The Atom and Radiation Nuclear Radiation Goals: To answer the following questions What is radiation? Are there different types? Are all forms (equally) dangerous? Where is radiation found? What is radiation used for? Is all radiation man-made? Are there benefits to some types? How long is something radioactive for? The Discovery of Radioactivity The German physicist W.K. Roentgen “accidentally” discovers a mysterious source of radiant energy that can pass through low density shields (like card board). He calls this mysterious energy X-rays. Further research showed that X-rays cannot pass through everything, particularly high density materials like lead and bone. Roentgen takes the first X-rays of his wife’s hand to present to his colleagues. Hand X-ray, December 22, 1895 The Discovery of Radioactivity The French physicist Henri Becquerel takes interest in Roentgen's X-rays in 1896. He investigated whether certain minerals could emit X-rays. He experiments with Uranium and a photographic plate (develops upon exposure to light). Another accident happens…Becquerel becomes frustrated with his research, wraps the photographic plate in black paper (to prevent light exposure), throws it in his desk drawer with a piece of Uranium on top and closes it up. What do you know??? A few days later, Becquerel discovers that the photographic plate has been exposed while sitting in his dark drawer. The Discovery of Radioactivity What Becquerel inadvertently discovered was radioactivity, the spontaneous emission of nuclear radiation. Soon after (in 1898,) Becquerel's colleagues, Marie Curie and her husband Pierre discover two other radioactive elements: polonium and radium. What is Radioactivity? Radioactivity: the spontaneous emission of nuclear radiation. We now know that there are two categories of radiation: Non-ionizing radiation – low-energy radiation that transfers energy to matter usually only harmful in large amounts Ionizing radiation – high-energy radiation that can eject electrons from atoms/molecules to form highly reactive ions and can cause serious cell damage exposure should be limited. Concerns….. But radiation is all around us…the question is, should we be concerned about our safety?? Are we in danger of serious exposure to radiation? Can we use radiation? Forms of Radiation Radiation comes in several forms as shown in the electromagnetic spectrum below; but not all forms are represented here Types of Radiation Three main types (from the 2 categories) : 1. Non-ionizing electromagnetic radiation Radio Micro Infrared Visible low energy UV 2. Ionizing electromagnetic radiation High UV X-rays Gamma rays 3. Ionizing atomic particle radiation radioactive elements Why are some elements radioactive? To answer this question, you must understand a little about atomic structure. All matter can be broken down into atoms: 1. 2. 3. An atom is composed of three parts: Protons Neutrons Electrons Isotopes (cont.) Some isotopes are stable and others are unstable. This is where radioactivity comes in. A stable isotope is not radioactive, but an unstable isotope is! Ex. 12C is stable 13C is stable 14C is radioactive Radioactive elements will emit radiation until they become a stable isotope. Every Element has Isotopes – the amount of each isotope is fixed Ex. Uranium Mass 238 235 234 Abundance 99.28% 0.71% 0.0054% Which isotope of Uranium is used to make an atomic bomb? Emitted radiation This emitted radiation can be one of three types: Alpha ( 24 α or 42 He ) heavy particle radiation easily blocked because its so big, but the most dangerous particle Beta ( -10 β or -10 e) particle radiation smaller than alpha Emitted radiation This emitted radiation can be one of three types: 0 β or 0 e ) Positron ( +1 +1 positive beta radiation Gamma ( 00 γ ) high energy radiation Emitted radiation Alpha and Beta emission cause radioactive elements to change to a new element. Gamma causes no change in the radioactive element. Radiation Exposure Naturally occurring radioisotopes provide a constant small dose of radiation Radioactive isotopes constantly decay, releasing alpha, beta and/or gamma radiation. This constant, inescapable radiation is called background radiation. Natural background radiation: - Outer space All forms of electromagnetic radiation - Ground water, rocks, soil contain Uranium and Thorium - Atmosphere contains radon - Food and Environment like C-14 and potassium Radon Produced as Uranium in the soil decays. Uranium decays to produce radon gas: When this gas is inhaled, it further decays in your lungs into Polonium, Bismuth and Lead (these heavy metals cannot be exhaled). The resulting alpha radiation is being released into your body, causing cell damage. Manmade background radiation Fallout (nuclear weapons testing) Airplane flights Released from burning fossil fuels nuclear power plants mining making cement concrete sheet rock Medical Applications Medical uses of radioisotopes fall into two categories. Diagnostic Therapeutic Diagnostic A standard x-ray cannot produce an image of an organ like the heart, liver, pancreas, blood vessels, etc. To illuminate the targeted region, a radioisotope is injected into the body. Radioisotopes used are low dosages with a short half-life. localized 0.1 to 50 rem doses are common Commonly Used Radioisotopes Americium-241= Diagnose thyroid disorders, smoke detectors. Cesium-137= Cancer treatment. Iodine-125,131= Diagnosis & treatment liver, kidney, heart, lung and brain. Technetium-99=Bone and brain imaging; thyroid and liver studies; localization of brain tumors. CAT & PET scans A computerized tomography scan is an enhanced x-ray machine using multiple beams capable of producing a 3D image. A positron emission tomography scan uses a positron emitter to generate a 3D image. CAT & PET scans MRI In magnetic resonance imaging, a powerful magnetic field is used along with low energy radio frequency to generate an image. Based on the premise that hydrogen atoms have “spin.” In a powerful magnetic field, these hydrogen atoms can be made to flip between the two spin states. THIS IS NOT NUCLEAR RADIATION MRI Therapeutic In radiation therapy, radiation is used to target cancer cells. Radiation levels are in very high dosages. localized 4000 – 6000rem doses are common Cyberknife treatment uses computer technology to aim 100’s of x-ray beams precisely at a tumor. Measuring Radiation Mainly, two units are used to measure radiation: RAD = radiation absorbed dosage RBE = a multiplier for each type of radiation. 1 RAD = 1.0 x 10-2 J / kg of body tissue alpha = 20; protons, neutrons = 10; betas, positrons, and gammas = 1. REM = radiation equivalent in humans REM = RAD x RBE There are several other units out there; we are not going to worry about those. Biological Effects Alpha particles cannot penetrate our skin, yet internally they can cause massive damage on soft tissues like the lungs and intestinal linings. Beta particles can cause a burn on the outer portion of the skin. Gamma particles penetrate completely and if exposed to large quantities is deadly. Biological Effects Radiation affects those cells in our body that undergo rapid cell division like bone marrow, intestinal lining, and the skin. Radiation tends not to affect cells that remain unchanged like our brain, liver, muscles, etc. Doesn’t mean it CAN’T, it just is less likely How It Works… When radiation hits a molecule like water, it ionizes. H 2O radiation H 2O 1 1e- This water molecule reacts with another water molecule. H 2 O 1 H 2 O H 3O 1 OH How It Works… The “dot” on the OH is an odd electron. Molecules with an odd electron are called free radicals. Free radicals are electron scavengers and interfere with electron transfer reactions – many of which are vital in the function of the body. How much is safe? Ionizing radiation breaks bonds in molecules within the body. At low exposure levels, your body can fix the minimal damage. Higher exposure levels that your body cannot fix will lead to damaged DNA, causing mutations (tumors and birth defects) Average U.S. individual receives 0.360 rem per year. About 0.300 rem of this is from natural sources U.S. limit for background radiation in a given area is 0.500 rem. U.S. safe exposure in the work environment is 5.000 rem. Dose Response Relationships 0-15 rem—No or minimal symptoms 15-40 rem—Moderate to severe illness 40-80 rem—Severe illness deaths start above 50 rem Above 80 rem—Fatal ***Acute whole body doses Your Annual Exposure Activity Smoking Typical Dose 280 millirem/year Radioactive materials use in a UM lab <10 millirem/year Dental x-ray Chest x-ray Drinking water Cross country round trip by air Coal Burning power plant 10 millirem per xray 8 millirem per xray 5 millirem/year 5 millirem per trip 0.165 millirem/year Radiation Protection Decrease Time Increase Distance Increase Shielding Measurement and Detection A Geiger tube is often used to detect radiation. Consists of a metal tube filled with a gas like Argon. When radiation enters the tube, it ionizes the gas. The ions are attracted to a negative charged wire and the electrons are then counted. Measurement and Detection Animation: http://www.dlt.ncssm.edu/tiger/Flash/nuclear/GeigerTube.html Alpha Radioactive isotopes decay until a stable nucleus can be formed. What happens when radioactive isotopes decay? Many elements release alpha radiation: 226 Ra 88 (radium) 4 2 He + (alpha particle) 222 86 Rn (Radon) As these radioactive isotopes decay, an alpha particle is released and a new element is formed. Alpha Particles •Alpha Particles: 2 neutrons and 2 protons •They travel short distances, have large mass •Only a hazard when inhaled or formed in the lungs •because they can’t pass through skin) Beta Many elements release beta radiation: 222 86 Rn (radon) As 0 -1 e + (neg. beta particle) 222 87 Fr (Francium) these radioactive isotopes decay, a beta particle is released and a new element is formed. Beta Many elements release beta radiation: 222 86 Rn (radon) As 0 1 e + (pos. beta particle) 222 85 At (Astatine) these radioactive isotopes decay, a beta particle is released and a new element is formed. Beta Particles Beta Particles: Electrons or positrons having small mass and variable energy. Electrons form when a neutron transforms into a proton and an electron or 1 0 n 0 -1 e + 1 1 H Gamma In addition to releasing a radiation particle (alpha or beta), most radioactive decay is accompanied by the release of gamma radiation too. Remember, gamma radiation is just energy; it is not a particle, so it does not cause the element to change its identity. Gamma Rays Gamma Rays (or photons): Result when the nucleus releases Energy, usually after an alpha, beta or positron transition X-Rays X-Rays: Occur whenever an inner shell orbital electron is removed and rearrangement of the atomic electrons results with the release of the elements characteristic X-Ray energy Neutrons Neutrons: Have the same mass as protons but are uncharged; they behave like bowling balls- they wreck things when they hit them - Identify the starting element and write the symbol. - Identify the type of radiation released. - Subtract the two upper left numbers to find the mass of the new element formed. - Subtract the two lower left numbers to find the atomic number of the new element formed. - Look up the new atomic number on the periodic table to find the new element made. In a completed nuclear equation, the sum of the mass numbers of the unstable isotope and the products are equal sum of the atomic numbers of the unstable isotope and the products are equal Sum of Mass Numbers 251 251Cf = 247Cm 98 98 + 251 4He 96 = 2 98 Sum of Atomic Numbers 57 58 Write an equation for the alpha decay of STEP 1 Write the incomplete equation: 222 86 Rn ? + 4 2 222Rn. He STEP 2 Determine the mass number: 222 – 4 = 218 STEP 3 Determine the atomic number: 86 – 2 = 84 STEP 4 Determine the symbol of element: 84 = Po STEP 5 Complete the equation: 222 86 Rn 218 84 Po + 4 2 He 84 Po 85 At 86 Rn 4 2 He 59 STEP 1 Write an equation for the decay of K42 (potassium-42), a beta emitter. 42 19 K ? + e 0 -1 STEP 2 Mass number: (same) = 42 STEP 3 Atomic number: 19 + 1 = 20 STEP 4 Symbol of element: 20 = Ca 42 19 K 42 20 Ca + 0 -1 e STEP 5 Complete the equation: 0 -1 e 19 K 20 Ca 60 Write the nuclear equation for the beta decay of Co-60. 61 60 27 Co 60 28 Ni + 0 -1 e beta particle 62 In positron emission, a proton is converted to a neutron and a positron 1 1 H n 1 0 0 +1 e the mass number of the new nucleus is the same, but the atomic number decreases by 1 49 25 Mn 49 24 Cr + 0 +1 e 63 In gamma radiation, energy is emitted from an unstable nucleus, indicated by m following the mass number the mass number and the atomic number of the new nucleus are for the same element 99m 43 Tc 99 43 Tc + 0 0 64 65 What radioactive isotope is produced when a neutron bombards 59Co? 59 27 Co + n ? + He 1 0 4 2 66 Sum of mass numbers 60 59 27 = Co + n 1 0 27 = 56 25 60 4 2 Mn + He 27 Sum of atomic numbers 67 Energy and Atomic Structure There is energy associated with holding the parts of an atom together Remember that the protons repel each other There is no electrostatic attraction that holds the neutrons together, nor holding them to the protons But…. The nucleus still stays together despite the repulsion and lack of attraction It is held together by what we call “strong force” or nuclear force. Stability of Nuclei and Energy Remember that all things like to be at the lowest energy level possible. Forming a nucleus releases energy, putting the particles in a lower energy state than when alone as p+, n0, and e- alone Some nuclei are inherently more stable than others so building a bigger nucleus isn’t the final answer in getting lower in energy Decay stabilizes the nucleus, getting to an arrangement of protons and neutrons that is favorable for that element So, what makes some nuclei radionuclides? If the correct proton to neutron ratio is not present for that atom, it will spontaneously give off radiation (decay) in order to achieve a more stable nucleus that has a more favorable proton to neutron ratio for that element The proper ratio ISN’T NECESSARILY 1:1 For most elements over 18, there are more neutrons than protons in the stable isotope(s) All nuclides that with a mass number (A) ≥ 83 are inherently unstable, but lighter elements can be unstable, too Radioactive atoms give off radiation (decay) spontaneously, but at a constant, predictable rate for that radionuclide This is the half-life of the radionuclide The Odd-Even Rule In the odd-even rule, when the numbers of neutrons and protons in the nucleus are both even numbers, the isotopes tends to be far more stable than when they are both odd. Out of all the 264 stable isotopes, only 5 have both odd numbers of both, whereas 157 have even numbers of both, and the rest have a mixed number. This has to do with the spins of nucleons. Both protons and neutrons spin. When two protons or neutrons have paired spins (opposite spins), their combined energy is less than when they are unpaired. http://library.thinkquest.org/3659/nucreact/stability.html The Magic Numbers Another rule of nuclear stability is that isotopes with certain numbers of protons or neutrons tend to be more stable then the rest. These certain numbers are called the magic numbers, and they are, for reasons to detailed to explain here, 2, 8, 20, 28, 50, 82, and 126. When a nucleus has a number of protons and neutrons that are the same magic number, it is very stable. For example: 42He, 168O, and 4020Ca. One stable isotope of lead, 20882Pb, has 82 protons and 126 neutrons. http://library.thinkquest.org/3659/nucreact/s tability.html •Band of Stability: The area of stable nuclei (here, the middle of the dots) •Based upon location near the band, the type of radiation emitted is predictable Radionuclides emit radiation until a stable nuclei is reached Half-Life Radioactive isotopes change what they are as they decay and release radiation. Scientists call the amount of time it takes for half of a radioactive sample to decay a half life. 14C has a half life of 5,730 years. This means that if we started with 100 grams of 14C, only 50 grams of 14C would remain after 5,730 years have passed. The other 50 grams will have turned into 14N as a beta particle is released. Half-Life How long does it take for a radioactive sample to decay? Although it is not possible to predict when any individual isotope will decay, this question can be answered for an entire radioactive sample by the half-life of each radioisotope. The half-life of radioisotopes varies greatly, but is constant for a particular radioisotope. So constant and reliable, it could be used to keep time. How long does it take for a radioactive sample to decay? Why would anyone want to know this? It’ very useful to know how long a radioisotope used in medicine will remain radioactive within the body, to plan how long hazardous nuclear wastes must be stored and to estimate the age of ancient organisms, cavitations or rocks (fossils). Learning Check The isotope Cr-51 has a half-life of 28 days. How much of a 160.mg sample would remain after 112 days? A patient is injected with N-13, which has a half-life of 10 minutes. If the original activity of the sample is 40 mCi, what activity would be remain after 40 minutes? The amount of F-18 decreases from 40.mg to 10.mg in 220 minutes. What is the halflife of this radioisotope? Learning Check The isotope Cr-51 has a half-life of 28 days. How much of a 160.mg sample would remain after 112 days? 10mg A patient is injected with N-13, which has a half-life of 10 minutes. If the original activity of the sample is 40 mCi, what activity would be remain after 40 minutes? 2.5 mCi The amount of F-18 decreases from 40.mg to 10.mg in 220 minutes. What is the halflife of this radioisotope? 110 minutes Fusion Fusion involves taking two or more smaller nuclei and fusing them together. Once again, mass is converted to energy. This is the process by which all stars work. All elements lighter than Fe have formed in stars via fusion reactions 1 1 H 11H 11H 11H 42 He 201 β Fusion On our planet, fusion has been achieved. 2 1 H 31H 42 He 01n The temperatures required are extremely high. Currently, more energy is required to achieve fusion than we get back from the reaction. Research continues as this represents the “holy grail” of energy. Learning Check In one possible fission reaction for U-235, the U-235 is bombarded with a neutron producing Kr-91, three neutrons, and another nuclei. What is the unidentified nuclei? Fission Nuclear fission is the process by which a larger nuclei is split into two smaller ones. During this process, a small percentage of the mass is converted to energy as predicted by Einstein. E = mc2 ; where c = speed of light. 1 x 10-3 g “lost” can generate 9.0 x 1010 kJ of energy. Only two fissionable isotopes are known. U-235 and Pu-239 Nuclear Fission How much energy ??? The fission of uranium-235 produces 26 million times more energy than the combustion of methane. It releases the nuclear binding energy How does nuclear fission work??? + 235U —> 93Kr + 140Ba + 3 1n + ENERGY Bombarding a uranium atom with one neutron produces two smaller atoms and two more neutrons, free to collide with other uranium atoms. This causes a chain reaction to occur. 1n Animation U-235 Fission Animation 2- moderation v unmoderatied Fission Begins when a neutron strikes a U-235 atom. The products are numerous – below is just one example. 235 92 U 01n 139 56 Ba 94 36 Kr 3 01n energy On average, three new neutrons are produced. Each new neutron can split another U-235. Since not all of the neutrons produced will hit and split a uranium nucleus, a minimum amount of uranium is necessary. The more uranium present, the more likely the produced neutrons will hit and split another uranium nucleus. This minimum amount of uranium is called its critical mass. It is the minimum amount of fissionable material required to sustain a chain reaction. Fission In a nuclear weapon, a ____________ of U-235 is imploded producing an uncontrolled chain reaction. Fission In a nuclear power plant, the quantity of U235 cannot sustain a chain reaction. Control rods absorb excess neutrons. Waste products, with long half-life’s, from spent fuel rods are stored in large pools at the power plant. Reactor Animation Cooling System Uranium Mined from the ground as Uranium Oxide U3O8 Two isotopes 1. Uranium-235 - natural abundance = 0.720% - used for fission in nuclear reactions and weapons 2. Uranium-238 - most abundant = 99.275% Enrichment Must have between 1 to 3% U-235 for fission 2 ways to enrich U-235 1. Change U3O8 into UF6 gas - needs to be done about 1200 times - get 4% u-235 2. Use lasers - excite electrons of lighter isotope (U-235) - collected using magnetic fields - works in 1 try Decay Series of Uranium Mass Defect Difference between the mass of an atom and the mass of its individual particles. 4.00260 amu 4.03298 amu Courtesy Christy Johannesson www.nisd.net/communicationsarts/pages/chem Nuclear Binding Energy Energy released when a nucleus is formed from nucleons. High binding energy = stable nucleus. E= 2 mc E: energy (J) m: mass defect (kg) c: speed of light (3.00×108 m/s) Courtesy Christy Johannesson www.nisd.net/communicationsarts/pages/chem A nucleus will become more stable if a reaction brings it closer to the iron peak Nuclei heavier than iron do this by breaking up into smaller nuclei via Fission Nuclei lighter than iron do this by joining together via Fusion reactions Mass Defect and Nuclear Stability 2 protons: (2 x 1.007276 amu) = 2.014552 amu 2 neutrons: (2 x 1.008665 amu) = 2.017330 amu 2 electrons: (2 x 0.0005486 amu) = 0.001097 amu Total combined mass: 4.032979 amu = 4.002602 amu The atomic mass of He atom is 4.002602 amu. This is 0.030366 amu less than the combined mass. This difference between the mass of an atom and the sum of the masses of its protons, neurons, and electrons is called the mass defect. Nuclear Binding Energy What causes the loss in mass? According to Einstein’s equation E = mc2 Convert mass defect to energy units 0.030377 amu 1.6605 x 10-27 kg 1 amu = 5.0441 x 10-29 kg The energy equivalent can now be calculated E = m c2 E = (5.0441 x 10-29 kg) (3.00 x 108 m/s)2 E = (4.54 x 10-12 kg m2/s2) = 4.54 x 10-12 J This is the NUCLEAR BINDING ENERGY, the energy released when a nucleus is formed from nucleons. Mass Defect If you add up a certain number of neutrons and protons and put them together in a nucleus you end up with less mass than you started with! The ‘missing mass’ is known as the Mass Defect and we can use that mass change to determine the energy released by using E=mc2 How do we detect that energy? That energy is released as heat and/ or light That light does not need to be visible light, but can be any form of electromagnetic radiation, or EMR The heat is what we harness in nuclear power plants that use fission The following information is F.Y.I Nuclear Weapons Fission Bomb (a.k.a. Atom Bomb) 1. 2 non-critical masses portions of U-235 are propelled into each other – make 1 critical mass 1 neutron then starts fission, then…BOOM! 2 2. 1 critical mass Usually Plutonium Compressed to get explosion Nuclear Weapons Fusion Bomb (a.k.a. H-Bomb) Uses Lithium Hydride High temperatures create fusion Fusion: 2 different isotopes fuse together Releases more energy (100x) Nuclear Power There are many benefits in using nuclear technology to create electricity, but this must be carefully regulated. If the reactor reaches temperatures that are too high, the danger of a meltdown occurs. A nuclear meltdown can occur when temperatures inside the reactor reach levels that are too high. The materials used to construct the reactor actually melt. If this happens, the chain reaction is no longer contained and dangerous radioactive material can be expelled into the environment. Animation Animation 2 How does it work? When the steam from the generator is cooled by water from When the steam from nearby water sources the generator is cooled by water from nearby water sources Cooling Tower Nuclear Power has reached dangerous conditions three times. Three Mile Island Chernobyl 1979, Pennsylvania 1986, Russia the reactor reached dangerous temperatures, but no meltdown occurred the reactor reached temperatures high enough to cause the core to melt caused by both equipment failure and human error caused by both poor plant design and improper operation while some radioactive material was expelled into the atmosphere, no damage sustained by people or environment radiation spewed into the atmosphere and spread over the entire Northern Hemisphere caused government to create stricter regulations over nuclear power plants an estimated 75 million people exposed Fukushima Daiichi http://www.youtube.com/watch?v=BdbitRlbLDc The Chernobyl incident happened April 26, 1986 in Ukraine. The Chernobyl accident was a result of a flawed reactor design that was operated with inadequately trained personnel and without proper regard for safety. When the operator went to shut down the reactor from it’s unstable condition arising from previous errors, a peculiarity of design caused a dramatic power surge. 3 mile island is located in Harrisburg PA The 3 mile island is a nuclear generating station What Happened? Occurred on 4:00 a.m. March 28, 1979 Problem in secondary, non-nuclear section of the plant The main water pump failed and prevented steam generators from removing heat that the radioactive material was producing The pressure in the primary system (nuclear part of plant) increased What Happened? The relief valve on top of the pressurizer did not close when the pressure decreased Workers reduced the flow of coolant which made the fuel overheat Half of the long metal tubes which held the nuclear fuel pellets ruptured and the pellets started to melt Future Technology… Nuclear Fusion - the joining of two smaller nuclei to create a large nucleus and tremendous energy release. Produces more energy per atom than fission Requires tremendous heat and pressure! Technology does not yet exist that allows more energy to be produced than must be put in.