Y=S+B K0 – K+ 00 K– + I3 = Q + ½Y K0 The Nucleus Atoms consist of a positively charged nucleus plus electrons •Nuclear charge is Ze, where Z is an integer called the atomic number •This determines what chemical element it is -e -e •The mass/potential energy (E0=mc2) of a neutral atom has three +Ze components: -e •The mass of the nucleus -e •The mass of the electrons – there are Z of these •The binding energy of the electrons •Binding energy is tiny, so mAtom mNucleus Zme mbinding mH 938.27203 MeV/c 2 .51100 MeV/c 2 .00001 MeV/c 2 mNucleus mAtom Zme Tables of isotopes give the mass of the neutral atom in u The Mass of an atom •Not all neutral atoms of the same element have the same mass •Atoms come in different isotopes with different masses •All isotopes have masses that are approximately integer multiples of the same common unit •The atomic mass unit (u) is defined as 1/12 of 12C atom •The integer closest to M/u is called A, the mass number u 1 12 m C 931.494 MeV/c 12 2 M Au Avogadro’s number •The ratio of u to g is called Avogadro’s number •Useful for lots of problems 1g NA 6.022 1023 1u 11Li: 11.0438 u 118Sn: 117.9016 u Naming isotopes •Isotopes are described by telling their charge Z, their atomic mass number A, and the name of the chemical symbol A A X or X •The chemical symbol X tells you Z, so normally skipped Z •Sometimes an isotope has a bit of extra energy – we call it an isomer •Denoted by putting a * on it A X* •Almost always very unstable The size of the nucleus •Can be measured in various ways •My favorite: replace an electron by the 200 times heavier muon •Wave function is 200 times smaller •The wave function responds to the finite nuclear size •Radius goes crudely as A1/3 1/3 R R A 0 •Volume roughly proportional to number of nucleons R0 1.2 fm +Ze The composition of the nucleus All normal nuclei have only two types of particles in them: •The proton has charge +e 0 # Particle •There are Z of these +e +e Z Proton 0 •The neutron has charge 0 N Neutron •There are N of these Electron •Electrons are not found in the nucleus Mass 1.007276 u 1.008665 u 0.000549 u •The mass of an atom is protons + neutrons + electrons + binding •To a crude approximation, this is just the number of protons + neutrons •This is why the mass is almost an integer A Z N What is Z, N, A, and the approximate mass of 235U? A 235 M 235 u Z 92 N 235 92 143 Q +e 0 -e m Z N u Radioactivity •Many nuclei decay over time •This is a quantum mechanical process – you can’t predict when it will happen •If you have a lot of atoms, the rate at which they decay will be proportional to the number of atoms dN dN •The radioactivity destroys the atoms R N dt dt •Integrate to see how number changes N t with time N N e 0 ln N t k •N is number of atoms •N0 is initial number of atoms R R0 e t • is the decay rate •Also, multiply by •R is the rate at which atoms are decaying •R0 is the initial rate •Half-life, t1/2 is the time it takes for half the atoms to decay •Let’s find a formula for it 1 2 N 0 N 0e t 1/2 e t1/2 2 t1/2 ln 2 Sample problem 134Cs has a half-life of 2.065 y. •What is the decay rate ? •If we start with 1.000 g, what is the initial decay rate? N 0 •How long must we wait until the decay rate is less than 1.000 Ci = 3.700 104 s-1? ln 2 0.692 0.3357 y1 t1/2 2.065 y 6 23 6 10 6.022 10 M 1.000 10 g m 133.9067 u 133.9067 4.497 1015 1 R0 N0 0.3357 y 1 4.496 1015 1.509 10 7 y 4.784 107 s 1 3.166 10 s/y 7 1 R0 4.784 10 s t t 1293 e R R0 e 4 1 R 3.700 10 s 7.164 7.164 t ln 1292 7.164 t t 21.34 y 1 0.3357 y 15 Particles and anti-particles •Several particles are important for understanding nuclear processes •Protons, neutrons, and electrons have already been discussed •The photon is a particle of light •The neutrino is a massless (or nearly massless) neutral particle Anti-Particles p+ n0 e- e+ Particle Proton Neutron Electron Photon Neutrino anti-Elec. anti-Neut. Mass (MeV) 1.007276 u 1.008665 u 0.000549 u 0.000000 u 0.000000 u 0.000549 u 0.000000 u •For every particle, there is an anti-particle •Same mass, opposite charge •Some particles (the photon) are their own anti-particles •For nuclear physics, the important ones are the anti-electron and anti-neutrino Sym. p+ n0 e e+ Neutron decay and anti-particles Particle processes are a lot like equations •You can turn them around and they still work •You can move particles to the other side by “subtracting them” •This means replacing them with anti-particles •(However, you have to make sure energy works) •The neutron (in isolation) is an unstable particle •Decays to proton + electron + anti-neutrino •This occurs in – decay n0 p+ •Turn the reaction around •Put the neutrino on the other side •This occurs in electron capture •Put the electron on the other side •This occurs in + decay p+ p+ p+ + + e- + + + + en0 e- n0 n0 + + e+ Calculating Energetics in a decay Nuclear decay is when an isolated nucleus spontaneously breaks apart •Typically (not always), there is one Parent nucleus and one Daughter nucleus •Also, typically, some other particles too P D + ? We want to know how much energy is released •The potential energy of each component is just mc2 •The difference between these values is Q – the energy available •Unfortunately, we aren’t given the nuclear masses, just the atomic QM c M nuc 2 P c m?c nuc 2 D 2 M Nuc M Atom Zme Q M PAtom Z P me c 2 M DAtom Z D me c 2 m?c 2 Q M P M D c2 Z D Z P mec 2 m?c 2 This formula is just a bridge to the formulas we really want •This energy generally appears as kinetic energy, mostly of the lighter products on the right (the ? particles) Nuclear Decay Processes •There are many types of decay processes, we will focus on only the most common •Our goal is to figure out how to calculate, for those we consider: •The daughter isotope (Z,A) P D + ? •The energy Q produced •Whether the process actually occurs •Processes can occur if Q > 0 •We won’t worry about •How slowly it goes (some virtually never occur) (higher Q helps) •Which are more likely than others (higher Q helps) •– decay •Electron capture •+ decay •Spontaneous fission • decay • decay decay – n0 p+ + •– is another name for the electron and + for the positron •A neutron inside a nucleus can decay to a proton •Example: 3H 3He + p n0 +0 p ne •The daughter nucleus: •Total number of nucleons unchanged •Charge increases by 1 •(Z,A) (Z+1,A) •The change in energy (Q): Q M P M D c Z D Z P mec mec m c 2 2 M P M D c 1 mec mec 0 2 2 Q MP MD c 2 2 2 2 e- + Electron capture p+ + e- •A proton in the nucleus captures one of the electrons in the atom •Example: 7Be 7Li e•The daughter nucleus: •Total number of nucleons unchanged •Charge decreases by 1 •(Z,A) (Z-1,A) •The change in energy (Q): Q M P M D c2 Z D Z P mec 2 mec 2 m c 2 M P M D c2 1 mec2 mec2 0 Q M P M D c2 n0 + p+ 0 n + 0 p n + + p 0p n n0 decay + p+ •A proton in the nucleus decays to a neutron •Example: 11C 11Be •The daughter nucleus: •Total number of nucleons unchanged •Charge decreases by 1 •(Z,A) (Z-1,A) •The change in energy (Q): Q M P M D c2 Z D Z P mec 2 mec 2 m c 2 M P M D c2 1 mec2 mec 2 0 Q M P M D c2 2mec2 n0 + + p0+n0p+0 n p ne+0 +n + + p 0 0p n p+n e+ Sample problem What would be the resulting isotope and the Q-value for each of the following decays of 40K? (a) - decay (b) electron capture (c) + decay - decay: (Z,A) (Z+1,A) •Daughter is 40Ca u 931.494 MeV/c 2 2me c 2 1.022 MeV Q M P M D c2 39.964000 39.962591 uc2 .001409 931.5 MeV 1.312 MeV Z el. A 18 Ar 36 37 38 39 40 42 19 K 39 40 41 42 43 20 Ca 40 41 42 43 44 46 48 mass (u) 35.967547 36.966776 37.965903 38.964314 39.962384 41.963049 38.963708 39.964000 40.961827 41.962404 42.960716 39.962591 40.962279 41.958618 42.858767 43.955481 45.953687 47.952534 Sample problem What would be the resulting isotope and the Q-value for each of the following decays of 40K? (a) - decay (b) electron capture (c) + decay Electron capture: (Z,A) (Z-1,A) •Daughter is 40Ar Q MP MD c 2 u 931.494 MeV/c 2 2me c 2 1.022 MeV 39.964000 39.962384 uc2 .001616 931.5 MeV 1.505 MeV + decay: (Z,A) (Z-1,A) •Daughter is 40Ar Q M P M D c2 2mec2 1.505 1.022 MeV 0.483 MeV Z el. A 18 Ar 36 37 38 39 40 42 19 K 39 40 41 42 43 20 Ca 40 41 42 43 44 46 48 mass (u) 35.967547 36.966776 37.965903 38.964314 39.962384 41.963049 38.963708 39.964000 40.961827 41.962404 42.960716 39.962591 40.962279 41.958618 42.858767 43.955481 45.953687 47.952534 Spontaneous Fission •A large nucleus has a lot of electrostatic repulsion •It would like to separate, but strong forces hold it together •More on this later •It is possible, but rare for it to break apart into two (or more) pieces •Commonly, neutrons are emitted as well. D2 P 0 n D n0 1 •A quantum tunneling process •Very rare when large chunks are involved •No naturally occurring elements •We need a small, very stable chunk to make this work better •The particle is such a chunk Decay •The particle is the nucleus of Helium – it is very stable •Two protons and two neutrons •Because it is light, it has a good chance of tunneling out •The daughter nucleus: •Nucleons decrease by four •Charge decreases by two •(Z,A) (Z–2,A–4 ) •The change in energy (Q): 0 n p+ 0p+ D P n Q M P M D c2 Z D Z P mec2 m c2 M P M D c2 2mec 2 m c 2 •m + 2me is just the mass of a helium atom Q M P M D M 4 He c2 0 n p+ 0p+ n Decay •Sometimes, nuclei have internal energy •Like an atom in an excited state •Like an atom, the energy comes out in the form of a photon •The daughter nucleus: •No change in nucleons •(Z,A)* (Z,A ) D P •The change in energy (Q): Q M P M D c2 m c2 Q M P M D c2 How did we get an excited nucleus in the first place? •Usually a byproduct of a previous nuclear decay 60 To us, this just looks like it Co 60 Ni** e came from the Cobalt 60 ** 60 * Ni Ni 1.17 MeV 60 Ni* 60 Ni 1.33 MeV Summary Decay Z +2 – +1 e.c. –1 + –1 0 A +4 0 0 0 0 Formula for Q (MP – MD – M4He)c2 (MP – MD)c2 (MP – MD)c2 (MP – MD)c2 – 2 mec2 (MP – MD)c2 Radiation Hazards All of these processes (except electron capture) produce high-energy ionizing radiation that can be extremely damaging to you • particles are easily stopped, by paper or dead skin, if they are outside your body • radiation can penetrate more deeply, so they are more dangerous • radiation is very penetrating, and hence is most dangerous