CHAPTER REVIEW 6 The following icons indicate the Achievement Chart category addressed by each question. What Do you Remember? 1. Zinc oxide, ZnO, is an active ingredient in some sunscreens. Zinc oxide can be made by heating zinc sulfide strongly in air: 2 ZnS(s) + 3 O2(g) → 2 ZnO(s) + 2 SO2(g) the coefficient for zinc sulfide the number of sulfur atoms in sulfur dioxide the coefficient for oxygen (the element) the number of different reactants the total number of reactant molecules the states of matter present in this reaction (6.1) K/U 2. The combustion of hydrocarbons sometimes producesayellowflameandasootyresidue.(6.9) K/U (a) Describe the conditions when this might occur. (b) Name this type of combustion. What Do you Understand? 3. Consider the six types of reactions discussed in this chapter. All involve elements and compounds. Identify the type(s) of reaction that has the following reactants: (a) two elements (b) two compounds (c) oxygen and afuel (d) only one compound (e) an element and a compound(6.5–6.10) K/U K/U 5. Hydrogenperoxideisaclear,colourlessliquid used to disinfect cuts. The chemical equation for the decomposition of hydrogen peroxide is K/U T/I (a) Explain the difference between the state symbols (aq) and (l). (b) Predict what you would expect to see in a test tube of hydrogen peroxide undergoing this reaction. (c) Describe how to tell when the reaction is complete. (d) Predict how the mass might change as the reaction proceeds. Explain. 258 Chapter 6 • Chemicals and Their Reactions Knowledge/Understanding Communication Thinking/Investigation Application T/I A 6. People can choose to have the underside of their vehicle sprayed with oil once a year. How does a coating of oil help prevent rusting? (6.10) K/U A 7. Balance and classify each of the following chemical equations. (Note that some may fit into more than one category.) (6.3–6.9) (a) (b) (c) (d) (e) (f) (g) (h) (i) (j) T/I K2O → K + O2 Na + I2 → NaI Cu(NO3)2 + NaOH → Cu(OH)2 + NaNO3 KClO3 → KCl + O2 Ca(NO3)2 + HBr → CaBr2 + HNO3 Sn(OH)2 → SnO + H2O P4 + N2O → P4O6 + N2 Fe + Al2(SO4)3 → FeSO4 + Al AlCl3 + Na2CO3 → Al2(CO3)3 + NaCl C3H6 + O2 → CO2 + H2O 8. Explain why you should not cook on a barbecue in an enclosed space. (6.9) T/I A 9. The following chemical reactions take place, one afteranother,whenanautomobileairbaginflates. Balance and classify each reaction. (6.3–6.6) K/U (a) Th egasneededtoinflatethebagcomesfrom the reaction of sodium azide, NaN3. NaN3(s) → N2(g) + Na(s) 4. Use the law of conservation of mass to explain why chemical equations should be balanced. (6.2, 6.3) 2 H2O2(aq) → 2 H2O(l) + O2(g) (6.1, 6.3) C K/U Referring to this chemical equation, write (a) (b) (c) (d) (e) (f) K/U (b) The sodium produced in reaction (a) is dangerous. It is removed by a reaction with iron(III) oxide, Fe2O3, in the airbag. Na(s) + Fe2O3(s) → Na2O(s) + Fe(s) (c) The sodium oxide quickly reacts with carbon dioxide and moisture from the air to form sodium hydrogen carbonate. Na2O(s) + CO2(g) + H2O(g) → NaHCO3(s) solve a Problem 10. Fuels burn faster as the concentration of oxygen is increased. For example, iron wool burns in pure oxygen to produce iron(III) oxide and a great deal of energy. (6.1, 6.3, 6.9) K/U T/I (a) Write the word and chemical equations for this reaction. (b) Design an experiment using this reaction to confirm the law of conservation of mass. NEL 11. A student placed a piece of zinc metal in a solution of hydrochloric acid. The chemical equation for the reaction that occurred is 14. (a) Develop a visual organizer, such as a chart or a consequence map, to show the risks and benefits of burning fossil fuels. Zn(s) + 2 HCl(aq) → H2(g) + ZnCl2(aq) (b) Write two paragraphs, each written from a different perspective, outlining why we should (or should not) continue to burn fossil fuels for energy. (6.9) The following data were collected from the experiment: initialmassofzincreacted: 2.5g initialmassofhydrochloricacid: 52.6g finalmassofsolution: 54.8g (6.3,6.5) A Reflect on your learning T/I (a) Calculate the mass of hydrogen produced. (b) Do the results of this experiment violate the law of conservation of mass? Explain. 12. Two properties that make gasoline potentially dangerous are that it evaporates quickly at room temperature and that its vapour ignites readily. Despite these hazards, many homeowners keep a small amount of gasoline on hand to fuel small devices like lawn mowers and snowblowers. What must be considered when handling or storing gasoline? Explain your answer. (6.9) A Create and Evaluate 13. A routine test of the drinking water at Edgevale High School revealed slightly higher than normal concentrations of lead. Exposure to lead is known to slow brain development, particularly in children. The lead was coming from the corrosion of the solder metal used to join lengths of copper pipe together. Edgevale school officials were faced with a difficult decision. Closing the school was not an option. The copper pipes could not be replaced until the following summer. However, staff and students needed a safe supply of drinking water now. Two options being considered were • providingbottledwaterforall1500staff and students or • turningonalldrinkingfountainsforat least 20 minutes each morning before studentsarrive.(After20minutes,thelead concentrations decreased to within the “normal” range.) (6.10) (a) List the risks and benefits of both options. (b) If you were the school principal, which option would you choose? Why? A 15. (a)Howrelevantwastheideaofachemical reaction to you before reading this chapter? (b) Outline how your understanding of the role of chemical reactions in your life has changed. Web Connections 16. What is the “fire triangle”? How does it relate to the work of firefighters? (6.10) K/U A 17. The “carbonyl process” is a method of refining nickel that involves passing carbon monoxide gas over impure nickel at high temperature. This produces a compound called nickel carbonyl: Ni(s) + CO(g) → Ni(CO)4(g) Nickel carbonyl is then strongly heated to produce pure nickel and carbon monoxide gas: Ni(CO)4(g) →Ni(s)+CO(g)(6.5) K/U T/A (a) Classify each of these reactions. (b) Research the properties of nickel carbonyl and carbon monoxide. Why must the reactions be conducted in an airtight chamber? 18. Dinitrogen monoxide is also known as nitrous oxide, N2O(g). Dentists sometimes use this gas to relax their patients. Nitrous oxide can be made from solid ammonium nitrate. Water is also producedinthisreaction.(6.3,6.5,6.9) K/U C A (a) Write the chemical equation for this reaction. (b) Classify this reaction. (c) Research how nitrous oxide can be used to improve the performance of racing cars. Summarize your findings in a short web article for car enthusiasts. Include safety advice regarding the use of nitrous oxide in car engines. To do an online self-quiz or for all other Nelson Web Connections, Go to NElsoN sCIENCE NEL Chapter 6 Review 259