VIBRATION-DRIVEN MEMS ENERGY HARVESTER WITH VERTICAL ELECTRETS K. Yamashita1,2*, M. Honzumi1,2, K. Hagiwara1,3, Y. Iguchi3, and Y. Suzuki1,2 1 Dept. of Mechanical Engineering, The University of Tokyo, 2 G Device Center, BEANS Project, and 3 NHK Science & Technology Research Laboratories *Presenting Author: yamasita@mesl.t.u-tokyo.ac.jp Abstract: A MEMS electret generator with vertical electrets has been developed with the aid of novel soft X-ray charging. Fluorinated parylene deposited on the comb drive is employed as the electret. The resonance frequency and the quality factor of the present early prototype are respectively 6.1 kHz and 10.2. Under external oscillation at the resonant frequency and 15 G, 0.4 Vp-p output has been obtained, which corresponds to 2 nW. Keywords: Energy harvesting, Vertical electrets, Comb drive, Soft X-ray charging, diX-F INTRODUCTION Electret is a dielectric material with quasipermanent charges. Recently, electrets are applied to various micro devices including MEMS microphone [1], low-voltage droplet manipulation [2], and vibration-driven energy harvester [3-7]. However, since corona discharge is usually employed for poling the electrets, assembling is necessary after charging. Recently, we have developed a new charging method using soft X-ray irradiation [8], and found that surface potential and thermal stability of electrets charged with the soft X-ray are as good as those with corona discharge [9]. Since soft X-rays can penetrate into narrow gaps and generate ions by photoionization, vertical electrets on the sidewall of high-aspect-ratio trenches such as MEMS comb fingers can be realized [10], which enables fabrication of electret energy harvesters with a single wafer approach. In the present study, we design a comb-drive energy harvester with vertical electrets, and examine its performance using our early prototype. electrets. Figure 2 shows surface potential of vertical electrets charged through narrow gaps versus the distance from the opening. 2-µm-thick parylene-C is deposited on one side of copper substrates. Soft X-ray tube of 9.5 keV is used for irradiation. The bias voltage and the irradiation time are respectively chosen as 100 V and 10 minutes. The surface potential is measured with an electrostatic voltmeter (Monroe Electronics, model 244A). The surface potential is almost constant up to the distance 20 30 times of the gap opening. Therefore, almost uniform surface charge distribution on vertical electrets should be available up to the depth of 100 µm for gap opening of a few µm. VERTICAL ELECTRETS CHARGED WITH SOFT X-RAYS Corona discharge is a conventional charging method for electrets, in which colona ions emitted from a high-voltage needle transfer their charges onto the electret film when they arrive at the surface. Since corona ions cannot penetrate narrow gaps due to charge build-up near the opening, electret films should be exposed during charging. Therefore, with electrets, one could not employ single-wafer approaches such as comb-drive capacitive generators [11, 12]. Recently, we have developed a new electret charging method using soft X-rays [8, 9], and successfully microfabricated vertical electrets. As shown in Fig. 1, with soft X-rays irradiation, positive and negative ions equally generated in the air gap. The ions are driven toward the sidewall with the electric field across the gap, transferring the charges to the Figure 1: In-situ charging method for vertical electrets using soft X-ray irradiation. Figure 2: Soft X-ray charging tests in narrow gaps. 2µm-thick parylene-C is used as the electret film. into the 50-µm-thick device layer with DRIE (Fig. 4b). The handle layer is etched from the backside with DRIE to release the structure and to avoid stiction of the proof mass during parylene deposition (Fig. 4cd). Figure 3: Time history of the surface potential for 1.7mm-thick fluorinated parylene electrets (diX-F, KISCO). Data for different charging temperatures are plotted. For electret materials on vertical walls, we employ parylene, since electret films with uniform thickness can be deposited after fabrication of the structure. Lo and Tai [5] found that perfluoro parylene (parylene HT, SCS) has very high surface charge density. In this study, we evaluated fluorinated parylene (diX-F, KISCO), in which two out of four hydrogen atoms of parylene-N are replaced with fluorine as shown in the inset of Fig. 3. Figure 3 shows the surface charge density of 1.7-µm-thick diX-F films charged with corona discharge. The surface charge density is 1.4 mC/m2, which is much lower than that of parylene HT with no hydrogen atoms. However, the surface potential of about 100 V is reasonably high for initial tests using our early prototype. Note that the surface potential with charging temperature of 90 C° is higher than the other cases. DESIGN OF HARVESTER ELECTRET Figure 4: Fabrication process of the comb-drive MEMS electret energy harvester prototype. a) b) ENERGY To demonstrate the performance of vertical electrets, an electret energy harvester prototype with comb drives was designed. An SOI wafer with a 50µm-thick device layer was used. The length of suspension beam is 400 µm with a cross section of 50 µm x 6 µm. The comb length and width are respectively 30 µm and 5 µm, while the initial gap between facing combs is 5 µm. After deposition of 1.5µm-thick diX-F electrets, the gap becomes 3 µm. The proof mass is 3.2 mm x 2.1 mm. Designed values of the resonant frequency and the capacitance of the comb drives are 2 kHz and 2.6 pF, respectively. A numerical model based on one-dimensional electrostatic field [13] is employed to design parameters. c) MEMS FABRICATION Fabrication process of the comb-drive electret generator is shown in Fig. 4. Process starts with EB lithography on a 4” SOI wafer using thick EB resist (Fig. 4a). Springs and comb fingers are then etched Figure 5: SEM images of the comb-drive MEMS energy harvester prototype with vertical electrets. a) Overview, b) Close-up view of spring suspension, c) Close-up view of comb fingers with diX-F electrets. Fig. 6: Photograph of the electret generator fixed on a PC board for wire connection. Figure 8 shows the output voltage. Radio noise below 100 Hz is removed with a high-pass Fourier numerical filter. Output voltage of 0.4 Vp-p has been obtained, which corresponds to 2 nW power output. Figure 9 shows the output voltage amplitude versus external vibration amplitude. The output voltage is almost linearly increased with the vibration amplitude. Surface potential estimated by the curve fitting is 95 V, showing that diX-F verticacl electrets work properly. Figure 10 shows simulation results of the output power versus external load at the resonant frequency. The power output is maximized at a 34 MΩ external load, and the maximum power is 0.17 µW at 10G. After the SiO2 layer is released with vapor HF (Fig. 4e), 1.5-µm-thick diX-F film is deposited by CVD on the whole structure forming electret films on both sides of the comb fingers (Fig. 4f). The device is fixed on a PC board and wired for experiments. Figure 5 shows SEM images of the fabricated device with a proof mass supported with the 6-µmwide Si beams. Figure 5c shows the close-up view of the comb fingers with diX-F electrets. The device fixed on a PC board is shown in Fig. 6. EXPERIMENTAL RESULTS Soft X-ray of 9.5 keV is used to charge diX-F electret with the bias voltage of 150 V for 45 minutes. The device is then fixed onto an electromagnetic shaker (ET-126B-1, Labworks), and in-plane oscillation is applied to the device. The amplitude is measured with a laser displacement meter (LC-2430, Keyence). The resonant frequency is measured with a vibration analyzer (Polytec, MSA-500). As shown in Fig. 7, the resonance frequency is 6.1 kHz, which is much higher than our designed value of 2 kHz. The Qfactor is 10.2. For some limitation of our experimental set-up, experiments were made at 500 Hz, which is much lower than the resonant frequency. A 10MΩ resister is used as the external load. Figure 8: Output voltage across a 10 MΩ load resistor at 500 Hz and 15 G acceleration. Figure 9: Output voltage versus amplitude of external vibration at the resonant frequency of 6.1 kHz. Figure 7: Frequency response of the MEMS electret generator prototype. Figure 10: Simulated output power versus external load at the resonant frequency 6.1 kHz. [3] [4] [5] Figure 11: Simulated output power versus external acceleration at the resonance frequency of 6.1 kHz. Simulated output power at the resonance frequency versus external acceleration for the mamtched impedance of 34 MΩ is shown in Fig. 11. The output power is estimated to be 0.67 µW at 20 G, where the estmates of the amplitude and the capacitance change are respectively 1.4 µm and 0.17 pF. Although the power output of the present early prototype is small even at high frequency oscillations, the present approach of using vertical electrets can be easily applied to capacitive generators with comb drives and make contribution to development of cost-effective efficient capacitive energy harvesters. [6] [7] [8] [9] CONCLUSIONS Early prototype of MEMS electret energy harvester with vertical electrets on comb drive has been designed and successfully microfabricated. The resonant frequency and the quality factor of the present prototype device are respectively 6.1 kHz and 10.2. 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