vii TABLE OF CONTENTS CHAPTER 1 2 TITLE PAGE DECLARATION ii ACKNOWLEDGEMENT iv ABSTRACT v LIST OF CONTENTS vii LIST OF TABLES x LIST OF FIGURES xii LIST OF SYMBOLS xvi INTRODUCTION 1.1 Literature Review 1 1.2 Q-Switching Laser 2 1.3 Passive Q-Switching 5 1.4 Research Objective 6 1.5 Research Scope 6 1.6 Thesis Outline 7 THEORY 2.1 Introduction 9 2.2 Pulsed Dye Laser 9 2.2.1 Active Medium 10 2.2.2 Wavelength Selection in Pulsed Dye Lasers 10 2.2.3 Excitation Method 11 viii 2.3 2.4 2.5 3 2.3.1 15 Pumping Mechanism of Q-Switching Q-Switching Methods 16 2.4.1 Mechanical Q-Switches 17 2.4.2 Electro-Optic Q-Switches 17 2.4.3 Acousto-Optic Q-Switches 18 Passive Q-Switches 19 2.5.1 20 Mechanism Of Bleaching 3.1 Introduction 24 3.2 Sample Preparation 25 3.2.1 Organic Dyes 25 3.2.2 Cr4+: YAG Crystal 26 3.4 Dye Laser 26 3.3.1 Pulse Detection 28 3.3.2 Mode of Triggering 29 Image Processing System 31 3.4.1 31 Processing Software 3.5 Calibration of Optimum Laser Performance 33 3.6 Experimental Setup 34 DYE LASER 4.1 Introduction 36 4.2 Externally Triggrering Dye Laser 37 4.3 Diagnose The High Performances of Dye Laser 40 4.3.1 Wavelength 40 4.3.2 Cavity Length 44 4.4 5 14 METHODOLOGY AND MATERIAL 3.3 4 Q-Switching Summary 50 PASSIVELY Q-SWITCHED DYE LASER 5.1 Introduction 51 5.2 Passive Q-Switch With Different Saturable Absorber 52 ix 5.2.1 Organic Dyes Saturable Absorber 52 5.2.1.1 DODCI 53 5.2.1.2 DQOCI 60 5.2.1.3 Cryptocyannine 65 5.2.1.4 Comparison of Organic Dyes 70 Saturable Absorber 5.2.2 5.3 6 Summary 75 76 DIAGNOSE OF PASSIVE Q-SWITCH LASER BEAMS 6.1 Introduction 78 6.2 Analyzing The Beam 79 6.2.1 Gaussian Fit Analysis 79 6.2.2 Beam Spot 86 6.3 7 Cr4+: YAG Crystal Saturable Absorber Summary 89 CONCLUSIONS AND SUGGESTION 7.1 Conclusions 90 7.2 Problems And Suggestion 93 REFERENCES 95 APPENDIX 1 100 x LIST OF TABLES TABLE NO. 4.1 TITLE Power depending on wavelength of dye laser with PAGE 41 Coumarin 500 as a lasing medium 4.2 Power depending on wavelength of dye laser with Rhodamine 590 as a lasing medium 41 4.3 Pulse duration of dye laser with Coumarin 500 as lasing medium produced at different cavity length 45 4.4 Pulse duration of dye laser with Rhodamine as lasing medium produced at different cavity length 45 4.5 Pulse Energy of dye laser with Coumarin 500 as lasing 47 medium produced at different cavity length 4.6 Pulse Energy of dye laser with Rhodamine 590 as lasing medium produced at different cavity length 47 5.1 Pulse duration of passive Q-switch laser upon concentration of DODCI 53 5.2 Pulse energy of passive Q-switch laser upon concentration of DODCI 55 5.3 Peak Power of passive Q-switch laser upon concentration of 58 DODCI. xi 5.4 Pulse duration of passive Q-switch laser upon concentration of DQOCI. 61 5.5 Pulse energy of passive Q-switch laser upon concentration of DQOCI 63 5.6 Peak power of passive Q-switch laser upon concentration of DQOCI 64 5.7 Pulse duration of passive Q-switch laser upon concentration 66 of Cryptocyannine. 5.8 Pulse energy of passive Q-switch laser upon concentration of Cryptocyannine 67 5.9 Peak power of passive Q-switch laser upon concentration of DQOCI 69 5.10 Pulse duration, pulse energy and peak power for different position of saturable absorber 75 6.1 Gaussian width in horizontal and vertical profiles for 83 DQOCI saturable absorber due to working distance. 6.2 Gaussian width in horizontal and vertical profiles for Cr4+: YAG saturable absorber due to working distance. 83 6.3 Beam spot perimeter and area due to working distance for passively Q-switched dye laser with Coumarin 500 as a lasing medium 87 6.4 Beam spot perimeter and area due to working distance for passively Q-switched dye laser with Rhodamine 590 as a lasing medium 88 xii LIST OF FIGURES FIGURE NO. TITLE PAGE 2.1 Energy level diagram of a dye laser 2.2 Absorption and fluorescence emission spectrum of a typical organic molecule 13 2.3 Mechanism for dye laser action 2.4 Development of a Q-switched laser pulse. (a). The pumping source output, (b). Cavity loss, (c).Population inversion, and (d). Q-switch output. 2.5 Mechanical Q-switch (rotating chopper). 2.6 Electro-optic Q-switch 2.7 Acousto-optic Q-switch. 2.8 Saturable absorber Q-Switch 2.9 Absorption as a function of incident light intensities for a saturable absorber 12 14 16 17 18 19 20 21 xiii 2.10 Energy-level diagram for most saturable absorber dye molecules in solution 21 2.11 Schematic illustration of the three processes, absorption, spontaneous emission and stimulated emission. 22 3.1 Schematic dimension of Cr4+: YAG crystal 26 3.2 LN120C top view 27 Dye module Optical Layout 27 3.4 BPX 65 Photo detector Circuit 29 3.5 Block diagram of trigger unit 30 3.6 Experimental set-up for measuring the delay time of the dye 30 laser 3.7 CCD Profiler Window 31 3.8 Calibration screen option for Video Test 5.0 Software 32 3.9 Dye laser alignment set-up for calibration 34 3.10 Laser cavity of passively Q-switched dye laser 34 3.11 Schematic diagram of experimental set up for passively QSwitched dye laser 35 4.1 Pulse of input voltage from trigger unit 37 4.2 (a). Channel 1: Pulse from trigger unit. 38 3.3 (b). Channel 2: Pulse from BPX 65 photo detector 4.3(a) Pulse shape of the dye laser with Coumarin 500 as a lasing medium. 39 4.3(b) Pulse shape of the dye laser with Rhodamine 590 as a lasing medium 39 xiv 4.4 Accumulated power of dye laser with Coumarin 500 upon on wavelengths 42 4.5 Accumulated power of dye laser with Rhodamine 590 upon on wavelength 43 4.6 The pulse duration and output power versus cavity length of 46 passively Q-switched Rhodamine 590 dye laser. 4.7 The output energy of dye laser upon cavity length with different lasing medium 4.8 The pulse duration and output power versus cavity length of 49 passively Q-switched Rhodamine 590 dye laser. 5.1 Pulse Duration versus concentration of DODCI on different lasing medium 54 5.2 Pulse Energy versus concentration of DODCI on different lasing medium 55 5.3 Graph natural logarithm of pulse energy versus concentration 57 5.4 Peak Power versus concentration of DODCI on different lasing medium 59 5.5 Graph natural logarithm of peak power versus concentration 60 5.6 Pulse Duration versus concentration of DQOCI on different lasing medium 61 5.7 Graph natural logarithm of pulse duration versus concentration 62 5.8 Pulse Energy versus concentration of DQOCI on different lasing medium 63 5.9 Peak Power versus concentration of DQOCI on different lasing medium 65 5.10 Pulse Duration versus concentration of Cryptocyannine on different lasing medium 66 48 xv 5.11 Pulse Energy versus concentration of Cryptocyannine on different lasing medium 68 5.12 Peak Power versus concentration of Cryptocyannine on different lasing medium 69 5.13(a) Figure 5.13(a): Pulse duration versus concentration of different saturable absorber materials 70 5.13(b) Pulse duration versus concentration of different saturable absorber materials 71 5.14(a) Pulse energy versus concentration of different saturable absorber materials 72 5.14(b) Pulse energy versus concentration of different saturable absorber materials 73 5.15(a) Peak power versus concentration of different saturable absorber materials 74 5.15(b) Peak power versus concentration of different saturable absorber materials 74 6.1 Gaussian profile of passive Q-switch laser beam. (a) Vertical profile, (b). Horizontal profile 80 6.2 Beam Profile of Q-switching laser; (a). Three-dimensional image shows the distribution of Gaussian beam profile (b). Two-dimensional image. 81 6.3 Correlation upon working distances for DQOCI saturable absorber. 85 6.4 Correlation upon working distances for Cr4+: YAG saturable absorber. 85 6.5 Two-dimensional image of passively Q-switched dye laser using DQOCI upon different working distance 86 6.6 Two-dimensional image of passively Q-switched dye laser using Cr4+: YAG crystal upon different working distance 87 6.7 Beam spot area against working distance 88 xvi LIST OF SYMBOLS Q - Quality factor F - Photon flux of the incident light σ12 - Absorption cross section W12 - Absorption probability σ 21 - Stimulated emission cross section m - Grating order λ - Wavelength d - Grating constant θ - Angle between the grating and the laser gain axis I - The intensity of a pixel at location x i(h, v) - The intensity at location (h, v) V - The maximum intensity of the fitted Gaussian curve (Peak Intensity) C - The centre of the Gaussian fit peak (Centroid) σ - The radius of the Gaussian fit curve at the 1/e2 intensity level (diameter)