Cycloaliphatic from Cooper Power Systems THE ULTIMATE GAS-FREE, OIL-FREE AND MAINTENANCE-FREE SOLUTION FOR AUTOMATION, PROTECTION AND SWITCHING APPLICATIONS O O CH – CH2 – O – C CH2 O O C – O – CH2 – CH CH2 NOVA Technology Kyle Distribution Switchgear Cycloaliphatic NOVA Utilizes State-of-theArt Insulation Material The use of polymeric materials is not new to the electric power industry. It is not, however, a trivial task. To assure optimum performance, a designer must match material characteristics to the expected environment. Physical properties dictated from the equipment itself are also key to material selection. Material selection for insulators or arresters, for example, have similar environmental requirements, but vary widely in physical demands. Recloser and switch products are dynamic devices in thermal, electromagnetic, and mechanical characteristics. Cooper Power Systems, Kyle Distribution Switchgear manufactures economical, reliable, and compact switchgear products that provide higher performance and greater value. In today's electric power environment, switchgear products must also meet increasing needs for longer life, lower maintenance, environmental safety, and adaptability to system automation, and new technology development. The choice of materials utilized in the insulation and structural systems of switchgear are critical in meeting these goals. Key elements in the selection of cycloaliphatic epoxy for use in power interruption applications are: Kyle’s NOVA solid insulation system features a proprietary cycloaliphatic epoxy formulation manufactured by Ciba Geigy. A resin-hardener-filler system, this formulation is compounded to provide the optimum physical, surface, and processing characteristics necessary to produce durable and reliable distribution switchgear products. • Surface tracking resistance for BIL retention. • Superior hydrophobicity and low vapor transmission levels. • High ultraviolet resistance indicating material stability and property retention. • Physical properties matched to power interruption duty. NOVA Development Pays Off NOVA is the product of design experience, advanced dynamic modeling techniques, and years of field and laboratory life testing. When combined with Kyle’s extensive vacuum interrupter experience, NOVA products are uniquely qualified and tested for long, troublefree service to the electric power industry. NOVA Cycloaliphatic Epoxy Epoxides are compounds which contain a three-member ring composed of two carbon and one oxygen molecules. The majority of epoxy rings remain closed until they are mixed with hardener agents. O C C Epoxy molecular structure. Hardener The second component of the epoxy system is the hardener, or anhydride, which is the catalyst of the crosslinking process. The epoxy rings open and crosslink when mixed with the hardener. Filler The epoxy and hardener are both filled with a modified silica flour. The silica flour filler improves the physical properties of the molded material to provide superior crack resistance, fracture toughness, thermal conductivity, and reduced shrinkage. All critical components undergo finite element analysis for validation purposes. 2 Cycloaliphatic Cycloaliphatic Advantages samples were exposed to ionic solutions which simulate concentrated contaminants found in highly polluted locations. When compared to polyurethane, cycloaliphatic required 50 percent more voltage before tracking occurred. Also, once voltage was removed, the epoxy ceased combustion while the polyurethane sample continued to burn. Surface Tracking To a large extent, dielectric failure of equipment accounts for a majority of all outages on distribution systems. NOVA’s exceptional ability to resist electrical tracking will reduce both the flashovers and the associated cost of repairs. Coastal Degradation Coastal locations are typically the harshest of all environmental conditions and a significant source of contamination. The large amount of salt accumulations severely degrade the dielectric properties of most insulating materials. Cycloaliphatic performs exceptionally well under these conditions. Surface tracking occurs when particulates accumulate on the insulating surface. As a result, dielectric properties are compromised, creating a low-impedance path for the resulting energy. The type of insulating material employed plays a very important role in the amount of contaminants it is able to withstand before a failure occurs. It is under these extreme conditions that the essential qualities of cycloaliphatic are accentuated. NOVA field test units installed in North Carolina verify resistance to surface degradation in seacoast locations. After two years of exposure to date, surface roughening from erosion was minimal. There was no visuallydetectable loss of gloss and no evidence of chalking. When installed in heavily polluted locations, standard porcelain bushings frequently require extended creepage distances. NOVA’s ability to resist tracking allows use of a standard module in these installations. Production NOVA modules were independently tested by Arizona State University to determine susceptibility to contaminants as outlined in IEC 815, “Guide for the Selection of Insulators in Respect of Polluted Conditions.” No tracking or flashovers occurred even after the contaminants applied exceeded the highest pollution level (very heavy) as defined by IEC 815. NOVA VCS-1 switch at environmental test station in Kure Beach, North Carolina. NOVA cycloaliphatic epoxy material (left) and polyurethane material (right) after incline plane track testing. Furthermore, ASTM test simulating harsh seacoast conditions were independently performed to validate the performance of the epoxy. No tracking was evidenced after exposure to very heavy contaminants typical of coastal conditions and sea-spray as described by IEC 815. The industry standard incline plane test (ASTM D2303: Test Methods for Liquid-Contaminant Tracking and Erosion of Insulating Materials) is often used as the benchmark for comparison of insulating materials in outdoor applications. Cycloaliphatic and polyurethane 3 Cycloaliphatic Flashover Failures Hydrophobicity Flashovers result from objects making contact with energized portions of the equipment, causing an arc which often results in significant material damage. A large number of flashovers are a direct result of wildlife contact. NOVA minimizes the effect of these occurrences with its remarkable physical resilience and extraordinary arc-quenching properties. These attributes permit the unit to withstand the enormous forces experienced during faults without wholesale damage to the modules. The cycloaliphatic epoxy’s self-healing ability also permits re-energizing after external flashover without cleaning or removal of resulting residue. NOVA cycloaliphatic material and mold design provide superior moisture protection. These abilities were demonstrated in tests performed on modules at Cooper Power Systems’ Edison Technical Institute. A fault was established across a NOVA module and then re-energized at rated voltage. No dielectric breakdown occurred even though no repairs or cleaning was performed on the unit between tests. when heated by continuous flow, create a dry band path that further deteriorates the creepage withstand level. Surface arcing and pitting are byproducts of this activity and will eventually lead to complete breakdown or flashover. NOVA cycloaliphatic epoxy maintains excellent hydrophobicity, a property characterized by water “beading” into isolated drops, and resisting moisture absorption into the material. These isolated drops prevent continuous sheets of water from forming leakage current paths which, NOVA module during thermal shock testing. NOVA cycloaliphatic epoxy also has a high resistance to moisture absorption that causes the bonds of the material to break the exposed surfaces. As a result, NOVA resists surface degradation and increases it’s useful life. The lower the absorption rate, the lower the effect on dielectric and mechanical property characteristics. NOVA module undergoing staged fault test (video still). Water Absorption Level Polyurethane = .23% NOVA module after staged fault test. Unit remained intact without physical damage and was successfully re-energized (video still). Water Absorption Level Cycloaliphatic Epoxy = .14% Comparison of water absorption levels between cycloaliphatic epoxy and polyurethane. 4 Cycloaliphatic Ultraviolet Resistance Physical Properties Ultraviolet light will break down electrical bonds of most materials over time. This molecular bond breakdown appears as chalking and cracking on exposed surfaces, decreasing the material’s hydrophobicity. Cycloaliphatic’s tight, cross-linked bonding structure increases the resistance to decomposing in intense ultraviolet environments. As a result, NOVA maintains a smooth, self-cleansing, unblemished surface with low adhesion to contaminants. To date, NOVA has been subjected to more than two years of testing to confirm the impact of high ultraviolet radiation levels on cycloaliphatic epoxy. Results show only minimal chalking NOVA VCS-1 switch at environmental test and no surface station near Phoenix, Arizona. degradation. Outdoor switchgear will likely see extreme temperature fluctuation during its installed life. Materials used in these applications must have outstanding physical properties which will withstand severe thermal shock. In addition, designers must consider the high thermal shock during duty cycle tests (per ANSI C37.60) as a four-shot, 12 kA sequence will conduct additional heat through the insulation system. NOVA Reduces Thermal Expansion NOVA’s low expansion coefficient significantly reduces thermal expansion to one-fifth the level of polyurethane formulations. Thermal expansion is a major consideration in reducing fracture potential. Conversely, higher coefficients in thermal expansion result in increased forces on the internal components, and stress the bond between components and the solid insulation. COEFFICIENT OF LINEAR THERMAL EXPANSION -5 15 x 10 Polyurethane is nearly five times more likely to fracture due to thermal stress and expansion. Shed Design -5 3.5 x 10 By careful design, NOVA uses alternate-sized skirts to enhance material properties of hydrophobicity and ultraviolet resistance. NOVA’s major shed extension shields and protects the minor sheds from moisture and ultraviolet exposure, eliminating the formation of microcracks, and ensuring extra protected creepage against surface degradation. The sheds are designed with sharp edges to direct water away. This is more dramatically apparent in freezing conditions where ice formations are broken and eliminated. Creepage distance is designed in accordance with IEC 815 to exceed 25mm per kV, meeting the requirement for “heavy” contaminant levels. Cycloaliphatic Epoxy TENSILE STRENGTH MPa (psi) Major Shed 8 (1200) Glazed Porcelain Minor Shed NOVA shed design utilizes major and minor sheds for maximum creepage protection from ultraviolet light and contamination. 5 Polyurethane Formulations 80 (12000) 14 (2000) Polyurethane Formulations Cycloaliphatic Epoxy Cycloaliphatic Field Experience NOVA Tensile Strength Provides Long Life NOVA modules are tough and non-fragmenting because they possess outstanding tensile and flexural strength characteristics. A 12-gauge shotgun test supports the non-fragmenting performance and displays the ability of NOVA to thwart vandalism attempts by successfully passing a highpotential withstand test. Polyurethane and porcelain insulation materials, in comparison, have relatively low tensile strength. Cycloaliphatic is superior and withstands a greater severity of mechanical loads from wind, snow, and ice NOVA module after being shot twice loading without failure. Cycloaliphatic epoxy bushings, installed in 1986 at a substation subject to severe pollution from a paper mill, show promising results. The cycloaliphatic epoxy has shown excellent resistance to insulator flashover in this contaminated environment. Prior to use of cycloaliphatic bushings in that substation, flashovers of bus insulators and equipment bushings caused periodic interruptions in service. The cycloaliphatic bushings have not required cleaning since installation in 1986. The success of these cycloaliphatic bushings in preventing flashover in a contaminated environment, over ten years, is strong evidence that cycloaliphatic epoxy is an exceptional insulating material. European experience with cycloaliphatic epoxy has been extensive and long-term with millions of insulators in service. Virtually no maintenance was required on insulators in environments with severe surface contamination. In addition, the insulators experienced extremely low failure rates. More than 1,000,000 cycloaliphatic epoxy insulators are in service in Finland. After nearly 25 years of service, no failures have been attributed to the mechanical characteristics of the cycloaliphatic epoxy. with 12-gauge shotgun. NOVA’s proprietary material composition results in superior, trouble-free, and maintenance-free operation. Testing and field-experience verify that Cooper Power Systems’ NOVA cycloaliphatic epoxy is the “shape of things to come.” CYCLOALIPHATIC EPOXY POLYURETHANE EXCELLENT Poor Electrical Properties OUTSTANDING Poor Mechanical Strength EXCELLENT Adequate Track Resistance EXCELLENT Poor Weatherability EXCELLENT Adequate Hydrophobic Properties EXCELLENT Adequate .14% .23% UV Ozone Resistance Water Absorption (in percent) Source: Conference on Polymeric Material Notes 1990 - Chicago, IL USA 6 Cycloaliphatic NOVA Cycloaliphatic Epoxy Outperforms Other Insulating Materials in Outdoor Switchgear Applications NOVA is the Shape of Things to Come Cooper Power Systems, Kyle Distribution Switchgear NOVA switchgear products (reclosers, switches, sectionalizers) incorporate a state-of-the-art cycloaliphatic epoxy solid insulation system. Cooper Power Systems, Kyle Distribution Switchgear has invested in extensive field and laboratory testing to validate the performance of the NOVA cycloaliphatic epoxy. Comparisons between NOVA cycloaliphatic epoxy and other insulating materials provide solid evidence that cycloaliphatic epoxy is superior in outdoor switchgear applications. NOVA combines Kyle’s 55 years of design experience, advanced modeling and testing tools, years of field experience, and unparalleled vacuum interrupter expertise. Designed for extended life, reliability, and maintenance-free operation, NOVA is “the shape of things to come.” NOVA cycloaliphatic epoxy excels in tracking and erosion resistance, ultraviolet resistance, hydrophobicity, chemical and physical properties. Polyurethanes possess relatively low insulation resistance, high dielectric loss, and susceptibility to ultraviolet radiation and acid rain. Porcelain has poor tracking characteristics which require extra creepage distances in high-contaminant areas, and low tensile strength. 7 Cycloaliphatic ©1998 Cooper Power Systems, Inc. Kyle® is a registered trademark of Cooper Industries, Inc. NOVA™ is a trademark of Cooper Industries, Inc. Bulletin 98009 • March 1998 • New Issue P.O. Box 1640 Waukesha, WI 53187 USA www.cooperpower.com KTM 3/98