Air pollution control : an economic analysis of a Montana smelter's SO2 emissions by Edward Barry Asmus A thesis submitted to the Graduate Faculty in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY in Agricultural Economics Montana State University © Copyright by Edward Barry Asmus (1971) Abstract: This paper presents a model which is capable of estimating efficient emission control levels for a particular smelter and which can be adapted to other emitters and other pollutants, The focus of the analysis is the development and use of a methodology to empirically estimate the damage costs of sulfur dioxide pollution. The household damage costs are estimated using local weather data in a computer program along with local population and housing data, and the value data from a St. Louis property value study by Ronald Ridker. Agricultural damages from SO2 are found using a methodology to estimate pollution concentration, the absorption rate of the plant, and the duration of fumigation. By combining the estimates of pollution costs with control costs estimated by the Environmental Protection Agency and E. Van Dornick, the total cost equation is written and the minimum point is found which indicates the most efficient level of emission control under the basic assumptions and alternative assumptions using sensitivity analysis. The analysis indicates that zero emission control is optimal for the smelter studied. Although significant damages are estimated, the high costs of control relative to estimated damages would indicate that zero control is socially efficient. 72 906 300 AIR POLLUTION CONTROL: AN ECONOMIC ANALYSIS OF AMONTANA'SMELTER'S Sp EMISSIONS by EDWARD BARRY ASMUS A thesis submitted to the Graduate Faculty in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY in Agricultural Economics MONTANA STATE UNIVERSITY Bozeman, Montana August, 1971 ill ACKNOWLEDGMENTS I want to express my sincere thanks to Professor Richard Stroup for his valuable guidance, detailed suggestions, and encouragement throughout rhe writing of this thesis. By sharing with me his philosophy and approach to economics, he has made this past year a stimulating and rewarding one. Particular thanks are also due to Professor Norman Dudley for his careful reading and useful comments and. to Professor Eugene Sharp, who helped me through the biological aspects ■ •of this paper. I owe a particular debt of gratitude to Professor -Richard J. McConnen, Department Chairman, for his help on this thesis and for the guidance and friendship exhibited during my years in graduate .. school.Also deserving special thanks are Harlen Hames for his help in computer programming, to Ben Wake who is head of Montana's Air Pollution Control Office, to Stan Lane who is manager of the American Smelting and Refining Company, and to fellow graduate students Diane Reklis and Charles Hash. Last but certainly not least, I express a deep.appreciation for my wife Mandy, who had to relinquish countless hours of my time that rightfully belonged to her. Her encouragement during my years of graduate school have been most important.. iv T M L E OF CONTENTS Chapter I. IT. III. ' Page INTRODUCTION............ ................ ..............' I THE LITERATURE ON POLLUTION . . . . . ................ 4 General Literature on Air Pollution .......... . . . . . Economic Literature on Air Pollution.................. The Literature on Plant Injury by .Air Pollutants. . . . 4 7 14 AN ECONOMIC PRESENTATION: DIAGRAMMATICAL AND MATHE­ MATICAL ............................................ .. . ' 20 Diagrammatic. ........... Mathematical.............. .. . . . . . . IV. STUDY AREA— ElUTTERS............ '.............. .. Problem Area................ Plant Description .......... V. 20 ...........22. . . . . . . . . . .... ....... 24 24 26 ESTIMATING THE DAMAGE COSTS OF POLLUTION.................29 Household Damage Costs.................... ' Damage Costs to Agriculture . ............ 29 33 VI. ■' ESTIMATING THE CONTROL COSTS OF POLLUTION . ' '.......... 45 VII. SENSITIVITY OF RESULTS TO PARAMETER CHANGES ............. 50 Comments bn Results . . . . ... .. ... . ............. 56 Implications of Results ........ ....... 58 VIII. SUMMARY M D CONCLUSIONS . . . .. . . . . . Limitations of.Study. . . . . . . . . . Future R e s earch................. ... . . . ... • 61 62 63 APPENDIX A. ' A NARRATriE DESCRIPTION OF THE COMPUTER PROGRAM' ., 66 Listing of Computer Program . ....... . .. . ...... . 78 APPENDIX B . ■ A DESCRIPTION AND LISTING OF PROGRAM TO CALCULATE ■CROSS-WIND DISTANCE . '. . . '. . .' . ... . . . . . 83 V TABIiE OF CONTENTS (continued) Page APPENDIX C. ADJUSTING POLLUTION CONCENTRATION LEVELS........ 88 APPENDIX D. GLOSSARY OF SYMBOLS USED IN THE P R O G R A M ........ 94 LITERATURE CITED ......................... ............... . . . 97 Vi LIST OF TABLES Table Page I RELATIVE SENSITIVITY OF CULTIVATED AND NATIVE PLANTS TO INJURY BY SULFUR DIOXIDE................................. 17 II EMISSION FROM COMBUSTION AND PROCESS OPERATIONS, HELENA, ' EAST HELENA, HELENA VALLEY, MONTANA......................... 25 III IV V VI VII VIII ANNUAL HOUSEHOLD DAMAGE COSTS............ '......... .. 32 AVERAGE ANNUAL HOUSEHOLD DAMAGE COSTS AT. 6 DISCRETE LEVELS OF CONTROL........................................... 32 AVERAGE ANNUAL DAMAGE COSTS TO ALFALFA AND BARLEY FOR YEARS 1965-1969....................... 44 MARKET PRICES- OF ELEMENTAL SULFUR NEEDED TO FORCE CONTROL COSTS TO ZERO GIVEN THREE RATES OF INTEREST USED TO CONVERT CAPITAL COSTS TO ANNUAL COSTS.......... . . ............... ' 46 COST DATA FOR SULFUR EMISSION CONTROL. . . ............... 48 THE DISCRETE CASE CONTROL COSTS ESTIMATED BY EPC AND E . VAN DORNICK ..."..... 53 Appendix- Table A-I A-2 STABILITY CLASS AS A FUNCTION OF NET RADIATION AND WIND SPEED. ■.................... • . .......................... 68 STABILITY CLASS AS A FUNCTION OF SOLAR RADIATION . . . . . . 70 vii LIST OF FIGURES Figure ■ ■ Page 1 System D i a g r a m .............. 19 2 Control Costs, Damage Costs, and Emission Rates.............20 3 Total Costs. . ............. 4 Total Costs................ 21 5 Pollution Concentration Diagram.................. 40 6 Estimating Pollution Concentration and Fumigation Duration . ........................... 21 Appendix Figure A-I Generalized Flow Chart for the Computer Program.......... 77 C-I Spatial Distribution of Sulfation Measurements .......... 90 C-2 Spatial Distribution of Sulfation Measurements (July 1969X 91 C-3 Spatial Distribution of Sulfation Measurements (September 1969) ..................... 52 C-4 An Iso-Error Spatial Distribution of Percentage Differences Between Actual and Predicted Sulfation Measurements ■ (July-November 1969) . ... . . . . ....................... 93. viii ABSTRACT This paper presents a model which is capable of estimating efficient emission control levels for a particular smelter and which can be adapted to other emitters and other pollutants, The focus of the analysis is the.development and use of a methodology to empirically estimate the damage costs of sulfur dioxide pollution.. The household damage costs are estimated using local weather data in a computer program along with local population and housing data, and the value data from a St. Louis property value study by Ronald Ridker. Agricultural damages from SOg are found using a methodology to estimate pollution concentration, the absorption rate of the plant, and the duration of fumigation. By combining the estimates of pollution costs with control costs estimated by the Environmental Protection Agency arid E. Van Dornick, the total cost equation is written and the minimum point is found which indicates the most efficient level of emission control under the basic assumptions and alternative assumptions using' sensitivity analysis. The analysis indicates that zero emission control is optimal for the smelter studied. Although significant damages are estimated, the high costs of control relative to. estimated damages would indicate that zero control is socially efficient. CHAPTER I INTRODUCTION Air, the thin envelope of gases and particles- surrounding the earth, is a resource whose quantity and quality play a significant role in determining man's economic, social, and esthetic well-being. Used as a sewer, the atmosphere has varying capabilities for waste disposal. If pollution emitters discharge their wastes with Iitt.].e 'cost to thems e l v e s t h e quality of the atmosphere will deteriorate. This creates a problem,.that, demands increased attention. In order to minimize.society's problem, both the costs of pollu­ tion control and the cost of pollution damage must be specified. As the following passages note, specifying these costs become a necessary first step in making good pollution control decisions. We must have a description of the damage per unit of each object affected as a function of the intensity of air pollution, all other factors that could cause such " damage being held constant [48,p.15]. In sum, the positive and negative values (costs) associated with external effects on environmental quality are ordinarily difficult to gauge and some can never'be measured with precision. Nevertheless, there are oppor­ tunities for research which should yield information useful for more rational and effective management of environmental quality [26,p.88]. Without benefit-cost calculations, we cannot deter­ mine the desirable amount of abatement [20,p.102]. The process of proceeding from criteria to clean air, which might be termed air management, might be divided into the various steps: I. Determine the [economic] effects of various pollutant concentrations and exposure durations on people, animals, plants,- and property [33 ,p. 214] .- - 2 Everything worthwhile has a. cost.’ Whenever'you think you are getting something for nothing, look again someone, somewhere, somehow is paying for it. .. . . The " task of ecological economics is to figure Out how to restructure the economic- system so that these hidden costs ■ will be brought out into the open, with the ■ultimate aim that no one who benefits from the use of the environment will be able to escape without paying in full [15,p.14]. It is the lack of information (on the costs of. pollu­ tion). that.is the crux of the matter. . . . I think you will agree that there is no hope of estimating the welfare damages of pollution by simply asking people what they would pay to avoid them. I don't think- they .• know [13,pp.40,43]. This, study represents an attempt to. measure some of the individual,. 'property, and agricultural damages from sulfur dioxide pollution in the Helena Valley cf Montana, connect these damage costs with the appropriate costs of control, and by.answering the what and.bow questions discussed in elementary economic textbooks,. indicate how pollution costs could be minimized. 1. "What" emission levels will minimize costs? 2. "How", can resources be combined most efficiently to attain . that level? Sensitivity analysis will then be used to examine the economic, importance of various assumptions, about the -parametric data.- Changing 'the parameter estimates with'in the "reasonable range" of each will indicate ,.potential payoffs-to narrowing that range of-estimates for . ■each parameter by appropriate research, subject to interaction effects between parameter levels.. It will be demonstrated that without -better 3 information on.some of these physical and economic parameters, mistakes will occur, the effects of which will vary from.minor to extremely costly. The level of these costs will depend oh the parameter in question. In this manner', researchers in each area can receive guidance and, in the appropriate instances, support in concrete terms for the contention that a proposed piece of research would be valuable to society. CHAPTER II " THE LITERATURE ON AIR POLLUTION General Literature on Air Pollution Although receiving considerable recent attention, air pollution is an enigma that has plagued man for more than 600 years. Members of the nobility petitioned Edward I concerning coal smoke in London in 1300 A.D. One hundred years later, Henry V passed a regulation restricting the movement of coal into.the London area, particularly to reduce air pollution [55]. A paper written in 1661 entitled, "Fumifugium", [17] caused such public concern that the English Parliament appointed numerous committees to appraise and recommend solutions to the problem. In America, Spanish explorers in the sixteenth century, discovered layers of smoke in the Los .Angeles area emanating from Indian camp­ fires. Although not reaching dangerous proportions until: 1943 [6], inversion layers' have continually plauged the Los. Angeles air basin. Although public awareness was slow in coming, the study of pollution problems and concern for the environment is growing. The American Public Health Association [4] has recently prepared a Guide to the Appraisal and Control of Air Pollution which includes a . general discussion of the effects of air pollution,an estimation of the quantities■of pollutants emitted into the atmosphere, meteoro­ logical aspects, detection■and measurement, and a general appraisal of air pollution problems. 5 The National Air Pollution Control Association's' Abstract Bulletin [39] provides one .survey; of the research being conducted in this field. The. research is categorized into 14 broad subject fields, some of which include: Emission Sources The characteristics of specific classes of emission sources including types, rates, and the industries involved. Control Methods The operating principles, design, operation, and efficiency o.f equipment and methods of removing pollutants. Measurement Methods. ■ The development, testing, and evaluation of pollutant determina­ tion methods and equipment. Effects on Human Health Medical and' epidemiological, studies. Effects on Plants and Livestock. Pollution.effects- on plants and livestock. Effects on Materials .-' Research'on the corrosion and deterioration .of physical materials buildings, and structures.• 6 Economic Aspects • . . Studies that relate and examine pollution damage costs and pollution control costs. Standards and CriteriaRecommended or adopted guides, criteria, and standards for allowable emission limits or pollutant concentrations, air quality, equipment characteristics, and fuels. Other periodical guides to the air pollution literature include Air Pollution Titles [3] , APCA Abstracts [2], and Air Pollution Abstracts [1]. Important periodicals such as Environmental Pollution, The Journal of the Aii Pollution Control Association and Environmental Science and Technology publish an array of papers dealing with air ' pollution. . The Natural Resources Journal and Land Economics specialize in the.economics and sociology of environmental control, while papers on the health aspects of air pollution occasionally appear in the American Journal of Public Health, and the Archives of Environmental Health.. Hagevick [23] has recently written an excellent book on air pollution control. •.After a brief introduction examining the pollu^ tants responsible for the current.situation, he examines the economic, political, and institutional issue's by applying them to a specific airshed. Through case studies of Los. .Angeles and New York City, a I basis is provided for integrating decision-making with the economist's minimum-cost solution (Chapter III of this thesis develops this concept), pointing out the strong as well as the weak decision­ making strategies. Before good decisions can be made, estimates of the total damages attributable to air pollution in the airshed at various possible emission levels must be made. The Report of the Air Conservation Commission resulted in a book entitled. Air Conservation [14]. Authored by 12 leading authorities from many fields of specialization, this book provides a wide ranging view of air pollution, including meteorology,- pollutants and their effects, the need for air conservation, pollution control, and the socio-economic factors that accompany air pollution arid urban develop­ ment. Because of its complexity, the authors outline the broad tasks facing the scientific community, including basic and applied research on pollutant interactions, effects, and control. The task of govern­ ment would be one of supporting the appropriate research/ helping gather the necessary information, enforcing pollution decisions, and educating its citizens to create a broad public understanding of the problem. ■' Economic Literature on Air. Pollution Whenever the welfare of an economic unit (or units) is directly affected by. the activities of another, externalities exist. Air poilu 8 tion represents a classic example of an externality. Because air appears to the emitter as a free resource, it is overused. Overuse reduces efficiency in that receptors suffer more from damages than ' emitters will save, in not having to control their pollution. Overuse affects equity by forcing owners of air rights (unless all rights are owned by emitters) to suffer damages without proper compensation. Various possible solutions to the externality problem are examined by Coase [10] and Mill [20] . The possibilities include emission taxes., payments based on marginal pollution damages, flexible emission stan­ dards, zoned emission standards, prohibition ,of emissions, factor . subsidies, and others. Care must be taken to account for the' addi­ tional and informational costs associated with each proposed solution. When external effects cause a misallocation of production, the goal becomes one of accounting for all the benefits and costs flowing from the economic activity being studiedv. Treatments of benefit-cost analysis and its application to the micro-economic theory.aspects of pollution control can be found in Eckstein [16], Grosse [22] , Harberger [25] ,. Herfindahl and Kneese [27] , Brest and Turvey [46] , Steiner [58] , Wilson and Minnotte [74], Zerbe [77], and Stroup [60]. These papers present the elements of a research strategy for conceptualizing the problem, specifying the relationships and variables necessary for making "changes in control decisions, and applying empirical information to actual case study situations. 9 Prest and Turvey1s paper is perhaps the most comprehensive survey of benefit-cost literature and it does provide an extensive' bibliog­ raphy.' Benefit-cost analysis, these authors note, is a way of setting out the factors which need to be taken into account to make certain economic choices. Questions such as Which' costs and which benefits are to be included in the analysis? How are they to be valued? At what interest rate are they to be discounted? and What a.re the partic­ ular constraints applicable to the analysis? are a few of the'generalprinciples of benefit-cost analysis that are enumerated. 'Wide divergence of opinion-exists over the usefulness of.benefitcost analysis. At one extreme is Hall's statement [24,p.173]: We have begun to grope our way towards a practical concept of economic planning which may prove in a few. years' time to be as revolutionary in its policy implications as was the Keynesian revolution in economics thirty years ago. It also originated, many years ago, with a Cambridge economist: Keynes' contemporary Pigou. • It is the concept of social costs and social benefits. . . . This leads to the revolutionary concept that we can actually . add up the social costs■and benefits, in money terms, by asking what value people would themselves put.on them. . We can then express them as a rate of return on capital, as an ordinary capitalist would, and so determine our investment rationally, from the point of the community as a whole, just as the capitalist can now do from his., private point of view. Another statement indicating an opposing view is by Smithies [56,pp.344-345], which states: The foregoing discussion [on benefit-cost analysis] leads to two major'conclusions: First, judgment plays such an important role in the estimation of benefit-cost ratios ■ 10 that little significance can be attached to the precise numerical results obtained. . . . Second, competition is likely to drive the agencies towards increasingly optimis­ tic estimates; and far from resolving the organizational difficulties, computation of benefit-cost ratios may in fact make them worse. Brest and Turvey [46] take a position between the two extremes, recognizing that even if benefit-cost analysis cannot give right answers, it can play the negative role of screening projects and . rejecting those answers which are less promising. They.argue the case for benefit-cost analysis is strengthened if its limitations are openly recognized and emphasized. Many of the estimates of the damage costs of smoke and air pollu­ tion from the turn of the twentieth century until 1950 can be found in papers by Bennet [7], Flagg [18] , Gibson [19] , Johnson [31,34] , Obermeyer [41], Parsons [43,44,45], Bolleston [50], Shaw and Owens' [53], Simon [54,57] , Mellon Institute ■[63,72]-, Uhlig [75], and the Beaver Committee [21]. Basically, these articles represent rough estimates of. the smoke damages suffered by various cities and countries. Annual smoke damages (1939) to Indianapolis, for example, were estimated to be $15 million [31], while Milwaukee suffered $10 million [34]. Simon [57] estimated the annual smoke damages (1946) to Great Britain to ' be $50 million. S . B. Flagg [18]. added an interesting twist to the 11 damage cost estimates cited by other authors. He viewed smoke in terms of damage to emitters, rather than receptors.. Because smoke indicates inefficiency in fuel consumption, half-burnt coal, and dividends that should be distributed to stockholders, he called for an improved design of furnaces and mechanical equipment. The incentives for improving "control equipment" would come from a strict enforcement of statutes controlling emissions. Research in the last■decade on the damage costs of air pollution would include Mchelson and Tourin [35,36,37], Ridker [48], Ridker and Henning [49], Aiiderson and Crocker [5], Wilson and Minnotue [74], and Stroup [50]. Michelson and Tourin [37] used questionnaires to estimate the added household expenditures of cleaning resulting from•suspended ' particulates. Although interesting, their .study suffers from the problems associated with questionnaire techniques and the difficult question of how to evaluate the damages of pollution which were not paid for in the form of extra cleaning, laundry, painting, etc. Ridker, in his book, Economic Costs of Air Pollution [48], used a number of approaches in an attempt to measure air pollution damages.. In an effort to link the incidence of disease with air pollution, he examined correlations between polluted areas and premature deaths, treatment, and absenteeism. The costs would be . the value of medical treatment and foregone income. ' His study 12 revealed, no conclusive evidence using this method. Another approach was one similar to Michelson and Tourin's questionnaire determining . soiling costs. By comparing the laundry, dry cleaning, and other costs associated with pollution of different cities, Ridker hoped to capture an amount people actually did pay for living in a polluted area. Here again, the results were indeterminate. Ridker's third approach, and. the one whose results are used in this thesis, investi­ gated the differences in property values resulting from polluted " versus nonpolluted;s i t u a t i o n s U s i n g a cross-section study of St. Louis property values, Ridker was able to explain 92 percent of the variation in property values with a regression equation. Using sound econometric analysis, he showed that St. Louis residents were 2 willing to pay about $245 more for a. house for each .25 mgSO^/lQO cm / day avoided. IIere, ..a single market price reflects what people were willing to pay to get away from pollution where they lived. Anderson and Crocker's study of air pollution.and residential real estate values also proceeds on the basis that a‘ substantial portion of air pollution damages to artifacts and organisms is capitalized negatively into the value of lcind. They first develop 'a qualitative- model to determine residential property values which include charac­ teristics of both households and properties as explanatory, variables.Basically, they used the postulates of Lancaster's development of consumer behavior theory. Using log linear forms estimated by 13 Ordinary Least Squares, instead of a linear fit which appeared to be best for Ridker, they showed that marginal property values were reduced from $300 to $700 per property because of pollution.. I Anderson and Crocker used particulates as an explanatory variable, whereas Ridker reported unsatisfactory results using particulates, and they were critical of Ridker's use of 1960 Census Data coupled with pollution data gathered in 1963 and 1964. This, they argued, could result in biased estimates. Wilson and Minnotte1s study, of soiling caused by stationary sources of particulate emissions in the Washington,.-D. C., area [74] uses benefit-cost analysis to make.pollution control recommendations By combining a diffusion model with Michelson's data on soiling damages, they calculate a benefit figure, for each control increment. Costs of control are then subtracted from the calculated benefits, yielding a net benefit calculation for every control level. They conclude that benefit-cost analysis can be used in making emission control decisions, and with better input data can be used to estab­ lish emission levels for all types of pollutants. They warn that their model can be used only for illustrative purposes, as it deals with only one type, of pollutant and one geographic area. I 3 Marginal damages refer to an !additional 10 mg/m /day of sus­ pended particulates plus an additional .1 mg SO^/lOO cm2/day 0f sulfation. 14 Stroup develops a model [60] which is capable of locating optimal control levels for any number of air pollution sources under the juris­ diction of a control authority. The model is then used to analyze various control strategies, detailing the.strengths and weaknesses of each. By applying the model to a particular copper smelter, it is demonstrated that several million dollars in annual damages can b e . avoided at optimal control strategies-.. Many developments in this paper are based on Stroup's methodology. The Literature on Plant Injury by Air Pollutants Scientific attention was directed to the problem of pollutant injury to plants as far back as 1871, when Stockhardt [59] wrote about smoke damage to German forests and whe n .Cameron [9] examined the damage to vegetation in London. Research on sulfur dioxide damage to plants in this country began at the turn of,the century [64], with Swain [62] reviewing the outstanding periodic developments. Another good review of the effects of pollution damage to plants, is Crocker [12] who reviewed much of the early work on sulfur dioxide and other pollutants by the Boyce Thompson. Institute. A publication by the National Research Council of Canada [40] examines much of the sulfur dioxide research in connection with smelter injury to plants. Also, an excellent comprehensive review of the.entire problem of air pollution effects on vegetation is given by Thomas [64] and updated by him in 1961 [65] . 15 It has been established in the literature [42,66] that sulfur dioxide injury to vegetation follows the relationship (C - C0)t = K. (2-1) In this equation, C is the concentration of sulfur dioxide (parts per. million— ppm) which can cause traces of injury to alfalfa in t hours, and and K are constants. Under conditions of maximum- sensitivity, Cq was found to be 0.33 and K equalled 0.92. That is, given a concentration of 1.25 ppm, incipient markings can be found on alfalfa in one hour. Notice that a concentration of 0.33 ppm can be endured indefinitely without causing injury. Thomas and Hill [67] generalized the preceding equation, calcu­ lating equations for various amounts of leaf destruction at maximum sensitivity for alfalfa as .follows: t(C - 0.24) = 0.94 Incipient Injury t(C - 1.4) = 2.1 50% Leaf Destruction t(C - 2.6) = 3.2 100%.Leaf Destruction (2-2) From these equations, concentration levels of 1.2, 3.5, and 5.8 ppm would, in one hour, destroy traces, half, or all of the leaf ■ area of the crop, respectively. The different species of plants vary considerably in their susceptibility to injury by sulfur dioxide. .0'Gara-worked .out factors for about 300 species and varieties of plants, giving their sensitivity 16 relative to alfalfa as unity.' These have been published and. some are listed in Table I [66]. Environmental factors have a significant effect on predisposing vegetation to SO 9 injury [32,52,66]. Relative humidity is perhaps the most important' external factor affecting a plant's susceptibility, High relative humidity favors the opening of the. stomata and this allows a high absorption rate of the plant. Soil moisture is another important environmental factor, causing plants to become extremely resistant when moisture approaches the wilting point. VJhen the soil moisture is very low, the leaf stomata tend to close in order to guard against excess transpiration losses. When moisture is adequate for growth, however, .variations within wide limits do not appreciably affect susceptibility. The importance of light intensity and its relation to the response of a plant has been assessed differently by various investigators. Swain [62] considers it to be a major factor, while Holmes [29] and Setterstrom [52] believe it to be of minor importance. Considering atmospheric temperature, Swain [61] concludes that a plant is more resistant to sulfur dioxide at temperatures of 5 0C and below, with little,-variation above 5°C, Wells [73] agrees with this basic conclusion. Brisley and Jones [8], Hill and Thomas [28] , Holmes, Franklin, and Gould [29], National Research Council of Canada [40], and Thomas and Hendricks [66] found that reduction in.yield is proportional to 17 TABLE I . RELATIVE-SENSITIVITY OF CULTIVATED AND NATIVE PLANTS TO. INJURY BY SULFUR DIOXIDE (Determined by O'Gara). Sensitive________ :_____ Intermediate____ :_____ ■ Resistant ____ ■ ________ Cultivated Plants ___ ' -_____ More probable factors based on later experience. O I CO to Io- CO b/ 1.6a 1.6 1.6 1.6 1.6 1.7 1.7 1.7 1.8 1.9 2.0 2.1 2.1 2.1 2.1 2.1 2.2 2.2 2.2 2.3 LO a/ Gladiolus(1.1-4. 0)b 2. Ga Horse-radish 2.6 2.6 Sweet cherry Canna 2.6 Rose 2 . 8 -4.3 3.0 Potato (Irish) 3.2 Castcrbean 3.3 Maple 3.3 Boxelder 3.3 Wisteria 3.5 Mock orange 3.5 Honeysuckle 3.7 Hibiscus 3.8 Virginia creeper 3.8 Onion 4.0 Lilac 4.0. Corn Cucumber 4.2 5.2 Gourd Chrysanthemum -7.3 5.8 Snowball 6.4 2.3 .Celery 6.5-6.9' 2.3 •Citrus 2.3 Cantaloupe 7.7 2.3 (muskmelon) 7.8 2.3 Arbor vitae 12.0 2.4 Currant blossom 14.0 2.4 Live oak 15.0 2.4 Privet 2.5 C o m silks and .2.5 21.0 tassels 25.0 Apple blossoms 87.0 Apple buds Factors of relative resistance compared with alfalfa as unity. Alfalfa I. pa Cauliflower Barley 1.0 Parsley 1.0 Sugar Beet Endive 1.0 Sweet William Cotton Four o'clock 1.1 Aster Cosmos 1.1 Tomato (1.3-1. 7)b Rhubarb 1.1 Eggplant Sweet pea 1.1 Parsnip 1.2 Apple Radish 1.2 Catalpa Verbena . 1.2 Cabbage Lettuce 1.2 Hollyhock Sweet potato 1,2 Peas Spinach . Bean 1.1--1.5 Gooseberry 1.3 Zinnia (1.2)b Broccoli Brussels sprouts 1.3 Marigold 1.3 Hydrangea Pumpkin 1.3 Leek Table beet 1.3 Begonia. Oats Bachelor's-button 1.4 Rye (l.O)b 1.4 Grape Clover ■ Squash(I.1-1.4)b 1.4 Linden. 1.5 . Peach Carrot 1.5 Apricot Swiss chard 1.5. Kale Turnip 1.5 Nasturtium Wheat Elm Birch Iris ' Plum Poplar • • 18 the amount of leaf area destroyed. The following equation may•then be used when the constants have been determined. Y = a - bX where: (2-3) Y = the yield; X = the percentage leaf area destroyed; a = a constant approximately 100 percent: and b = the slopes The question frequently arises as to how far conclusions drawn from the results of experimental fumigations under cabinets may be applied to crop plants growing under natural field conditions in a smelter zone. Katz [32,p.2458] found that "the results demonstrated conclusively that the response of crop plants to sulfur dioxide under natural conditions is not essentially different from that found in . fumigation'experiments under cabinets." The issue at hand is not just one of specifying effects, but actually determining whether these effects have any economic impor- ' tance. Regardless of the biochemical mechanisms involved, or the striking damage appearing on colored photographsthe essence.of the analysis must be an estimate of the magnitude of losses' suffered by society. Chapter III,-presents a methodology and Chapters V and VI use it to empirically, investigate :the damages■from sulfur dioxide pollution by a.specific smelter. , CHAPTER III AN ECONOMIC PRESENTATION: Dirty air is expensive. sive. DIAGRAMMATICAL AND MATHEMATICAL Unfortunately, clean air is also expen­ The resulting trade-off is one between the size of control costs and the size of pollution damage costs. These costs are the focus of the following economic analysis and tneir subsequent measure­ ment the key to sound decisions of control. The monev and prices used to measure these costs are useful as a unit of account and a common denominator. The focus of interest is not on dollars and prices themselves, but rather their role as a yard­ stick in measuring the problems, opportunities, and choices or people. The price system in a market economy is a system of social accounting which (in the absence of externalities) keeps track of all the benefits and costs of an economic activity. Diagrammatic A simplified view of the physical problem is shown in Figure I, and its resultant economic aspects in Figures 2, 3, and 4. Pollution (emissions) vented to the atmosphere (transport mechanism) yield levels of ambient air (air quality) which cause some degree of economic losses (damages) as shown in Figure I. Transport Mechanism Emissions ▼ Figure I. 20 If society wants a certain standard of air quality maintained, such as point A in Figure 2, control costs of CC^ must be incurred. Given CC^ of control, quantity costs. of emissions would cause DC^ damage Damage costs can then be thought of as a function of emissions (or an air quality standard). By combining the southeast and southwest quadrants of Figure 2, the damage and control costs of various levels of emissions can be represented by Figure 3. Adding damage costs to control costs yields a total cost curve for varying emission levels pictured in Figure 4. TC^ and E^ represent minimum total cost at an optimum level of emissions. At this point, E^, the marginal costs of control equal the marginal costs of pollution damage. Air Quality Standard Figure 2. 21 Total Costs Damage Costs + Control Costs Control Cos ts Damage Costs Emissions Figure 3. Figure 4. 22 Mathematical Economic analysis indicates that marginal damage costs of pollu­ tion must equal the marginal costs of pollution control in order to achieve minimum cost quality objectives. Specifying both as a func­ tion of emissions, DCi = d (E) (3-1) and CC1 = c. (E) ] . 3 where: (3-2) th. , DC^ = cost of the i type of pollution damage, i = I, n CCj= cost of the type of control, j = 1, m; and E = emissions. The total cost to society, TC, become the sum of equations (3-1) and (3-2) : TC = DC . 1 + DC 2 + ... + DC + CC1 .+ CCn + ... n I 2 CC ■ = m (3-3) d (E) + d (E) + ... + d (E) + C1 (E) + c„(E) + .. . + Cm (E) ■ I 2 ■ n x. ' 2 111 Minimizing TC with respect to emissions produces the minimum cost to society and the optimum air quality objectives.'The necessary first-order, conditions are ' 23 --■^ E) = (E) + ... + dn (E) + C1 (E)- + . + c (E) = O in (3-4). and the sufficient second-order conditions are 2 d TCE > 0 (3-5) To satisfy the necessary conditions., the summation of the. marginal costs of pollution control and damages must equal zero, or likewise, that the marginal costs of pollution damages equal the marginal costs of pollution.control. .That is. Zdi (E) ■ (P) dE 4 dE L ± I dE^ so that •I i -C (E) = I — a=— g (3-6) The. foi lowing chapters represent an empirical attempt to combine the control costs of pollution with pollution damage costs to.enable decision makers to make marginal evaluations of emission control. ■ CHAPTER IV STUDY AREA—rEMITTERS ■ Problem Area The Helena Valley in Montana has an air pollution problem (Table II) Located between the Big Belt Mountains on the north and east and the main chain of the continental divide on the west and south, the. valley houses approximately 30,006 residents .who are subjected to various ■ degrees of pollution. In particular...the■American Smelting and Refining Company operates a custom lead smelter, emitting- quantities of sulfur dioxide ,to the- atmosphererwhich substantially exceed the Airibient. Air Quality.Standards' set for Montana and are in excess of the most .lenient air standards set anywhere in the nation [3.8 ,p. 3] . Government studies [38] indicate that concentrations of sulftir dioxide in excess of 15 ppm ,(parts' per million) have been recorded near the plant, causing considerable damage to commercial .crops and other vegetation.. Basically, sulfur dioxide is a. colorless gas that can.be.tasted at concentration levels of .3 ppm to I ppm and can.cause pungent, irri­ tating odors at concentration levels above 3 p p m . Once in the atmosphere, sulfur dioxide is partly converted to sulfur'trioxide or to sulfuric acid, by photochemical or catalytic processes.. .In the ■■ presence of moisture,'sulfur trioxide is immediately converted to . , sulfuric acid. - ' '• . . . ■ . . . . - ' The'rate -at which sulfur dioxide oxidizes in the atmosphere depends■on factors such as residence time, amount of ., '. TABLE II. EMISSION FROM COMBUSTION M D PROCESS OPERATIONS, HELENA, EAST HELENA, HELENA VALLEY / M O N T M A (Tons Per Day Averaged Over the Year) .* Pollutant Sulfur Dioxide TotalEmissions 198.03 58.65 Carbon Monoxide Source and Amount of Emissions Industrial and Commercial ■Domestic Fuel Process Fuel Gas Wastes Emissions Oil Gas Wastes Coal ' Oil 1.68 .001 .001 .2 .001 .001 .005 0.5 5.26 .07 .001 Neg .03 Oxides of Nitrogen (NO3) 5.51 1.40 .001 .30 .06 22.72 290.17 5,70 .03 .09, Particulate .TOTAL . .010 .001 2.0 .001 .001 .001 Neg .002 .001 Neg Unknown 16.0 .02 0.21 ■O.lO 54.0 0.15 .11 4.7 0.35 .38 .22 2.6 0.55 .03 .31 1.8 .30 .26 *Source: Montana State Department of Health', Divisioh of Air Pollution Control and Industrial Hygience, "A Study of Air Pollution in the Helena-East Helena Area," October 1965-October 1968, p. 10. 25 Hydrocarbons 196.0 Vehicular Diesel Gas Fuel 26 . moisture present, and the intensity and duration of sunlight. The presence of catalytic material, hydrocarbons, nitrogen oxides, and sorptive and alkaline materials also affect the oxidation process [70]. Plane Description The American Smelting and defining Company's smelter was built in 1885 and has vented to the atmosphere all by-product sulfur dioxide since that time. A brief description of the plant's operation is : included here. All incoming shipnenus of lead concentrates are sampled and deter­ mined for sulfur content. After being mixed with zinc residues, lime­ stone and siliceous ere, the concentrate is pelletized to give a charge conforming to metallurgical requirements. After the pelletized charge is delivered to the sintering plant, it. is mixed with return sinter and fed to one of four Dv/ight Lloyd's sintering machines where the sulfur content is reduced through oxidation and the charge is agglom­ erated into a product known as sinter. The sinter is then screened for removal of fines, which are in turn crushed and used as return sinter for blending with more fresh charge coming from the charge preparation system. Once delivered to the blast furnace, the gases from the sinter are conducted through flues to the electrostatic precipitator plant (ESP) where the dust in gases is. largely removed and the cleaned gases still containing sulfur dioxides are discharged up a 400-foot stack. 27 ■ Finished sinter .and coke are- then charged in one'of two blast furnaces where they are melted and reacted to form lead bullion and slag. The molten products flow but of the furnace through a patented tapper and are separated by gravity in a brick-lined settler. The slag overflows the settler into slag pots for delivery co Anaconda's zinc fuming plant while the lead bullion is tapped into other pots for transfer'to the dressing plant. ,.Dust from the gases of the blast furnace is filtered through large woolen bags in the baghouse. Cleaned gases are then vented to the atmosphere through three baghouse stacks."* The two sources of air pollution.produced by the American Smelting and Refining C o m p a n y t h e n , are the effluent gases from the ESP plant (DSps of total) and the.gases from the baghouse (2% of total) . The other source of SO^ pollution in the area is the Anaconda Company's zinc 'fuming plane. This, slag-treating plant processes the waste slag of the American Smelting and Refining Company to make a zinc cxide product. The process involves charging molten slag to a fuming furnace where a 2 2 0 0 °E temperature causes the zinc and lead to I ■ Plant visit to the American Smelting and Refinery Company in East Helena, Montana on October 15, 1969... Attending .were: Stanley Lane, Plant Manager; K . W. Nelson,- Director, Department of Environ­ mental Science; Carl Thompson, Public .Relations; Ben Wake, Director, Division of Air Pollution Control, Montana; members of the National Air Pollution Control Association., 28 fume off and form zinc oxide and lead oxide. Furnace gases are then cooled before passing into a large radiant cooler. Zinc oxide and lead oxide in the cooled gases are then removed by a fabric filter equipped with Dacron bags before the gases still containing sulfur■ dioxide are discharged into the atmosphere. The gases from these five stacks, 100 feet high, account for approximately 2 percent of the SO^ in the area. CHAPTER VESTIMATING THE DAMAGE COSTS OF POLLUTION Household Damage Costs The area surrounding the stack was divided into 540 sectors corre­ sponding to each of the 36 wind directions, each sector I mile deep, out to 15 miles discant from the polluting stack (15 x 36 .= 540) . The number of houses in each sector were found by using Highway Survey maps, which indicate the location of each house, and the'1970 U. S. Census of Population, for locating the number of bouses in Helena. I The additions to sulfation loadings in each sector were calculated using local weather data (three hourly observations) and a dispersion equation. Additions to pollution concentration (sulfation) resulting from stack emissions were calculated every 3 hours and summed on an 2 annual basis for the years 1965-1969. The basic dispersion equation" 3 used in the computer model^ follows the form..: Chi = cxp[.5 (HZaz)1 2I (5-1) ■ z 1 Bob Keck,,Highway Planning Survey Superintendent, and his crew of engineers- deserve.speed al thanks for their efforts.■ 2 •Mr. Bruce Turner, Air Pollution Control Office, Durham,.North Carolina, communicated this equation to. me in a telephone'conversation November 5, 1970 (see {71,p.38]). 3 See- Appendix A for description of computer model. 30 where: Chi = pollution concentration;. Q = emissions (2,772 grams at zero control) ; X = distance from stack in meters; U = wind speed in meters per second; o = vertical dispersion coefficient, a function of downwind distance and atmospheric stability; and H = effective stack height in meters. The computer model's predicted sulfation measurements were tested by comparing them with lead peroxide candle sulfation measurements taken by the Federal Government 4 in a study conducted June through November 1969, in East Helena, Montana. The lead peroxide candle is a widely used technique used for determining a sulfation rate. Although it provides no indication of short-term fluctuations it can give reasonable indications of sulfur dioxide concentrations for periods o f ' one month duration [55,p.103]. By comparing the'lead peroxide candles to the computer-model's predictions, it was found the model underpredicted sulfation concentra­ tions by about. 15 percent (arithmetic mean) from I to 8 . miles distance from the stack.^ Government-measurements of.sulfation did not.exceed .8 miles from the polluting stack. . —-T-— Title of project: Helena Valley, Montana ,. Area Environmental Pollution Study. Principal investigators: ,The National Air Pollution .Control Administration and the Montana Department, of■Health. 5 See Appendix: C for a discussion of how these values were'deter­ mined. 31 The damage costs of pollution to households were found, then, using a dispersion model to estimate pollution concentration (sulfation) in each sector, the relative decreases in property value which people were willing to pay for increased sulfation as determined by Ridker's study, G where calculated damages to households were found by Ridker to be directly proportional to pollution concentration, and the number of houses in each sector. ■Sn. interest rate of 6 percent was used to convert present value to annual costs. Damage costs, then, follow the form: DC = XiHiRB ' where: X± (5-2) ; the increment of pollution concentration from the large stack (annual average) in the i*-*1 sector with no control; . H , = the number of dwellings in the It*1 sector; i R = the annual damage■per unit of pollution concentration per dwelling (Ridker)U and E = the proportion of generated pollutants which are emitted.. Table III and IV present.the results. See Chapner II, where it was noted, that Ridker found that peopl| did pay approximately $245 more for a house for each ;25 mgSO /100 cm / day (annual, average sulfation) avoided in St. Louis in I960.. /7The use of Ridker's value data is virtually a necessity,as no other data, comprehensive- in scope of damages and considering SO^ ' specifically, is currently available. . 32 TABIE III. ANNUAL HOUSEHOLD DAMAGE COSTS.(100% Emissions). Year - Household Damage Cos ts a■ „ ''b .' 1965 31,922 22,302 1966 30 ,,772 19,929 1967 33,720 24,260 1968 33,570 19,946 1969 .32,600 21,200 ■ . . ■ ^Calculated costs stemming from a sulfation rate adjusted to empirical data . Figure C--4 in Appendix C indicates the adjustments. Ij Calculated costs stemming from an unadjusted model. TABIE IV. AVERAGE ANNUAL HOUSEHOLD DAMAGE COSTS AT 6 DISCRETE LEVELS OF. CONTROL (100% Emissions). Control Level •Percent ■ 45 78. 88 90 93 99.4 Household Damage. Costs Dollars ■ 17,220. 4,270 - 3,046 • 2,321 1,347 , 1.86 Calculated, costs stemming from a sulfation rate adjusted to empirical data. 'Figure Cr-4 in Appendix. C indicates the adjustments. 33 Damage ..Costs to Agriculture ■ The following discussion describes the procedures by which damages (yield reduction) to alfalfa and barley is calculated. . A: basic oat­ line is included to acquaint the reader with the order of terms which follow» Basic Outline I. Yield reduction is a function of leaf damage. A. Leaf damage is a function 'of the absorption, rate of the ■plant, A; concentration level of pollutant, C; and duration Lof fumigation, T . a. A is a function, of light, intensity,'; soil moisture, temperature, and relative humidity. b. C is calculated using a dispersion equation that includes, emissions from the .stack: and effective stack height as constants. Variables include . horizontal and vertical dispersion coefficients ■ which depend on stability conditions and downwind distance from the source; windspeed and a cross-wind . distance variable y which depends on changes in wind •• direction. •c. T. is a variable time interval over %hlch C- is . constant. 34 Recalling from Chapter II that reduction in yield is proportional to the amount of leaf'area destroyed. YR = f (LD) (5-3) where: . ■ YR = yield reduction; LD = leaf damage. . An equation was formulated to predict leaf damage from the work of Thomas and Hill (67 ,p.299-300) which follows the form: TCA ~ 610 - 155T 14.0 + 15.4T where: (5-4) LD - leaf damage; T = time (duration of fumigation); C = concentration level of pollutant; and A - absorption rate of the plant. Procedures to estimate the absorption rate of the plant, the concentra­ tion level of p o l l u t a n t a n d the duration of fumigation are discussed in turn. Absorption Rate of the Plant The absorption rate' of the plant ■depends on a number of environ­ mental factors, including light.intensity, soil moisture, temperature, and relative humidity. The model formulated in this study assumed- damage to plants would only take place in daylight, hours, adequate 35 soil moisture, and. daytime temperatures above 40°F. When these condi­ tions are favorable for damage, relative humidity becomes the crucial variable of plant susceptibility to sulfur dioxide. O 1Gara [42] recognized the importance of relative humidity by specifying a ' quadratic equation which gave the relative sensitivity of plants at different air humidifies. Hendricks and Hill [6 8 ]. TABLE IV. This equation was confirmed by Thomas, Table IV gives solutions to the equation.* RELATIVE SENSITIVITY OF PLANTS TO INJURY BY SULFUR DIOXIDF. AT DIFFERENT ATMOSPHERIC RELATIVE. HUMIDITIES.* Relative Hunudity Percent Percent 100 100 80 60 50 40 30 89 77 69 54 31 18 13 • 20 10 0 *Source: .. Relative Sensitivity ■ 10 O 1Garaf P. J . , "Relative Sensitivity of Cultivated and • Native Plants to Injury by Sulfur Dioxide," Magii, et al. ,(Eds.) , Air Pollution Handbook, 1956.. . . The variable A, then, becomes a measure of the absorptive rate per unit (dry) weight of the leaves and is mathematically independent of the duration and intensity of fumigation. The data collected by.. Thomas and Hill revealed that A ranged from a minimum of 30 to.a 36 maximum of 650 in their different daylight experiments-. The dimensions.■ of A were so chosen that when duration;of fumigation was expressed in hours and concentration of SO^ in the air by parts per million by volume, the absorption was given as parts per million of the dry leaf' tissue [67,p.302]. Using 100 percent relative humidity as repre­ senting maximum sensitivity of plants' to injury,-' the absorption rate. . was estimated by multiplying relative'humidity by 650, i.e., a relative humidity of 100 percent' = '1 .0 - Dcllution Concentration and Fumigation 'Duration* 7 Calculating■pollution concentration (C) and fumigation .duration (T) for a receptor field in a given wind direction required.a "disper­ sion model Which would reflect varying pollution concentration^ with changes•in wind direction. As wind.changed from its initial direction, the center of'the plume would meve away from the receiving field and the field would suffer, smaller, concentration levels of.pollution., The . 7 dispersion model used was of the form: C - — ■&. TTO- O ■ eyp[-.-5(y/c )2]exp;[-.5 (H/a )2] U Y . (5-5) 6 From. U . .S. Department,of Health ,-'Education and Welfare,. Public Health Service, Workbook'of Atmospheric. Dispersion Estimates,•Pub. No. 999-AP-26, Revised 1969, p. 7. 37 where: C = concentration level of pollutant; Q = emissions; ir = 3.14159; a ^ = horizontal dispersion coefficient, a function of downwind distance and stability; .#2 = vertical dispersion coefficient, a function of downwind distance and stability; U =-: wind speed; H = effective stack height; and' y = cross-wind distance (distance.in meters from plume centerline) . Cross-wind distance, y, reflects the distance of plirme centerline from a receptor field, where increasing, distance results in. a decreasing pollution concentration. '■By calculating y and relating it to a time interval, pollution concentration and fumigation duration could then be estimated. A computer program was written.(see Appendix B) .which Would esti­ mate cross-wind distance y resulting 'from changes in wind direction. By using the formula for arc length, AL - (5-6) 180 where: AL = arc length in meters; TT = 3.14159; r '= distance in meters from pollution emitter to receptor field; and 38 0 = the difference between original wind direction in degrees and the new wind direction in degrees.. the arc length (cross-wind distance = y) could be found for a change in wind direction (6 °). ■ Assume, for example, the receptor field to be I ltdIe from the polluting stack and in the 90° wind direction. If the wind blew in the 90° direction continuously, the given field would receive centerline plume concentrations. The cross-wind distance variable y in the dispersion model would, be assigned, the Valua zero and a pollution concentration would be calculated using the simplified dispersion model c = y z e^ 1- 5 tozoZ'21 . <5-7> If, however, the field was fumigated half the time by a wind in the 95° direction, che field would suffer less than center plume line concentration levels, and equation (5-6) used in Appendix B would, be ■ used to calculate y for use in dispersion equation (5-5). ■ A Rustrak recorder was used to provide continuous wind direction data which was collected in Bozeman by the meteorologists, at Montana State University. Employing sensitive graph paper moving an inch an . hour, the recorder indicates .wind direction every 2 seconds'. Wind speed in mph.was averaged for each hour so that a constant windspeed was thus assumed for.each of.the 1,800 wind directions for that 39 hour. Each hour of data was then partitioned using the arbitrary rule of minutes it takes for the wind to move one-half mile. Wind direction data of wind speeds equalling 5 miles per hour, for example, were partitioned into 6 -minuce intervals (the time it takes for wind moving at that velocity to move one-half mile); 6 miles per hour into 5-minute intervals; and so on to wind speeds' of 12 miles per hour into 2.5-minute intervals. If the wind speed was 5 miles per hour, the hour's wind direction data were partitioned into 10 intervals with ISO wind directions in each interval. averaged for each interval. Wind .direction was then 8 * Ar: array of the above averages was then obtained for each wind speed representing wind direction in degrees. For example, 280°, 278°, 272° ... for a wind speed of 5 miles per hour indicated a wind direc­ tion of 280° for 6 minutes, 278° for 6 minutes,. 272° for 6 minutes, and so on for the remainder of the data for that hour. Using these wind direction data for each wind speed in a computer program (see Appendix B) produced estimates of the cross-wind distance, y, for each of the time intervals - Pollution concentration was then calculated for that dWind speed of less than 4 miles per hour and greater than 12 miles per hour were omitted. Basically, wind speeds of less than 4. miles per hour exhibited such variability that a receptor field wouli seldom receive fumigation durations sufficient enough to cause plant, damage. Wind speeds of greater than- 12 miles per hour, on the other hand, would not produce high-enough levels.of pollution concentration to cause plant injury. -Exceptions will be discussed .belovj. 40 particular wind speed for each 1 -mile sector from the polluting stack. This was then repeated for each of three 1-mile segments. Pollution concentration and fumigation duration was then plotted, for each of a number of combinations of miles from the polluting stack, stability conditions, and wind speed. Figure 5 illustrates the procedure. Pollution Concentration (ppm) Time (Hours) Figure 5. Pollution Concentration Given a Wind Speed of 5 Miles per Hour, a Downwind Distance of 3 Miles from the Source, and an Unstable Stability Condition. -41 Notice first in Figure I that for a wind speed of 5 mph the distance between any two points represents 6 minutes. In this example, 30 points were calculated and plotted, each representing a pollution concentration of 6 minutes duration and in total a. period of 3 hours. Each graph was examined and average pollution concentra­ tions during specific periods of time were estimated visually. In this example, a pollution concentration of one ppm was chosen for the 2-hour innerval from .5 to 2.5 hours. Since research has indicated that a plant can withstand .3 to .5.ppm indefinitely without sustaining any leaf.damage,, concentration levels of pollutant between zero and 0.5 hours and between 2.5 and 3 hours were treated as- zero in any calculations of leaf damage. ■ A minimum of 5 and a maximum of 10 graphs 9 . were plotted for each combination of wind speed, distance from the polluting stack, and stability condition, from which average pollution concentration C for each T was estimated from each graphi Estimates of pollution concen- Recall that each pollution concentration C was calculated using a different cross-wind distance variable y and that each y was the result of wind direction averaged for a specific interval depending on wind speed. Wind speeds of 12 mph, for example, required direction averages for 72 intervals for a 3-hour period, each interval 2.5 minutes duration. Approximately 350 intervals were averaged for each wind speed, yielding enough.data for.five 3-hour graphs at wind speeds of 12 mph.and.ten 3-hour graphs for wind speeds of 5 mph. The writer recognizes the limited data plotted and suggests refinements and mechanization for future work. 42 tration and fumigation duration ranged from an average pollution con­ centration for the entire 3-hour period to three or four average pollution concentrations, each with fumigation durations whose total was 3 hours. Figure 6 presents another illustration of the discussion. Pollution Concentration (ppm) -1.7 Time (Hours) Figure 6 . Estimating Pollution Concentration and Fumigation Duration. This data, for example, was plotted, visually inspected and esti­ mated for pollution concentrations C of 1.2, 0.9, and 1.7 ppm each of I hour duration. Combining each C and its T with an absorption rate of the plant A, leaf damage was calculated for each hour of the 3-hour period. Total leaf damage for each graph representing a 3-hour period was then calculated, and by adding the leaf damages for all calculated 43 under the same conditions and dividing by the number of 3-hour periods, a mean (average) leaf damage was found and used to calculate yield reduction for each set of conditions. Please note that the graphs were averaged visually and therefore no claim is made for a completely accu­ rate prediction of leaf damage. If a computer routine had been devised, slightly different results might have been produced. Calculating Yield Reduction The following equations were then used to predict yield reduction as a percentage of total crop yield by using leaf damages calculated above. Since alfalfa does not exhibit a stage of growth effect [28,66], equation (5-3) becomes, for all stages of growth Y = 100 - .302X where: ' (5-8) Y = percent of total yield; X = percentage leaf damage (i.e., 10% = X = 10). For barley, which does suffer greater damages with increasing ■ growth, the following coefficients were used to estimate, loss in yield [8 ] . Y = 100 - .OOX 1 st - 6 th week Y = 100 - .2 OX 7th - 9th week Y = 100 - .35X 1 0 th - 14th week . (5-9) 44 The average annual yield of alfalfa and barley in each sector, assuming no pollution, was determined using data supplied by the Helena Valley Irrigation Project. Alfalfa was assumed to yield 2 tons per acre at $23.50 a ton, and barley was assumed to produce 40 bushels an acre at 85 cents a bushel. Each fumigation, coupled with the right environmental facnots, would reduce the total yield attributable to that sector as discussed above. Table V depicts the average annual damages to alfalfa and barley for all sectors given emission levels ranging from 100 percent to 50 percent. TABLE V. AVERAGE ANNUAL DAMAGE COSTS TO ALFALFA AND BARLEY.FOR'YEARS' 1965-1969. Emission Level Percent 100 95 90 80 70 60 50 Alfalfa Barley ---Dol] ars---- Total■ 494 392 273 161 105 59 14 2,500 ■. 2,052 '1,717 1,391 1,139 801 505 2,006 • 1,660 1,444 .1 ,220 . 1,034 . 742 491 . ■ ■ A curve was fitted .to the cost estimates of varying emission levels using least squares regression analysis which took the form: ADC = .0203 + ..081E - .105E where: 2 + .046SE 3 ADC = agricultural damage costs; E = emission levels (100% = .E = 1.0) ■ XO ADC is in millions of dollars. 10 CHAPTER VI ESTIMATING THE CONTROL COSTS OF POLLUTION. Attempts have been made to control sulfur oxide emissions for the • last 150 years [51]. High costs of control as well as the fact that the costs of not controlling emissions are mainly external to the emitter have generated little volition on the part of emitters to purchase control equipment- When econ'omic conditions or pollution control regulations do warrant control, sulfur dioxide has been recovered as sulfuric acid or elemental sulfur. Recently a cheaper way to convert polluting oxides to elemental sulfur was' announced by E . Van Dornick, whose process would rid the ■ ■ I gas of 90 percent of its sulfur content at a cost of $5 per ton. ■ The process is now being tested and preliminary results are now becoming available. In correspondence with Van Dornick, he estimated the . capital cost of the process plant for the American Smelting and Refining Company in East Helena to be $11 million and the operating costs to be $5 to $6 per ton of elemental sulfur product. Unfortunately for potential users of this process, the price of elemental sulfur has fallen from $38 a ton in 1968 to under $10 a ton presently. 2 ■A description of the sulfur dioxide pollution reduction process by E . Van Dornick can be obtained•by writing the Chemical Technology . Corporation,'9400 Whitmore Street, El Monte, CA .97131. 2 ■ Wall Street.Journal, November 9, 1970, p. 18. 46 A planned 60 percent increase in flue gas concentration by ASSR would reduce the capital costs of the process plant to $7 to $8 million. 3 Assuming, then, a capital cost of $8 million, operating costs of $5.50 per ton, and the production of 42,000 tons of elemental sulfur per year. Table VI reveals the market price of sulfur which would have to be received for a breakeven control cost. TABLE VI. Interest Rate Pet. MARKET PRICES OF ELEMENTAL SULFUR NEEDED.TO FORCE CONTROL COSTS TC ZERO GIVEN THREE RATES OF INTEREST USED TO CONVERT CAPITAL COSTS TO ANNUAL COSTS. Capital Operating Total Cost Cost Cost -- Millions of Dollars— 9? Market Price Contro] of Sulfur" Costs ---- Dollars-- • .30 .22 1.03 24.52 0.00 6 . .48 .23 ■ .71 16.88 0.00 3 .24 .23 .47 Ili 19 0.00 .10 The process plant is based on a 90+ percent SO^ removal and a 95+ percent elemental sulfur recovery. . Essentially all of the particu­ lates can be conveniently removed either by the process equipment alone or with nominal auxilliary facilities. The process is designed speci- . fically for a 90+ percent SO^ .removal and is a 95+ percent operation. Van Dornick explains that the process could not be operated at lower levels of recovery or SO^ removal.3 3 . This information 'was communicated to me by E . Van Dornick in a letter dated September "8 , 1970. 47 Minimum cost control- methods of more conventional design for the ASKR lead smelter under consideration were furnished by the Environ­ mental Protection Agency.^ Cost data for control of a Dxvight Lloyd sintering machine were given that would result in the lowest cost per ton of sulfur removed for the control level specified. Basic assumptions used to derive the capital and operating costs for various levels of control efficiency are explained as follows. Investment and operating costs were taken from the Systems Study for Control of Emissions: Primary Nonferrous Smelting industry, .by. Arthur G. McKee and Company, June 1969. 5 A 15-year straight-line depreciation, with interest costs at 10 percent, and administration costs of 3 percent:, were used for calculating annual capital costs. A credit of $5.35 per ton of recovered acid was assigned wherever applicable. ■ At the 99.4 percent control level,' the smelter's operator is assumed to purchase reactive.lime for $4 per ton rather than invest in a lime kiln and produce the material. This■assumption is valid, because of the small quantity of lime needed to treat the final I per­ cent of waste sulfur dioxide. T"~ The cost data are listed in Table VTI.- ■ ” _ Mr. Frank Bunyard,■Environmental Protection Agency, Air Pollution Control Office, Division of Economic Effects', Research, communicated the necessary information to me in a letter dated February 11, 1971. 4 ^Available from the clearinghouse for Federal Scientific and Tech­ nical Information, U. S , Department of Commerce, Springfield, Virginia. 48 TABLE VII. CQST DATA FOR SULFUR EMISSION CONTROL.* Control Efficiency I. 45 ■: 78 Percent : 88 : 93 99.4 Capital Cost ($ million) a. .b . c. • d. Limestone grinder Lime kiln Scrubber & waste treatment■ Contact acid plant Total'Capital Cost 2. : : .7 1 .1 2.9 ■' 1.1 1 .8 . .1.2 a. b. c. 1.3 . 8.4 • 3.4 9.7 1 .6 8 ; 1.94 1.37 (.80) 1.60 ( .80) ' .Annual capital costs Operating. & maintenance costs By-product credits .36': Total Operating Costs *Source: 4.1 2.3 Annual Operating Cost ($ million) 8.4 ' 1.2 .46 .83 .46 ■ .82 ■ 1.05. .82 1.28 1.88 2.25 ' ■ 2.75 . Mr. Frank Bunyard corrarmnicated the information in this table to me in a letter date February 11, 197i. 49 Least•squares regression was used to fit a curve to the five data points for the various emission levels which took the form: . CC = -2.97 + 6.311* e (~E) where: C C = control costs; E = emissions. A linear fit was suggested by Mr. Bunyard for control efficiencies between 0 and 45 percent control. ship took the form: CC = -2.22E - I. The fit for this linear relation' CHAPTER VII SENSITIVITY OF RESULTS TO PARAMETER CHANGES • In the search for ways to improve the misallocation [of resourcesJ resulting from external effects, care must always be exercised to take into account any additional costs or penalties associated with the remedy. It is quite .possible, for example, to set standards designed to reduce external effects so strict that there will be a loss to national product rather than a gain [26 ,p.9]. Estimaues of the social costs of pollution and control, although difficult, must be made for rational control policies. These esti­ mates are reviewed, here for purposes of analysis, enabling authorities to.make better decisions because of increased information. Under the assumption that Ridker's value data do not fully cap- ' ture the disbenefits associated with SO , the average annual household 2 ■ i damage costs of $33,000 listed in Table ill were, doubled. average annual agricultural damage costs of $2,500 Adding (Table V), total ^Recall that damages per household were estimated using Ridker's St. Louis study where people■there paid $245 more for a house for each .25 mg SO 3 /IOO cm^/day avoided. At 6 percent interest, $245 represents about $1.20 per month per household. Ridker's value data estimate only household damages. Since damages occur to people and property, the somewhat arbitrary assumption was made to double the damages calculated by using Ridker's numbers to capture total damages. 51 pollution costs were estimated to be $68,500.. Total annual costs, including control, agriculture, and household, can. then be summarized ' by TAC. .= -2.22E + 2.22 - .0203 + .C81E - .105E2 + .046SE3 + .066E where: TAC = total annual costs; E = emissions (100% = 1.0); ' -2.22E + 2.22 = control costs ; -.0203 + .081E - .105E 2 + .0468E ■; 3 = agricultural damage costs; .066E = household damage costsi All cost figures are in millions of 1971 dollars. If the socially desirable amounts of pollution control are assumed to be the least costly combination of means available, the level of pollution sought,should be the point where the cost of a further reduction would just exceed the benefits, i Given the damage costs' estimated in this study and the control possibilities estimated by the Environmental Protection.Agency, there is no level of The linear control cost function is included here where an interest rate of 10 percent was used to convert capital costs to annual costs. Least squares regression analysis was used to fit a curve ■to the five "discrete control costs estimated by NAPCA.. taking the- form C = -2.97 + 6 ..311*Exp(-E) . C represents costs and'E represents emission levels. V \ 52 control which can presently be justified on efficiency grounds. Although substantial damages have been estimated, the total cost ... function i s ■minimized at 100 percent emission levels and a total cost of $63,500. Table VIII shows the pollution and control costs for seven discrete points of control and for changes in the basic assumptions. Ar. asterisk (*) indicates the control levels necessary to minimize costs given various assumptions about the data. The first line in each set of assumptions indicate a zero level of control. by EPC Lines 2 through 6 indicate, the control costs estimated for five discrete control levels.. Line 7 gives the control cost estimates by E. Van Dornick (EVD) for. the 90 percent control, level. The basic assumption, B , indicates a doubling of household damage costs estimated using Ridker's value data. Ten, 6 and 3 percent indi­ cate the rate of interest used to convert capital costs to annual costs. Control cost estimates for E . Van Do m i c k 's 90 percent control method .are estimated as follows. The basic capital cost is converted to annual costs by the appropriate interest rate, The plant is capable o f 'producing 42,000 tons of elemental sulfur per year at an operating cost of $5.50 per ton.. Assuming the market price of sulfur to be. $9 per ton, $378,000 are then subtracted from the plant's total annual operating and capital costs to yield the annual control cost estimates.■ Assumptions I, 2, and 3 indicate that total costs would be minimized at 0 percent control levels■given the basic assumption B •. ; ■ 53 TABLE VIII. Change in Assumptions THE DISCRETE CASE CONTROL COSTS' ESTIMATED BY EPC AND E. VAN DOBNICK (EVD). (All Costs are in Annual Terms) Agricultural Control Control Damage Household Emissions Level Costs Costs Costs Pet. — Millions of Dollars-— I. R- (10%) 0 1.0 .55 .22 45 78 88 93 99.4 90 .12 .07 .006 EVD 2. B .1 (6 %) 0 1.0 45 78 .55 .22 EVD 3. B .12 88 .07 .006 93 99.4 90 .1 (3%) .55 .22 EVD 4. 20B (10%) - 45' 78 .12 88 .07 .006 .1 . 93 99.4 90 1.0 .55 .22 .12 .07 .006 EVD 0 1.0 .1 0 45 78 88 93 99.4 90 .0025 0.00 1.00 .0002 .0000 1.51 2.29 3.09 3.72 ..652 • .0000 .0000 .0000 .0000 0.00 .0025 .928 1.418 2.126 2.754 3.332 .332 .0002 .0000 .0000 .0 0 0 0 ' .0000 .0000 0.00 .0025 .874 1.349 2.003 2.502 3..041 .092 .0002 .0000 .0000 .0000 0.00 1.00 1.51 2.29 3.09 3.72 .652 ' ; . ooo'c .0000 .0025 .0002 .0000 .0000 .0000 .0000 .0000 .0660 .0172 ,.0043 .0030 .0013 .0001 .0023. .0660 .0172 ,0043 .0030 .0013 .0001 .0023 Total Costs .0685* 1.0172 I.,5143 2.2930 . 3.0913 3.7201 .6543 .0685* ■' .9452 I, 4223 2.1290 2.7513 3.3321 .3343 .0660 . .0685*. .0172' .8912 . .0043 1,3533 .0030 2.0060 . .0013 2.5033 3.0411 .0001 .0943. .0023 ■1.3200 .3440 .0860 .0600 .0260 .0025 .0460 (table■continued) 1.3225 I .3440 1.5960 2.3500 3.1160 .6980* .54 TABLE VIII. (continued) Agricultural. Change in Control Control Damage Household Total Assumptions .Emissions Level Costs .Costs Costs Costs Pet. —-- — -Million's of Dollars-----— 5. 20B (6 %) o 45 78 1.0 .55 .22 .12 • .07 .006 EVD ,' ' .1 6 . 2OB.. (3%) 1.0 .55 45 78 .1 (7%) EVD 8 . 7B (?%) EVD ' % 9.3 99.4 90 1.0 0 .1 90 i.o .1 . 88 .07 .006 7. B 93 99.4 SO 0 ,22 ' .12 EVD 88 ■ 0 90 0.00 .0025 0.928 I..418 2.126 2.754 3.332 .332 .0002 .0000 .0000 .0000 .0000 .0000 0.00 .0025 0.874 1.349 2.003 2,502 3.041 .0.92 0.00 ..413 0.00 .413 9. B .(7%) EVD ■ '1.0 0 .1 90 0.00 .056 .0002 .0000 .0000 .0000 .0000 •.0000 .0025 .0000 1.3200 1.3200 .3440 1.2180 .0860 1,4350 .0600 2.0630 . .0260 ‘ 2.7800 .0025 ■3.0735 .1380* .0460 1.3200 .3440 .0860 .0600 .0260 .0025 .0460 .0660 .0023 1.3200 .1.2720 ■1.5040 2.1860 2 *5280 . 3.3345 . .378* . .0685* .4153 .0000 .4620 ..0161 ..4645, ■ .4291* .0025 .0000 .0660 .0023 .0685 .0583* .0025 55 and for .interest rates of 10, 6 , and 3 percent. The market price of elemental sulfur would have to be $23,00, $15.42, and $9.72 for assumptions I, 2, and 3, respectively, before EVD would become a minimum cost solution. Multiplying household damage costs by 20 (20B) as shown by assump­ tions 4, 5, and 6 , indicates that minimum cost solutions would involve zero control for the cost figures estimated by EPC. Excluding Van Dornick and using the lowest discrete control level,destimated by EPC, the basic estimate of damage costs would have to be increased by a factor of 20 before control could be justified on efficiency grounds. If damages were 203, EVD becomes the minimum cost solution at a control level of 90 percent. Assumptions 7 and 8 are included to indicate the viability of the EVD control process as a minimum cost means of control. interest rate of 7 percent 4 3 Using an . and a market price of elemental sulfur of $9 , the conclusions are as follows. Given the basic assumption,^ The money rate of interest was determined by checking the corporation bond market in the July 23, 1971 Wall Street Journal for the American Smelting and Re fining Company. Showing a coupon value (contract rate of interest) of 4 5/8, a $1,000 bond was selling for $705, maturing in 17 years. By examining the. present value of $1,000 due in 17 years and the present value of annuity of $42.63 received at, the .end. of each year >■a .money rate of interest of I ■percent was determined. ^Price of a long ton of elemental sulfur f.o-b-. Alberta, Canada July 23, 1971. 56 B , no control can be justified as shown in assumption 7. Assump­ tion 8 indicates that the basic estimate of damages would have to be increased by a factor of 7 before EVD minimizes costs. Assumption 9, indicates the market price of sulfur would have to be approximately $17.50 before EVD becomes the minimum cost solution. Comments on Results Conclusions other than those reported in this study would be warranted given the following possibilities.■ First, damage costs may be significantly underestimated. Second, control methods less costly . than those reported may become available. '■ And finally, the alterna­ tive of plant shutdown as a control alternative is a possible solution. Imperfect information about the pollutant’s effect on health, vegetation, and materials, a lack of certainty in the diffusion model, and the possibility of an increased effect (synergism) by a chemical recombination once,airborne, could all affect estimates of damage costs. The damage costs, calculated in this study are probably under­ estimates . Care was taken to adjust annual sulfation rates by a conserva­ tive factor of 10 percent, and though damages could occur at annual 2 sulfation levels below .49 mg SO^/lOO, cm /day, all damages below this level were excluded. ' v • ‘ • : 57 This was consistent with Ridker's study of using .49 mg as a background level. In addition, the harmful effects of intermittent high level concentrations of sulfur dioxide were not estimated. Estimated damages to agriculture were also minimum. Although the relevant research indicated differences of opinion regarding damages to alfalfa and barley during night hours, damages were estimated only. during daylight hours. Abnormal weather conditions causing heavy con­ centration levels of pollution and/or extended fumigation durations in relatively small areas could cause significant leaf damages. Although these conditions probably .inflict greater, damages than those estimated, the frequency of occurrence was not known and hence not evaluated. An indication of the underestimate of crop damages is the fact that over $14,000 were paid for crop damages in 1967, 1968, and 1969 by AS SR while chis study indicated damages of $7,2 3‘5 for the comparable 3-year period. Means of conurol less costly than those estimated by the Environ­ mental Protection Agency (EPC) and E . Van Domick could also alter the conclusions in this study. A representative of EPC indicated, however, that."the one control scheme that would result in the lowest cost per ton of sulfur removed for the specific control level" was used, and further, "in a practical sense, a smelter operator would choose the least-cost strategy for a given control level similar to the approach 58 I am presenting you ." 5 Concerning the EVD control process, many engineering evaluations indicate that it is superior in simplicity and cost compared to other existing methods recovering elemental sulfur from flue gas. / 6 Another possibility would be the alternative of plant shutdown. If the basic assumptions in this study are correct then shutdown would appear to be socially efficient if expected annual rent losses to land, labor, and capital were less than $68,500. An estimate of these losses would be. difficult and is beyond the scope of this study. ■ ‘ Implications of the Results Damages of $68,500 are certainly not inconsequential, especially when seven-tenths of these damages occur within I 1/2 miles of the stack. If people do have the right to clean, air, equity would require that they be compensated by the amount they are damaged. Remuneration, for example, might include direct payments from AS SR to the receptors.' A payment schedule appears to be an attractive alternative, both on equity and incentive grounds. First, damaged parties are compensated j^r. Frank Bunyard communicated this•information to me in a letter dated February 11, 1971. . ^ ’Scientific Evaluation, Engineering and Technological Appraisal of the Van Dornick Sulfur Dioxide Reduction Process," Dr. Walter W. Walker, P.E., F.A.I.C.,729 No. Richey Blvd.,. Tucson, Arizona and Joseph H.; Herz, Chief Technologist, California Portland Cement Co.,' Colton, California. 59 according to the costs they incur... And second, the current trend of dogmatic' insistence.by polluters that control mechanisms are too expensive could be reversed by creating an incentive to seek control methods which would cost less than damages paid. If the damages to receptors are known and payments enforced, the plant would continue to emit only as long as the costs, from additional emissions axe less than.that which it would have to pay to reduce emissions. Until cheaper control possibilities- are: discovered or future, research indicates damages-presently unaccounted for, the gain i n • efficiency by better social control decisions at this plant appear to be negligible. Further research on the significant parameters in this study as they apply to this plant of the American.Smelting and Refining Company, [except on the possibility of shutdown) would, not appear to be warranted. Given that receptor damages depend in part on factory location and wind patterns,' it appears that this plant is suitably located. If tne prevailing winds, for example, were toward the city,of Helena 95 percent of the time, instead of the current 4 to 6 percent, the model indicated household damages of $4,423,000 and an emission control level of 90+ percent. The model was also, applied to the ASSR copper smelter in Tacoma, Washington;' (emissions only double), where household damage costs totaled $8 million and the minimum cost-solution called for 90+.percent 60 emission control. Plant location, then, as well as emissions and . control costs affect control decisions. CHAPTER VIII SUMMARY AND CONCLUSIONS A 1969 governmental study of the ASSR lead smelter in East Helena, Montana recommended that a substantial reduction in sulfur oxj.de was necessary and. in keeping with the. varying activities and economic interests of the area. Empirical guidance for determining the efficiency of a "substantial reduction" has been lacking due. in part to the lack of information on pollution costs. A computer program was written, to refine and extend a methodology developed by Stroup to estimate household damage costs, while agr cultural damage costs were estimated.using -a -new methodology for calculating yi.eld loss due to S0„ fumigations. 'Combining these pollution costs with control costs estimated by EPC and Van Dornick, a total cost equation was estimated and minimized to indicate efficient levels of emission control. The household damage costs were calculated using local weather ■ data in a computer program written to predict annual sulfation rates, population and housing data, and the value data from a St. Louis property value study by Ridker.. Agricultural damage costs were estimated by combining a dispersion model to predict pollution con­ centration , and a study by Thomas indicating the absorption rate of the plant, with estimates of fumigation duration using wind direction data. 62 The basic total cost estimate was minimized at zero control, where efficiency indicated that even if estimated damages were increased by a factor of 20 using EPC estimates or a factor of 7 using Van Dornick estimates, uncontrolled emissions were still optimal.' Substantial pollution damages were estimated, however, arid if people do have the right to clean air, remuneration seems equitable. In summary, the model presented in this paper was an attempt to give an operational answer to the hard policy questions facing decision makers. The model can be adapted to other situations: as it was in Tacoma, or it can be adjusted for new numbers when new research like Ridker's becomes available. Limitations of Study The lack of empirical research similar to the study by Ridker makes air pollution control decisions difficult. Reasons for assuming his numbers low as applied to Montana would include the increased awareness of the environment, since his I960 study and the possibility that people who live in Montana have greater preferences for clean air. Differing supply conditions for housing of each environmental quality, between Helena and St. Louis, also could affect the applicability of Ridker's figures in Helena. Any new research made available and yielding new numbers, however, could easily be incorporated into the model. 63 The methodology developed to estimate agricultural damages is lengthy and improvements in estimates could be made by refining and mechanizing it. In addition, the dispersion model used to estimate agricultural damages was not empirically tested, although it is widely published as being a reasonable representation of the real world. Future Research Perhaps the most difficult of all control alternatives to evaluate, and one not considered in this paper, is plant shutdown. Loss of rents to the emitter as well as to the employees and suppliers in the area of the emitter basically comprise the social costs of this strategy In view of the- conclusions of this study, such an evaluation might be deemed worthy. If emission control is considered necessary, further study of the feasibility of the E . Van Dornick control process would be warranted. . In this case the price of -elemental sulfur and the costs involved of increasing the concentration of sulfur dioxide in the flue gas to reduce capital costs become important determining factors. Further information on the damage costs of SO^ to people could be ■ acquired by medical studies examining East Helena resident health costs with comparable residents of nonpolluted areas. .The damages estimated in this paper could be partially validated by conducting a survey in the area asking people how. much they would be ( . 64. willing to pay to have pollution reduced. For example, the people in East Helena could be asked, "would you like pollution to be reduced-by X percent (excluding cost of living increases) or would you rather receive a payment of Y percent with present uncontrolled emissions?" An analysis could be made indicating the importance of plant location to damage costs and therefore to air pollution control decisions. 65 APPENDICES APPENDIX AA NARRATIVE:DESCRIPTION OF THE COMPUTER PROGRAM v The following verbal, presentation' of the computer.program . including a flow chart and a listing of the computer program describes the information necessary 'to calculate sulfation pollution in each sector and the damages it causes to households and crops. The numbers of the steps that follow are the same as those assigned to corresponding parts of the'flow'chart and to the card numbers in the computer program. Please refer to Appendix D 'for definitions of the symbols used. Steps I 18.— Define the format, dimension, and integer statements. Steps 19 - 38.— Read, dimension, integer, store data and initialize variables. Steps 39 - 40;— Read the three hourly weather data•cards for the annum. Step,41.-— When windspread equals zero, wind direction is.also zero. The decision was made to read the next weather data card and.' double the concentrations in each sector for that wind direction using a multiplier (MULT). ■ ' :■ ■ Steps 42 - 63.— In order to calculate concentration levels of pollution using the dispersion models discussed in Chapter IV, sta­ bility classifications must be estimated. Basically, these stability classifications for each of the eight-'daily WBAN Hourly Surface • 67 Observations are based on the work by Dr. F. Pasquill of the British Meteorological Office. Net radiation and wind speed are the primary factors affecting stability conditions near the ground. On a cloudless day, incoming radiation (insolation) is dependent upon solar altitude, which is in turn a function of time of day and time of year. course, decreases incoming and outgoing radiation. Cloud cover,.of In this system, insolation is estimated by solar altitude and modified for existing conditions of total cloud cover and cloud ceiling height. Night estimates of outgoing radiation, are made by considering cloud cover. The stability classes are as follows: Stability Class I 2 3 4 5 6 7 . Extremely unstable Unstable • ■ Slightly unstable Neutral Slightly stable Stable Extremely stable Appendix Table A-I gives the stability class as a function of net radiation and wind speed. The net radiation index ranges from 4, highest positive net radiation directed toward the ground, to -2 , the highest negative net radiation directed away from the earth. , Stable conditions occur with high negative net radiation and light wind speeds neutral conditions with cloudy skies or high wind speeds, and unstable conditions with high positive net radiation and low wind speed. 68 STABILITY CLASS•AS A FUNCTION OF NET RADIATION . AND WIND SPEED. 4 -' Net -Radiatlon Index 3 ' ' 2 /• I O H APPENDIX TABLE A-I. I I 2 3 4 6 7 2, 3 I 2 2 3 ■4 6 7 4, 5 I 2 3 4 4 '5 6 6 2 2 3 4 4 5 6 ■ 7 , ■ 2 2 3 4 4 O Wind Speed Knots' . „1 ■■ 4 5 8, 9 2 3■ 3 4 4 10 3 •3 4 4 4 ' 4 5' . 11 3 3 4 4 4 • 4 >12 3 4 ' 4 4 4 4 ■ 4 '4 " , ■ -2 ' 4 5 69 Stability classes were determined using the following scheme [69]: 1. If the total cloud cover is 10/10 and the ceiling is less than 7,000 feet, use net radiation index equal to zero (whether, day or night) ; . 2. For nighttime (between sunrise and sunset): ■ a. If total cloud cover _< 4/10, use. net radiation index equal to - 2 . b. If total cloud cover > 4 / 1 0 , use net radiation index equal to -I. . 3. For daytime-.-steps 1-15 in computer subroutine: a. Determine the insolation class number as a function of solar altitude^ from .Appendix Table A-2. b. If total cloud cover <_ 5/10, use the net radiation index in Appendix Table A-I corresponding to the insolation class number. c. If cloud cover > 5/10, modify the. insolation class number for the fo lowing conditions: 1) Ceiling <7,000 feet, subtract,2. 2) Ceiling >_ 7,000 feet, but < 16,000 feet, subtract I. . 3) Total cloud dover equal 10/10, subtract.I. . 4) If modified insolation class number is. less than I, let it equal I. 5) Use the net radiation index in Appendix Table A-I .corresponding to the modified insolation class number. Step 64.— Converts wind speed given in knots to meters, where wind speed in knot's times' .514.8 equals wind speed in meters. •Solar altitude was determined by using the Smithsonian Meteoro­ logical Tables, Sixth revised.'edition, pp. 495-497. > 70 APPENDIX TABLE A-2. Solar Altitude (a) Insolation Insolation Class Number 60° < a Strong 4 35° < a _< 60° Moderate 3 15° < a <_ 35° Slight 2 a < 15° Weak I 71 Step 65.— Determines effective stack height in meters. .Effective stack height equals actual stack height plus the rise of the plume. The rise of the plume above the stack was determined using Hollands equation: Vd • (1.5 + 2.63 x 10 H = where: T - T ■d — — p (A-I) H = rise of plume above stack; •V s = stack gas exit velocity, m sec -I ; d = inside stack diameter (16 feet = 4.876 meters); U = wind speed, m sec -I ; p = atmospheric pressure, mb (26 inches = 881 mbs); T = stack gas temperature, °K (130°F.=.328°K); T = air temperature, 0K (43°F = 2790K). V .= VolHne ^ 1 9 M 0 0 _ c f m s Area 201 where: = 4.85'm sec"1' (A-2) Area = r^ .=■ 3.14(8^) = 201. Therefore, AH = 4 ‘85 (- - - --[1.5 + 2.68 x 10~3 (881) (328 ~R279)4.876) U uZO 76.23/U . (A-3) Step 6 6 .— Q represents emissions from the polluting stack of 2,772 grams per second at zero control; Step 67.— Permits examination of a.3-hour period- (DAYS = 1/8) up ■to a year (DAYS - 365).. ' 72 Steps 68 - 73.-r-Calculate the pollution concentration Chi and store this concentration in the appropriate wind direction, K r and for each of 15 miles distant from the stack, M. Chi was doubled using the multiplier if wind speed was zero. ■ Step 74.-— The model assumed agricultural damages to occur only within 3 miles of the stack. Step 75.— Unless the stability conditions were calculated to be either 2 of 3, pollution concentrations were not sufficient to inflict agricultural damages, and another data card was read. Step 76.— Agricultural damages only occur from May 25 to August 25 Step 77.— The model assumed agricultural damages to occur only with wind speeds between 2 and 10 knots. Step 78.— The model assumed agricultural damages to occur only when temperature ■was greater than 40°F. Steps"79 - 80.— The model assumed agricultural damages to occur only during daylight hours. Steps 81 - 82.— This step calculates the absorption rate of the plant. Since relative humidity was hot punched on the data cards, it was calculated using the dewpoint vapor pressure divided by the temperature vapor pressure. This calculation (relative humidity) was then multiplied b y 650 to indicate the sensitiveness of the plant [67,p.302] . hh-f;; ■ . ■ 73 Steps 83 - 9 6 .— These steps are used to estimate the agricultural damage.costs (yield losses) to alfalfa and barley. Percent yield loss was calculated previously and entered as data in this main program. Each card contains percent yield loss for alfalfa and barley given an absorption rate of the' plant, a particular wind speed, the relevant day and month, a particular stability conditions, and the distance of the field from the stack. After calculating the absorption rate of the plant, steps 81 - 82, the absorption rate (11 = 1,7) is partitioned into seven categories, steps 83 - 90. If the calculated absorption rate falls between 600 and 650, Il was set equal to I. Likewise, a rate between 500 and 600 forced Il = 2, between 500 and 550, 1 1 = 3 , and so on to Il = 7, where the absorption rate falls somewhere between 300 and 350. An absorption rate below 300 was not sufficient to generate leaf damages given the, pollution concentration levels. Steps 91 - 93.— Set 12 = I if the day and month was•between Iiay 25 and July I; 12 = 2 if the date is between July 2 and July 21.; 12 =■ 3 if the date is between July 21 and August 25. Damage to alfalfa was assumed to occur throughout the summer as mentioned in Chapter V. Barley suffered increasing damages, with no damage the first six weeks (1 2 = I), increasing damage the next three weeks (12 = 2 ), and maximum damage (12 = 3). 74 Steps 94 - 96.— -Set T 3 = I if windspeed was between .2 and 5 knots, 13 = 2 if windspeed was between 5 and 8 knots, and 13 = 3 if windspeed was either g, 9, or 10 knots. . Step 97.— Set 1.5 = I for fields I mile distant from the stack, 15 = 2 for 2 miles, and 15 = 3 for 3 miles. Step 98.— Set. 16 .= I if the crop was alfalfa and 16 = 2 if the crop was barley. Steps 99 - 102.--Multiplies the potential yield of each crop (16) in the appropriate sector (wind direction^ K, and distance from stack 15) by the percent yield IoSs given by a 3-'llour fumigation at a certain absorption rate (Il), windspeed (12), day and month (13), stability condition (14 = S), miles from stack (15) > and crop (16). The number of acres of alfalfa and barley in each, sector was deter mined by interviews in the area,^ data supplied by the Helena. Valley. 3 4 Irrigation Project,■ and aerial photographs. Barley was assumed to ' produce 40 bushels an acre at 85 cents a bushel. Alfalfa was assumed to yield 2 tons per acre at $23.50 a ton. 2 - Special thanks to Paul Kleffner, long-time farmer-rancher in the East Helena'area, for his assistance. ■ 3 Special thanks to Bob Green, superintendent of the Helena Valley Irrigation Project, for his assistance. . 4 ' • ‘ U. S . 'Department of Agriculture,.. Agricultural- Stabilization' and Conservation Service, Invitation. No. ASCS-7-64-dc, item 4., 8' 75 Steps- 103 - 104.r— Set multiplier equal to I and read another data card. Steps 105 - 108.— After all weather data cards are read, these steps give the format and,read statements for adding the contribution of small stacks. Steps 109 - 111.— These steps convert pollution in,g m _3 given by the dispersion equation to pollution in parts per-million (ppm) , add the contribution of small stack's., adjust the model according to empirical data, and print the pollution in ppm for each of the 540 sectors; Steps 112 - 115.— These steps set the pollution concentration in each sector to zero if annual concentration is less than .017.ppm 2 (.49 mg of SO_/ 100 cm /day) and subtract the marginal contributions 3 of smaller stacks; ,Ridker used this figure as a background level of which.■anything below i f cannot be included in pollution damages. ■ Steps 116 — 121.— Concentration of pollution in ppm is converted to,a sulfation rate by using parallel measurements found in the litera­ ture [47,76],' and concurred by the Montana State Department of Health and the National Air Pollution Control Administration.• Parts per million.were converted to sulfation rates using the relationship I tag. 2 ■ ‘ of SOyzIOO cm /day (sulfation) is equivalent to ,035.ppm SP2 . ' tion was then printed out for the 540 sectors. Sulfa­ 7.6 Steps 122 - 129.-'-These steps print out the household damages from pollution for each of the 540 sectors and their total. the damages to households in the Step .126 states wind direction and the j mile out equals the amount of sulfation in that sector divided by .25 and multiplied by $245, where Ridker fdund the decrease in property value to be $245 for every .25 mg of SO^/lOO cm^/day, multiplied by an interest rate of '6 percent to convert present value to annual costs, •' multiplied by the number of houses in that sector, and.multiplied by the increase in the price level. Steps 130 -■ 137-.— ^These steps print out ,the damages to alfalfa and barley for each wind direction and each mile, out, with a total for each sector, and a final crop damage total for all sectors. . Steps 138 - 139.— End of program. 109 Cp- add the c o n trib u tio n o t small stacks. A d lIist m o d , nd convert grams u f (K)UutiOi. to p,im I ^$TA»T^ I 38 I Re.id.intcyvr, and dim vnsion data. In itia lize variablfs Read Pata has data ended? * \/rc Enrl c /IJotJ I Convert ppm to sultauon JIl 46 A ___ t ’ 27-130 Print damages tn housvdolds in e :ch sector and u ta l ---Tyt- 05 is tvtu l Cl x id cover less Uv*. o r equal to 4- *,C? t I S T A B Il ITY C O N D ITIO N FQ UALS n 3 kn ot J j 5 ) v- cufate p o llu tio n concentratir r* Ciu Cl is w nd r.| cd I than h kn ot:./ J ta A \yf- "Lr IZIZl"tZ --A9 is w in d sp«xd less than o r equal to 10 k n o t - _X stcr* the concentration m ea-h ar ca in t r • anr-i,fupr-attf w in d dir- c tio n k., and ai fo r each n tie o u t. M 4 - 61 is w ind sr " rX' ess than 3 knots? 131-137 P rint c ro p d a in t ies i.i each sector and total dspci ----J?,T- .s s ta b ility co n d itio n euusl to 2 o r I y - \ 14r is w i d spct J less than o r ei|ual to 6 knots? I__ I I \ ____ Ak GStifttvulil He use stahiMty co nd itio n subroutine - 2 C is ceiling height less than 7,000 ft? IZiiL S u trv irin e 1-17 is tem pcra’ ure greater than 40 degrees F ? - O o Z -T A I is it a d ayligh t hour? JZ 8-89 determ ine date S iib rru tiite use s ta b ility c o n d itio n S ibrou nnc = 4 *s the w ind speed between 2 and 10 knots? CMCLiate the absorption rate o f the plan t use S tahility co n d itio n subroutine = 3 ___________ ml) /5 is the date between May 25 and August 2 5 ? is total cloud cover less than o r equal to 5 '1 0 i y I --- 1--- 1-17 determ ine w in d speed LzV L calculate and store crop damage in each sector has the 3CS-duy period ended yet? Figure A- L. '2 6 Cz.’i .u la tc h ot.schoki damag is I { K 9-12 1 P rint sulfntio n rate in each area is it a mght hour? C 119 E ~ps~ is to ta l clrxid c o v e = I U IO iilm g I- Iqht less m an 7.C j O It? tl H i Subtract c o n trib u tio n o f sin.nlI stacks t o get concentration in each a > c a b y th ? I ig stuck _j ( L os v, spci equal equal izero^ I I 117113 Set concentration in each area equal to zvro if p pm < .017 J_ 3S 40 ®< H O 111 Print concentration in each art a (ppm) Pd) Generalized Flow Chart for the Computer Program. C A L C U L A T E A IK P A L L L T T'S. C a m / O rS 3 r SRt'AT !SllO) . I: 4 • Fe-^AT(ISIR) 10 F 5 4 A T (fX, 1 2 F 5 » 4 ) F C F v A T ( p y . 12, 14, I 2 , A 2 , I S X , I 2 ; I 2 , I 2 ; 4 X , I 3 , 6 X , A 1 , 2 5 X ) 4 SCCC 6 FSRf AT.( 11 ) . . .5 S l l O F S T v AT ( 'C ' , 1 2, 'C M L F g tE) 6 Si CC FBTrr AT (,I ClAj PARTS' PCP y ILL I 6 \ i / 3 X , 1518) 7 S1 30 F G R v A T (,I S U L F A T I 0 N R A T E r / 3 X j 1518) 5 O IC 11 12 12 14 15 16 17 IS 15 2C 21 22 22 24 Pr 26 27 22 PS SC 31 32 33 .3'4 25 36 37 3g 39 40 F U G FSRrAT ( 11 3131 E-'LL AF D a MAOf S HSLSE^BLCS') F c R 1'AT (///' T c T A L R M j S E C Ar AGE I, 11 c ) SlSc FSFrAT!!C 'I I2/2X>1EJ8) 81 7Q F S R ivAT ( U ' ) F U O FSRf AT ( / / / ' C R S F C a.N.a CE IN D O L L A R S IN D IR E C T I SN M 2 ) Sl SO F B s f A T ( (TS-Ta l C r SF R A M A G E V S X ' A u F A L F A S A r l EV 1ST A l '/SX s 18 ) LOGICAL NCELHT C I Mc NS ISN X H E ) ,SIGZ ( 7 , 15),CI A ( 3 6 , 1 5 ) , C S S (26,1.5 ), ADj (36,15 ) INTr-CER C-, M , CRLHT, CLCCV, H S U S E (36-, 15), C R ^ P V (36, 3, 2 ), C R Q P D (2.6, 4,3 ) I, AM T !,CR' F C T (2.) ■ CAiA CRPrD/43P-*:C/.*C-SPCT/3■wC/ ■ R E A L CRC-F(7,3,3,? :3,3,S) CS i I= 1,36 C C l O = 1 ,1 5 I C I A ( I , v ) = CCS SC 1= 1, 15 R E A D ( I C E , 3). X < I ) , ( 5 I G Z ( J , I >/0=1,7) ■ 56 C S N T I N L F CS c 1= 1, 36 2 READ ( I C E , 4 I (hPL'S.E ( I, U ), J = I, 15 ) CS 8 I =),36 READ ( 1 c 5>4.) ( (CRSFV( I.,J,K), v = 1 , 2 ) , K = 1 , 2 ) ■ a CPNTINLE • C S s 11 = 1,7 CS s I E = I , 3 ■ - . CS S 12 =1 ,3 9 ■ FE AC (IC=J 10) ((! (CROP( II, 12, 13, 14,1-5, 16) ), 15 = 1,3), 1 4 = 2 , 3 ) / I6 = U £ ) R E / C (105, ICC > ( ( A D J ( U J ) , J-=U 15), I = 1,36) R E A-C (I CF, I CC ) ( (CSS (I, J ), J = 1,15 ), I = I, 3 / ) 5 RE A:-.( I CE, PDCC, END = S I O )N VR, N/'SDA Y, N H S ijR » C E l -HT , NDEV.PT, N 1,!IN'DI, NKNDSp, INTt-' Ft C L C C V calculate a , I . fc2 ^3 ■ 44 -.45 46 47 48 .49 EC El : 5c 53 5^ EE 56 57 5? ES .6C . 61 ■ 62 63 64 '65 66 67 63 69 7-C 71 .72 "73 74 7E 76 77 78 75 SC A IR P e L l L T I Q N CA'-'A Cr. 5 - IF ( !a M l SP-*FC.C ) P L L T = PU LT + 1 « I GC T 8 5 N C L i - H - , T R l F.,IF (L F L P T ^L t » 3 H 7.c )NCEl.l-'T=-F A i„ SE. IF (C L C C v • E C , I h ~ ) N C L C C V = I'C J C f: T 5 7 . C E C " C h (4j 6 j C L C C V LN CL DCV 7 I F ( \ C L C C V . C C , 1 C , A N C , , N E T s N C E L H T ) S « 4 ; 08 TB SCO IF (N h QLP • E.Cf.C-:. 5R, N H e L R = EG, CE-'IR, NH CU Re E g «20. Q R d N W Q U R «EC «23) 33 . ITE 5CC T R ( N C L C C V e L F f E ) CA LL S T A B (E / 2 , N i'N C 5 P A' P 5 C A Y > N H 5 U R ) j GQ T0 SCO I F ( N C L C C V f C T fE , A N D . . N Q T o N C E L H T ) CA LL S T A E ( 3 ; 3 ^ N N N D S P i N P Q D A Y ^ N H Q U R J 1 1 GP TC SC: IP' (' C L C C V • CT * E » AND e I'CEL MT ) C A L L S T A B ( S ; M n NCSP^ N>6CAY#.NH8UR ). I I GE Tb 8GC S=Ej CG TS PCC ECO J F (■' C L D C V ,LE, 4 ) Ge TB H O '■ GB TO 620 * . 61C IF (''NNDcPfLEeS )S = 7 1GC TB SCti IF ('■ N N D £ P « LE « 6 )3 = 6 j G 3 TQ gCO I F ( M f 1-DSPflFe-IC)S = E j G e TS SCC IF (I■N t\D g F , GT , IC )S = 4 ; GS T 5 SCC 620 IF (:-N n D c p . LE'. 3 )S = 6 j CS TB SCC l F ( ' k h C s P . L E , 6 ) S » S ; S e - TB SCC I f (N v n -'-SP.GT«6 )S = 4;GQ Ta aco SCO L r N ''NDSf- * ,E14P- H= Icl• + 76.g3/U -G = 277 2 DAYS- a 365 DB 3C2 N = U l E CF I=4« 567b*G/(Si GZ(Sj>PI)*X (P) *U)*EXP(-.5* (H/S.IG.Z (S;>N) )##2) IF (N1 A IND I«G-T i) 1> ) K= NkINDI -18 IF (: M h D I»lL «13 )■ K= N'klhCl +.12 CHI = CH I M M L I C-I A(KtP)-= C I a . ( K t N ) + CHI I F t fMfcT,!) -OF- -TS -gG 2 IF ( ~ • i'E ,2 • a ' c «'P . NE , 3 )G TB 8 CE IF ('"■^ B D A Y , LT ,-E25 «S R ,NH-QDA.Y» G.T. SEE ) GB TB SCE IF ('•k-NCsF.l E ,2.GReNVhD$P«GT.10> GB TB 802 IF ( N T E N F . L T . 4 0 Ge TB R C 2 IF ('NHQLR. N E . 8. A N D . N H B U P ,NE, 11. A N D , N H Q U R .NE «14 » A N D ,N H S U R o N E . I? ) IGB TO S-C2 •^3 VD AIR 'FEiLtTIQK C*"AGrc A = ((,cCF2kLCLApTm.cCCC7*\CELPTf»2+,CCOCC2*KDEkPT**3)/(,CCc8* gS: IKTr'•F- ,CCCCy^NTErF**2-i- »CCCCC2 # KTEKF>»S ).)-* 65C S3: Il = I SA: IE ( A *L7 »6CC ) 11=2 '■ ' SE: IF'(-'LT,55C) 11=3 J E (A ,L T ,5005 Il=S S-6: £7 I F i A - L T A 5 C ) Il=E ss: If (At. I.Tt A CC.) 11=5 SS'J IF L I . 35C) 11=7 IE { a ,L i *S Q C ) CO TB 8 c E so: si:' SC3 12 = 1' . . Es; lF(i'^ e C A V . CT ,7 C 1 > 12 = 2 S3: IFu--v S C A V . C l * 721) 12 = 3 SA ; ■ 13=1' . SE: Ic (i' V A D f F t G T t E ) 13 = 2 sc: I F ( 'W NE £ F •G T .£ ) 13 = 3 57; CS '"'CA T5 =l /3 92: CS '--CA 16 =1/2 ss: KR;:"" C R S P V (K , 1 5 / 1 6 ) * C F S F ( 1 1 , 1 2 , 1 3 , S j 15,16) I Co: CR'jr;DC-<, I5-, 16 )= CRSPC.(K> -I5, 16)+ KR3P ' I c i : SC A CR3' E(X,I5,2 )* - C R 6 F D (K,I5,3) + KRQp SCE CSRT INUr . : 1C2: : ICS: r u u r =■ i«' calculate *-i: . ICA.: . " GQ I? 5 .. ■ Ic 5 : 'Slc KR IT E.( 1C 2, =IOC M l I )', 1 = 1,15) icc: CS AlS 1=1,36 IC7 : ICC f S- ' A T ( I E c B r c ) DQ -Ell U = I j t E Ics: • 1:9: 811 CIa (Ij w) = (CIA(I,J)/(S,*CAYS)*262 + CSS(I,J ))*ADJ(I/J) lie: ill: If(I.EG.19) K R l T E ( I C S j S l C C ) ((N),N =l,15) ',RITE (1C.?, SI 1C) I, { C I A U , W:), J = I, 15) CS. ~ 12 C = I f l E ■ ' . IiS: IF (C I ( I, u') «LT «»C l 7 ) C I A ( U j ) =C, 113: 117: I F (ClA (I , v IrKErC,) C I A ( I j U ) « C l A ( I j J ) - C S S ( U U ) W A D U ( I j U ) ■ ' . . n s : ' 812 - C f t IR l E ' lie: 'a R IT E ( IC 8 , 2 13 C ) ( ( I ) , 1 = 1,15.) 117: CS f U 1 = 1,36 ' ns: Ce > 1 3 v = U 15 ns: 813 CI a ( IjJl=CI •' ( I, j) * 2 8 , 6 IF (U £G ,19 ) KR ITE (108,8130 ((N) ,KuUlE ) ■ice: C A L C U L A T E AIR PeLL1-TlCV- CAN-/,CES 814 UR IT E (IC 2 a 2 1 1 C )■ I/ (CIA('I,U),Usl#15) I? I! R;I T E (I q ? ^ P 5,4 C ) 122 ' 123 ■ AM- =C, 124 CP K l t I = I v 36 CE' 6 IB 1 ,15 125 HEULE(1,J) = ((C!A(I,J)/.25)*245*«C6 *H6USE(IvJ )4.5)*i»344 ' 126 " 127 815 APT = AMT+ HCUoE(IjJ) . 816 129 U R l T E d C S ' 9131) APT ' I29 8151 VR I T E U C S /« .170 Isc :is: 138. 132 1 34 125 136 137 138 139. DC S 17 P =I.,36 UR I T E (’ I CS' ? I £ C ) K CS 7 1,7 +=1,3.. CS S 18 -16 = 1,3 818 CRfiPCT( 1 6 ) = CRfiPCT( 1 6 ) +CRfiPO(K j M t 16) 817 U R l T E ( I c P j J i E Q ) M, (CRfiPC (K ' P j> I ) / I = I / 3 ) ■ -URI T E d C S j 8 1 9 0 C R S P D T STOP END ’ 1 COMPUTER SUBROUTINE • •-. CALCULATE A:IR. FSLL1^ I3K D-V-1AGCS 'I';. .2 i S U 3 ‘;8U.T IKE S T A H < S, N, N|*\CsP, N M s b A Y A 1H S U R ) . IKTliGtR Al (A, A ).« A('+,5'3); A 5 ( 1 4 , 4 ) , T I X E , S 3? ■ .^ I CATa Al/ ' I^ I^“C = “G 9 / ^ 2 5 / 6 5 IC U is 1.4 15 Iqi Sif^ ll;2/2,l,2;3,3,2,3,4,k,i,2,3,3,Q,1.-2,2,0'I'I,I;I,I,1,1., !,1,2,2, 2.1, V I, I,c, I, I, I,C/ I, I^ I, I, I, 2, 2,1,2,3,.3,1, I, 2, 2, c, I, I, I, r/ . 7 2 SE IiSg I»7q I^7 1 3 / 1 2 3 1/ Iqq ■ DAJA AS/ ' 13,3*3.,3,4,4,4, 4,4,4,4, t,4,4,2,2,2'2, 3,3, 2, 3, 3,3, 4,4,4,4, I, i,2,2,2, 22,2,2,3,3,3,3,3,4,%,I,I,I,I,i,2,2,2,2,3,3,3,3/ . TIvE =(KHSvR-S)/3 +1 CG IC 1=1,4, . 10 IF('VGDAY.LE.Al(TIh'E,I!) GQ TQ 11 ■ I=S IT S =Ab (K'a KDSF, (A (T IKE, I, N -1))* • RET1--RK ' EKD ' OD to APPENDIX B A DESCRIPTION AND LISTING OF PROGRAM TO CALCULATE CROSS-WIND DISTANCE VARIABLE (y) As discussed in Chapter V, a change in wind direction for any receptor field will affect the level of pollution concentration it suffers, and hence, the damages it sustains. This program uses the wind direction data as input to generate changes in cross-wind distance y, to be used in dispersion equation!(5 -5 ). The program uses BASIC language, which is gaining, wide acceptance as a general-purpose computer language, particularly in modern time­ sharing systems.. Each step is numbered, which will facilitate exposi­ tion^ Program to Calculate Cross-Wind Distance Variable for a Distance of I Miles from Stack 5 DIM M(IOO) 10 DE .= 30 15 MAT READ M(DE) 20 DATA 230,233,245,236,234,235,233,225',. etc. 30 Ml = I 35 N= Ml*2 + I 50 Y =O 51 L — N—2 • .55 Y= Y +(N-L)*14*(M(N) -M(L)) . 56 N = N-I • 57 Y = Y+ 64 N = N-I 65 IF N > L THEN 56 (N-L) *14* (M.(L)-M(N).) . ■, 84 70 N + N+l 75 IF N > NE THEN 999 80 PRINT Y 82 N + N+2 85 G0 T0 50 999. ST(Z)P Step.5 : This step dimensions the data matrix. saves 100 spaces for the matrix. In this case, the computer Although only.30 entries were read in as data in this particular problem, the number 100 was chosen to cover any likely application. Henceforth, only the; DATA statement heeds changing. Step 10; This step indicates the number of data entries and will be used to close the run.. Step 15: . ' This step instructs the computer to read the 30 data entries. Step 20; This step enters the 30 wind directions; for a particular 3-hour, period. ■ 233 represents the 233° win d .direction;, etc. Step 30: This step indicates the miles from polluting stack.. 85 Steps 35-80: These steps calculate the cross-wind distance y as follows: Using the formula.for arc length, equation (5-6) in Chapter V, the distance center plume line moves away from the receptor field of I mile can be calculated by estimating the degree (°) change in wind direc­ tion for each period. Since each wind direction estimate represents the time it takes for wind to travel one-half mile, the distance of plume centerline from a field I mile out depends on wind, direction at the time the plume left the stack and again at the one-half mile distance. Assume a filed, lay in the 240° wind direction and that wind direction in the previous period was 238°, and the period before that 235°. How many meters distant would the plume be from the receptor field? Using formula (5-6), the first calculation would be: irr„° 3 ^ ~W (3.14159) (1609) = I s o - 5° 140 meters The half mile calculation would be: AL (3.14159)(804.5) 180 42 meters As the plume left the stack, wind direction was 235°. Assuming no directional change, a 5° directional difference (240° - 235°) would cause the center plume to be 140 meters distant from the field. However, wind changed directions after moving one-half mile. Now the directional change is 3° (235° - 238°), and since the plume is already 86 half the distance to the field— 804 meters, instead of 1,609— 42 meters must be subtracted from 140 meters to yield a cross-wind distance y of 98 meters. For a receptor field I mile distant from the stack., then> crosswind distance y is calculated by. subtracting the differences of wind ■ direction between" a given period and two periods previous, multiplied by 28, arid algebraically adding this to the difference between wind direction two periods previous and one period previous, multiplied by 14. Notice, ^ ap],rollImately 28 ana ^ - I 4^ ) (8 O4 ,5), is approximately 14. Each cross-wind distance y represents the distance of plume center line from a receptor field in a specified wind direction. Steps 82-85 These steps .increment N , go back to step 50, set y = 0, and begin the steps necessary to calculate another y . , For distances of 2 miles, wind direction is needed ,for four stages the wind direction when plume leaves.the stack, wind direction at onehalf mile, wind direction at I mile, and wind direction at I 1/2 miles. The-following-changes were needed in the. program for distances of 2 miles and for distances of 3 miles.. I 87 For 2 Miles 30 Ml = 2 51 L = N-4 52 Y = Y + (N-L)*14*(M(N)-M(L)) 53 N = N-I 54 Y = Y + (N-L)*14*(M(L)-M(N-2)) 55 . N = N-I 56 Y = Y + (N-L)*14*(M(N-I)-M(L+2)) 57 N = N-I 58 Y = Y + (N-L)*14*(M(L+2)- M (N+2)) 60. N = N-I 82 ■ N = N+4' For 3 Miles 30 Ml = 3 51 L = N ^-6 52 Y = Y + (N-L)*14*(M(N)-M(L) ) 53 N = N-I 54 Y = Y + (N-L) *14*'(M(L) -M(N-4) ) 55 ■N = N-I 56 Y = Y + (N-L)*14*(M(n-3)-M(L+2)) 57 N = N-I 58 Y = Y 59 N =' N-l. 60 Y = Y 61 N = N-I 62 Y = Y + (N-L)*14*(M(L+4)-M(N+4)) 82 N =■N +6 + (N-L)*14*(M(L+2)-M(N)) + (N-L)*14*(M(N+1)-M(L+4) ) APPENDIX C ADJUSTING POLLUTION CONCENTRATION LEVELS The Montana State Department of Health, and the National Air Pollution Control Administration conducted a study beginning in June through November 1969 of the types, amounts, sources, distribution, and effects of environmental pollution in the Helena Valley. In particular, continous measurements of sulfur dioxide were taken at five locations, while monthly measurements were taken at approximately 215 locations using Huey sulfation plates. Sulfation measurements after November were made.on a three month basis for purposes of surveillance and obtaining annual sulfation rates. These figures were used.for comparison and adjustments of the model used in this study to predict annual concentrations of sulfur dioxide. Figure C-I shows the percentage error of actual against predicted pollution concentrations, An arithmetic addition of the underpredic­ tions and overpredictions indicates the model underpredicted sulfation rates by 15 percent.for the combined months of July tilrough November. Figures C-2 and C-3 were included to show the percentage differences for two specific months,. July and September. The model underpredicted actual measurements by 4 percent in July and by 30 percent in September., Using the data from Figure C-I, an iso-error map was drawn indicating the percentage underestimation and overestimation for all sectors less than 8 miles distant from the polluting stack. Depicted in Figure C-4, this map was used to make the appropriate adjustments 89 to the values estimated.by the model for each sector. For distances greater than 8 miles.>. a correction factor of 1.1 was used’ for each sector, indicating the model to be underpredicting by 10 percent. A corrective factor of 10 pergent for all .sector's outside the,.limits of empirical data would appear to be conservative. An. R 2 of .74 was calculated before the adjustment., indicating that 74 percent of the variation in observed sulfation levels was explained'■ by variations in.the predicted sulfation level. calculated after the model was adjusted. ' 2 An R of .99 was- 90 360° A t -45 “7 0 -30 -14 0 -42\. 3 miles Figure C-I. 180° 9 = stack Spatial Distribution of Percentage Differences Between Actual and Predicted Sulfation Measurements (July November, 1969). 91 360° 3 miles stack 180° Figure C-2. Spatial Distribution of Percentage Differences Between Actual and Predicted Sulfation Measurements (July 1969). 92 360° -50 0 -25, -20 +16 0 3 miles Figure C-3. stack Spatial Distribution of Percentage Differences Between Actual and Predicted Sulfation Measurements (September 1969). 93 I" - 3 miles (b = stacK Figure C-4r. An Iso-Error Spatial Distribution of Percentage Differences Between Actual And Predicted Sulfation Measurements (July-November, 1969). APPENDIX D GLOSSARY OF SYMBOLS USED IN THE PROGRAM • The symbols used in the program are defined here. If a symbol was defined in detail in the program, it will not be defined at length in this appendix. A = absorption rate of the plant ADJ = adjustment of pollution concentration in each sector AMT = the amount of dollar damages to households resulting from a 3-hour addition to pollution loadings in each sector CELHT = ceiling height CHI = pollution concentration CIA = concentration in each area (sector) CLDCV = cloud covei CROPD = crop damage in each sector CROPDT =■ total crop damage CROPV ■= potential crop value (yield in dollars) in each sector CSS ■ =: contribution of smaller stacks by the American Smelting and Refining Company and the Anaconda Company to total pollution levels in the study area DAYS = days (length of study) EXP = exponential used in dispersion model H = effective stack height HOUSE. = the number of houses in each sector 11 . = the absorption rate•of the plant categorized 12 = the date by month and day 95 13 = wind speed in mph •14 = stability conditions 15 = miles from stack 16 = crop K = wind direction M = miles from stack MULT = multiplier- If wind speed equals zero', another data card is read and its contribution to pollution loadings is doubled for that wind direction - NCELHT = ceiling height . NCLDCV = cloud cover NDEWPT NHOUR = dewpoint = hour NMODAY = month and d a y ■ NTEMP • ='temperature . NWINDI = wind direction NWNDSP = wind speed ■■ NYR = year Q = emissions. S = stability conditions Sig Z = vertical dispersion coefficient STAB = stability condition subroutine T = duration (time) of fumigation . " " 96 wind speeddistance from 'stack, in meters LITERATURE CITED 1 Air Pollution Abstracts, Ministry of Technology, United Kingdom, Warren Spring Laboratory, Gunnels Wood Road, Stevenage, Herts., United Kingdom. 2 Air Pollution Control Association, Air Pollution Control Association Abstracts, 4400 Fifth Avenue, Pittsburgh, Pennsylvania' 152.13. 3 Air Pollution Titles, Information Services, Center for Air Environ­ ment Studies, Pennsylvania State University, University Park, Pennsylvania 16802. 4 American Public Health Association, Guide to the Appraisal and Control of Air Pollution, 2nd Edition, 1969. 5 Anderson, Robert J . , J. and Thomas D . 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Public Health Service,.CPE, 1969). 23 Hagevik, George H . , Decision-Making in Air Pollution Control, Praeger Publishers, 1970. 24 Hall, P., Labours New Frontiers, London: 25 Harberger, Arnold C . , "Survey of the Literature on Cost-Benefit Analysis for Industrial Project Selection," In ter-Regional Symposium in Industrial Project Evaluation, Sponsored by the Economic and Social Council of the United Nations, Committee for Industrial Development,. Prague, Czechoslovakian S . R., October 1965. Andre Deutsch, 1964. 99 26 Herfindahl, Orris C. and Allen V. Kneese, Quality of the Environ­ ment: An Economic Approach to Some Problems in Using Land, Water, and Air, Resources for the Future, Baltimore: John Hopkins, 1965. 27 ____________ ______ , Quality of the Environment: . An Economic Approach to Public Policy, Baltimore: John Hopkins, 1965. 28 Hill, George, R. Jr. and M. D. 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