Saturation in Liquid/Gas Coalescence Presented by Mark Hurwitz, Pall Corporation P. Aceves Sanchez, N. Bailey, M. Bruna, P. Cesana, B. Chakrabarti, J. Chakraborty, C. J. Chapman, L. Cummings, M. Dallaston, J. Dietz, P. Dondl, C. Finn, I. Griffiths, J. Herterich, C. Holloway, M. Hurwitz, A. Hutchinson, R. Kgatle, D. Khoromskaia, A. Krupp, V. Lapin, N. Letchford, A. Lewis, A. Manhart, M. Moore, A. Münch, H. Ockendon, J. Oliver, D. Paccagnan, A. Patel, B. Piette, C. Please, R. Purvis, T. Rafferty, M. Saxton, D. Stuerzer, Y. Sun, A. Tamsett, J. Uddin, T. Vo, Y. Wei, M. Zagórowska ESGI100 University of Oxford April 11, 2014 1 / 13 The problem If the concentration of the droplets on the fibres becomes too large, we have saturation and the gas flow may re-entrain the droplets. We aim to model the processes occuring in the coalescer in order to understand saturation. 2 / 13 Our approach 1 Macro-scale model of the coalescer 2 Micro-scale considerations for droplets within the filter 3 Constitutive relations for macro-model determined by micro-scale considerations 3 / 13 Macro-scale: Canonical one-dimensional problem The quantities αlg , αlm , αg , ug , ul , p vary with position and time according to αlg + αlm + αg = 1, ∂ ∂ (ρg αg φ) + (ρg αg ug φ) = 0, ∂t ∂x ∂ ∂ (ρl αlg φ) + (ρl αlg φug ) = −fd , ∂t ∂x ∂ ∂ (ρl αlm φ) + (ρl αlm φul ) = fd , ∂t ∂x ∂ ∂p µg [(ρg αlg + ρg αg )φug ] = − − φug , ∂t ∂x kg ∂ ∂p (ρl αlm φul ) = − − Flm . ∂t ∂x (1) (2) (3) (4) (5) (6) Here, fd = fd (αlg , αlm , ug ) and Flm = Flm (αlm , ug , ul , λlm ) are determined by micro-scale considerations. 4 / 13 Macro-scale: Simple case in 1D ∂ ∂ x̃ ∂ ∂ x̃ ∂ ∂ x̃ ∂ P̃ α̃lg ∂ x̃ ! ∂ P̃ ∂ x̃ ! ∂ P̃ α̃g ∂ x̃ ! 4 α̃lm Concentrations along the filter 1 = Aα̃lg , 0.8 = −Bα̃lg , 0.6 αlm αlg 0.4 = 0, αlg0 α̃lg + αα̃lm + α̃g = 1, 0.2 0 0 0.2 0.4 0.6 0.8 1 x̃ (Along width of filter) where A= λL2 µg , kg φρl (P1 − P0 ) B= λL2 µlm αlg0 . 3 αφρ (P − P ) klm g 1 0 We assumed that α̃g ≈ 1 ⇒ P is linear. å Analytical solutions for αlg and αlm . 5 / 13 Macro-scale: Simple case in 2D ∂ ∂ x̃ " − ∂ ∂ x̃ 4 α̃lm ∂ P̃ ∂ x̃ α̃lg ! + 2 ∂ P̃ ∂ x̃ ∂ ∂ ỹ ∂ ∂ x̃ α̃g ! ∂ ∂ ỹ !# + 2 ∂ P̃ ∂ ỹ ! 4 α̃lm ∂ P̃ ∂ x̃ + 2 α̃lg −E ∂ ∂ ỹ ∂ P̃ ∂ ỹ ! = Aα̃lg , ∂ (α̃lm ) = Bα̃lg , ∂ỹ ! ∂ P̃ α̃g = 0, ∂ ỹ Contour plot of αlm where µlm Lρlg . E= 3 klm (P1 − PO ) ỹ (Along filter height) 1 0.25 0.8 0.2 0.6 0.15 0.4 0.1 0.2 0.05 0 0 0.2 0.4 0.6 0.8 x̃ (Along filter width) 1 6 / 13 Micro-scale considerations I Capture rate of droplets: fd = αlg ρl vg (1 − φ)(df + dd ) (7) Penetration length λ = fd /vg ≈ 0.2 mm Stokes flow along fibres Assume fibres coated by liquid Stokes flow of liquid along the fibre R0 : fibre radius, R1 = R0 + h radius of coated fibre Flow: 2π ∂p (R12 − R02 )(3R12 − R02 ) R14 R1 Q= − ln µ ∂x 16 4 R0 (8) Experimental data → h ≈ 0.1µm. Coated fibres can sustain large fluid flow. 7 / 13 Micro-scale considerations II Droplet displacement Balance surface tension variation when moving on fibre against drag force on droplet: rd = (Nf − 1)γdf 3ηug (9) Droplets with radii below rd do not move. Continuum equation to implement this: αlm = nλ ∂αlm ∂ul αlm + = ug αlg (1 − φ) ∂t ∂x ( 0, ul = ∂p 1 ug + ∂x 3πµrd η , (10) Vdrop < Vdrop minimum Vdrop > Vdrop minimum 8 / 13 Markov approach I One-dimensional lattice model that includes crossings and open space Particles move freely in the open space and as a function of size on the crossings k e k is small Two regimes; r(k) = Crossover behaviour −3 k k is large Saturation transition dependent on parameters such as crossover and influx of particles Do we provide a tool to help design a coalescent? Find optimal operating conditions? 9 / 13 Markov approach II The mathematics; Markov generator X Lf (η) = r(ηx )(f (η 0 ) − f (η)) Paticles on crossings X + u(f (η 0 ) − f (η)) Term due to particles in open space + u(f (η + δ1 ) − f (η)) Term due to incoming particles Defining saturation - When a single particle is of N (the total number of particles) Controlling the average particle number d dt E(N (t)) = u − E(ηL r(ηL )) 10 / 13 Markov approach: working coalescer 11 / 13 Markov approach: saturated coalescer 12 / 13 Results Multiple macro-scale models to describe the physical processes going on in the coalescer: Continuum model Markov approach Two possible micro-scale mechanisms for flow of liquid droplets through the fibre network: Stick/slip idea Stick/film-flow idea Simulations for continuum and Markov models 13 / 13