Applied Chemistry Name _____________________________ Nuclear Unit Period _______ Date _________________ I. Radioactivity A. Discovery 1. In 1896, Becquerel noticed that a piece of _______________________ ore, called pitchblende, exposed a piece of photographic film. Uranium gave off invisible rays called _______________________ rays. Uranium is ________________________________________ 2. Pierre and Marie Curie (1903): Shared the in chemistry with Becquerel. They discovered 2 new radioactive elements, 1. Marie called Radium the “ native and . ” element and Polonium she named for her . 3. Radioactivity is the release of particles, energy, or both from the ______________ of an atom. Natural radioactivity is found on the . o Everyone receives background radiation at low levels from ________________________________________________, ________________________________________________, ________________________________________________, and ________________________________________________. o Exposure to radiation _________________ make you or anything else radioactive ___________________ radioactivity is produced in the lab B. Types of Radiation 1. Energy Nonionizing radiation is radiation with ____________ energy. o Examples: ____________________________________________, ____________________________________________, and ____________________________________________. Ionizing radiation is radiation with _____________ energy. o Examples: ____________________________________________, ____________________________________________, and ____________________________________________. 1 2. Particles released from the ________________________ of an atom Examples: _____________________ and _______________________ particles 3. Characteristics of Radiation Type Symbol Composition Penetration Stopped by … alpha particle beta particle gamma ray C. Exposure and Uses of Radiation 1. Radon is a decay product of ______________________ found in the soil or bedrock. This is _______________________ radioactivity. Radon is a colorless, odorless __________. Some radon produced in the soil dissolves in __________________________________. Many houses have _______________________ in the foundation and basement floors that permit radon to collect and concentrate. Most radon enters your body by ___________________________________________. Radon decays by alpha emission to produce _____________________, _____________________, and ____________________. These are heavy metals that are not exhaled and produce damaging particles in the body. Radon in your home ___________ be checked by you. Increased ______________________________ and ___________________________ cracks in the floors are 2 ways you can reduce radon exposure. 2 2. Smoke detectors use ______________________________ as the ionizing source Americium emits ___________________ particles. Special _________________________ of smoke detectors is required. 3. Radioactive Dating Used for determining the age of previously _______________________ material. For material up to 25,000 years old, ___________________________ is used. For material over 25,000 years old, ____________________________ is used. 4. Some EXIT Signs use tritium or _____________________________ instead of electricity. The tritium gas is contained in sealed glass tubes. The insides of the tubes are lined with a ____________________. Low-energy _______________ particles (electrons) emitted by the tritium bombard the phosphor, causing it to _______________. 5. Agricultural and Consumer Product Use Many everyday products and food are treated to kill ______________________ and _______________________. Examples: _______________________ ____________________________ _______________________ ____________________________ Products are irradiated with ______________________ rays from __________________, Irradiated products are not ___________________________________. 6. Medical Uses Diagnostic Tools using radioisotope-tracer studies Radioisotopes prepared in a nuclear reactor can be used to both _____________ and ________________ various medical conditions. Tracers can be used to _____________ a particular isotope through its normal path in the body to show any _________________. Tracers used in the body will typically have _____________ half-lives. o Iodine-123 is used to study ___________________________ function. o Technetium-99 is used to locate _________________ and can also collect in _________________. o Barium-140 is used in upper and lower GI studies to find ____________________ and _______________________________ problems. o Thallium-201 collects in ________________muscle. 3 Diagnostic Equipment o Computer-Axial Tomography scans or ______________ scans use _____________________ to produce cross-sectional images of the body. o Magnetic Resonance Imaging or ___________ uses ______________________ to “see through” bones to produce images of soft tissue. o Positron Emission Tomography or _______________ scans use a _____________________________ attached to a sugar molecule to detect and display differences between normal and cancerous tissue. Cancer Treatment using radiation o ___________________ and ________________ are used to treat shallow tumors. o ___________________ is used to treat thyroid cancer. o ___________________ is used to treat leukemia. o 4 Exposure to Radiation: 5 D. Measurement of Radioactivity 1. Units rad measures the absorbed _____________ of radiation. rem measures the _______________________________ effect on living organisms. o In humans, ionizing radiation is measured in millirem, abbreviated ___________. The maximum annual dose is _______________ mrem. The average annual dose is _______________ mrem. 2. Devices used to measure radioactivity: In the Laboratory In the Workplace 1. 2. 3. E. Half-Life is the time for ________________ of the nuclei in a radioactive sample to decay. 1. Abbreviation: ____________ 2. Units can vary from ___________________ to ___________________ of years. 3. Example: Plutonium-239 has a half-life of 24,000 years. A sample of this plutonium today will be half gone in _____________________. A 16-g sample today will have a mass of _______________ in 24,000 years. After another 24,000 years, its mass will only be ______________. 4. Problems a. A radioactive element has a half-life of 64 years. You have a 48-g sample of this element. What is its mass in 192 years? (amount problem - How much) 6 b. Another radioactive sample has a half-life of 37.2 minutes. How long will it take for a 55-g sample to decay to 3.4 g? (time problem - How long or how old) c. The half-life for fluorine-18 is 109.8 minutes. How long will it take a 3.60 μg sample to decay to 0.225 μg? d. The half-life for americium-241 is 432 years. How much of a 50 mg sample will remain after 1296 years? 7 II. Nuclear Energy A. Sources 1. Nuclear Fission is the _______________________ of a large nucleus into smaller nuclei of similar size. 93 1 U 01n 140 56 Ba 36 Kr 3 0 n energy 235 92 A ____________ amount of mass is converted into a ______________ amount of energy Examples o Atomic bomb uses U-235 or plutonium. 1st military use of an atomic bomb was in ______________________________ on August 6, 1945 during World War II. o Nuclear Power Plants A ________________________________ occurs when the material used to start the reaction is also produced until the fuel is used up. o In the above fission reaction, the fuel is ______________________ and the starter for the reaction is the ______________________. ____________________ _______________ is the minimum amount of fissionable material present (the fuel) to sustain a chain reaction. 8 2. Nuclear Fusion is the ___________________________ of smaller nuclei to form a larger nucleus. 2 1H + 2 2H 1 → 1 4 He + 2 1H + energy 2 1 A _____________________ amount of mass is converted into a _____________________ amount of energy that is 4 to 7 times more than a fission reaction. Examples o Sun o Hydrogen bomb We are currently unable to control fusion as an energy source. Temperatures of ___________________________are required. Fusion produces ________________________ waste. B. Nuclear Power Plants 1. Commercial Use 1st plant in US________________________________________________________ 1st plant in the world __________________________________________________ In the US, there are ____________ units in ___________ states to generate __________ of our electricity. There are __________ plants in Pennsylvania. __________________________________________ is the closest nuclear plant to NPHS. Worldwide, there are ______________ plants in over 30 countries that provide __________ of the world’s electricity. In France, __________ of its electricity is produced by nuclear energy. 9 2. Overall process at a nuclear power plant: fission reaction → produces heat → to heat water into steam (545oC) → the steam drives turbines in a generator → the generator produces electricity 3. The chain reaction of a fission reaction takes place in a nuclear reactor. The reactor is made up of a fuel, control rods, a moderator, and a coolant. Nuclear reactors are housed within a concrete containment structure. 4. The fuel is U-235. Nonfissionable uranium is ________________. Uranium ore contains 0.7% U-235. The enriched fuel is packed as ____________________ of 3% U-235 and 97% U-238 Weapons-grade uranium is at least 90% U-235. The pellets are packed into long steel cylinders called _________________________ that are 12-14 feet in length. Fuel rods are replaced every ________ months. Used fuel rods are known as _______________ fuel rods. 5. Control rods are used to absorb the _________________ resulting in slowing down or stopping the chain reaction. _________________ and ____________________ are commonly used in control rods. 10 6. A Moderator is used to _____________________________the high-speed neutrons for more fission reactions to occur. Common materials used as moderators are ___________________________________, _________________________________________, or __________________________ . Heavy water is D2O, where D is _________________________________. Light water is _________________________________________ or H2O. 7. A Cooling system is used to cool the _______________________. Water outside of the reactor is used to cool the steam. The cooled steam _____________________________ into water and is reused inside the reactor. The water used to cool the steam is cooled itself through a _________________________ before it is discharged to a receiving body of water, such as, a river. Water in the cooling tower __________________________ come in contact with the reactor core. Each nuclear reactor has a cooling tower. At the Limerick Generating Plant, the primary water for the cooling system comes from the _________________________________ River and its secondary source is from the ______________________________ River. At the Limerick Generating Plant, the cooled water is discharge into the _________________________________ River. 11 C. Advantages and Disadvantages of Nuclear power Plants 1. Advantages Disadvantages 1. 1. 2. 2. 3. 3. 4. 12 2. Nuclear Waste a. Types High-level nuclear waste is radioactive waste products with _______________ levels of radioactivity. Low-level nuclear waste is radioactive waste products with _______________ levels of radioactivity. b. Sources High-level nuclear waste o _______________________________________________________ o _______________________________________________________ Low-level nuclear waste o ________________________________________________________ o ________________________________________________________ o ________________________________________________________ e. Other Facts Spent fuel rods are still highly radioactive for _____________________________ of years. About 3100 ________________ of commercial high-level nuclear waste are produced annually in the US. There is no permanent storage place for high-level nuclear waste in the US. Federal law mandates the spent fuel rods are stored _________________________, usually in steel-lined storage tanks or pools of water. Some plants are keeping the spent fuel rods in dry cask concrete vaults on the surface. US government is developing a permanent storage site in ________________________________________ in Nevada. o The waste will be buried at least ___________________ below the surface in vaults. o Progress for completion has been delayed from 1998 to 2017 at the earliest. o Delays are due to ____________________, ___________________________________, and ____________________________________ concerns. 13 D. Nuclear Accidents 1. Three-Mile Island Date: _______________________________ Location: ________________________________________________________________ ______________________________________ and ______________________________ lead to the worst nuclear accident in US. 2. Chernobyl Date: _______________________________ Location: ________________________________________________________________ _______________________________________________ and _______________________________________________ resulted in the worst nuclear accident in the world. 14