Open Cycle mf_dot fuel QH_dot combustor 3 2 ma_dot air compressor 4 turbine W_dotnet= Wt_dot+Wc_dot 1 ( turbine ... ( ) mf_dot ⎞ ⎛ Wt_dot = −ma_dot + mf_dot ⋅ h 3 − h 4 = −ma_dot⋅ ⎜ 1 + ⋅ T − T4 ⎟ ⋅c ma_dot p_prod 3 ⎠ ⎝ ( Jet engine ) Wc_dot = −ma_dot⋅ h 2 − h 1 = −ma_dot⋅ cp_air⋅ T2 − T1 power ... compressor ... )( ) ( ) as a side note: if the net work were converted to velocity via a nozzle (jet engine) the relationships would be Wnet_dot = Wt_dot − Wc_dot determines state 4 out of turbine at p 4 > p1 atmosphere is state 5 ( wnet = cp ⋅ T3 − T4 T 4 determined from equation for net work ) γ−1 could determine p 4 from nozzle anlysis: First law, Q = W = 0 ⎛ p4 ⎞ =⎜ ⎟ T3 ⎝ p3 ⎠ T4 γ−1 γ determine T 5 from ⎛ p5 ⎞ =⎜ ⎟ T3 ⎝ p3 ⎠ T5 γ or ... γ−1 ⎛ p5 ⎞ = ⎜ ⎟ T4 ⎝ p4 ⎠ T5 γ 2 V h4 = h5 + 2 determines V, thrust from momentum change combustor ... 1 = atmosphere ... 0 = HR2 − HP3 rewrite using LHV ... adiabatic combustion Q = W = 0 0 = Enthaply of reactants at combustor inlet, compressor outlet - Enthalpy of products out of combustor - first law ( ) 0 = HR2 − HR0 − HP3 − HP0 + LHV rewrite using specifi enthalpy and mass flows ... on a per unit mass flow of fuel ... ma_dot ma_dot ⎞ ⎛ 0 = h f2 − h f0 + ⋅ h a2 − h a0 − ⎜ 1 + ⎟ ⋅ h p3 − h p0 + LHV mf_dot mf_dot ⎝ ⎠ ( ) ( to account for incomplete combustion introduce combustion efficiency ... 12/19/2005 1 ) only obtain η comb⋅HV Given ma_dot ma_dot ⎞ ⎛ 0 = h f2 − h f0 + ⋅ h a2 − h a0 − ⎜ 1 + ⎟ ⋅ h p3 − h p0 + η comb⋅LHV mf_dot mf_dot ⎝ ⎠ ( can solve for ) ) ( ( ma_dot introduce average specific heat ... cp_bar_air = ) ( ) ( ( ) h p3 − h p0 − h a2 − h a0 h a2 − h a0 cp_bar_prod = T2 − T0 ( ) h p3 − h p0 T3 − T0 ( cp_bar_fuel = η comb⋅LHV + cp_bar_fuel⋅ T2 − T0 − cp_bar_prod⋅ T3 − T0 = ( ) ( cp_bar_prod⋅ T3 − T0 − cp_bar_air⋅ T2 − T0 mf_dot or ... inverting ma_dot ) η comb⋅LHV + h f2 − h f0 − h p3 − h p0 = mf_dot mf_dot ) mf_dot Find ma_dot → h f2 − h f0 − h p3 + h p0 + η comb⋅LHV ⋅ −h a2 + h a0 + h p3 − h p0 ma_dot/mf_dot ma_dot ( = ( ) ) T2 − T0 ) ( cp_bar_prod⋅ T3 − T0 − cp_bar_air⋅ T2 − T0 ( h f2 − h f0 ) ( ) η comb⋅LHV + cp_bar_fuel⋅ T2 − T0 − cp_bar_prod⋅ T3 − T0 gas turbine efficiency efficiency dividing by m a_dot mf_dot ⎞ ⎛ 1 + ⋅ ( T − T4 ) − cp_bar_air⋅ ( T2 − T1 ) ⎜ ⎟ ⋅c Wnet_dot Wt_dot + Wc_dot ma_dot p_bar_prod 3 ⎝ ⎠ η= = = mf_dot ⋅LHV mf_dot ⋅LHV mf_dot ma_dot kg⋅ SFC = hr power = kW SFC = 12/19/2005 fuel mf_dot Wnet_dot = = kg kW⋅ hr mf_dot = ⋅ lb not equality ... hp⋅ hr LHV Wnet_dot LHV = 1 η ⋅ LHV 2 ⋅LHV ) Open cycles have similar alternatives to closed analysis would be similar as well so not repeated here Open Cycle Regenerative (Recouperative) 6 regenerator 3 combustor mf_dot fuel mp_dot products 2 5 4 ma_dot air compressor turbine W_dotnet= Wt_dot+Wc_dot 1 static data for plot T-s diagram temperature 1000 irreversible cycle irreversible, heat exchanger maximum regeneration inlet temperature irreversible 500 1 1.2 1.4 1.6 1.8 2 entropy N.B. cycle is drawn closed from state 6 to 1 but is taking place in atmosphere 12/19/2005 3 2.2 Intercooled Regenerative (Recouperative) Cycle stack Rolls Royce WR-21 is an example see links regenerator 8 5 combustor mf_dot fuel 6 mp_dot products QL_dot 1 compressor 2 ma_dot air 7 4 3 turbine compressor W_dotnet= Wt_dot+Wc_dot static data for plot T-s diagram 1200 irreversible cycle irreversible, heat exchanger maximum regeneration inlet temperature irreversible temperature 1000 800 600 400 0.8 1 1.2 1.4 entropy 12/19/2005 4 1.6 1.8 2 thermodynamic models for combustion Various thermodynamic models can be used for analysis of products of combustion: 1. Single gas model perfect gas, constant cp (1 kJ/kg*K close enough), γ = 1.4 2. Two gas model a) perfect gas - air for compression, c p = 1.0035 kJ/kg*K, γa = 1.4 b) perfect gas combustion products; c pp = 1.13 kJ/kg*K, γp = 1.3 3. Tabulated data (e.g. Keenan & Kaye Gas Tables) property data for air: Table 1: Air at low pressure: T deg F abs, t deg F, h, pr, u, v r, φ Table 2. Air at low pressures: T, t, c p , cv, k = cp /cv, a, Gmax/pi , μ, λ, Pr Table 3: R Log N for air Table 4: Products - 400% Theoretical Air (for One Pound Mole) Table 5: Products - 400% Theoretical Air (for One Pound Mole) fuel data Table 6: Products - R_bar Log e N +4.57263 n Table 7: Products - 200% Theoretical Air (for One Pound Mole) etc. data for oxygen, hydrogen, carbon monoxide, dioxide etc. T = deg F abs t = deg F h = enthalpy per unit mass pr = relative pressure c p = specific heat at constant pressure c v = specific heat at constant volume G = flow per unit area or mass velocity k = cp /cv u = internal energy per unit mass vr = relative volume ⌠ ⎮ φ= ⎮ ⎮ ⌡ p = pressure Pr = Prandtl number = cp*μ/λ R = gas constant for air a = velocity of sound λ = thermal conductivity μ = viscosity T cp T dT T0 Notes: Appendix (Sources and methods - " ...calculated for one particular composition of the hydrocarbon fuel, it has been shown that it represents with high precision the properties of the productsof combustion of fuels of a wide range of composition - all for 400% theoretical air." page 205 bottom - problems involving intermediate mixtures to Table B: can be solved by interpolation based on theoretical air or ... extrapolated to 100% for products is valid except for effects of disassociation .products . reactants air_and ⎛ . ⎞ ⎜ Table %theor %theor %theor water_vapor ⎟ ⎜ ⎟ Number air fuel fuel mass_%_water ⎟ ⎜ Table_B = ⎜ 1 ⎟ inf 0 0 0 ⎜ 4 ⎟ 400 25 14 6.7 ⎜ ⎟ 200 50 28 . ⎝ 7 ⎠ 12/19/2005 5 4. Polynomial equations - example in combustion example c p = f(θ polytropic process compressor isentropic process dT dp ds = cpo⋅ − R⋅ T p (7.21) in gas relationships R⋅ dp dT = η pc⋅ cpo⋅ p T T dp p = dT 1 ⋅c ⋅ R po T T ⌠ 1s ⎛ p1 ⎞ 1 ln⎜ ⎟ = ⋅ ⎮ ⎝ p 2 ⎠ R ⎮ ⌡T p1 cp T p2 dT =e 1s cp η pc ⌠ ⎮ ⋅ dT T R ⎮ ⌡T 2 turbine 2 T p1 p2 =e ⌠ 1s c p 1 ⎮ ⋅ dT T R ⎮ ⌡T T ⌠ 1s c p ⋅⎮ dT ⎮ T η pt⋅R ⌡T 1 p1 2 p2 =e High Temperature Gas Turbines Advantages: high efficiency - low specific fuel consumption high specific horsepower - small size and weight Disavantages: materials strength problems (Creep) see separate notes re: creep corrosion Solutions: better materials blade and combustor cooling ceramic materials 12/19/2005 6 2 blade cooling mf_dot fuel QH_dot combustor 3 2 4 to blades ma_dot air compressor turbine W_dotnet= Wt_dot+Wc_dot 1 cooling flow compressed air ducted into stationary AND rotor blades. Temperature reuduced by: convective heat transfer transpiration (evaporation of water from surface) film nominal data for plot Cooling effectiveness (nominal) effectiveness % 60 40 20 convective film transpiration 0 0 1 2 3 4 cooling flow/turbine flow % cooling_effectiveness = 12/19/2005 Tblade_gas − Tblade_metal Tblade_gas − Tcooling_air 7 5 6 1500 K T3 nominal ΔT over stages defining where cooling is required 1st nozzle @ stator 1st rotor 2nd nozzle @ stator 2nd rotor metal temperature @ critical value 800 K T4 Ceramic materials examples silicon nitride, silicon carbide can be pressed, bonded and/or sintered to produce complete rotor system 25 _deg_C ( 75_deg_F) ⎛ . ⎜ . MPa tensile_strength = ⎜ 552 ⎜ Si3 ⋅ N4 ⎜ 193 ⎝ Si⋅ C 12/19/2005 . . 1400 _deg_C ( 2500_deg_F) ⎞ ksi MPa ksi 80 172 25 28 138 20 8 ⎟ ⎟ ⎟ ⎟ ⎠ Intercooled Regenerative Gas Turbine typically two spool design stack regenerator 10 combustor 5 mf_dot fuel 6 mp_dot products QL1_dot 3 2 7 4 1 9 lp compressor power turbine lp turbine hp turbine hp compressor ma_dot air 8 W_dotnet= Wt_dot+Wc_dot 6 7 8 T 5 9 10 4 2 3 1 s powers ... (review) reversible ( ) HP_comp = −mair_dot⋅ ( h 4 − h 3 ) HP_turb = ( mair_dot + mfuel_dot) ⋅ ( h 6 − h 7 ) ( LP_comp = −mair_dot⋅ h 2 − h 1 ( )( LP_turb = mair_dot + mfuel_dot ⋅ h 7 − h 8 ( )( 12/19/2005 ) w_dot LP_comp = −w_dot LP_turb w_dot HP_comp = −w_dot HP_turb mair_dot ) Power_turb = mair_dot + mfuel_dot ⋅ h 8 − h 9 )( QH_dot = mair_dot + mfuel_dot ⋅ h 6 − h 5 mfuel_dot ) 9 from combustion analysis Marinization Problems: 1. sea water droplets in air (inlet) 2. sea water in fuel 3. coupling to the propeller 4. long ducting Solutions: 1. sea water in air 1. design of inlet - demisters to remove droplets demisters wire mesh inertial separation 2. select corrosion resistant materials 3. surface treatment of components - plating to improve corrosion resistance 4. water washing and abrasive cleaning 2. sea water in fuel 1. treat to remove sodium 3. coupling to propeller (later) 4. long ducting inlet and exit pressures reduce the pressure ratio across turbine reduction in power increase in fuel consumption additional effect from inlet density p ⋅ v = R⋅T => p ρ = R⋅ T ρ = p R⋅ T static data for plot 12/19/2005 10 T-s diagram irreversible cycle nominal pressure losses inlet and exaust temperature 1000 500 0.9 1 1.1 1.2 1.3 1.4 1.5 1.6 1.7 entropy similar effect for T inlet > nominal cycle will walk up p1 curve normally cannot increase T H to account for these losses other issues/topics Materials coatings use of titanium fuel treatment sodium - bad - corrosion from products remove by washing add agents such as demulsifiers water combines with sodium - remove by centrifuge vanadium - in Bunker C combines with sulfur - creates corrosive combustion products GE fro example has an additive to modify ash to prevent adhering to blades problem 3 above: coupling to propeller 1. Controllable Reversible Pitch Propeller (CRP) 2. reversing gearbox 3. electric drive 4. reversing turbine concentric opposite direction direction blade annuli 12/19/2005 11 Brayton cycle applied to turbocharging reciprocating engines power ... mf_dot fuel in ( comp = −mair_dot⋅ h 2 − h 1 out 2 ma_dot air compressor ( ) ( turb = mair_dot + mfuel_dot ⋅ h 3 − h 4 stack 3 ) 4 ) turbine 1 ( ) ( ) ( w_dot comp + w_dot turb = 0 = mair_dot + mfuel_dot ⋅ h 3 − h 4 − mair_dot⋅ h 2 − h 1 mfuel_dot ⎞ ⎛ h2 − h1 = ⎜ 1 + ⎟ ⋅ h3 − h4 mair_dot ⎝ ⎠ ( ) ) p3 may be > or < p2 depending on what happens in engine combined cycles - gas turbine and Rankine - or other 3 T maximum available power from T 4 -> T5 4 2 5 1 s ⎛ w_dot rev ⎞ ⎜ ⎟ = ψ 4 − ψ 5 = h 4 − T0 ⋅ s4 − ( h 5 − T0 ⋅ s5 ) = h 4 − h 5 − T0 ⋅ ( s4 − s5 ) ⎝ m_dot ⎠ max second law ... T⋅ ds = dh − v ⋅ dp assuming cpp constant ds = dh T if ... = cpp⋅dT p 4 = p 5 = p atmos => T ⎛ w_dot rev ⎞ ⎛ ⎛ T4 ⎞ ⎞ ⎜ ⎟ = ψ 4 − ψ 5 = cpp⋅ ⎜ T4 − T5 − T0 ⋅ ln⎜ ⎟⎟ ⎝ m_dot ⎠ max ⎝ ⎝ T5 ⎠ ⎠ 12/19/2005 12 ⎛ T4 ⎞ s4 − s5 = cpp⋅ ln⎜ ⎟ ⎝ T5 ⎠ dp = 0 ds = dh T example LM 2500 T4 := 825 K T0 := 300 K GT_power := 330 ⎛ 500 ⎞ T5 := ⎜ 400 ⎟ ⎜ ⎟ ⎝ 300 ⎠ ⎛ 325 ⎞ T4 − T5 = ⎜ 425 ⎟ ⎜ ⎟ ⎝ 525 ⎠ kJ kg⋅ K ⎛ w_dot rev ⎞ ⎜ ⎟ = W_m_dot_max ⎝ m_dot ⎠ max ⎛ T4 ⎞ T0 ⋅ ln⎜ ⎟= T5 ⎝ ⎠ ⎛ 150.233 ⎞ ⎜ 217.176 ⎟ ⎜ ⎟ ⎝ 303.48 ⎠ ⎛ ⎛ T4 ⎞ ⎞ W_m_dot_max := cp_prod⋅ ⎜ T4 − T5 − T0 ⋅ ln⎜ ⎟ ⎟ ⋅K T5 ⎝ ⎝ ⎠⎠ ⎛ 188.749 ⎞ kJ W_m_dot_max = ⎜ 224.45 ⎟ ⎜ ⎟ kg ⎝ 239.241 ⎠ W_m_dot_max GT_power 12/19/2005 kJ := 1000J kg s cp_prod := 1.08 1 < cp_prod < 1.33 kW ⎛ 0.572 ⎞ = ⎜ 0.68 ⎟ ⎜ ⎟ ⎝ 0.725 ⎠ 13