FABRICATION AND EVALUATION OF NDFEB MICROSTRUCTURES FOR ELECTROMAGNETIC ENERGY HARVESTING DEVICES Yonggang Jiang1, Takayuki Fujita1,2, Minoru Uehara3, Kensuke Kanda1, Tomohiko Toyonaga2, Keisuke Nakade2, Kohei Higuchi1 and Kazusuke Maenaka1,2 1 Maenaka Human-sensing Fusion Project, Japan Science and Technology Agency, Japan 2 Gradulate School of Engineering, University of Hyogo, Japan 3 Magnetic Materials Research Laboratory, NEOMAX Co., Ltd., Osaka, Japan Abstract: A novel electromagnetic energy harvester is proposed using micro-fabricated NdFeB permanent magnet. The simulation results show that the miniaturization of NdFeB structures can achieve a magnetic field gradient as high as 3000 T/m at 16 μm away from the micro-magnetic array. The generated power is then calculated using the results of the magnetic field distribution, the geometry of coils, and the vibration conditions. NdFeB microstructures as thick as 12 μm are successfully fabricated using magnetron sputtering and silicon molding technologies. Magnetic force microscopy (MFM) method is used to characterize the magnetic field generated by the NdFeB microstructures. Keywords: energy harvesting, magnetic array, sputtered magnetic film, MFM. INTRODUCTION there are two challenges to be faced. The first challenge is to preparation of thick magnetic films with high uniformity in thickness and magnetic property over relatively large surface areas. According to the work of one of our authors, NdFeB films deposited by magnetron sputtering have shown magnetic properties that can catch up with that of commercial sintered NdFeB magnets [7]. NdFeB films as thick as 20 μm are achievable with a deposition rate of 90 nm/min. The second challenge is the structuring of the films at micro-scale size. Both wet chemical etching and reactive ion etching (RIE) methods have been used to fabricate magnetic microstructures [8, 9]. However, fine patterning cannot be achieved by wet etching method due to the large under-etch effect. It is also very difficult to fabricate thick NdFeB microstructures by RIE due to its relatively low etching rate and selectivity to mask materials. In our work, in order to develop an electromagnetic energy harvester as shown in Fig. 1, a silicon molding technique is used to fabricate high aspect ratio NdFeB magnetic microstructures. The details of fabrication and characterization results will be described in the following sections. Over the past decades, the electronic devices and wireless sensors have shrunk in size and energy consumption to unprecedented levels. Vibrationdriven energy harvesters become very attractive as the power source to take the place of the micro-batteries in the field of wireless sensor network and heath monitoring system [1]. The transduction mechanisms varying from electromagnetic, electrostatic, piezoelectric have been demonstrated for vibrationdriven energy harvesters [2-4]. Electromagnetic energy harvesters are widely studied due to the established theories and progress in integration of permanent magnets with MEMS devices. In addition, electromagnetic devices usually have a long lifetime, while the piezoelectric and electrostatic devices suffer from degradation in piezoelectric properties and charge leakage effect, respectively. The technological difficulty encountered at smaller size is to achieve high magnetic flux gradients [5]. High magnetic flux gradients can be generated by microfabricated magnetic arrays with narrow spacing and high magnetic flux density. The technological difficulty becomes fabricating magnetic microstructures with excellent magnetic properties. Nano-patterning techniques for magnetic materials have been widely used in the field of highdensity magnetic recording media, magnetic quantum devices, and micro-magnetic sensors [6]. For the applications such as electromagnetic actuators and energy harvesters, micro-scale patterning of magnetic films as thick as tens of microns is required to generate sufficient force or power. To achieve this, 0-9743611-5-1/PMEMS2009/$20©2009TRF DEVICE MODELLING As shown in Fig. 1, the electromagnetic energy harvester comprises of a bi-drectional micro-magnetic array and serially connected microcoils. The electrical power is generated due to the relative motion between the magnetic array and microcoils. The voltage output can be increased by connecting the microcoils in series. 582 PowerMEMS 2009, Washington DC, USA, December 1-4, 2009 By assuming that the vibrating acceleration is 1 G, the averaging frequency of the vibration source is 10 Hz, the vibration amplitude of the device is 1mm, the total coil area is 0.5 cm2 with a turn number of 3, the and the impedance of the load is equal to that of the microcoils, the calculated power output as a function of distance between the microcoil layer and the magnet layer is plotted in Fig. 3. The power output can be greatly improved by decreasing the distance between the microcoil layer and the magnetic layer, and increasing the vibration amplitude in x direction. As a result, the moving part of the device should be designed with a low spring constant in x direction to increase the vibration amplitude and a high spring constant in the thickness direction to avoid collision between the magnetic layer and microcoils. (a) (b) Figure 1. Schematic structure of the electromagnetic energy harvester (a) and crosssectional view of the device (b). The electrical power is generated due to the relative motion between the magnetic array and the serially connected microcoils. Using the measured J-H characteristics of NdFeB thin films [7], magnetic field distribution is simulated as shown in Fig. 2. Assuming the thickness of magnetic microstructures is 12 μm and the width is 40 μm, magnetic flux density as high as 0.12 T is achieved at 16 μm above the magnet surface. The average magnetic flux gradient in the direction parallel to the surface of the magnetic layer (x direction) is correspondingly as high as 3000 T/m. Figure 3. Generated power as a function of the distance between the microcoil layer and the magnet layer, by assuming the acceleration a=1G, the average frequency of vibration sources f=10Hz, the total coil area S=0.5 cm2 with a number of turns N=3, and the load resistance is equal to the coil resistance. FABRICATION ARRAY OF MICRO-MAGNETIC The fabrication process for the bi-directional micro-magnetic array is shown in Fig. 4. The starting material is a silicon substrate with a thickness of 525 μm (Fig. 4(a)). Photolithography and deep reactive ion etching (RIE) are utilized to fabricate the silicon mold with a depth of 12 μm (Fig. 4(b)). Magnetron sputtering is used to deposit the NdFeB-Ta mutilayers (Fig.4(c)). The top Tantalum layer is used to protect the NdFeB layer from oxidation. The NdFeB microstructures are formed by a polishing process (Fig. 4(d)). Deep RIE is done again to form the silicon mold (Fig. 4(e)). Chromium and gold is deposited by plasma sputtering as the seed layer for the following Figure 2. Magnetic flux density generated by the bi-directional magentic array variation with the distance (d) from the magnet surface. 583 electroplating process. The NdFeB magnetic array is magnetized at a high magnetic field. Nickel is electroplated to fill the silicon trenches (Fig. 4(f)). The final structure of the bi-directional magnetic array is formed after a final polishing process (Fig. 4(g)). The magnetic direction of the Ni microstructures is inversely to that of the NdFeB microstructures due to a natural magnetization effect at the presence of the magnetic field generated by the NdFeB microstructures. Figure 5 illustrates a cross-sectional scanning electron microscope (SEM) micrograph of silicon trenches which are seamlessly filled by Ta-NdFeB multi-layers with a thickness of 12 μm. Figure 6(a) is the cross-sectional SEM micrograph of NdFeB magnetic array after the polishing process is finished. Figure 6(b) is the top view micrograph of the polished magnetic array measured by a confocal microscope. The NdFeB magnetic array is successfully fabricated using the silicon molding technique. The next step is to magnetize the NdFeB microstructures and fabricate the Ni magnetic structures using the silicon molding process and electroplating technique. Figure 5. SEM image of silicon molded NdFeB microstructure. Figure 6. Cross-sectional SEM micrograph of the polished NdFeB magnetic layer (a), and micrograph of its top surface measured by a confocal microscope (b). CHARACTERIZATION AND DISCUSSION After magnetizing the NdFeB microstructures, magnetic force microscopy (MFM) is used to characterize the magnetic field distribution generated by the NdFeB magnetic array. MFM is carried out using an atomic force microscope (AFM) and an AFM probe with a magnetic tip (MFMR-10; Toyo Corporation, Japan). Figure 7(a) illustrates the atomic force microscope image of the surface of the magnetic array, and Fig. 7(b) shows the MFM image, which indicates the magnetic field distribution at 1μm above the NdFeB magnetic surface. The magnetic field line Figure 4. SEM image of silicon molded NdFeB microstructure. 584 of the NdFeB microstructure is narrower than its corresponding topography line, which is probably due to the oxidation of the edges of the magnetic microstucture. After the polishing process shown in Fig 4(d), a tantalum layer should be deposited again to protect magnetic microstructures from oxidation. (a) REFERENCES [1] Roundy S, Wright P K and Rabaey J M 2003 Energy Scavenging for Wireless Sensor Networks (Boston, MA: Kluwer) [2] Beeby S P, Torah R N, Tudor M J, GlynneJones P, O’Donnell T, Saha C R and Roy S 2007 A micro electromagnetic generator for vibration energy harvesting J. Micromech. Microeng. 17 1257–1265 [3] Tsutsumino T, Suzuki Y, Kasagi N and Sakane Y 2006 Seismic power generator using highperformance polymer electret Proc. Int. Conf. MEMS’06, (Istanbul, Jun. 2006) 98–101 [4] Renaud M, Sterken T, Fiorini P, Puers R, Baert K and Hoof C 2005 Scavenging energy from Human body: design of a piezoelectric transducer Proc. 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Magn. 41 3838–3843 [8] Kishioka S, Aogaki R and Nakagawa J 1999 Comparison of Nd-Fe-B surface treated by chemical etching in the absence and presence of a magnetic field Chemistry Letters 589–590 [9] Walther A, marcoux C, Desloges B, Grechishkin R, Givord D and Dempsey N M 2009 Micro-patterning of NdFeB and SmCo magnetic films for integration into microelectro-mechanical-systems J. Magn. Magn. Mater. 321 590–594 (b) Figure 7. AFM image of NdFeB microstructures (a), and magnetic field distribution at 1μm above the surface of NdFeB microstructures measured by magnetic force microscopy (b). CONCLUSION NdFeB magnetic microstructure was fabricated using silicon molding techniques. The magnetic field distribution was measured using a magnetic force microscope. By combining with a Ni electroplating technique, a bi-directional magnetic array can be realized for electromagnetic energy harvesting application. The bi-directional magnetic array can generate high magnetic flux gradient according to our simulation, and will greatly improve the performance of electromagnetic energy harvesting devices. ACKNOWLEDGEMENT The author appreciates the discussions and help in device fabrication from Mr. Iga and Mr. Hashimoto from University of Hyogo. 585