PHGN311 Homework #4 Due Friday, Sep. 20, 2013 at the beginning of class Complex numbers and Differentials Show your work on all problems. Finish Chapter 2 on complex numbers and read Chapter 4 on partial differentiation 1. Boas 2.15.5 2. Boas 2.16.8 3. Boas 2.17.25 4. Using complex variables, find the general solution to the homogeneous differential d 3z equation: 3 − 8z = 0 . Write the solution in real form since its likely in physical dx problems we want a real solution. 5. Boas 4.1.6 6. Boas 4.4.3 (these kinds of approximation problems using differentials are commonly used in physics). 7. Boas 4.4.7 8. Boas 4.4.15 9. Boas 4.13.10 (use the chain rule) 10. In thermodynamics, it’s common to work with differentials. We can write dU = TdS − PdV where U is the internal energy, T is temperature, S is entropy, P is pressure and V is volume. € ! ∂U $ a. Find # & " ∂ S %V b. If we define the Gibbs free energy G as G = U − TS + PV find simple expressions (involving things like P, S, V or T, etc. not complicated partial ! ∂G $ ! ∂G $ derivatives) for # & and # & " ∂ T %P " ∂ P %T c. Assuming G is a smooth nice function, use your results from b to derive the " ∂ S % " ∂V % Maxwell relation − $ ' = $ ' # ∂ P &T # ∂ T &P