Design of a high temperature falling bed air preheater for direct coal-fired MHD power generation using liquid slag droplets by Raymond Lee Prill A thesis submitted in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE in Mechanical Engineering Montana State University © Copyright by Raymond Lee Prill (1977) Abstract: A unique design for a falling liquid droplet heat exchanger is presented. The major problem associated with this type of heat exchanger, that of obtaining uniformly sized liquid droplets, has been solved by utilizing vibration induced atomization of the liquid. With this method the drops are formed by disturbing a liquid capillary jet by either vibrating a distributor plate through which the liquid flows or by holding the plate stationary and producing the disturbance with external sound pressure waves. Specific use of this type of heat exchanger as a direct coal fired air preheater for MHD power generation is examined. Digital solution of the governing equations has determined the effect of particle size and size distribution on the chamber size requirement. Comparisons with other MHD preheater design concepts, including the cored brick, show the present design has numerous advantages. STATEMENT OF PERMISSION TO COPY I n p r e s e n tin g t h i s t h e s i s i n p a r t i a l f u l f i l l m e n t o f th e re q u ire m e n ts f o r an advanced, degree a t Montana S ta te U n i v e r s i t y , L i b r a r y s h a l l make i t I agree t h a t th e f r e e ly a v a ila b le f o r in s p e c tio n . I f u r t h e r agree t h a t p e rm is s io n f o r e x t e n s iv e cop yin g o f t h i s t h e s is f o r s c h o l a r l y purposes may be g ra n te d by my m a jo r p r o f e s s o r , o r , in h is absence, by th e D i r e c t o r o f L i b r a r i e s . I t i s und erstoo d t h a t any c o p y in g o r p u b lic a tio n o f t h is th e s is f o r f in a n c ia l w i t h o u t my w r i t t e n p e r m is s io n . S ig n a tu re g a in s h a l l n o t be a llo w e d ' . I DESIGN OF A HIGH-TEMPERATURE FALLING BED AIR PREHEATER FOR DIRECT ' COAL-FIRED MHD POWER GENERATION USING LIQUID SLAG DROPLETS ' by RAYMOND LEE PRILL A t h e s i s s u b m itte d i n p a r t i a l f u l f i l l m e n t o f th e re q u ire m e n ts f o r the degree of • MASTER OF SCIENCE in Mechanical E n g in e e rin g Approved: MONTANA STATE UNIVERSITY Bozeman, Montana May, 1977 . iii acknowledgments ' The a u th o r wishes t o tha n k ,Dr. R. Mussulman f o r h i s guidance and i n s t r u c t i o n d u r in g th e course o f t h i s p r o j e c t . S p e c ia l thanks a ls o goes t o Dr. R. W a rrin g to n f o r h is s u g g e s tio n s and encouragement. The w r i t e r a ls o thanks Dr. W. G e n e tti f o r h i s a s s is ta n c e . T h is s tu d y was s u p p o rte d by ERDA/MHD D i v is i o n and th e Mechanical E n g in e e rin g Department o f Montana S t a t e U n i v e r s i t y . ■ • • .f TABLE OF CONTENTS Page VITA. ................................................. ................................................................... . . . ii ACKNOWLEDGMENTS.................................................................. •......................................i i i LIST OF TABLES.................................................- ................................. .......................... .... v i LIST OF FIGURES.................................................................................... ' ................... v i i NOMENCLATURE. : ....................................... v iii ABSTRACT.................................................................................................................. CHAPTER I x ii ...........................* . .............................. ......................................................... INTRODUCTION........................................ .... . - ................................................ I I 6 CHAPTER I I ....................................... ANALYTICAL MODEL ....................................................................................................... 6 6 R a d ia tiv e T r a n s f e r ............................................................. D r o p le t Energy Balance ............................................ 11 C o n tro l Volume Energy B a la n c e .......................................................... 13 Heat Loss From th e W a l l ....................................................................... 13 F a l l i n g D r o p le t Dynamics . .............................................................. 19 D im ensionless R e l a t i o n s ....................................................................... 19 Method o f S o lu t io n 24 ................................................................................ CHAPTER I I I ........................................................ 27 DROPLET FORMATION................................... 27 CHAPTER I V ................................................................................................................... . 33 RESULTS......................................................................................................' . . . 33 F u l l Load Design . . . ...................... 33 I . .-/ - V - TABLE OF CONTENTS ( c e n t ) P a r t i a l Load O p e ra tio n CHAPTER V. . .................................... SUMMARY .................................... APPENDIX . ' ...................... ' . . APPENDIX I ............................... APPENDIX I I BIBLIOGRAPHY . - vi .. T ab le LIST OF TABLES ' Page 2 .1 PROPERTIES OF THE INSULATING MATERIALS. . . . ........................... 15 4 .1 DESIGN SPECIFICATION FOR 3000 MWt MHD PREHEATER . . . . . . 43 4 .2 INSULATION SPECIFICATIONS FOR HEAT EXCHANGER CHAMBERS . . . 44 4 .3 OPERATING SPECIFICATIONS FOR 3000 MWt MHD PREHEATER AT 3 /4 LOAD............................................................................................. 49 ! ■ - v ii LIST OF FIGURES F i gure L I . 2 .1 2 .2 Page FALLING LIQUID SLAG DROPLET AIR PREHEATER........................................ 4 INCREMENTAL SPHERE FOR DERIVATION OF SHADOWING EFFECT...................................................................................................... 8 INCREMENTAL ANNULUS FOR DERIVATION OF RADIATIVE TRANSFER...................................................................... 8 2 .3 DROPLET ENERGY BALANCE ............................................................................ 14 2 .4 CONTROL VOLUME FOR'ENERGY BALANCE...................................................... 14 2 .5 GEOMETRY FOR THE CASE OF THREE LAYERS OF INSULATION. 20 2 .6 DROPLET FREE BODY DIAGRAM....................................................................... 20 3 .1 EFFECT OF PARTICLE DISPERSION ON LENGTH AND DIAMETER OF THE UPPER CHAMBER FOR A 3000 WMt MHD FACILITY. . . 28 EFFECT OF SLAG TEMPERATURE AND CAPILLARY DIAMETER ON THE PRESSURE DROP THROUGHTHE CAPILLARY ...................................... 35 4 .2 EFFECT OF SLAG TEMPERATURE ON SLAG MASSFLOW RATE...................... 36 4 .3 EFFECT OF SLAG TEMPERATURE ON CHAMBERLENGTH .............................. 37 4 .4 EFFECT OF CAPILLARY DIAMETER AND DISTURBANCE FREQUENCY ON THE.UPPER CHAMBER LENGTH ..................................................... 39 EFFECT OF CAPILLARY DIAMETER AND DISTURBANCE FREQUENCY QN THE LOWER CHAMBER LENGTH. .................................................. 40 OPTIMUM DISTURBANCE FREQUENCIES FOR VARIOUS CAPILLARY ' DIAMETERS . ' .......................... ........................ .......................... 41 VARIATION IN PROPERTIES FROM THE TOP OF THE UPPER CHAMBER.................................... .................................. .... ...................... 45 VARIATION IN PROPERTIES FROM THE TOP OF THE LOWER CHAMBER......................................................... 46 4 .1 4 .5 4 .6 .4.7 4 .8 . . . ■f - v iii r- NOMENCLATURE SYMBOL DESCRIPTION a a c c e le ra tio n o f g r a v it y Rosseland a b s o r p tio n c o e f f i c i e n t ar C s p e c i f i c heat d d r o p l e t d ia m e te r f shadowing f a c t o r o r fre q u e n c y f u n c t io n h hea t t r a n s f e r c o e f f i c i e n t 1b ■ b la d k body r a d i a t i v e i n t e n s i t y k therm al c o n d u c t i v i t y Z le n g t h ifi mass f lo w r a t e n d r o p l e t number d e n s it y q . heat f lu x r r a d iu s sd ( p e r u n i t area and tim e ) s ta n d a rd d e v i a t io n t tim e X d is ta n c e fro m th e to p o f th e chamber A area CD drag c o e f f i c i e n t 'D d ia m e te r F fre q u e n c y Gr Grashof number - ix SYMBOL DESCRIPTION H o v e ra ll heat tr a n s fe r c o e f f ic ie n t L chamber le n g th N t o t a l number o f d e s c re te s iz e s o f d r o p l e t s Nu N u s s e lt number P chamber p re ssu re Pr P r a n d tl number Qr r a d i a t i v e h e a t t r a n s f e r r a te Qcov c o n v e c tiv e h e a t t r a n s f e r r a te R gas c o n s t a n t o r r a d iu s Re Reynolds number T te m p e ra tu re T1 te m p e ra tu re a t to p o f upper chamber T2 te m p e ra tu re a t bottom o f upper chamber te m p e ra tu re a t to p o f lo w e r chamber T3 T4 - te m p e ra tu re a t bottom o f lo w e r chamber U d im e n s io n le s s v e l o c i t y param eter V v e lo c ity v e l o c i t y a t to p o f upper chamber vI V2 v e l o c i t y a t bottom o f upper chamber ■ v e l o c i t y a t to p o f lo w e r chamber V3 V4 . v e l o c i t y a t bottom o f lo w e r chamber , X SYMBOL DESCRIPTION ' '. a a b s o r p tio n c o e f f i c i e n t B volume c o e f f i c i e n t o f expansion Tl d im e n sio n !e ss d is ta n c e <t> . d im e n s io n le s s te m p e ra tu re param eter y dynamic v i s c o s i t y p d e n s it y a S te fa n -B o ltzm a n n c o n s ta n t as fi! s u r fa c e t e n s io n sol i d a n g le d im e n s io n le s s q u a n t i t y c h a r a c t e r i z i n g h e a t t r a n s f e r chamber re q u ire m e n ts SUBSCRIPTS a a ir C c a p illa r y g gas in in n e r ; J je t m mean max maximum mi n minimum O o u te r ' ,^ - xi DESCRIPTION- SYMBOL opt optimum r r e la t iv e o r ra d ia tiv e S s la g term t e r m in a l W ' wal I SUPERSCRIPTS I * d e r iv a tiv e d im e n s io n le s s q u a n t i t y ABSTRACT A unique design f o r a f a l l i n g l i q u i d d r o p l e t hea t exchanger i s p re s e n te d . The m a jo r problem a s s o c ia te d w i t h t h i s ty p e o f hea t e x ch a n g e r, t h a t o f o b t a i n i n g u n i f o r m ly s iz e d l i q u i d d r o p l e t s , has been s o lv e d by u t i l i z i n g v i b r a t i o n induced a t o m iz a t io n o f th e l i q u i d . W ith t h i s method th e drops a re formed by d i s t u r b i n g a l i q u i d c a p i l l a r y j e t by e i t h e r v i b r a t i n g a d i s t r i b u t o r p l a t e thro ugh w hich th e l i q u i d f lo w s o r by h o ld in g th e p l a t e s t a t i o n a r y and p ro d u c in g th e d is tu r b a n c e w i t h e x t e r n a l sound p re s s u re waves. S p e c i f i c use o f t h i s ty p e o f h e a t exchanger as a d i r e c t coal f i r e d a i r p r e h e a te r f o r MHD power g e n e r a tio n i s examined. D i g i t a l s o l u t i o n o f th e g o v e rn in g e q u a tio n s has determ ined the e f f e c t o f p a r t i c l e s iz e and s iz e d i s t r i b u t i o n on th e chamber s iz e r e q u ire m e n t. Comparisons w i t h o t h e r MHD p r e h e a te r d e sign c o n c e p ts , i n c l u d i n g th e cored b r i c k , show th e p r e s e n t design has numerous advantages. CHAPTER I INTRODUCTION The e f f i c i e n c y o f a f o s s i l f u e le d open c y c le magnetohydrodynamic power g e n e r a tin g p l a n t depends s t r o n g l y on th e te m p e ra tu re o f the w o rk in g g a s . The r e q u i r e d com bustion te m p e ra tu re s , on th e o r d e r o f SOOOKj can be a chieved by e i t h e r , p r e h e a tin g th e com bustion a i r to a high te m p e ra tu r e , around 2000K, o r by use o f oxygen e n r ic h e d a i r . Because o f th e amount o f oxygen t h a t would be needed i n a l a r g e s c a le MHD power p l a n t , th e l a t t e r o f these methods was n o t c o n s id e re d in t h i s s tu d y . There are two b a s ic types o f a i r p re h e a te rs f o r open c y c le MHD a p p l i c a t i o n s - th e d i r e c t l y f i r e d and i n d i r e c t l y f i r e d . f i r e d p r e h e a te r u t i l i z e s The d i r e c t l y th e therm al energy o f th e e xh a u s t gas from th e MHD channel t o p re h e a t th e a i r w h il e th e i n d i r e c t l y f i r e d f a c i l i t y uses th e e xha ust gas fro m a s e p a r a t e ly f i r e d , cle a n f u e l combuster. The i n d i r e c t l y f i r e d p r e h e a t e r , though n o t having t o w it h s t a n d the d e l e t e r io u s p r o p e r t ie s o f th e f l y ash s l a g , s u l f u r , and potassium seed c o n ta in e d in an MHD exh a u st gas, would r e q u i r e an expensive c le a n b u rn in g f u e l e ffic ie n c y . such as n a t u r a l gas'a n d w ould lo w e r th e o v e r a l l p l a n t T h e r e f o r e , th e f u l l e x p l o i t a t i o n o f the e f f i c i e n c y advantages o f an MHD power . p la n t i s dependent on th e employment o f h ig h te m p e ra tu re d i r e c t l y f i r e d a i r p r e h e a te r s . Four types o f p r e h e a te r designs have in th e p a s t been c o n s id e re d f o r coal f i r e d MHD a p p l i c a t i o n s : - 2 1) th e chequerwork packed bed p r e h e a te r 2) th e packed pebble bed p r e h e a te r 3) th e cored b r i c k packed bed p r e h e a te r 4) th e f a l l i n g bed p r e h e a te r Al I o f the se are r e g e n e r a tiv e ty p e h e a t e xch a n g e rs. P o lis h r e s e a r c h e r s . have s iz e d th e chequerwork ty p e p r e h e a te r and found th e dim ensions q u i t e l a r g e ( I ) . Creep o f th e ceram ic b r ic k s a t th e bottom o f such a massive chequerwork i s a s e r io u s problem . The packed pebble bed ty p e p re h e a te rs have th e in h e r e n t problem o f p lu g g in g up from th e coal s la g d e p o s it s , though th e y are f e a s i b l e in an i n d i r e c t l y f i r e d f a c i l i t y (2 ). The cored b r i c k p r e h e a te r o f f e r s X both th e p o s s i b i l i t y o f n o t p lu g g in g from th e exhaust gas coal s la g d e p o s its and good therm al e f f e c t i v e n e s s A ll (3 ). packed bed ty p e p r e h e a te rs (chequ erw ork, pebble bed and cored b r i c k ) o p e ra te in a c y c l i c mode o f h e a t-u p and blow-down. This r e q u ir e s la r g e gas v a lv e s i n t h e MHD exh a u st gas f lo w stream o p e r a tin g p e r i o d i c a l l y and s e a l in g a g a in s t th e d i f f e r e n t i a l i n l e t and o u t l e t o f th e MHD channel h ig h te m p e ra tu re s (around 2000K ). p re s s u re between th e ( a p p r o x im a te ly 7 atmospheres) a t These v a lv e s r e p r e s e n t Targe c a p i t a l c o s ts and r a is e s e r io u s r e l i a b i l i t y q u e s t i o n s . T h is problem , teamed w i t h th e problems o f f i n d i n g a d u ra b le bed m a t e r ia l and r e d u c in g p lu g g in g and f o u l i n g t o an a c c e p ta b le l e v e l , has caused p r e h e a te r desig n t o la g behind development o f o t h e r MHD components. - 3 The f a l l i n g bed conce pt re p r e s e n ts one s o l u t i o n t o th e problems o f o t h e r d i r e c t l y f i r e d MHD p r e h e a te r design c o n c e p ts .. T h is design employs h e a t t r a n s f e r fro m p a r t i c l e s f a l l i n g gas. thro ugh a c o u n t e r f lo w o f In th e MHD a p p l i c a t i o n th e p a r t i c l e s would be heated in one s e t o f chambers by th e e xha ust from th e MHD c h a n n e l. p a r t i c l e s would then f a l l second chamber. These heated th ro u g h a c o u n t e r f lo w o f com bustion a i r i n a F ig u re 1.1 shows th e f lo w process i n v o lv e d . Continuous r e c y c l i n g o f t h e bed m a t e r i a ls e l im in a t e s any v a lv e s i n th e exhaust gas f l o w . The la r g e s u r fa c e - a r e a - t o - m a s s r a t i o o f th e p a r t i c l e s f a l l i n g bed p r e h e a te r g iv e i t \ p o te n tia l f o r h ig h hea t t r a n s f e r r a t e s . Two typ e s o f bed m a t e r i a l ' f o r t h e f a l l i n g been proposed; s o l i d p a r t i c l e s o f a m a t e r ia l l i q u i d d ro p le ts o f a m a te ria l l i k e i n th e coal s la g . p a r t i c l e p r e h e a te r have l i k e alum ina ( 4 , 5) and E x te n s iv e research was done on th e a t o m iz a t io n o f l i q u i d s la g by a team o f E n g lis h eng ine ers ( 6) . These s t u d ie s were focused on th e use o f t w in j e t a to m iz e r s , b r e a k in g .u p a j e t o f l i q u i d s la g w i t h a j e t o f a i r . T h is ty p e o f a to m iz e r had th e d isa d va n ta g e o f a w ide d i s p e r s io n o f d r o p l e t s iz e s , c a u sin g la r g e chamber le n g t h r e q u ire m e n ts . I f th e d r o p l e t s are m ono-disperse in s i z e , th e y can be p a r t i a l l y " f l o a t e d " by th e gas and th e chambers can be v e ry compact. As the d r o p l e t s iz e d is p e r s io n in c re a s e s th e v e l o c i t y o f th e gas m ust.be decreased to a v o id e l u t r a t i o n o f th e s m a ll e r p a r t i c l e s and th e chamber le n g t h must be in c re a s e d to p r o v id e adequate re s id e n c e tim e f o r heat SLAG (1650K) EXHAUST GAS ( 1 8 1 GK) i r ~ 1.1X10 PASCALS MHD ___ ! EXHAUST GAS ( 2 2 00K) SLAG < 1 9 2 0 K) 1.2X10 PREHEATED Al R ( I BOOK) A I R ( I 2 OOK ) FIGURE 1.1 FALLING LIQUID SLAG DROPLET AIR PREHEATER - 5 “ t r a n s f e r to o r from th e l a r g e r d r o p l e t s . o f a fa llin g T h e r e fo r e , th e f e a s i b i l i t y bed hea t exchanger u s in g l i q u i d s la g as th e bed m a te r ia l i s dependent on a narrow d is p e r s io n o f th e d r o p l e t d ia m e t e r s . M ono-disperse sprays have been a ch ie ve d by v i b r a t i o n induced a t o m iz a t io n . W ith t h i s method th e d r o p l e t s a re fo rm e d .by d i s t u r b i n g a l i q u i d c a p i l l a r y j e t by e i t h e r v i b r a t i o n sound p re s s u re waves ( 9 , 1 0 ). (7 , 8) o r w i t h e x te rn a l E xp erim e ntal data has shown t h a t drops u n ifo r m i n d ia m e te r t o w i t h i n f i v e p e r c e n t o f th e mean can be o b ta in e d u s in g l i q u i d s as i n v i s c i d as w a te r and as v is c o u s as g l y c e r i n . The co n ce p t o f th e above d e s c rib e d d r o p l e t g e n e r a to r and the f a l l i n g bed h e a t exchanger u s in g l i q u i d s la g as th e hea t t r a n s f e r media are combined in th e f o l l o w i n g p r e h e a te r d e s ig n . d r o p l e t s iz e d i s t r i b u t i o n s I t i s shown, t h a t narrow o b t a in a b le w i t h the d r o p l e t g e n e r a to r can r e n d e r an e f f i c i e n t and compact d i r e c t l y f i r e d , h i g h te m p e ra tu re p r e h e a te r f o r open c y c le f o s s i l f u e le d MHD a p p l i c a t i o n s . Some o f th e o f f design o p e r a t io n a l c h a r a c t e r i s t i c s are a ls o c o n s id e r e d . . CHAPTER I I ANALYTICAL MODEL The d i f f e r e n t i a l e q u a tio n s f o r th e h e a t t r a n s f e r w i t h i n th e heat exchanger were o b ta in e d from b a s ic p r i n c i p l e s . R a d ia tiv e T r a n s f e r R a d ia tiv e energy exchange between any two d r o p l e t s in th e chamber depends upon th e s o l i d a n g le subtended by one d r o p l e t as viewed from th e o t h e r . T h e re fo re , it i s necessary to d e r iv e an e x p re s s io n f o r th e shadowing e f f e c t o f t h e p a r t i c l e s . . C o nsid er an in c re m e n ta l sphere o f r a d iu s £ and th ic k n e s s . d£ c e n te re d about a d r o p l e t o f d ia m e te r d / as shown in F ig u re 2 . 1 . Assume, th e sphere i s o ccu p ie d by d r o p l e t s o f d ia m e te r dm lo c a te d randomly w i t h an average number d e n s it y n. subtended by a l l Let ( £ ) r e p r e s e n t t h e t o t a l s o l i d ang le o f th e d r o p l e t s w i t h i n th e sphe re . The f r a c t i o n o f s o l i d ang le n o t y e t shadowed by these d r o p l e t s i s f (£■) = (4fn - fi(£))/4TT 2.01 Then th e s o l i d ang le subtended by th e d r o p l e t s w i t h i n th e in c re m e n ta l sphere is dO(&) = (-------9— ) (4Tr£2d£.) f (£) 2.02 4A T h is y i e l d s th e d i f f e r e n t i a l e q u a tio n + 2.03 / - I - With- th e boundary c o n d i t i o n f i( o ) = 0 , th e s o l u t i o n is B(Jl) = 4ir( I - B - m d J y 4 2 .04 T h e re fo re , 2.05 To d e r iv e th e e q u a tio n s f o r th e n e t r a d i a t i o n i t was assumed t h a t th e d r o p l e t s are b la c k b o d ie s . I t was f u r t h e r assumed t h a t the d r o p l e t s form an o p t i c a l l y dense c lo u d and th e r a d i a t i o n p e n e t r a t io n d is ta n c e i s sm all compared w i t h th e d is ta n c e o v e r which s i g n i f i c a n t te m p e ra tu re changes o c c u r . Thus th e gas was c o n s i d e r e d . t r a n s p a r e n t . A f t e r th e e q u a tio n s were s o lv e d , t h i s l a t t e r assum ption was checked-and th e a b s o r p tio n by th e gases was found to be small (1 1 ). The r a d i a t i v e t r a n s f e r fro m a d r o p l e t o f d ia m e te r dm i n th e annul us to th e d r o p l e t o f d ia m e te r d- as shown i n F ig u re 2 .2 is 2 .0 6 where 2 .07 and 2 Jr = 2 + r 2 2 .0 8 I - 8 - FIGURE 2.1 INCREMENTAL SPHERE FOR DERIVATION OF SHADOWING EFFECT 2 I FIGURE.2 .2 INCREMENTAL ANNULUS FOR DERIVATION OF RADIATIVE TRANSFER - 9 The t o t a l r a d i a t i v e t r a n s f e r from a l l x= °° 2 2 2 now d, dm 8 I r— o f th e d r o p le t s i s then r re-(,n7rdnl2(x 2+ r2) ’5 4 X=- 00 dr dx x2 + r 2 r= o 2.09 I n t e g r a t i n g w i t h re s p e c t t o r y i e l d s X= CO 2 2 2 now d. dm 2+1 8 J 2.10 Tsm4(x) El ( IotxD dx X-- CO where 2.11 a = 1/4 nnd and ( x ) is the f i r s t exponential in te g ra l fun ction E1( X) 2.12 The i n t e g r a t i o n o f e q u a tio n ( 2 .1 0 ) r e q u ir e s th e te m p e ra tu re o f th e s la g d r o p l e t s to be s p e c i f i e d as a f u n c t i o n o f x . Since t h i s i s n o t known, a T a y l o r ' s s e r ie s expansion about x=0 t r u n c a te d a f t e r th e f i r s t f o u r terms o f the s e r ie s i s employed. sm g (x ) - g ( o ) + x g ' ( o ) + g" (o) + Qm i (O) 2 .1 3 - 10 S u b s titu tin g ( 2 .1 3 ) i n t o ( 2 .1 0 ) and u s in g th e r e l a t i o n s h i p 0, n J x nE1 ( | x | ) d x OO 2 y ie ld s odd 9 9 9 ncnr d.. a_ Ji m Qr2+1 = — JJ I x " E1( x ) d x , n even 2.14 g ( o ) E 1 (ax)+%x 2g " ( o ) E 1(a x ) 2.15 I n t e g r a t i o n o f e q u a tio n ( 2 .1 5 ) g iv e s , Qr^ 1 = a-rrd_.2T. 4 + Ji l Sm " 16a d.2 i 9 Sm d 2.16 4' Since th e r a t e o f therm al em ission from th e d r o p l e t d^ is Q r 1 = OTTd12I 5 . 4 , 2.17 th e n e t r a d i a t i v e h e a tin g r a t e o f th e d r o p l e t is IGod1 io o o :2 Qr net T T zr Sm d_ d2<Tsm4 > + =TTd1 (Tsm - Ts1' 2.18 E q uation (2 .1 8 ) re p re s e n ts th e n e t r a d i a t i v e h e a tin g o f a d r o p l e t o f d ia m e te r d 1 by the s u r ro u n d in g d r o p l e t s o f d ia m e te r d ^. in c lu d e d in th e energy balance f o r th e f a l l i n g d r o p l e t s . energy balance f o r th e c o n t r o l volume i s a p p li e d , i t T h is i s When th e i s necessary to - 11 r e p r e s e n t th e n e t r a d i a t i v e h e a t f l u x . I f th e average mean f r e e path o f a photon e m it te d by a d r o p l e t is sm all compared w i t h th e d is ta n c e o v e r w hich s i g n i f i c a n t te m p e ra tu re changes o c c u r , then th e n e t r a d i a t i v e h e a t f l u x i s o b t a in e d by use o f th e Rosseland d i f f u s i o n e q u a tio n ( 1 2 ) . qr -IGoT 3 3a_ dT dx 2.19 where ar i s th e Rosseland- mean a b s o r p tio n c o e f f i c i e n t . In t h i s case a ^ would equal a d e fin e d in e q u a tio n ( 2 . 11) and T th e lo c a l mean s la g te m p e ra tu r e . Then 64oTsm d (Tsm) 2.20 Smclm2.! E q uation ( 2 .2 0 ) r e p r e s e n ts th e r a d i a t i v e d i f f u s i o n th ro u g h the s la g d r o p l e t c lo u d . D r o p le t Energy Balance Fine (13) has found th e therm al d i f f u s i v i t y o f s la g s s i m i l a r to coal s la g a t te m p e ra tu re s o f 1600K t o be on th e o r d e r o f 5 x 10- / (m / s e c ) The r e s u l t i n g B i o t modulus f o r th e d ia m e te rs c o n s id e re d i s between 0 .3 and 0 . 8 . Based on th e s e low B i o t numbers and th e i n t e r n a l m ix in g w i t h i n th e d r o p l e t , an is o th e rm a l sphere i s assumed. C o n sid e r a d r o p l e t o f d ia m e te r d. f a l l i n g th ro u g h a c o u n te r f lo w o f gas as shown i n F ig u re 2 . 3 . TTdi 3 ps cs i ( 6 Then d(Ts . ) ^ dt ~ ^cov + ^ r n e t 2 ‘ 21 - 12 but d (L ,) d (T . ) d (L ,.) 2.22 and qCOV = - h I dI 2 .2 3 (Tg - Ts 1 > 24 it,. 2.24 - 2vSmdSdm30,-n2 Combining e q u a tio n s ( 2 .2 1 ) th ro u g h ( 2 .2 4 ) and ( 2 .1 8 ) si _ dx 6M W , qds ( ^ s m dmDi n 2 ) 2 ds cs i d i Vs i d^ O + 18cS id1-vS iltS ps cs i d i v s i 2.25 (T=m4 - L , 4 ) sm s1 E q uation ( 2 .2 5 ) re p re s e n ts th e d e r i v a t i v e w i t h r e s p e c t t o p o s i t i o n o f th e te m p e ra tu re o f th e p a r t i c l e s o f d ia m e te r d^ as th e y f a l l chamber. through th e For the i d e a l i z e o case o f one d r o p l e t d ia m e te r (m o n o -d isp e rse ) t h e r e i s one e q u a tio n o f t h i s fo rm , and d. equals d , I . equ als I , • III Ol oIII e tc . When t h e r e i s d i s p e r s io n in th e d r o p l e t d ia m e te r s , t h i s is accounted f o r by l e t t i n g d^ denote th e d ia m e te r o f th e d r o p l e t s o f the i t h d i s c r e t e s i z e ; i = l denotes th e s m a ll e s t d r o p le t s and i=N denotes th e l a r g e s t d r o p l e t s . Thus, t h e r e a re N e q u a tio n s o f th e above form 13 (one f o r each d i s c r e t e s i z e ) . C o n tro l Volume Energy Balance The e q u a tio n f o r th e heat exchange between the d r o p l e t s and the gas i s d e r iv e d u s in g th e c o n t r o l volume shown in F ig u re 2 . 4 . The h e a t lo s s fro m th e w a ll s per u n i t area i s re p re s e n te d by qw . The r a d i a t i v e d i f f u s i o n te rm , q r? is p resen ted in e q u a tio n ( 2 . 2 0 ) . energy b alance f o r th e c o n t r o l volume y i e l d s ^lflS icS i1Si Ix " rflS icS i1Si I x+ax + ( c gltgT9 l x+Ax " W An n g l Xl " V 0Oi x “ qJx+Ax^ 2.26 = 0 R e arran ging and u s in g e q u a tio n ( 2 .2 0 ) lflS icSl i= 1 d fx S i1 2lj2opSV i n 4vSm 9V g cg V g d fT Av ' sm 3 d fx Sm1 ' . dx qWll0O 2.27 ' cg% Heat Loss From th e Wall B e fore th e h e a t lo s s can be c a l c u l a t e d , th e i n s u l a t i o n m a te r ia l and t h ic k n e s s has to be d e te rm in e d . i n s u l a t i o n c o n s id e re d are l i s t e d The e i g h t ty p e s o f ceram ic in Table 2 . 1 . The in n e r w a ll - 14 - I FIGURE 2 .3 DROPLET ENERGY BALANCE ltS FIGURE 2.4 V Ag CONTROL VOLUME FOR ENERGY BALANCE - 15 - TABLE 2 .1 M a n u fa c tu re r PROPERTIES OF THE INSULATING MATERIALS Type Thermal C o n d u c t ! v it y ( j/ m - s e c - K ) Upper Temperature L i m i t (K) Standard S ize (cm) Norton AN-599 1.290 2140 7.62 J o h n s -M a n v ille JM-3200 0.503 2030 11.43 Johns-Manvi l i e JM-3000 0.475 1920 11.43 J o h n s -M a n v ille JM-2800 0.424 1810 11.43 J o h n s -M a n v llIe JM-2600 0.338 1700 11.43 J o h n s -M a n v ille JM-2500 0.308 1640 11.43 J o h n s -M a n v ille JM-2300 0.144 1530 11.43 Johns-M anvil Ie Cerawool 0.078 1140 5.08 - 16 te m p e ra tu re i s assumed to be equal t o th e lo c a l mean s la g d r o p l e t te m p e ra tu re and th e o u t e r w a ll i s s p e c i f i e d a t 370K. Because o f th e c o r r o s iv e e n viro n m e n t w i t h i n th e e xcha nger, Norton AN-599 bubble alum ina b r i c k i s used as th e f i r s t l a y e r o f i n s u l a t i o n . t o be 7.62 cm. t h i c k . The o u t e r l a y e r o f i n s u l a t i n g m a t e r i a l , J o h n s -M a n v ille C eraw ool, i s chosen because o f i t s c o n d u c t i v i t y and i t s lo w e r therm al a b i l i t y to absorb any co nd ensatio n which m ig h t o c c u r on th e i n n e r w a ll o f th e e n c lo s in g p re ssu re v e s s e l. i s t o be 5 .08 cm t h i c k . ig n o r e d . T h is l a y e r R e spective th ic k n e s s e s o f th e re m a in in g i n s u l a t i o n s a re chosen by a computer t r i a l o u t l i n e d below . T h is l a y e r i s and e r r o r te c h n iq u e as Thermal r e s is t a n c e o f t h e metal p re s s u re vessel i s ' =» To d e te rm in e th e c o n v e c tiv e f i l m n a t u r a l c o n v e c tio n i s assumed. c o e f f i c i e n t on th e o u t s id e w a l l , For an am bient a i r te m p e ra tu re o f 295K and a c h a r a c t e r i s t i c le n g t h o f e i g h t meters th e G rashof number P r a n d tl number p r o d u c t i s GrPr = 2 .5 x 10 Since t h i s 12 i s i n t h e t u r b u l e n t range f o r n a t u r a l c o n v e c t i o n ,. the r e s u l t i n g N u s s e lt number i s Nu = . I S ( G r P r ) ' 333 (14) Then k a 2.28 - 17 The o p t i m i z i n g c r i t e r i o n f o r d e t e r m in in g th e i n s u l a t i o n th ic k n e s s e s i s th e o u t e r chamber d ia rtie te r; th e id e a b e in g t o maxim ize th e th ic k n e s s o f t h e lo w e r c o n d u c t i v i t y m a t e r i a ls and thus m in im iz e t h e o u t e r d ia m e te r. The desig n c o n s t r a i n t s are t o keep th e te m p e ra tu re s a t th e i n t e r f a c e s w i t h i n th e l i m i t s o f th e r e s p e c t iv e i n s u l a t i o n s . The com puter r o u t i n e t h a t chooses and s iz e s th e r e s p e c t iv e i n s u l a t i o n s begins by t r y i n g o n ly th e h ig h therm al r e s is t a n c e m a t e r i a l between t h e s p e c i f i e d i n n e r and o u t e r la y e r s . . I f th e i n t e r f a c e te m p e ra tu re s a re to o h ig h ,- s u c c e s s iv e la y e r s o f t h e lo w e r r e s i s t a n t i n s u l a t i o n s a r e added u n t i l th e i n t e r f a c e te m p e ra tu re s a re w i t h i n th e l i m i t s o f th e r e s p e c t iv e in s u la tio n s . \ C o n sid e r th e case where o n ly one ty p e o f i n s u l a t i n g m a te r ia l between th e s p e c i f i e d o u t e r and i n n e r la y e r s o f i n s u l a t i o n s as shown i n F ig u re 2 . 5 . From th e s o l u t i o n o f t h e c o n d u c tio n e q u a tio n s f o r r a d ia l heat t r a n s fe r w ith c y lin d r ic a l T i s used Ro ( To - Ta ,h1,,(R2/ R l> 2 Ro ( To - Ta>h1n<R3/R 2> T3 ’ T2 symmetry 2 .2 9 2 .30 E q uating th e h e a t i n and o u t o f each fa c e R, = ( A - T s i^ V V h R , 2.31 - 18 These are s o lv e d by use o f s u c c e s s iv e s u b s t i t u t i o n and the i n t e r f a c e te m p e ra tu re s are checked a g a in s t th e upper te m p e ra tu re l i m i t s p e c i f i c a t i o n s o f th e i n s u l a t i o n m a t e r i a l s . I f these are t o o h ig h , a l a y e r o f th e n e x t h i g h e r r a te d te m p e ra tu re i n s u l a t i n g m a t e r i a l i s added, and th e i n t e r f a c e te m p e ra tu re s are c a l c u la t e d and checked. Each l a y e r o f i n s u l a t i o n added i s a v a ila b le . T h is method i s 11.4 cm t h i c k - - t h e s iz e c o m m e rc ia lly repeated u n t i l a l l o f th e tem p e ra tu re s were w i t h i n th e l i m i t s o f th e r e s p e c t iv e m a t e r i a l s . A f t e r these ste p s are co m p le te d , a n o th e r check i s made t o see i f any o f th e i n t e r f a c e te m p e ra tu re s a re low enough t o r e p la c e a l a y e r o f i n s u l a t i o n w i t h th e n e x t lo w e r c o n d u c tiv e i n s u l a t i o n . For in s t a n c e , th e above method c o u ld r e s u l t w i t h a l a y e r o f JM-2300, a l a y e r o f JM-2500, and a l a y e r o f JM-2600, when th e te m p e ra tu re between th e JM-2500 and th e JM-2600 i s low enough t o r e p la c e t h e JM-2500 w i t h JM-2300. ' . Once th e i n s u l a t i o n s iz e s are d e te rm in e d , th e hea t f l u x term is c a l c u l a t e d u s in g an o v e r a l l h e a t t r a n s f e r c o e f f i c i e n t where qw r e p r e s e n ts the h e a t lo s s fro m th e w a ll as used in Equation ( 2 .2 7 ) and H = I/ " + E i (15) 2 .32 F a l l i n g D r o p le t Dynamics ■. The e x p re s s io n f o r th e dynamics o f a s p h e r ic a l d r o p l e t o f d ia m e te r d^ f a l l i n g th ro u g h a c o u n t e r f lo w o f gas i s d e r iv e d by use o f t h e f r e e body diagram i l l u s t r a t e d buoyant f o r c e i n F ig u re 2 . 6 . I g n o r in g th e (p / ps« 1 ) 3 4 CDpgVr i 2.33 d iP s ^ s i As w i t h e q u a tio n ( 2 . 2 5 ) , th e r e are N e q u a tio n s o f t h i s form (one e q u a tio n f o r each d i s c r e t e d r o p l e t s i z e ) . The d ia m e te r o f th e chamber depends on th e t e r m in a l v e l o c i t y o f X t h e s m a ll e s t p a r t i c l e . The t e r m in a l v e l o c i t y i s c a l c u l a t e d from the e x p re s s io n 4ap d. -V term .( is ■) 2 .34 D im ensionless R e la tio n s To f a c i l i t a t e ease o f s o l u t i o n and use o f d im e n s io n le s s em perical c o r r e l a t i o n s , th e above e q u a tio n s .w e re n o rm a liz e d u s in g th e f o l l o w i n g param eters — 20 - FIGURE 2 .5 FIGURE 2 .6 GEOMETRY FOR THE CASE OF THREE LAYERS OF INSULATION DROPLET FREE BODY DIAGRAM V r l" i M9 = Reynolds Number h ,-di Nu, N u s s e lt Number Pr = — p—^— E q u a tio n s ( 2 .2 5 ) , = P ra n d tl Number ( 2 .2 7 ) , and (2 .3 3 ) tra n s fo rm r e s p e c t iv e ly in to th e f o llo w in g : d<pS i _ 6Nu . U. ( m * + ¥2 - (J)si.) * ( Pr p C1 d, * (U1 - U ) d2< V ) 1 + du2 < C - +si ) dtp, 9 - ( i m ) ( Z c' i , X i * i= l A & n + ¥6 dn d<J>c 3 c DuI 1 W where V 4 p * d .* ( U .-U + ¥8 ) - 23 - I 0V V T2gpsdmDin 4vsmTl , s 4 18 D0 * s =g(T2 , g- T 1>g) qWn 0 O_____________ V g (T2,g " Tl,g> T7 ' aV v L r W Y8 W PAV l, r The va lu e s f o r th e N u s s e lt number were c o r r e la te d fro m p u b lis h e d data as Nu. = ^ g R e V 630P r - 333 (1 5 ) 2.3 8 The drag c o e f f ic ie n t was d eterm ined fro m th e Reynolds number Il O O 1 8 .5 /R e -600 5 .7 4 /R e -372 0 .44 Re<200 200<Re<1000 Re>1000 (1 6 ) 2 .39 - 24 The above param eters and e q u a tio n s a p p ly to t h e . to p chamber b u t w o uld be id e n t ic a l f o r th e .lo w e r chamber w ith th e e x c e p tio n t h a t T2 ’ V1 anc* V2 w ould be re p la c e d by T3 , T ^, V3 and r e s p e c t iv e ly . Method o f S o lu tio n The n o n - lin e a r s e t o f o r d in a r y d i f f e r e n t i a l e q u a tio n s (2 .3 5 ) th ro u g h (2 .3 7 ) re p re s e n t a boundary v a lu e system w ith one known b o u ndary. unknown. A lth o u g h th e boundary va lu e s a re known a t x= L, L i t s e l t is Assuming th e e q u a tio n s a re w e ll behaved, th e system can be s o lv e d by an i n i t i a l v a lu e n u m e rica l m ethod. An ene rg y balance o f th e e n t ir e h e a t exchanger system is used, to f in d th e te m p e ra tu re s a t th e to p o f th e chambers and th e mass flo w r a te s . Thus (.2N+1) i n i t i a l va lu e s a re known, le a v in g o n ly one t o be a p p ro x im a te d --th e f i r s t d e r iv a t iv e o f th e mean s la g te m p e ra tu re . The problem a r is e s fro m th e form o f e q u a tio n ( 2 .2 5 ) . For th e mean s la g te m p e ra tu re th e e q u a tio n is d2(Tsm d <Tsm> C1 (Tg-Tsm) + c2 where C l and C2 re p re s e n t th e v a r ia b le c o e f f ic ie n t s . I f th e system is s o lv e d w ith th e second term to th e r i g h t o f th e equal s ig n equal to z e ro , th e te m p e ra tu re p r o f ile s a re n e a r ly li n e a r . The a d d it io n o f th e second te rm re nde rs th e te m p e ra tu re s o lu t io n , and i t s d e r iv a t iv e s , e x p o n e n tia l in n a tu re and e x tre m e ly s e n s it iv e to th e i n i t i a l ft' v a lu e - 25 a p p ro x im a tio n and n u m e rica l tr u n c a tio n e r r o r . Any s l i g h t e r r o r w i l l compound i t s e l f e x p o n e n tia lly and dom inate th e e q u a tio n s , re n d e rin g th e s o lu t io n m e a n in g le s s . The second d e r iv a t iv e term re p re s e n ts a p o r tio n o f th e r a d ia t iv e t r a n s f e r w h ile th e f i r s t term to th e r i g h t o f th e equal s ig n re p re s e n ts th e c o n v e c tiv e t r a n s f e r . D e fin in g e as th e r a t i o o f th e se two terms and e m plo ying an o rd e r o f m agnitude a n a ly s is y ie ld s d2< C > C2 1 2 L dx^ C1 t V sm ■) + 4 T 3 Sm d2<Tsm> dx2 T r g-T smT V wI th AT L 2 and Cf For th e upper chamber AT L u s in g q u a n t it ie s from a n u m e rica l s o lu tio n o b ta in e d w ith th e r a d ia t iv e term n e g le c te d r e s u lt s in E = 0.030 and f o r th e lo w e r chamber E = 0.002 S ince th e s e r a t io s a re much le s s th a n one, th e r a d ia t io n term is sm a ll in com parison to th e c o n v e c tio n te rm . T h e re fo re , th e r a d ia tio n I - 26 second d e r iv a t iv e term in e q u a tio n th e e q u a tio n s . (2 .3 5 ) was ig n o r e d .in o r d e r to s o lv e T h is is n o t to say t h a t th e rm a l r a d ia t io n is ig n o re d in th e a n a ly s is ; b u t r a t h e r , th e second d e r iv a t iv e te rm in e q u a tio n (2..18) was dropped. The i n i t i a l c o n d itio n s a t th e to p o f th e chamber a re ♦st - V 1 V The i n i t i a l 0 va lu e f o r th e second d e r iv a t iv e term in e q u a tio n (2 .3 6 ) had to be a p p ro xim a te d in o rd e r to i n i t i a t e S ince t h is te rm had l i t t l e th e n u m e rica l i t e r a t i o n . e f f e c t on th e r e s u lt s ( le s s th a n one p e rc e n t) th e a p p ro x im a tio n d id n o t have to be v e ry a c c u ra te . • A f o u r th o rd e r R unge-K utta in t e g r a t io n te c h n iq u e was employed to s o lv e th e system o f e q u a tio n s . In th e bottom chamber th e le n g th was de te rm in e d by in t e g r a t in g u n t i l ^ equ ale d one, w h ile in th e to p chamber th e p re d e te rm in e d s la g e x i t te m p e ra tu re was used as th e p a ram eter to d e te rm in e th e le n g th . E r r o r a n a ly s is f o r h ig h e r o r d e r R unge-Kutta schemes is ve ry d i f f i c u l t o r im p o s s ib le to im plem ent f o r systems o f n o n lin e a r d i f f e r e n t ia l e q u a tio n s o f t h i s ty p e ( 1 7 ) . To check th e convergence and s t a b i l i t y s e v e ra l d i f f e r e n t s te p s iz e s were used. No a p p a re n t problem s a ro s e . CHAPTER I I I DROPLET FORMATION A c r i t i c a l elem e nt in th e d e sig n o f a f a l l i n g bed c o u n te rflo w h e a t exchanger is c o n tr o l o f the, d is p e r s io n o f t h e . d r o p le t d ia m e te rs . To p re v e n t any o f th e p a r t ic le s fro m b e in g blown o u t o f th e to p , th e v e lo c it y o f th e gas th ro u g h th e chamber must be li m i t e d by th e te rm in a l v e lo c it y o f th e s m a lle s t p a r t ic le s . I f th e d r o p le t s iz e s a re c h a r a c te r iz e d .b y a w ide d is p e r s io n , th e la r g e r p a r t ic le s w i l l f a l l much f a s t e r than th e s m a lle r ones and th e le n g th o f th e chamber w i l l become u n fe a s ib ly la r g e . For exam ple, th e p a r t ic le s iz e d i s t r ib u t i o n o b ta in e d fro m Heywood and Womack (6 ) u s in g a tw in j e t a to m iz e r would r e q u ir e chamber le n g th s in excess o f 100 m eters f o r an MHD p re h e a te r. F ig u re 3 .1 f u r t h e r i l l u s t r a t e s th e chamber d im e n s io n s . th e e f f e c t o f p a r t ic le d is p e r s io n on One c o n ce p tu a l s o lu t io n to t h i s problem is th e fo rm a tio n o f th e s la g d r o p le ts by v ib r a t io n a to m iz a tio n . In th e proposed a to m ize r,, r e fe r r e d to as a drop g e n e ra to r, th e l i q u i d is fo rc e d th ro u g h a c a p i ll a r y w h ich is v ib r a te d a t a p re ­ d e te rm in e d fre q u e n c y to produce u n ifo r m ly s iz e d d ro p s . T h is te c h n iq u e has been used p r im a r ily in re s e a rc h a p p lic a tio n s such as com bustion (.8) and drop co a lescen ce s t u d ie s . ( 1 8 ) . The f i r s t q u a n t it a t iv e a n a ly s is o f l i q u i d j e t d i s in t e g r a t io n was made in 1878 by Lord R a y le ig h ( 1 9 ) . His r e s u lt s , w h ich a re a p p lic a b le to an in v is c i d f l u i d w ith o u t any a e ro ­ dynamic fo rc e s a c t in g on i t , showed t h a t th e fre q u e n c y f o r maximum i n s t a b i l i t y , and hence th e optimum fre q u e n c y f o r u n ifo r m ly s iz e d d ro p s . - 28 — - 3.25mm M hameter length O u te r Chamber D iam eter (m e te rs ) d P e rc e n t V a r ia tio n Between Mean and Minimum D iam eter FIGURE 3 .1 EFFECT OF PARTICLE DISPERSION ON LENGTH AND DIAMETER OF THE UPPER CHAMBER FOR A SOOOMWt MHD FACILITY - 29 is g iv e n by 3.01 Fopt - Y 4-508 Do T h is a n a ly s is was extended by L e v ic h ( 2 0 ) - to in c lu d e th e e f f e c t s o f f l u i d v is c o s it y and s u rfa c e te n s io n fo rc e s r e s u lt in g in 'V 1Fo p t = ( 13 S o p ) ( % r~ T 3 y_. 3.0 2 ) U j The minimum fre q u e n c y f o r th e fo rm a tio n o f n e a rly u n ifo r m ly s iz e d drops was d e te r m in e d .e m p ir ic a lly by R ajogopalan and T ie n (7 ) as Fmin 3 .0 3 0 -4 Fo p t These same re s e a rc h e rs a ls o d e te rm in e d th e t h e o r e t ic a l e x p re s s io n f o r . th e drop s iz e r e s u lt in g fro m th e j e t d is in t e g r a t io n V, 1 /3 d = 1.145 ( - J l H 2 /3 D- 3 .04 The minimum average v e lo c it y in th e c a p i ll a r y nece ssary to form a s ta b le j e t , as de te rm in e d by L in d b a ld and S ch neider (1 8 ) is 8 or Vc,min = ( - T . % -1 3-05 Harmon (2 1 ) has r e la te d th e c a p i ll a r y d ia m e te r to th e f r e e stream j e t d ia m e te r by. D- = 0.867 D„ 3.06 - 30 The above e q u a tio n s were used to s im u la te th e drop g e n e ra to r th e h e a t exchanger a p p lic a t io n . fo r There a re two methods o f d is tu r b in g th e l i q u i d j e t : 1) F lo w in g th e l i q u i d th ro u g h c a p i l l a r i e s in a p la te w hich is v ib r a te d w it h in a p re d e te rm in e d fre q u e n c y range 2) F lo w in g th e l i q u i d th ro u g h c a p i ll a r ie s in a s t a tio n a r y p la te w ith th e d is tu rb a n c e produced by e x te rn a l sound p re s s u re waves. U n ifo rm ly s iz e d drops ( to w it h in f i v e p e rc e n t o f th e mean) have been a ch ie ve d by th e f i r s t method ( 7 , 8 ) . The second method was in v e s tig a te d by Miesse (9 ) b u t no s iz e d i s t r ib u t i o n s were p u b lis h e d . A m a jo r f a c t o r in th e v a r ia t io n o f d r o p le t d ia m e te rs is th e v a r ia t io n in th e c a p i l l a r y d ia m e te rs . c a p illa r ie s is The re q u ire d number o f in th e d i s t r i b u t o r p la t e at. th e chamber to p is 4 til Number o f C a p illa r ie s = ---------------------- p— pSvC T Dc,m 3 .0 7 ■ Because o f th e h ig h te m p e ra tu re s , e x tru d e d ceram ic tu b in g is suggested f o r th e c a p i l l a r i e s . The s ta n d a rd to le ra n c e s f o r t h is tu b in g w ith in s id e d ia m e te rs ra n g in g fro m 1 .3 x 10 is ±3% o r 1 .3 x 10 4 m e te rs , w h ic h e v e r is g r e a te r . to 1 .3 x IO "'3 m ete rs These to le ra n c e s were used to f in d th e minimum c a p i l l a r y d ia m e te r f o r a s p e c ifie d mean c a p i l l a r y d ia m e te r. For la m in a r flo w th e p re s s u re d ro p .a c ro s s th e s m a lle s t c a p i ll a r y is g iv e n by I - 31 3 2 ]i AP £ C s TT Vc , min 3.0 8 c ,m in where Vc mi- n is th e minimum v e l o c it y re q u ire d to form a j e t in th e s m a lle s t c a p i l l a r y . S ince th e c a p i l l a r y le n g th s a re equal j, th e v e l o c it y in th e mean c a p i ll a r y d ia m e te r is g ive n by V = V . D Cjl In m c,m c ,m n 2 2 3.09 c ,m in The optimum o p e ra tin g fre q u e n c y is c a lc u la te d u s in g e q u a tio n ( 3 .0 2 ) . From e q u a tio n (3 .0 4 ) th e mean d r o p le t d ia m e te r fro m th e s m a lle s t c a p i ll a r y and th e mean d r o p le t, d ia m e te r from th e mean c a p i l l a r y are o b ta in e d . Assuming th e d r o p le t d ia m e te rs from any c a p i l l a r y va ry w it h in 5% o f th e mean d r o p le t d ia m e te r o f t h a t c a p i l l a r y , th e s m a lle s t d r o p le t w it h in th e exchanger is c a lc u la te d from th e mean d r o p le t d ia m e te r o f th e s m a lle s t c a p i l l a r y . min dm T hat is .95 d m,min dm,m The c a p i l l a r y d ia m e te rs and th e d r o p le t d is p e rs io n s a re assumed t o f o llo w a normal d i s t r i b u t i o n . d e v ia t io n , i t was f u r t h e r assumed In o rd e r to c a lc u la te th e sta n d a rd t h a t 99% o f a l l o f th e d ro p le ts w i t h in th e chamber a re w i t h in th e d ia m e te r range a s .c a lc u la te d above T h is r e s u lt s in a s ta n d a rd d e v ia tio n o f - Sd " dmin ;-------- 27576 32 - ( 22) 3 .1 0 The fre q u e n c y fu n c t io n f o r th e p a r t i c l e d i s t r i b u t i o n was then g e n erate d by / ,( d r dn. ) 2 f(d .) 3.11 - S d VZTr For th e d is c r e t e number o f d r o p le t s iz e s as modeled in th e com puter code th e r e s p e c tiv e number f r a c t io n s were o b ta in e d by in t e g r a t io n o f th e fre q u e n c y f u n c t io n . y CHAPTER IV RESULTS The e q u a tio n s p re se n te d in C hapter I I and C hapter I I I w e re .a p p lie d to th e d e sig n o f an MHD a i r p re h e a te r system . The’ com puter program o u t lin e d in Appendix I I was used to n u m e r ic a lly in te g r a te th e e q u a tio n s . The o p e ra tin g c o n d itio n s f o r th e 3000 MW therm al open c y c le f a c i l i t y c o n s id e re d were s im il a r to th o s e o f th e ECAS Base Case One Open C ycle s tu d y (2 3 ) b u t w ith h ig h e r o p e ra tin g te m p e ra tu re s . in c re a s e th e th e rm a l e f f i c ie n c y o f th e p la n t . H ig h e r te m p e ra tu re s The p re s s u re a t th e in g re s s o f th e channel was a ls o h ig h e r than t h a t o f th e ECAS s tu d y ; t h is b e in g a p p ro p ria te f o r th e h ig h e r o p e ra tin g te m p e ra tu re s (2 4 ). A fte r th e chambers were s iz e d u s in g th e se o p e ra tin g c o n d it io n s , p a r t ia l \ lo a d o p e ra tio n was s tu d ie d . F u ll Load Design The d ia m e te rs o f th e chambers a re dependent on th e mass flo w r a te o f th e gas th ro u g h th e chamber and th e te rm in a l v e lo c it y o f th e s m a lle s t d r o p le t . In o r d e r to keep these d ia m e te rs re a s o n a b le , i t was nece ssary to use th re e , s e ts o f p re h e a te rs . Each o f these s e ts c o n s is ts o f th re e upper chambers and one lo w e r chamber as shown in F ig u re 1 .1 . p a ra m e te rs -T9 T9 , T1 , Iiiri, and rh. were s p e c if ie d . g b The Chamber le n g th , s la g mass flo w r a t e , and p re s s u re drop th ro u g h , th e c a p i ll a r ie s were th e d e sig n c r i t e r i a w h ile th e s la g te m p e ra tu re s , c a p i ll a r y d ia m e te r and d is tu rb a n c e fre q u e n c y were th e v a r ia b le d e sig n p a ra m e te rs. .I - 34 - The e f f e c t s o f th e o p e ra tin g s la g te m p e ra tu re s on th e d esign c r it e r ia a re shown in F ig u re 4 .1 , F ig u re 4 .2 , and F ig u re 4 .3 . F ig u re 4 .1 was o b ta in e d by a r b i t r a r i l y ch o o sin g a c a p i l l a r y d ia m e te r o f 2mm and th e o p e ra tin g fre q u e n c y a t th e c o rre s p o n d in g ,o p tim u m d is tu rb a n c e " fre q u e n c y . The mass flo w r a te o f th e s la g was o b ta in e d by an energy ba la n ce on th e lo w e r chamber w ith th e h e a t lo s s from th e chamber w a lls assumed n e g lig ib le . I t was a ls o assumed t h a t th e h e a t lo s s from th e p ip in g t h a t tr a n s p o r ts th e s la g from one h e a t t r a n s f e r chamber to a n o th e r was n e g lig ib le ; t h a t i s , T1 c e q u a ls T„ Xjb 4jS and T9 _ e qu als T9 £jS djS The e xh a u st gas. te m p e ra tu re a t th e e x i t o f th e upper exchanger was c a lc u la te d fro m an energy balance f o r the. e n t ir e system and checked to be s u re t h a t i t was h ig h e r than th e dew p o in t o f th e potassium s u lf a t e (a b o u t 1600 K ). D e creasing th e te m p e ra tu re v a r ia t io n o f th e s la g in c re a s e s th e s la g mass flo w r a te re q u ire d and decreases th e ag g re g a te chamber le n g th . (The a g g re g a te le n g th r e fe r s to th e le n g th th e le n g th o f th e lo w e r cham ber). o f one upper chamber p lu s In o rd e r to keep th e le n g th s re a so n a b le w ith o u t th e flo w r a te o f th e s la g becoming e x c e s s iv e , th e t o t a l te m p e ra tu re d iff e r e n c e f o r th e s la g media was chosen a t 270K. S ince th e .s la g becomes v e ry v is c o u s a t lo w e r te m p e ra tu re s , th e p re s s u re drop th ro u g h th e c a p i l l a r i e s a t th e to p o f th e upper chamber is c r i t i c a l . T h e re fo re , th e lo w e s t w o rk in g s la g te m p e ra tu re was. chosen a t 1650K. Though th e p re s s u re drop would be le s s i f a h ig h e r te m p e ra tu re were P ressure Drop (MPas/cm) - 35 - CAPILLARY DIAMETER (mm) 700 1800 19 Slag Tem perature ( K e lv in s ) FIGURE 4 .1 EFFECT OF SLAG TEMPERATURE AND CAPILLARY DIAMETER ON THE PRESSURE DROP THROUGH THE CAPILLARY - 36 - HIGHEST SLAG TEMPERATURE ( K e l v i n s ) — 1900 1920 1940 950 1960 / 1 I8 6 0 260K 900 280K 850' 8001 300% 750 320% 1700 1650J 700 1600 Temperature ( K e lv Lowest S la g SVAC MASS o f SLW T effect f I GORt in s ) B ^ ure 0N fLOVl RATE A ggregate Chamber Length (m e te rs) - 37 - AT = 260K HIGHEST SLAG TEMPERATURE (Kel v in s ) 2.0mm 1600 1650 Lowest Slag Tem perature ( K e lv in s ) FIGURE 4 .3 EFFECT OF SLAG TEMPERATURE ON CHAMBER LENGTH - 38 ch ose n, th e chamber le n g th in c re a s e s r a p id ly above t h i s te m p e ra tu re . The n e x t d e sig n v a r ia b le c o n s id e re d was th e mean c a p i ll a r y d ia m e te r .. F ig u re 4 .4 and F ig u re 4 .5 i l l u s t r a t e th e e f f e c t o f th e c a p i l l a r y d ia m e te r on th e r e s p e c tiv e chamber le n g th s . F ig u re 4 .6 g iv e s th e optimum d is tu rb a n c e fre q u e n c ie s f o r th e upper and lo w e r chamber a t th e v a rio u s c a p i l l a r y d ia m e te rs . c a p i ll a r ie s The p re ssu re drop th ro u g h the and c lo g g in g a g a in become c r i t i c a l . To keep these a t a minimum, th e mean c a p i ll a r y d ia m e te r f o r th e upper chamber was chosen a t 2.2mm. In th e case o f th e lo w e r h e a t exchange chamber, th e s m a lle r c a p i l l a r y d ia m e te rs r e q u ir e h ig h d is tu rb a n c e fre q u e n c ie s because o f th e lo w e r s la g v is c o s it y . Because th e le n g th o f th e lo w e r chamber x 1 ■ v a r ie s by le s s than two m eters a t optimum fre q u e n c y f o r th e c a p i ll a r y d ia m e te rs c o n s id e re d , a la r g e r c a p i l l a r y d ia m e te r o f 2.5mm was s e le c te d . The optimum fre q u e n c y r e fe r s to th e fo rm a tio n o f th e d r o p le ts by th e d ro p .g e n e ra to r.a n d n o t th e d e s ig n o f th e h ea t e xcha nger. The optimum fre q u e n c y f o r j e t d is in t e g r a t io n is n o t n e c e s s a r ily th e b e s t c h o ic e f o r th e o p e ra tin g fre q u e n c y o f th e d e s ig n . U n ifo rm ly s iz e d drops have been produced by fre q u e n c ie s h ig h e r and lo w e r th e n th e optimum d is tu rb a n c e fre q u e n c y . The l i m i t on lo w e r fre q u e n c ie s has been found to be 40% o f optimum b u t no upper l i m i t has been s e t ( 7 ) . t h a t in c re a s in g th e fre q u e n c ie s by 50% s t i l l d r o p le t s . I t was assumed r e s u lt s in u n if o r m ily s iz e d To decrease th e le n g th o f th e upper cham ber, th e o p e ra tin g fre q u e n c y was s e le c te d a t 50% above th e optimum d is tu rb a n c e fre q u e n c y , O MINIMUM FREQUENCY (40* V OPTIMUM FREQUENCY- -150% OPTIMUM FREQUENCY C a p illa r y D iam eter (mm) FIGURE 4 .4 EFFECT OF CAPILLARY DIAMETER AND DISTURBANCE FREQUENCY ON THE UPPER CHAMBER LENGTH Chamber Length (m e te rs ) •MINIMUM FREQUENCY OPTIMUM FREQUENCY' 150% OPTIMUM FREQUENCY C a p illa r y D iam eter (mm) FIGURE 4 .5 EFFECT OF CAPILLARY DIAMETER AND DISTURBANCE FREQUENCY ON THE LOWER CHAMBER LENGTH Frequency ( H e rtz ) ■LOWER CHAMBER ( I UPPER CHAMBER (T = 1920K) = 1650K) 2.0 2.2 C a p illa r y D iam ter (mm) FIGURE 4 .6 OPTIMUM DISTURBANCE FREQUENCIES FOR VARIOUS CAPILLARY DIAMETERS \ I - 42 In th e lo w e r cham ber, th e o p e ra tin g fre q u e n c y was chosen as th e optimum d is tu rb a n c e fre q u e n c y . The d e sig n s p e c if ic a t io n s f o r th e upper and lo w e r chambers and t h e i r r e s p e c tiv e dim en sion s f o r th e SOOOMWt MHD f a c i l i t y p re se n te d in T ab le 4 .1 and T a b le 4 .2 . s tu d ie d a re F ig u re 4 .1 and F ig u re 4 .8 show th e te m p e ra tu re and v e lo c it y p r o f ile s w it h in th e r e s p e c tiv e chambers. The d r o p le ts in th e upper chamber a c c e le r a te f o r about th e f i r s t h a l f o f th e chamber th e n d e c e le ra te in th e bottom h a l f . in c re a s in g v e l o c it y o f th e gas. as i t T h is is due to th e r is e s th ro u g h th e chamber. The s la g is pumped to th e to p o f th e upper chamber by th e p re s s u re from th e lo w e r chamber. Assuming t h a t each upper chamber is fe d by th re e 20cm d ia m e te r s la g l i n e s , th e t o t a l f r i c t i o n lo s s .is on th e o rd e r o f 2 x IO4 p a s c a ls . The head lo s s , assum ing a t o t a l h e ig h t o f 30 m e te rs , 5 is 7 .7 x 10 p a sca ls and th e p re s s u re drop th ro u g h th e c a p i ll a r ie s is 1.1 x 10 p a s c a ls . T h e re fo r e , th e t o t a l p re s s u re re q u ire d , to push th e s la g th ro u g h th e p ip in g and c a p i l l a r i e s p a s c a ls . is a p p ro x im a te ly 9 .0 x IO5 S ince th e p re s s u re d iff e r e n c e between th e upper and lo w e r chambers is 1.09 x 10®, n o .s la g pumps a re r e q u ire d . T r a n s fe r r in g th e s la g fro m th e upper chamber to th e lo w e r is a c h ie v e d by use o f th re e r e s e r v o ir s as shown in one r e s e r v o ir is b e in g f i l l e d by i t s F ig u re 1 .1 . re s p e c tiv e upper h e a t exchange chamber, th e second is b e in g p re s s u riz e d and th e t h i r d in t o th e lo w e r h e a t e xcha nger. W hile is b e in g em ptied In t h i s manner a c o n tin u o u s flo w o f s la g - 43 TABLE 4 .1 DESIGN SPECIFICATIONS FOR 3000 MWt MHD PREHEATER Upper Chamber Number o f Chambers 9 Lower Chamber 3 Gas I n l e t Tem perature 2200K 1200K Gas O u tle t Tem perature 1816K 1800K Slag I n l e t Tem perature 1650K 1920K Slag O u tle t Tem perature 1920K 1650K Gas Mass Flow Rate 150 k g /s e c 375 kg/sec Slag Mass Flow Rate 288 kg /se c 864 kg/sec Chamber P ressure .11 MPas 1 .2 MPas Chamber In n e r D iam eter 6 .6 5 m 5.3 1 m Chamber O u te r D iam eter 8 .2 8 m 6 .9 3 m 16.80 m 4 .3 2 m Mean C a p illa r y D iam eter 2 .2 mm 2 .5 mm O p e ra tin g Frequency 245 H e rtz 411 H e rtz Mean D ro p le t D iam eter 3.0 2 mm 2 .7 0 mm .022 MPas/cm .002 MPas/cm Chamber Length C a p illa r y P ressure Drop - 44 - TABLE 4 .2 INSULATION SPECIFICATIONS FOR HEAT EXCHANGER CHAMBERS Type Upper Chamber Lower Chamber T h ickness Thickness N o rtra n AN-599 .076 m .076 m Johns M a n v ille JM-3000 . 114 m .114 m Johns M a n v ille JM-2800 .114 m .114 m Johns M a n v ille JM-2600 .229 m .114 m Johns M a n v ille JM-2300 .229 m .342 m Johns M a n v ille Cerawool .051 m .051 m I - 45 - MEAN DROPLET VELOCITY GAS TEMPERATURE MEAN SLAG TEMPERATURE Length (m e te rs ) FIGURE 4 .7 VARIATION IN PROPERTIES FROM THE TOP OF THE UPPER CHAMBER V e lo c ity (m /sec) Tem perature ( K e lv in s ) ' - 46 3 .5 MEAN SLAG TEMPERATURE 2 .5 GAS TEMPERATURE 2.0 MEAN DROPLET VELOCITY 1.5 1.0 Length (m e te rs ) FIGURE 4 .8 VARIATION IN PROPERTIES FROM THE TOP OF THE LOWER CHAMBER V e lo c ity (m /sec) Tem perature ( K e lv in s ) 3 .0 - 47 is s u p p lie d to th e lo w e r cham ber. P a r t ia l Load O p e ra tio n I t may be necessary a t tim e s to o p e ra te an MHD f a c i l i t y than f u l l lo a d . a t le s s The o p e ra tin g c h a r a c t e r is t ic s o f an MHD channel a t p a r t ia l lo a d has been s tu d ie d by Rosa ( 2 5 ) . As an example o f how th e p re h e a te r w o uld o p e ra te in such a ca se, a th r e e - q u a r te r lo a d o p e ra tio n was c o n s id e re d . The a i r te m p e ra tu re s in th e lo w e r exchanger a re th e same as in th e f u l l lo a d s it u a t io n , w h ile th e te m p e ra tu re o f th e e xh a u st from th e MHD channel is s l i g h t l y h ig h e r . Was k e p t th e same as in th e f u l l The mass f lo w r a te o f th e s la g lo a d s i t u a t i o n . An energy balance was employed to f in d th e te m p e ra tu re o f th e s la g a t th e bottom o f th e lo w e r chamber. Since th e le n g th o f th e ch a m b e r.is s p e c if ie d , i t was necessary to c o n tr o l th e h e a t t r a n s f e r by c o n t r o ll in g th e d r o p le t d ia m e te r. The c o r r e c t o p e ra tin g fre q u e n c y o f th e drop g e n e ra to r was determ ined by t r i a l and e r r o r u s in g a com puter p r o g r a m " s im ila r to th e one employed in th e f u l l lo a d d e s ig n . The fre q u e n c y was v a r ie d , and thus th e drop, d ia m e te rs , u n t i l th e s p e c ifie d te m p e ra tu re s a t th e bottom o f th e exchanger were reache d. The p ro ce d u re f o r th e upper chamber was much th e same. The e xh a u st gas te m p e ra tu re a t th e e x i t o f th e h e a t exchanger was d e te rm in e d by an energy bala n ce and th e d is tu rb a n c e fre q u e n c y was fo u n d by t r i a l . / - 48 and e r r o r . The r e s u lt s f o r b o th chambers a re p re se n te d in T ab le 4 .3 . In th e lo w e r chamber th e h ig h e r s la g te m p e ra tu re s compensate f o r th e decreased a i r mass flo w r a te and th e mean d r o p le t d ia m e te r and th e d is tu rb a n c e fre q u e n cy a re n e a r ly th e same as in th e f u l l case. lo a d In th e upper chamber th e mean d r o p le t d ia m e te r is s m a lle r and th e d is tu rb a n c e fre q u e n cy is la r g e r than th e f u l l lo a d s it u a t io n . T h is is due m a in ly to th e decreased flo w r a te o f th e gas. O th e r o p e ra tin g lo ads a re a chieved by fre q u e n c y v a r ia t io n in th e same manner as above o r by rem oving one o r two sets., o f th e p re h e a te r systems fro m o n - lin e . For in s ta n c e , h a l f lo a d is o b ta in e d by o p e ra tin g two s e ts o f th e h e a t exchanger systems a t th r e e - q u a r te r lo a d . The o p e ra tin g c h a r a c t e r is t ic s w ould be th e same as in T a b le ,4 .3 e xce p t th e re would be o n ly s ix upper chambers and two lo w e r chambers in o p e r a tio n . - 49 - TABLE 4 .3 OPERATING SPECIFICATIONS FOR 3000 MWt MHD PREHEATER AT 3 /4 LOAD Upper Chamber dumber o f Chambers Lower Chamber 9 3 Gas I n l e t Tem perature 2230K 1200K Gas O u tle t Tem perature 1850K 1800K Slag I n l e t Tem perature 1734K 1935K Slag O u tle t Tem perature 1935K 1734K Gas Mass Flow Rate 113 kg /se c 281 kg /se c Slag Mass Flow Rate 288 k g /se c 864 k g /s e c Chamber P ressure O p e ra tin g Frequency Mean D ro p le t D iam eter C a p illa r y P ressure Drop .110 MPas 433 H e rtz 2 .5 0 mm .010 MPas/cm 1.16 MPas 394 H e rtz 2 .7 4 mm .002 MPas/cm CHAPTER.V SUMMARY The f a l l i n g bed h e a t exchanger has many advantages o v e r th e cored b r ic k h e a t exchanger f o r h ig h te m p e ra tu re d i r e c t f i r e d a p p lic a t io n s . MHD These in c lu d e th e compact s iz e , th e e lim in a t io n o f m assive h ig h te m p e ra tu re v a lv in g , th e u n in te r r u p te d flo w o f th e e xh a u st gas and p re h e a te d a i r , and th e a b i l i t y o p e r a tio n . U t iliz a t io n o f t h is to a d ju s t e a s ily to p a r t ia l lo a d ty p e o f p re h e a te r in a c o r r o s iv e en viro n m e n t such as coal s la g has th e added advantage o f r e q u ir in g p e r io d ic re p la ce m e n t o f o n ly th e d i s t r i b u t o r p la te r a th e r th a n re p la c in g th e e n t ir e bed as w ould be nece ssary w ith th e cored b r ic k exchanger. P r e v io u s ly , the f a l l i n g bed p re h e a te r u s in g l i q u i d s la g as th e h e a t t r a n s f e r media had n o t been c o n s id e re d a v ia b le a lt e r n a t iv e to th e cored b r ic k h e a t exchanger because o f th e la rg e chamber dim ensions t h a t w ould be r e q u ire d . These la r g e chamber s iz e s were due to th e la c k o f c o n tr o l o f th e drop s iz e s and drop s iz e d i s t r i b u t i o n . has shown, a t le a s t c o n c e p tu a lI y , t h a t t h i s problem can be s o lv e d by em ploying v ib r a t io n a to m iz a tio n o f th e l i q u i d s iz e d d r o p le t s . T h is s tu d y to produce u n ifo r m ly The r e s u lt in g h e a t exchangers a re e f f i c i e n t and com pact. The m a jo r problem in h e r e n t w ith t h i s d i s t r i b u t o r p la t e . co nce pt is th e d e sig n o f th e The c re e p and therm al s tre s s a s s o c ia te d w ith a loaded p la te a t e le v a te d te m p e ra tu re s a re m a jo r c o m p lic a tio n s . it W h ile is p ro b a b le t h a t th e f i r s t g e n e ra tio n o f d i r e c t - f i red p re h e a te rs f o r - 51 MHD a p p lic a t io n w i l l b e .o f th e cored b r ic k d e s ig n , w ith adva ncin g h ig h te m p e ra tu re m a te r ia ls te c h n o lo g y th e f a l l i n g bed p re h e a te r w i l l p ro b a b ly become a v ia b le a lt e r n a t i v e . B e fo re f u r t h e r work can be done on th e d e sig n o f a l i q u i d s la g p re h e a te r system , e x p e rim e n ta l s tu d ie s on th e v ib r a t io n a to m iz a tio n o f l i q u i d s la g a re n e ce ssary to e it h e r r e in f o r c e o r a l t e r th e assum ptions used in t h i s s tu d y . , ' There a re many a d d itio n a l a p p lic a tio n s f o r th e l i q u i d hea t exchanger w hich sh o u ld be pursued. d r o p le t By add in g th e e q u a tio n s f o r mass t r a n s f e r , compact c o o lin g tow ers c o u ld be designed u s in g a w a te r to a i r system . O th e r a p p lic a tio n s can be found in coal g a s if ic a t io n o r in any area in v o lv in g c o r r o s iv e li q u i d s o r gases. APPENDIX - 53 APPENDIX I MATERIAL PROPERTIES F o llo w in g are th e p r o p e r t ie s as f u n c t io n s o f te m p e ra tu re f o r a i r , exhaust gas, and coal s la g as used in the design o f th e heat exchanger system. A ll tem p e ra tu re s are in K e l v i n s . A ir ca = 9 67 .+ 9.60 x IO- 2 T +1.29 x IO- 4 T 2- 4 . 37 x IO- 8 T 3 ( j o u l e s / k g - k ) (26) a d P 3 = 1.62 x ! C f 6! - 513 a a ( p a s c a l- s e c ) (26) 2.65 x IO3T3^ ( jo u le s / m - s e c - K ) (I + - P - (27) IO- 1 2 ^ a ) Exhaust Gas Cg = 917.+.031Tg (jo u le s /k g -K ) Pg = 7.46 x IO- 7 Tg - 582 k 9 = .029+2.9 x IO- 4 T g (28) ( p a s c a l- s e c ) (28) + .80 x IO- 8 T 2 ( jo u le s / m - s e c - K ) g Coal Slag Cg = 8 7 1 .+ .180Tg P (jo u le s /k g -K ) = 1.49(10( 1 -47x 1()4/(1-8Ts - 4 6 0 ) - 6 - 5)) (29) (30) (28) / . ■ - 54 The v i s c o s i t y o f th e s l a g . i s f o r c o a ls w i t h a h ig h c a lc iu m c o n te n t and a low s i l i c a c o a l. (a b o u t 35) s i m i l a r t o Montana s u b -b itu m in o u s For b itu m in o u s coal as would b e .fo u n d i n th e e a s te r n U n ite d S tates th e s i l i c a by t e n f o l d . it 's ra tio r a t i o i s around 55 and t h e ' v i s c o s i t y i s in c re a s e d In o r d e r t o use t h i s ty p e o f s la g i n a drop g e n e r a to r , v i s c o s i t y must be lo w ered by th e a d d i t i o n o f CaO. APPENDIX I I F o llo w in g i s an o u t l i n e o f th e computer program used in s i z i n g th e h e a t exchanger chambers. - 56 - O utp ut BIBLIOGRAPHY - 58 BIBLIOGRAPHY 1. J a s i c k i , A . , S a k a lu s 5 E ., K a li n s k i , A . , S iw e k5 A . , and W o jta s z e k 5G ., "The D i f f u s e r and Exchanger as Elements o f MHD- G enerator Coupled w i t h th e T r a d i a t i o n a l U n it o f / 7 2 0 + 2 5 7 / M W e S i x t h I n t e r n a t i o n a l Conference on Magentohydrodynamic E l e c t r i c a l Power G e n e ra tio n 5 1975, v. I 5 p. 91. 2. 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G eneration and Use, Babcock and MONTANA STATE UNIVERSITY LIBRARTFS 3 1762 100 5317 8 N378 P935 cop.2 DATE Prill, Raymond L Design of a high temperature falling bed air preheater for direct coal-fired MHD power generation ... IS S U E D TO /J3 X /