15 12:17 12:20 0.0007 0.0007 0.0002 44 21 38 2 3 0 0.0007 0.00045 0.0001 Avg Vol (m3) 0.084 0.081 Σ Avg Vol (L) Avg Conc (mg/L) Mass(mg) 84 81 32.5 29.5 2730 2389.5 165 Σ 5119.5 Avg Vol (L) Avg Conc (mg/L) Mass(mg) 84 81 10.5 14 882 1134 EMC 31.03 BOD No Time Q (m3/s) BOD5 ∆t(min) Avg Q(m3/s) 1 2 3 12:15 12:17 12:20 0.0007 0.0007 0.0002 10 11 17 2 3 0 0.0007 0.00045 0.0001 Avg Vol (m3/s) 0.084 0.081 Σ Σ 165 2016 EMC 12.22 COD No Time 1 2 3 12:15 12:17 12:20 Q (m3/s) 0.0007 0.0007 0.0002 COD Avg ∆t(min) (mg/L) Q(m3/s) 38 2 0.0007 66 3 0.00045 75 0 0.0001 Avg Vol (m3) 0.084 0.081 Avg Vol (L) 84 81 Σ 165 Avg Conc Mass(mg) (mg/L) 52 4368 70.5 5710.5 Σ 10078.5 EMC 61.08 170 Cu No Time 1 2 3 12:15 12:17 12:20 Q (m3/s) 0.0007 0.0007 0.0002 Cu (mg/L) 0.1 0.09 0.06 Dt(min) 2 3 0 Avg Q(m3/s) 0.0007 0.00045 0.0001 Avg Vol (m3/s) 0.084 0.081 S Avg Vol (L) 84 81 165 Avg Conc Mass(mg) (mg/L) 0.095 7.98 0.075 6.075 S 14.055 EMC 0.09 Pb No Time 1 2 3 12:15 12:17 12:20 No Time 1 2 3 12:15 12:17 12:20 Q (m3/s) 0.0007 0.0007 0.0002 Pb (mg/L) <0.02 <0.02 <0.02 The concentration values for each time are <0.02mg/L. Hence, the EMC value for Pb is <0.02 mg/L. Zn Q (m3/s) 0.0007 0.0007 0.0002 Zn (mg/L) 0.55 0.98 0.91 ∆t(min) 2 3 0 Avg Q(m3/s) 0.0007 0.00045 0.0001 Avg Vol (m3/s) 0.084 0.081 Avg Vol (L) 84 81 Avg Conc (mg/L) 0.765 0.945 Σ 165 Σ Mass(mg) 64.26 76.545 140.805 EMC 0.85 171 Oil & Grease No Time 1 2 3 12:15 12:17 12:20 Q (m3/s) 0.0007 0.0007 0.0002 Avg Oil&Grease ∆t(min) Q(m3/s) (mg/L) 9 2 0.0007 9 3 0.00045 13 0 0.0001 Avg Vol (m3/s) 0.084 0.081 Avg Vol (L) 84 81 Avg Conc (mg/L) 9 11 Σ 165 Σ Mass(mg) 756 891 1647 NH3-N No Time 1 2 3 12:15 12:17 12:20 Q (m3/s) 0.0007 0.0007 0.0002 AN ∆t(min) 1.5 0.9 0.8 2 3 0 Avg Q(m3/s) 0.0007 0.00045 0.0001 Avg Vol (m3) 0.084 0.081 Avg Vol (L) 84 81 Σ 165 Avg Conc Mass(mg) (mg/L) 1.2 100.8 0.85 68.85 Σ 169.65 EMC 1.03 EMC 9.98 172 EMC CALCULATION FOR EVENT 07/08/2008 Suspended Solid (SS) No Time Q (m3/s) 1 2 3 4 5 6 11:05 11:07 11:10 11:30 11:32 11:35 0.0009 0.00085 0.0008 0.0003 0.0003 0.0003 SS (mg/L) 12 2 15 9 14 9 ∆t(min) 2 3 20 2 3 Avg Q(m3/s) 0.000875 0.000825 0.00055 0.0003 0.0003 Avg Vol (m3) 0.105 0.1485 0.66 0.036 0.054 Avg Vol (L) 105 148.5 660 36 54 Avg Conc (mg/L) 7 8.5 12 11.5 11.5 Σ 1003.5 Σ Avg Vol (m3/s) 0.105 0.1485 0.66 0.036 0.054 Avg Vol (L) 105 148.5 660 36 54 Avg Conc (mg/L) 4 4.5 5.5 5 4 Σ 1003.5 Σ Mass(mg) 735 1262.25 7920 414 621 10952.25 EMC 10.91 BOD No Time Q (m3/s) 1 2 3 4 5 6 11:05 11:07 11:10 11:30 11:32 11:35 0.0009 0.00085 0.0008 0.0003 0.0003 0.0003 BOD5 (mg/L) 4 4 5 6 4 4 ∆t(min) 2 3 20 2 3 Avg Q(m3/s) 0.000875 0.000825 0.00055 0.0003 0.0003 Mass(mg) 420 668.25 3630 180 216 5114.25 EMC 5.10 173 COD No Time Q (m3/s) 1 2 3 4 5 6 11:05 11:07 11:10 11:30 11:32 11:35 0.0009 0.00085 0.0008 0.0003 0.0003 0.0003 COD (mg/L) 17 20 20 20 23 20 ∆t(min) 2 3 20 2 3 Avg Q(m3/s) 0.000875 0.000825 0.00055 0.0003 0.0003 Avg Vol (m3) 0.105 0.1485 0.66 0.036 0.054 Avg Vol (L) 105 148.5 660 36 54 Σ Avg Conc (mg/L) 18.5 20 20 21.5 21.5 Σ 1003.5 Mass(mg) 1942.5 2970 13200 774 1161 20047.5 Cu No Time 1 2 3 4 5 6 11:05 11:07 11:10 11:30 11:32 11:35 Avg Q Cu ∆t(min) Q(m3/s) (m3/s) (mg/L) 0.0009 0.81 2 0.000875 0.00085 0.69 3 0.000825 0.0008 0.08 20 0.00055 0.0003 0.07 2 0.0003 0.0003 0.03 3 0.0003 0.0003 0.52 Avg Vol (m3/s) 0.105 0.1485 0.66 0.036 0.054 Σ Avg Vol (L) 105 148.5 660 36 54 1003.5 Avg Conc (mg/L) 0.75 0.385 0.075 0.05 0.275 Σ Mass(mg) 78.75 57.1725 49.5 1.8 14.85 202.0725 EMC 0.20 EMC 19.98 174 Pb No Time Q (m3/s) 1 2 3 4 5 6 11:05 11:07 11:10 11:30 11:32 11:35 0.0009 0.00085 0.0008 0.0003 0.0003 0.0003 No Time 1 2 3 4 5 6 11:05 11:07 11:10 11:30 11:32 11:35 Pb (mg/L) <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 The concentration values for each time are <0.02mg/L. Hence, the EMC value for Pb is <0.02 mg/L. Zn Q (m3/s) 0.0009 0.00085 0.0008 0.0003 0.0003 0.0003 Zn ∆t(min) 0.42 0.4 0.34 0.19 0.4 0.35 2 3 20 2 3 Avg Q(m3/s) 0.000875 0.000825 0.00055 0.0003 0.0003 Avg Vol (m3/s) 0.105 0.1485 0.66 0.036 0.054 Avg Vol (L) 105 148.5 660 36 54 Avg Conc (mg/L) 0.41 0.37 0.265 0.295 0.375 Σ 1003.5 Σ Mass(mg) 43.05 54.945 174.9 10.62 20.25 303.765 EMC 0.30 175 Oil & Grease No Time 1 2 3 4 5 6 11:05 11:07 11:10 11:30 11:32 11:35 Q Oil&Grease 3 (m /s) (mg/L) 0.0009 <10 0.00085 <10 0.0008 <10 0.0003 <10 0.0003 <10 0.0003 <10 The concentration values for each time are <0.02mg/L. Hence, the EMC value for Oil & Grease is <0.02 mg/L. NH3-N No Time 1 2 3 4 5 6 11:05 11:07 11:10 11:30 11:32 11:35 Avg Q NH3-N ∆t(min) 3 Q(m3/s) (m /s) (mg/L) 0.0009 0.9 2 0.000875 0.00085 1.4 3 0.000825 0.0008 0.9 20 0.00055 0.0003 0.5 2 0.0003 0.0003 0.5 3 0.0003 0.0003 0.4 Avg Vol (m3) 0.105 0.1485 0.66 0.036 0.054 Avg Vol (L) 105 148.5 660 36 54 Avg Conc (mg/L) 1.15 1.15 0.7 0.5 0.45 Σ 1003.5 Σ Mass(mg) 120.75 170.775 462 18 24.3 795.825 EMC 0.79 176 EMC CALCULATION FOR EVENT 12/08/2008 Suspended Solid (SS) No Time 1 2 3 4 5 6 16:30 16:32 16:35 17:30 17:32 17:35 Q (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 SS ∆t(min) 23 62 29 9 4 9 2 3 55 2 3 Avg Q(m3/s) 0.1 0.1 0.1 0.1 0.1 Avg Vol (m3) 12 18 330 12 18 Avg Vol (L) 12000 18000 330000 12000 18000 Σ 390000 Avg Vol (m3/s) 12 18 330 12 18 Avg Vol (L) 12000 18000 330000 12000 18000 Avg Conc (mg/L) 42.5 45.5 19 6.5 6.5 Σ Mass(mg) 510000 819000 6270000 78000 117000 7794000 EMC 19.98 BOD No Time 1 2 3 4 5 6 16:30 16:32 16:35 17:30 17:32 17:35 Q (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 BOD5 ∆t(min) 7 8 7 5 4 5 2 3 55 2 3 Avg Q(m3/s) 0.1 0.1 0.1 0.1 0.1 Σ 390000 Avg Conc Mass(mg) (mg/L) 7.5 90000 7.5 135000 6 1980000 4.5 54000 4.5 81000 Σ 2340000 EMC 6.00 177 COD No Time 1 2 3 4 5 6 16:30 16:32 16:35 17:30 17:32 17:35 Q (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 COD ∆t(min) 33 39 39 16 10 16 2 3 55 2 3 Avg Q(m3/s) 0.1 0.1 0.1 0.1 0.1 Avg Vol (m3) 12 18 330 12 18 Avg Vol (L) 12000 18000 330000 12000 18000 Avg Conc (mg/L) 36 39 27.5 13 13 Σ 390000 Σ Avg Vol (m3/s) 12 18 330 12 18 Avg Vol (L) 12000 18000 330000 12000 18000 Avg Conc (mg/L) 0.04 0.035 0.035 0.035 0.035 Mass(mg) 432000 702000 9075000 156000 234000 10599000 EMC 27.18 Cu No Time 1 2 3 4 5 6 16:30 16:32 16:35 17:30 17:32 17:35 Q (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 Cu ∆t(min) 0.04 0.04 0.03 0.04 0.03 0.04 2 3 55 2 3 Avg Q(m3/s) 0.1 0.1 0.1 0.1 0.1 Σ 390000 Σ Mass(mg) 480 630 11550 420 630 13710 EMC 0.04 178 Pb No Time 1 2 3 4 5 6 16:30 16:32 16:35 17:30 17:32 17:35 No Time 1 2 3 4 5 6 16:30 16:32 16:35 17:30 17:32 17:35 Q (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 Lead <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 The concentration values for each time are <0.02mg/L. Hence, the EMC value for Pb is <0.02 mg/L. Zn Q (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 Zn ∆t(min) 2.29 1.15 1.14 0.42 0.32 0.27 2 3 55 2 3 Avg Q(m3/s) 0.1 0.1 0.1 0.1 0.1 Avg Vol (m3/s) 12 18 330 12 18 Avg Vol (L) 12000 18000 330000 12000 18000 Avg Conc (mg/L) 1.72 1.145 0.78 0.37 0.295 Σ 390000 Σ Mass(mg) 20640 20610 257400 4440 5310 308400 EMC 0.79 179 Oil & Grease No Time(a.m) 1 2 3 4 5 6 16:30 16:32 16:35 17:30 17:32 17:35 Q (m3/s) 0.1 0.1 0.1 0.1 0.1 0.1 Oil&Grease <10 <10 <10 <10 <10 <10 The concentration values for each time are <0.02mg/L. Hence, the EMC value for Oil & Grease is <0.02 mg/L. NH3-N No Time(a.m) 1 16:30 Q (m3/s) 0.1 2 3 4 5 6 16:32 16:35 17:30 17:32 17:35 0.1 0.1 0.1 0.1 0.1 2 Avg Q(m3/s) 0.1 Avg Vol (m3/s) 12 Avg Vol (L) 12000 Avg Conc (mg/L) 0.75 3 55 2 3 0.1 0.1 0.1 0.1 18 330 12 18 18000 330000 12000 18000 1.5 1.45 0.8 0.7 27000 478500 9600 12600 Σ 390000 Σ 536700 AN ∆t(min) 0.6 0.9 2.1 0.8 0.8 0.6 Mass(mg) 9000 EMC 1.38 180 EMC CALCULATION FOR EVENT 04/09/2008 Suspended Solid (SS) Sample Time (min) Q (m3/s) SS ∆t(min) Avg Q(m3/s) Avg Vol (m3) Avg Vol (L) Avg Conc(mg/L) Mass(mg) 1 2 3 4 5 6 7 8 9 10 0 10 15 20 25 30 40 45 55 65 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 60 1 4 3 1 2 3 0 2 0 0 10 5 5 5 5 10 5 10 10 0 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Σ 0 2910 3750 5295 8160 8565 11280 3150 2430 690 46230 0 30.7 2.5 3.15 1.95 1.5 2.4 1.7 1.25 1.1 Σ 0 89337 9375 16679.25 15912 12847.5 27072 5355 3037.5 759 180374.3 Time (min) 0 10 15 20 25 30 40 45 55 65 Q (m3/s) 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 BOD 13 3 3 2 3 5 3 4 2 2 Avg Q(m3/s) 0 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Avg Vol (m3) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Σ Avg Vol (L) 0 2910 3750 5295 8160 8565 11280 3150 2430 690 46230 Avg Conc(mg/L) 0 7.819 2.786 2.52 2.639 3.976 3.955 3.801 3.402 2.359 Σ Mass(mg) 0 22753.29 10447.5 13343.4 21534.24 34054.44 44612.4 11973.15 8266.86 1627.71 168612.99 EMC 3.90 BOD Sample 1 2 3 4 5 6 7 8 9 10 ∆t(min) 0 10 5 5 5 5 10 5 10 10 EMC 3.65 181 COD Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Q (m3/s) COD 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 128 0 14 15 1 15 0 0 0 0 Time (min) 0 10 15 20 25 30 40 45 55 65 Q (m3/s) Cu 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 0.16 0 0 0.08 0 0.05 0.13 0.11 0.13 0 ∆t (min) 0 10 5 5 5 5 10 5 10 10 Avg Q(m3/s) 0 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Avg Vol (m3) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Σ ∆t (min) 0 10 5 5 5 5 10 5 10 10 Avg Q (m3/s) 0 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Avg Vol (m3) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Σ Avg Vol (L) 0 2910 3750 5295 8160 8565 11280 3150 2430 690 46230 Avg Conc(mg/L) 0 64 7 14.5 8 8 7.5 0 0 0 Σ Mass (mg) 0 186240 26250 76777.5 65280 68520 84600 0 0 0 507667.5 EMC 10.98 Mass (mg) 0 232.8 0 211.8 326.4 214.125 1015.2 378 291.6 44.85 2714.775 EMC 0.06 Cu Sample 1 2 3 4 5 6 7 8 9 10 Avg Vol (L) Avg Conc(mg/L) 0 2910 3750 5295 8160 8565 11280 3150 2430 690 46230 0 0.08 0 0.04 0.04 0.025 0.09 0.12 0.12 0.065 Σ 182 Pb Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Q (m3/s) 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 Pb ∆t(min) 0.061 0.057 0.054 0.04 0.046 0.036 0.04 0.04 0.038 0.032 0 10 5 5 5 5 10 5 10 10 Avg Q(m3/s) 0 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Avg Vol (m3) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Σ Avg Vol (L) 0 2910 3750 5295 8160 8565 11280 3150 2430 690 46230 Avg Conc(mg/L) 0 0.059 0.0555 0.047 0.043 0.041 0.038 0.04 0.039 0.035 Σ Mass(mg) 0 171.69 208.125 248.865 350.88 351.165 428.64 126 94.77 24.15 2004.285 EMC 0.043 Zn Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Q (m3/s) 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 Zn 1.34 0.21 0.2 0.2 0.21 0.16 0.26 0.21 0.26 0.25 ∆t(min) Avg Q(m3/s) 0 10 5 5 5 5 10 5 10 10 0 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Avg Vol (m3) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Σ Avg Vol (L) 0 2910 3750 5295 8160 8565 11280 3150 2430 690 46230 Avg Conc(mg/L) 0 0.775 0.205 0.2 0.205 0.185 0.21 0.235 0.235 0.255 Σ Mass(mg) 0 2255.25 768.75 1059 1672.8 1584.525 2368.8 740.25 571.05 175.95 11196.38 EMC 0.24 183 Oil & Grease Sample Time (min) 1 0 2 10 3 15 4 20 5 25 6 30 7 40 8 45 9 55 10 65 Q (m3/s) 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 O&G ∆t(min) Q (m3/s) 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 NH3-N ∆t(min) 0 0 0 0 0 0 0 0 0 0 0 10 5 5 5 5 10 5 10 10 Avg Q(m3/s) 0 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Avg Vol (m3) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Σ Avg Vol (L) 0 2910 3750 5295 8160 8565 11280 3150 2430 690 46230 Avg Conc(mg/L) 0 0 0 0 0 0 0 0 0 0 Σ Mass(mg) 0 0 0 0 0 0 0 0 0 0 0 EMC 0.00 NH3-N Sample Time (min) 1 0 2 10 3 15 4 20 5 25 6 30 7 40 8 45 9 55 10 65 0.39 0.25 0.17 0.06 0.04 0.03 0.03 0.2 0.19 0.07 0 10 5 5 5 5 10 5 10 10 Avg Q(m3/s) 0 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Avg Vol (m3) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Σ Avg Vol (L) 0 2910 3750 5295 8160 8565 11280 3150 2430 690 46230 Avg Conc(mg/L) 0 0.32 0.21 0.115 0.05 0.035 0.03 0.115 0.195 0.13 Σ Mass(mg) 0 931.2 787.5 608.925 408 299.775 338.4 362.25 473.85 89.7 4299.6 EMC 0.09 184 NO3-N Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Q (m3/s) NO3-N ∆t(min) Avg Q(m3/s) Avg Vol (m3) 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 0.22 0.04 0.08 0.11 0.1 0.13 0.11 0.13 0.13 0.09 0 10 5 5 5 5 10 5 10 10 0 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Σ Avg Vol (L) 0 2910 3750 5295 8160 8565 11280 3150 2430 690 46230 Avg Vol (m3) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Σ Avg Vol (L) 0 2910 3750 5295 8160 8565 11280 3150 2430 690 46230 NO2-N Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Q (m3/s) NO2-N 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 0.008 0.001 0.003 0.004 0.002 0.003 0.003 0.002 0.001 0 ∆t (min) 0 10 5 5 5 5 10 5 10 10 Avg Q(m3/s) 0 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Avg Conc(mg/L) Mass(mg) 0 0.13 0.06 0.095 0.105 0.115 0.12 0.12 0.13 0.11 Σ 0 378.3 225 503.025 856.8 984.975 1353.6 378 315.9 75.9 5071.5 Avg Conc(mg/L) 0 0.0045 0.002 0.0035 0.003 0.0025 0.003 0.0025 0.0015 0.0005 Σ Mass(mg ) 0 13.095 7.5 18.5325 24.48 21.4125 33.84 7.875 3.645 0.345 130.725 EMC 0.110 EMC 0.003 185 PO4 Sample 1 2 3 4 5 6 7 8 9 10 Time (min) 0 10 15 20 25 30 40 45 55 65 Q (m3/s) PO4 0.0000 0.0097 0.0153 0.0200 0.0344 0.0227 0.0149 0.0061 0.0020 0.0003 0.58 0.22 0 0.22 0.09 1.58 0.11 0.33 1.72 0.02 ∆t (min) 0 10 5 5 5 5 10 5 10 10 Avg Q(m3/s) 0 0.00485 0.0125 0.01765 0.0272 0.02855 0.0188 0.0105 0.00405 0.00115 Avg Vol (m3) 0 2.91 3.75 5.295 8.16 8.565 11.28 3.15 2.43 0.69 Σ Avg Vol (L) 0 2910 3750 5295 8160 8565 11280 3150 2430 690 46230 Avg Conc(mg/L) 0 0.4 0.11 0.11 0.155 0.835 0.845 0.22 1.025 0.87 Σ Mass (mg) 0 1164 412.5 582.45 1264.8 7151.775 9531.6 693 2490.75 600.3 23891.18 EMC 0.52 186 APPENDIX I DESIGN CRITERIA CALCULATION 1050 1700 1700 1500 B Outflow (a) Inflow 500 2100 (b) The sizing of (a) Rubbish Trap (b) Section B 1. Determination of required removal efficiency: From Table 4.5, for condition Drainage system Upgrading, we get the reduction in Annual Average Pollutant Load from existing condition is 20% (for sediment) Therefore, the trap will be sized to trap 20% of the sediment ≥0.04mm dia. 2. Determination of catchment area, % urban area and soil type in the catchment: Catchment Area, Ac = 0.16 ha % Urban Area, U = 80% 3. Trial trap area ratio, R: Try R=2.25E-5 Soil Type = Silty Sand 187 4. Calculation of required trap area by trial and error: From Design Chart 34.A1, with R=2.25E-5, U=80%, Curve A, we get the P0.04=20% (ACCEPTABLE!) Therefore, the required minimum trap size is: At = R × Ac =2.25E-5 × (0.16×10^4) m2 =0.036 m2 5. Trap Area, At Trap area of rubbish trap = (1.70×1.05) + (1/2×1.5×1.05) + (1.5×1.7) = 5.1225 m2 5.1225 m2 > Required minimum trap size (0.036m2) Therefore, the size of the rubbish trap is OK! 6. Sediment Load, M Event M(kg) 4/8/08 0.005 7/8/08 0.011 12/8/08 7.794 4/9/08 0.180 Take the maximum M = 7.794kg = 7.794×10^-3 7. Average Annual Pollutant Retention, P0.01 From Design Chart 34.A1, with R=2.25E-5, U=80%, Curve B, we get the P0.01=14% From Design Chart 34.A2, with R=2.25E-5, (Silty Sand), we get F2=3.3 From Equation 34.4: P0.01* = P0.01 × F2 = 14% × 3.3 = 46.2% 188 8. Required minimum sediment trap depth From Equation 34.5: Dt = 0.0065×P0.01×M/At = 0.0065×46.2×7.794×10^-3 tonne/5.1225m2 = 4.57×10^-4 m 9. Peak flow, Q0.25 From Rational Method, the Q0.25 = 0.213m3/s 10. Determination of trash rack height, Hr From Equation 34.7: Hr = 1.22 (Q0.25/Lr)2/3 = 1.22 (0.213/2.1)2/3 = 0.206 m = 26.5 cm Hr of rubbish trap (50cm) > 26.5cm Therefore, the trash rack height of the rubbish trap is OK! 11. Determination of flow velocity, V0.25 Determination of the nominal flow velocity V0.25 in the water quality design storm is using Equation 34.8. Increase the dimensions of the sediment trap pool or increase the track rack height if the flow velocity V is greater than 1.0 m/s, to minimize the re-entrainment of deposited sediment. From Equation 34.8: V0.25 = Q0.25/(Dw+Hr)Wt = (0.213m3/s) / (4.57×10^-4 m + 0.5m) 1.7m = 0.25 m/s 0.25 m/s < 1.0 m/s, so no increment of Hr is needed 12. SUMMARY From the design calculation, it can be concluded that the rubbish trap size (Figure 27(a) and 27(b) is acceptable.