International Research Journal of Geology and Mining (IRJGM) Vol. 1 (1) pp. 001-011, November 2011 Available online http://www.interesjournals.org/IRJGM Copyright © 2011 International Research Journals Full Length Research Paper Geology and hydrogeology of Northern Ishan district, Edo state, Southwestern Nigeria O.C. Okeke, S.O. Onyekuru*, G. Uduehi and H. O. Israel Department of Geology, Federal University of Technology, Owerri, Nigeria. Accepted 23 August, 2011 o o o Northern Ishan District of Edo State, Nigeria, lies between Latitudes 6 41' – 6 5' and Longitudes 6 00' – o 6 30' and covers an area of about 150 square kilometers. The major towns in the area include Ekpoma, Irua, Uromi and Ubiaja. Their elevations range from 243.9m (800ft) to 426.6m (1400ft) above mean sea level. About 14 of the 27 boreholes drilled in the area were abortive. The study investigated the influence of the local geology on groundwater potential of the area. The geologic formations in the area are Ameki Formation and Ogwashi -Asaba Formation which consist of sandstone, clay and shale (Ameki Formation) and sandstone, clay and lignite (Ogwashi - Asaba Formation). Some of the aquifer characteristics include transsmisivity (average, 9.0 x 10-3 m2/s), storativity (average, 1.85x10-2), yield (average, 1.42x10-2 m3/s) and hydraulic conductivity (average, 1.47x10-2m/s). Sands of various sizes constitute the aquifer material in the area. The pH values of 4.80 - 6.00 in some of the borehole water samples and Fe content of 1.08 - 1.55 mg/l in all the water samples are outside the WHO acceptable limits of 6.5 - 8.5 and less than 0.3mg/l, respectively, for safe drinking water. The water may be classified as acidic, soft, and fresh and is generally good for domestic and agricultural purposes. Key words: Geology, Hydrogeology, Ameki Formation, Ogwashi-Asaba Formation, Aquifer Characteristics, Water Quality. INTRODUCTION The quantity and quality of ground water resources of any area are controlled by the climate and geology of the area. The climate through rainfall and surface water resources ensure constant supply or recharge to groundwater resources of an area in a complex hydrological cycle. The geology of the area determines the aquiferous zones where exploitable groundwater may occur and influences the geochemical characteristics of the groundwater, amongst other factors such as human activities (Domenico, 1972). The geochemical characteristics of the groundwater in turn influence the quality of the groundwater resources. Earlier works by Demenico, and Schwartz (1998), Ahiarakwem and Ejimadu (2002), Downey (1984), Aniya and, Schoenekeck K (1992), Idowu et al. (1999) and Awalla and Ezeigbo (2002) have confirmed the influence of local geology on the aquifer characteristics and quality of groundwater resources of any area. Human activities *Corresponding author E-mail: onyekuru2001@yahoo.com may also influence the quality of groundwater in the area (Alagbe, 2006). Northern Ishan District, in Edo State of Nigeria, lies between Latitudes 6040' - 60 51’ and Longitudes 6000' - 60 30' and covers an area of about 150 square kilometers (TAHAL, 1977). The distinct feature of the area is its higher elevation compared to the elevation of the surrounding towns outside the district. The major towns in the area include Ekpoma, Irua, Uromi and Ubiaja (Figure 1). The elevation of the towns within the district ranges from 243.9m (800ft) to 426.6m (1400ft) above mean sea level while the elevation of surrounding towns including Benin, Agbor and Auchi ranges from 60.96m (200ft) to 182.88m (600ft) (TAHAL 1977; Figure 2). The area is accessible through Benin - Auchi and Benin - Agbor Federal Highways (Figure 2). The area experiences tropical climate with distinct rainy and dry seasons that occurs from April to October and November to March, respectively. The average annual rainfall in the area is 1704mm with a range of 1562 1867mm for ten years record (Nigeria Meteorological 002 Int. Res. J. Geol. Min. Figure 1: Location map of the study area Figure 2: Topographic map of the study area Okeke et al. 003 Table 1: Stratigraphic sequence of sediments in the study area (Kogbe et al., 1976; Reyment, 1965) Age Miocene-Recent OligoceneMiocene Formation Benin Formation Ogwashi-Asaba Formation Eocene Ameki Formation Paleocene Imo Formation (Imo Shale) Nsukka Formation Maastrichtian Lithology Thickness (m) Unconsolidated sandstone with lenses of clay 200 Unconsolidated 300 sandstone and clays with lignite seams Sandstone, clays and 84 Shales Blue to gray dark shales and sandstone members 314 Sandstones and shales Agency, 2007). According to TAHAL (1977), the major rivers in the area with their flow rates include Ena River (3.41m3/sec or 2.2 million gallons per hour); Ubiaja River (0.03 m3/sec or 24000 gallons per hour); Ekpoma River (0.158 m3/sec or 125000 gallons per hour), and Ugbalo River (0.214 m3/sec of 170000 gallons per hour). The groundwater resources comprise the aquifers of the sedimentary formations in the area. The population of the area according to the 2005 population record is 834750, and assuming an annual growth rate of 3% for most towns in Nigeria, the estimated population of the study area will well be over 1million people in 2010. There have been several efforts to provide borehole water for this teeming population, which have led to reports of several cases of abortive water boreholes in the area. About 14 of the 27 boreholes (52% drilled in the area were abortive (Federal Ministry of Water Resources, 1989). It is believed that this is because of the complex geology of the area. In this study therefore, the geology and hydrology of the area were investigated with the aim of evaluating the influence of local geology on the groundwater resources of the area. Geology of the study area According to Reyment (1965), the study area, northern Ishan District, lies on the southwestern extension of the Niger Delta Basin which geologically consist of: a. Ameki Formation; b. Ogwashi -Asaba Formation; and c. Various Quaternary Deposits. The Niger Delta Basin is part of southern Nigerian Sedimentary Basin. Its origin and evolution have been discussed by several workers including Horspers (1965), Burke et al. (1972) and Nwachukwu (1972). The origin is believed to be linked to a series of tectonic activities that occurred in the south Atlantic region during the late Cretaceous times (Murat, 1972). The Sediments penetrated by the Gbakebo “B” well located at Okitipupa Ridge on the western flank of Niger Delta form part of the late Cretaceous and Tertiary with coal seams 233 sequences of the southern Nigerian Basin (Kogbe et al., 1976). Deposition of sediments in the Niger Delta Basin began in the Tertiary and continued into post Tertiary times. The Niger Delta sediments include Benin, Agbada and Akata Formations and they range in age from Eocene to Recent (Short and Stauble, 1967; Asseez, 1976). The Agbada Formation is a down -dip continuation of Eocene-Miocene Ameki and Ogwashi-Asaba Formations, while the Akata Formation is a down-dip continuation of Paleocene Imo Formation (Frankl and Cordy, 1967). Table 1 shows the stratigraphic sequence of the study area and environs as recorded in Gbakebo AB@ well (Kogbe et al., 1976; Reyment, 1965). Figure 3 shows the geologic map of the study area. MATERIALS AND METHODS The data concerning the geology, hydrology and water boreholes in the study area were obtained from the Benin offices of Nigerian Geological Survey Agency, Federal Ministry of Water Resources/Benin-Owens River Basin Authority and Edo State Water Board. Table 2 shows location description of water boreholes in the study area. Field investigations consisted of visits to some functional water boreholes in the study area and collection of water samples (both rainy season, June to October; and dry season, December) for laboratory analysis. The chemical characteristics including pH, Total dissolved solids, major clarion and anions were measured based on the procedures outlined in Hem (1970) and APHA (1971). The Total Hardness (TH) of the sample was determined with the expression below (Freeze and Cherry, 1979): 2+ 2+ TH = 2.5 (Ca 4.1 (Mg ) .............................. (1) where TH is expressed in mg/l CaCo3 The Sodium Absorption Ratio (SAR) that expresses the sodium hazard of the soil was determined using the expression below (Freeze and Cherry, 1979); 004 Int. Res. J. Geol. Min. Figure 3: Geological map of the study area Table 2: Location of water boreholes used in the study Borehole No. Uromi 1 Uromi 2 Uromi 3 Ekpoma 1 Ekpoma 2 Ekpoma 3 Irua 1 Irua 2 Ubiaja 1 Amendokien 1 Iruekpan 1 Ugboha 1 Ugboha 2 Description Central School Compound Central School Compound Km 4, Uromi – Ubiaja Road General Hospital Ambrose Ali University Campus Ihumudum Village, Ekpeoma Town Hall Central School Compound Mr Joseph Ikaro Compound Near motor park (Uzehe Street) Town Hall General Hospital Km 6, Ugboha-Ubiaja Road Okeke et al. 005 SAR = Na+ √ (Ca2+ + Mg2+)/2 ……… (2) RESULTS AND DISCUSSION Table 3 shows aquifer characteristics of some water boreholes in northern Ishan District, while Table 4 and 5 show chemical characteristics of groundwater samples in the area, expressed in mg/l and, in miliequivalent/l, respectively. Table 6 is a description of groundwater potential of an aquifer on the basis of trasimissivity values. Considering Table 3, the parameters storativity, transmissivity, yield and hydraulic conductivity are aquifer characteristics that quantitatively express the groundwater resource potential of the area (Davis and Dewiest 1966; Schwartz and Zhang, 2003; Chatterjee, 2005). These properties are usually controlled by the local geology of an area. The values obtained in the -4 study area include transmissivity (range, 1.37x10 -2 2 -3 2 3.14x10 m /s; mean, 9.0 x 10 m /s), storativity (range, 1.05 x 10-4 - 7.41 x 10-2; mean, 1.85x 10-2), yield (range, 2.2 x 10-3 - 4.5 x 10-2 m3/s; mean, 1.42 x 10-2 m3/s) and hydraulic conductivity (range, 2.74 x 10-6m/s - 1.81 x 103 m/s; mean, 1.47 x 10-3m/s). The average values and ranges of the aquifer properties cannot be assigned to particular geologic formations. However, boreholes with high yield have generally high transmissivity and storativity values. The Storativity of most unconfined aquifers range from 1x10-3 - 1x 10-5 (Schwartz and Zhang, 2003). Idowu et al. (1999) and Aniya and, Schoenekeck K (1992) reported similar results in multi–aquifer systems in the Dahomey Basin (southwestern Nigeria) and Bauchi area (northern Nigeria), respectively. Table 3 and Figure 4 also show that all the boreholes in the area have multi-aquifer systems. Moving in eastwest direction, boreholes at Iruekpan, Ekpoma, Irua Uromi which geologically lie within Ogwashi-Asaba Formation have 3 - layered multi-aquifer systems while boreholes at Ubiaja and Ugboha which geologically lie within Ameki Formation have 2 –layered multi-aquifer system. The relatively shallow unconfined aquifer in most of the boreholes are less than 120m deep while the deeper confined aquifers in all the boreholes are greater than 120m. The confining layers in boreholes at Iruekpan, Ekpoma, Irue and Uromi (Ogwashi-Asaba Formation) are lignite/clays and shales while the confining layers in boreholes at Ubiaja and Ugboha (Ameki Formation) are shales and clays. Figure 5 is the water table map of the area prepared from the elevation of the static water level of Table 3. The groundwater flow directions are generally in all the geographic directions (west-east; east-west; south-north and north-south). This is evidenced by many springs and rivers that exist in all the corners of the district/ plateau (Figure 5). Considering Table 4, the pH values range from 4.80 to 7.10 (average, 6.28), while Total Hardness, Ca2+, Mg2+, Fe (total iron), No3 - and CL- and HCO3- values range from 15.36 to 23.17mg/l (average, 19.28mg/l), 2.60 to 3.50mg/l (average, 2.95mg/l), 2.10 to 3.70mg/l (average, 2.92mg/l), 1.08 to 1.55mg/l (average 1.46mg/l), Nil to 0.03mg/l (average 0.02mg/l) 8.00mg/l to 25.50mg/l (average 15.16mg/l (and 15.00 to 25.00mg/l average, 18.00mg/l), respectively. Compared with WHO Drinking Water Standard, (2005), only pH values at Uromi (6.00) and Iruekpan (5.00) are below the acceptable limits of 6.50 - 8.50; and Fe values in all the water samples (1.08 to 1.55mg/l) are above the acceptable limits of less than 0.2mg/l. The groundwater in the area is generally slightly acidic (average pH = 6.28). Acidic waters such as the groundwater of the study area can lead to corrosion of plumbing materials in water distribution systems. The high iron content of the water may cause stains on clothing materials when the water is used for laundry, however iron generally do not have adverse physiological effect on humans. The high acidity and high iron content of the water may be corrected with addition of lime and aeration, respectively during water treatment processes (Charttergee, 2005). On the basis of Total Hardness of less than 60mg/l (Table 7; Hem, 1970), Total Dissolved Solids of less than 1000mg/l (Table 8; Carrol, 1962) and Sodium Adsorption Ratio (SAR) of less than 10 in Table 4 (Table 9; Freeze and Cherry, 1979), the groundwater of the study area may also be classified as soft, fresh and excellent for irrigation purposes, respectively. SAR values are used to measure the potential dangers posed by excessive sodium in irrigation water. According to Davis and Dewiest (1966), sodium reduces soil permeability and encourages hardening of the soil. The SAR values of groundwater in the study area that range from 0.33 to 0.89 (average, 0.63) will not cause any sodium hazard in the soil, and is therefore very good for irrigation. The high concentration of Fe and moderate concentration Ca2+, Mg2+, Na+, Cl- HCO3 are due to the local geology of the area. Ameki Formation is known for its content of calcareous shales and high amount of Fe203, which is a common geologic parameter that constitute most sediments of southeastern and southwestern Nigeria. The Na+ and Cl- contents may be as a result of indiscriminate use of fertilizer in the study area. The elements may enter the groundwater in boreholes drilled in relatively unconfined aquifers. CONCLUSIONS AND RECOMMENDATIONS Conclusions The underlisted conclusions may be made from the study: a. the geologic formations that underlie the study 006 Int. Res. J. Geol. Min. Uromi -1 255.8 Uromi -2 280.0 Uromi i -3 228.8 Ekpoma 1 216.4 Ekpoma 2 280.4 Ekpoma 3 289.4 Irua 1 335.0 Irua 2 331.0 Ubiaja 1 225.5 Amendokian 318.5 90.00 -110.00 225.0 -240.00 245.0 – 253.0 85.0 – 120.00 232.0 – 255.0 285.0 – 320.0 224.0 – 259.0 260.0 – 290.0 300.0 – 320.0 40.5 – 60.0 136.0 – 148.0 206.0 – 230.0 50.8 – 81.00 168.2 – 183.4 201.1 – 216.4 155.0 – 192.5 220.0 – 250.0 261.0 – 275.0 70.0 – 120.0 183 – 232.0 285.0 – 320.0 190.3 – 225.0 233.0 – 255.0 40.0 – 60.0 170.0 – 190.0 191.0 – 221.0 70.0 – 110.0 180.0 – 230.0 265.0 – 280.0 -2 19/6/94 335.2 195.2 149.0 215.5 6.01x10 18/7/2000 335.2 190.2 149.2 198.0 7.41x10 -2 18/8/2003 335.2 205.2 130.0 218.2 5.21x10 5/2/84 345.2 188.3 156.9 197.4 9/2/96 345.2 190.0 155.2 3/4/99 345.2 190.0 23/9/2000 426.2 4/9/200 -2 -2 -2 Remarks Hydraulic Conductivity (m/s) Yield (m3/s) Transmissivity (m2/s) Storativity Depth to Dynamic water level (m) (m) (m (m) Static Water Elevation level Depth to Static water table (m) Ground Surface Elevation (m) Date of Completion of Borehole Aquiferous Zone (m) Borehole Location/No Total Depth of Borehole (m) Table 3: Aquifer characteristics of some water boreholes in Northern Ishan District, Southwestern Nigeria (Compiled from FMWR, 1999 and Uduehi, 2004) -3 1.03x10 2.30x10 1.0 x10 Abortive 3.14x10-2 1.90x10-2 1.8 x10-3 Operational -4 -2 -3 1.92x10 1.3x10 1.21 x10 Operational 6.86x10 -3 1.02x10-2 1.x10-2 3.4 x10-4 Operational 200.5 9.75x10 -3 9.63x10-2 16x10-2 1.25 x10-4 Abortive 150.2 200.5 1.24x10 210.3 215.9 230.0 274.3 216.5 209.7 24/8/92 335.2 134.5 16/7/92 335.2 195.0 -2 -2 -2 -4 1.31x10 1.0x10 2.61 x10 Operational 2.68x10 -3 2.65x10-3 1.59x10-2 1.30 x10-2 Abortive 235.0 1.05x15 -2 2.62x10-2 4.50x10-3 1.30 x10-6 Abortive 139.8 172.65 4.44x10 140.2 201.10 3.52x10 -4 -4 -4 -3 -6 1.37x10 3.0x10 2.74 x10 Operational 1.38x10-4 2.2x10-3 3.35 x10-6 Abortive Okeke et al. 007 Table 3 continue Iruekpan 1 251.0 Ugboha 1 195.4 Ugboha 2 186.0 Uzea 1 310.0 100.0 – 120.0 140.0 – 160.0 201.9 – 249.0 70.0 – 110.0 142.5 – 182.0 40.00 – 85.0 120.0 – 185.0 60.1 – 110.4 160.0 – 200.0 20/8/87 335.2 135.5 199.7 163.64 1.32x10 -3 2.44x10-4 8.0x10-3 5.08 x10-6 Abortive 21/8/95 252.4 145.1 106.7 161.24 1.05x10 -4 3.36x10-4 1.1x10-2 8.44 x10-6 Abortive 5/2/89 252.4 155.4 87.9 178.04 1.01x10 -2 - 1.6x10-2 - Operational 6/4/87 426.6 208.3 217.7 220.0 - - 2.6x10 -2 - Operational 1.85x10-2 Average 9.00x10-3 1.42x10-2 1.47x10-3 Table 4: Chemical characteristics of groundwater from Northern Ishan District Parameters pH TDS (mg/l) Total Hardness (mg/l CaCo3) Ca2+ (mg/l) Mg2+ (mg/l) Na+ (mg/l) K+ (mg/l) Fe (Total Iron) mg/l No3- (mg/l) Cl- (mg/l) (So42- (mg/l) HC03- (mg/l) Uromi 1 6.00 10600 21.69 Uromi 2 6.80 98.00 15.36 Ekpoma1 7.00 85.00 16.34 Irua 1 6.50 109.00 22.09 Irua 2 6.50 110.00 23.17 3.10 3.40 8.40 0.75 2.53 Nil 25.5 1.00 18.00 2.70 2.10 5.80 0.40 1.49 Nil 23.50 1.00 15.00 2.60 2.40 4.30 0.70 1.50 0.07 12.80 0.50 16.00 3.50 3.40 9.60 1.00 1.49 0.03 7.40 0.40 25.00 3.20 3.70 9.90 1.20 1.50 0.10 8.00 0.60 23.00 Location/Standards Ubiaja 1 Iuekpan 1 Ugboha 1 6.30 5.0 7.10 87.00 105.00 110.00 16.75 18.89 19.8 2.60 2.50 3.30 0.80 1.35 0.01 14.00 1.00 23.00 2.80 2.90 4.80 0.90 1.48 0.03 10.50 1.00 18.00 2.91 3.00 5.10 0.85 1.08 0.01 23.20 0.80 23.00 Uzea 1 4.80 106.00 19.67 Average 6.28 102.00 19.28 WHO Standard (1984) 6.50 – 8.50 1000.00 100 – 500 3.11 2.90 8.70 1.00 1.34 Nil 11.00 0.80 20.00 2.95 2.92 6.66 0.84 1.46 0.02 15.16 0.79 18.00 75.00 200.00 200.00 200.00 0.3.00 10.00 250 200 500 008 Int. 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Table 5: Concentration of the chemical constituents in miliequivalent/l and Sodium Adsorption Ration (SAR) Values Location Uromi 1 Uromi 2 Ekpoma 1 Irua 1 Irua 2 Ubiaja 1 Iruekpan 1 Ugboha 1 Uzea1 Average 1 Ca2+ 0.16 0.14 0.14 0.18 0.16 0.14 0.14 0.15 0.16 0.15 Mg 2+ 0.28 0.18 0.20 0.28 0.31 0.21 0.24 0.25 0.24 0.24 Concentration in mequile and SAR values Na+ K+ ClNo3So42- HCo30.37 0.02 0.73 0.02 0.30 0.25 0.01 0.67 0.02 0.25 0.19 0.02 0.37 0.0007 0.01 0.26 0.42 0.03 0.21 0.0005 0.01 0.41 0.43 0.03 0.23 0.0002 0.02 0.38 0.14 0.02 0.40 0.0002 0.02 0.30 0.21 0.02 0.30 0.0005 0.02 0.38 0.22 0.02 0.66 0.0002 0.02 0.38 0.38 0.03 0.31 0.02 0.33 0.29 0.02 0.43 0.0004 0.02 0.33 SAR 0.78 0.63 0.46 0.88 0.89 0.33 0.48 0.49 0.85 0.63 Table 6: Gheorghe Standard for Transimissitivity (T) (Gheorghe, 1978) Transmissitivity Range Greater than 500m 2/dy (5.79 x 10-3m2/s) Between 50 and 50 m2/dy (5.58 x10-3and 7.3910-3x10-3m 2/s) Between 5 and 50 m2/dy (9.06 x 10-3 and 5.50 x 10-3 m2/s) Between 0.5 are sm2/dy 5.01x10-3 and 5.58 10-3m2/s Below .5m2/dy (5.01 x 10-3 m2/s) Figure 4: Acquire system of natural Ishan District (W – E) Transmissitivity Potentials High Potential Moderate Potential Low Potential Very low potential Negligible flat Okeke et al. 009 Figure 5: Water table contour map of Nortern Ishan district Table 7: Classification of water based on Total Hardness (TH) (From Hem, 1970) Total Hardness (mg/l) as CaCo3 0 – 60 61 - 120 121 – 180 > 180 Water Class Soft Moderately Soft Hard Very Hard Table 8: Classification water based on Total Dissolved Solids (TDS) (From Carrol, 1962) Total Dissolved Solids (mg/l) 1 – 1000 1000 – 10,000 > 10,000 Water Class Fresh Brakish Saline Brine 010 Int. Res. J. Geol. Min. Table 9: Classification of water based on Sodium Adsorption Ratio (SAR) (From US Salinity Laboratory, 1954) Sodium Adsorption Ratio 0 – 10 10 – 18 18 – 26 > 26 area, northern Ishan District are Imo Shale, Ameki Formation and Ogwashi – Asaba Formation; and the lithology consists of clays, shales, lignites and sandstones; a. all the boreholes drilled in the area penetrated only Ogwashi-Asaba and Ameki Formations; . multi-aquifer systems exist in the area, 3-layer aquifer system occur in boreholes drilled into the Ogwashi -Asaba Formation and 2-layer aquifer system occur in boreholes tapping water from the Ameki Formation. d. all the boreholes have unconfined aquifers (less than 120m depth) (1st layer in all the boreholes) and confined aquifer (greater than 120m depth) (2nd and 3rd layers in some boreholes). e. some of the aquifer characteristics include -2 2 transmissivity (range, 1.37 x 154 - 3.14 x 10 m /s, mean -3 2 -4 9.0 x 10 m /s), storativity (range, 1.05 x 10 - 7.4 x 10-2, mean, 1.85 x 10-2), yield (range, 2.2 x 10-3 - 4.5 x 10-2 m3/s; mean, 1.42 x 10-2 m3/s) and hydraulic conductivity (range, 2.74 x 10-6 - 1.81 x 10-3 m/s, mean 1.47x10-3m/s). f. sands and sandstones are the mean aquifer sediment materials because of their characteristic high hydraulic conductivity (1.47 x 10-3m/s) and high yield -2 3 (1.42 x 10 m /s). g. the low pH values (4.80 - 6.00) measured in water samples from some boreholes (at Uromi and Iruekpan) and high total iron (Fe) values (1.08 -1.55mg/l) measured in water samples from all the boreholes are not within the WHO standards acceptable limits of 6.5 - 8.5 and less than 0.20 mg/l, respectively. h. The high values of Fe and moderate values of 2+ 2 -1 Ca , Mg and HCo3 are traceable to the geology (mineralogical/chemical composition of the rocks) of the area; while moderate values of Na+ and Cl- may be due to use of fertilizers in the area. i. The groundwater of northern Ishan District may be classified as acidic, soft, fresh and excellent irrigation water on the basis of its pH, Total Hardness, Total Dissolved solids and SAR values, respectively. Recommendations Adequate geological and geophysical investigations should be conducted prior to drilling of any water Water Class Excellent Good Fair Poor borehole in the area to reduce the incidence of abortive boreholes. In order to improve the quality of groundwater from the area to be used for domestic and industrial purposes, it should undergo pH correction (by addition of lime) and iron removal (by aeration), which are aspects of water treatment to bring their values to fall within acceptable WHO standards. 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