Head-on collisions of electrostatic solitons in multi-ion plasmas Frank Verheest Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281, B–9000 Gent, Belgium & School of Chemistry and Physics, University of KwaZulu-Natal, Durban 4000, South Africa Manfred A. Hellberg School of Chemistry and Physics, University of KwaZulu-Natal, Durban 4000, South Africa Willy A. Hereman Department of Applied Mathematics and Statistics, Colorado School of Mines, Golden CO 80401–1887, U.S.A. (Dated: September 15, 2012) Head-on collisions between two electrostatic solitons are dealt with by the Poincaré-Lighthill-Kuo method of strained coordinates, for a plasma composed of a number of cold (positive and negative) ion species and Boltzmann electrons. The nonlinear evolution equations for both solitons and their phase shift due to the collision, resulting in time delays, are established. A Korteweg-de Vries description is the generic conclusion, except when the plasma composition is special enough to replace the quadratic by a cubic nonlinearity in the evolution equations, with concomitant repercussions on the phase shifts. Applications include different two-ion plasmas, showing positive or negative polarity solitons in the generic case. At critical composition, a combination of a positive and a negative polarity soliton is possible. PACS numbers: 52.27.Cm, 52.35.Fp, 52.35.Mw, 52.35.Sb I. INTRODUCTION There has been a recent upsurge of interest in the investigating of head-on collisions between two acoustictype nonlinear waves in various plasma models.1–14 This builds on earlier efforts by Su and Mirie,15 who dealt with a similar problem for surface waves on shallow water, by using an extension of the Poincaré-Lighthill-Kuo (PLK) method of strained coordinates.16 Head-on collisions present a particular challenge, in contrast to the overtaking interactions of several solitons propagating in the same direction. Both the standard and the modified Korteweg-de Vries (KdV and mKdV) equations are integrable, possessing, i.a., an infinite chain of conserved densities and exact solutions for interactions between N solitons, for all natural numbers N .17,18 Such N -soliton solutions correctly describe how taller (and faster) solitons overtake the smaller (and slower), with full nonlinearity during the interaction phase. Unfortunately, seeing that the typical solutions of the KdV equations are mildly superacoustic, all true KdV and mKdV solitons propagate in the direction that underlies the basic derivation of the parent equation, when observed in an inertial frame. As far as we could ascertain, there is no such powerful exact method to deal with head-on collisions, so that one is forced to use an approximate description, as done indeed by relevant theoretical papers in the literature.1–14 In a recent paper, Harvey et al.19 investigated experimentally the interaction of two counter-propagating solitons of equal amplitude in a monolayer strongly coupled dusty plasma. To quote their conclusions, it was found that the solitons are delayed after the collision, with soli- tons of higher amplitude experiencing longer delays. The amplitude of the overlapping solitons during the collision was less than the sum of the initial soliton amplitudes. Harvey et al.19 discuss a comparison with the theoretical analysis of Su and Mirie,15 which, however, like all papers using the same methodology, predicts a superposition of the amplitudes during the interaction. While the theoretical analyses give a qualitatively correct picture of the soliton structures outside the head-on collision region, plus the time delays,14 the PLK method is not really capable of accurately reproducing the amplitudes during the collision. In a previous paper14 we tried to give a detailed derivation of the relevant amplitude and time delay equations for the head-on collisions in a plasma composed of cold positive ions and hot Cairns distributed nonthermal electrons, with an emphasis on the fundamental, as well as the often tacitly assumed underlying hypotheses. Theoretical papers in the literature1–12,15 derive KdV equations for the amplitudes, with the corresponding phase shifts (time delay), and this for quite a variety of plasma models. As we discovered,13,14 several plasma models can also admit mKdV equations for the amplitudes, provided the model parameters can be chosen such that the coefficient of the quadratic nonlinearity in the KdV equations vanishes. Except for the papers by Demiray2 and Chatterjee et al.,5 whose plasma models do not give rise to critical parameters, other models1,3,4,6–12 are sufficiently sophisticated to allow critical compositions, yet these were not discussed. In the present paper, we investigate a plasma model composed of a number of cold (positive and negative) ion species in the presence of Boltzmann electrons, a model 2 not studied before in this context. The particular interest is that such a multi-ion plasma can cover several interesting situations, including some observed experimentally. In doing so, we will follow the outline of our previous paper,14 but in an abbreviated way, without repeating some of our comments on the basic aspects of the methodology, yet with sufficient detail to make this paper coherent and self-contained. The paper is organized as follows. In Section II the basic formalism is given for the generic case, which leads to KdV equations for the right- and the left-traveling soliton, respectively, plus the phase changes due to the head-on collision between the two solitons. Section III is devoted to the special case when the derivation leads to an mKdV equation, with corresponding changes in phases. Section IV then briefly summarizes our conclusions. So as not to hinder the flow of the main exposition, some special topics have been relegated to two Appendices. Appendix A covers the proof that even plasmas with only two cold ion species can exhibit critical parameters. Appendix B deals with some general properties of the coefficients of the quadratic and cubic nonlinearities in the KdV and mKdV equations. II. Basic Formalism The normalized continuity and momentum equations for the different ion species, with label i, are ∂ρi ∂ + (ρi ui ) = 0, ∂t ∂x ∂ui ∂ui ∂ϕ + ui + zi = 0. ∂t ∂x ∂x All species are coupled through Poisson’s equation, ∂2ϕ X + ρi zi − exp(ϕ) = 0, ∂x2 i (1) (2) The mass density ρi and fluid velocity ui have been normalized in terms of a reference mass density n0 M and where exp(ϕ) represents the hot Boltzmann electron contribution. P Charge neutrality in equilibrium requires the condition now adjust the referi ρi0 zi = 1, Pand we 2 ence i ρi0 zi = 1. In other words, P 2mass M2 so that i ωpi = n0 e /ε0 M defines M through the effective ion plasma frequency of the system. This can be done without loss of generality and simplifies the notational details of the algebra. One can also show that the normalization is such that the linear acoustic phase velocity is c = 1. ξ = ε(x − t) + ε2 P (ξ, η, τ ) + ..., η = ε(x + t) + ε2 Q(ξ, η, τ ) + ..., τ = ε3 t, The series expansions of the dependent variables are To lowest nonzero order (1), (2) and (3) lead to (6) (4) referring in ξ and η to a right- and to a left-propagating soliton, Sξ and Sη , respectively. The present description, to lowest order, treats the colliding waves as separate entities propagating in the same medium, and their stretching involves the unique linear acoustic phase velocity c = 1. This substitution leads to ∂ ∂ ∂ ∂P ∂P ∂ ∂Q ∂Q ∂ 3 =ε + +ε + + + + ..., ∂x ∂ξ ∂η ∂ξ ∂η ∂ξ ∂ξ ∂η ∂η ∂ ∂ ∂ ∂P ∂P ∂ ∂Q ∂Q ∂ ∂ =ε − + ε3 − + − + ε3 + ... . ∂t ∂η ∂ξ ∂η ∂ξ ∂ξ ∂η ∂ξ ∂η ∂τ ρi = ρi0 + ερi1 + ε2 ρi2 + ε3 ρi3 + ε4 ρi4 + ..., ui = εui1 + ε2 ui2 + ε3 ui3 + ε4 ui4 + ..., ϕ = εϕ1 + ε2 ϕ2 + ε3 ϕ3 + ε4 ϕ4 + ... . (3) As we are considering head-on collisions of two electrostatic solitons, and following methods in the cited literature, we introduce BASIC FORMALISM AND GENERIC COMPOSITION A. p of an ion-acoustic velocity Via = Te /M . The chargeper-mass ratios are expressed through the parameters zi = qi M/emi , so that only one combined parameter per ion species is needed, rather than working with the charges qi and masses mi separately. The electrostatic potential ϕ is given in units of Te /e, where Te is the kinetic temperature of the hot electrons with equilibrium density n0 . ∂ρi1 ∂ρi1 ∂ui1 ∂ui1 − + ρi0 + = 0, ∂η ∂ξ ∂ξ ∂η ∂ui1 ∂ui1 ∂ϕ1 ∂ϕ1 − + zi + = 0, ∂η ∂ξ ∂ξ ∂η (5) 3 X ρi1 zi − ϕ1 = 0. (7) i and τ , but not ξ, ρi1 = ρi0 zi (ϕ1ξ + ϕ1η ) , ui1 = zi (ϕ1ξ − ϕ1η ) , ϕ1 = ϕ1ξ + ϕ1η , The linear perturbations will consist of a term depending on ξ and τ , but not η, and another term depending on η Compact notation denotes the dependence on the space arguments ξ or η. To the next higher order (1), (2) and (3) give ∂ρi2 ∂ui2 ∂ui2 ∂ ∂ ∂ρi2 − + ρi0 + + + (ρi1 ui1 ) = 0, ∂η ∂ξ ∂ξ ∂η ∂ξ ∂η ∂ui2 ∂ui2 ∂ui1 ∂ui1 ∂ϕ2 ∂ϕ2 − + ui1 + + zi + = 0, ∂η ∂ξ ∂ξ ∂η ∂ξ ∂η X 1 ρi2 zi − ϕ2 − ϕ21 = 0, 2 i which yields ρi2 = ρi0 zi (ϕ2ξ + ϕ2η ) + ui2 = zi (ϕ2ξ − ϕ2η ) + 3 ρi0 zi2 (ϕ21ξ + ϕ21η ) + ρei2 , 2 1 2 2 z (ϕ − ϕ21η ) + u ei2 , 2 i 1ξ ϕ2 = ϕ2ξ + ϕ2η + ϕ e2 . Here ϕ e2 has been defined as the part of ϕ2 which depends on ξ and η together, besides τ , in a way which cannot be disentangled, with similar notation for other variables and orders. The expressions in (10) are coupled through constraints that arise from Poisson’s equation in (9), X 3 ρi0 zi3 − 1 ϕ21ξ = 0, (11) i X 3 ρi0 zi3 − 1 ϕ21η = 0, (12) i 2 X ∂ ∂ ∂2 3 ϕ e2 − ρi0 zi + ϕ1ξ ϕ1η 4 ∂ξ∂η ∂ξ ∂η i 2 ∂ ∂ − ϕ1ξ ϕ1η = 0. − ∂ξ ∂η (13) Here, (13) comes from the elimination of ui2 between the first two equations in (9) and using the third equation in (9) to replace ρi2 , for the terms which depend on ξ and η together. A similar procedure will be followed for the higher-order equations. The structure of (11) and (12) points to two possibilities: either the ion composition is very special, in that P 3 i ρi0 zi = 1/3, or ϕ1ξ = ϕ1η = 0. The P former case corresponds to critical ion densities,Pas i ρi0 zi = 1 (charge 2 neutrality in equilibrium) and i ρi0 zi = 1 (choice of normalization), and a third condition on the densities ρi0 is not generic. Examples of critical ion densities are (9) discussed in Appendix A, and the critical composition itself will be investigated in detail in Section III. B. (10) (8) Generic case Pursuing now the generic case, that is, setting ϕ1ξ = ϕ1η = 0, one is, from (9)–(13), once again led to separability. The expressions for the second-order variables then resemble (8) with the index 1 replaced by 2. Next, we find that the third-order variables obey linear equations akin to (7), and that these variables do not appear in the equations for the fourth-order variables. We thus simply set ρi3 = ui3 = ϕ3 = 0. Finally, interesting new contributions involving the fourth-order variables, as well as P and Q, will arise at the last step we consider. Picking out those terms that depend on τ , and on either ξ or η, but not both, we find the typical KdV equations ∂ϕ2ξ ∂ϕ2ξ 1 ∂ 3 ϕ2ξ + Aϕ2ξ + = 0, ∂τ ∂ξ 2 ∂ξ 3 ∂ϕ2η ∂ϕ2η 1 ∂ 3 ϕ2η − Aϕ2η − = 0, ∂τ ∂η 2 ∂η 3 (14) for the right- and left-propagating solitary wave, respectively. Here the coefficient of the quadratic nonlinearity, 1 X A= 3 ρi0 zi3 − 1 , (15) 2 i has already been encountered in a similar role in (11) and (12), but for a numerical factor. Further information is in the terms which contain both ξ and η, besides τ , combining into " # ∂2 1 X ϕ e4 − ρi0 zi3 − 1 ϕ2ξ ϕ2η ∂ξ∂η 2 i 4 ∂P ∂ϕ2ξ ∂ − Bϕ2η ∂ξ ∂η ∂ξ ∂ ∂Q ∂ϕ2η + − Bϕ2ξ = 0, ∂η ∂ξ ∂η + (16) with B= 1 X ρi0 zi3 + 1 . 4 i (17) The second and third terms in (16) would generate secular contributions at the next higher order, so they must vanish, leading to equations for the phase shifts, ∂P = B ϕ2η , ∂η ∂Q = B ϕ2ξ . ∂ξ (18) It is seen that ∂P/∂η cannot depend on ξ and thus P itself might contain an additive part which would depend on ξ and τ , but not on η. This would refer to changes in the phase of the right-propagating soliton due to its own propagation and can be omitted altogether. Analogous arguments hold for the absence of η in Q. Note that B might be positive or negative, an aspect that is further addressed in Appendix B. The one-soliton solutions of (14) are the well-known “sech squared” solitons of KdV theory, here r 3vξ vξ 2 ϕ2ξ = sech (ξ − vξ τ ) , A 2 r vη 3vη sech2 (η + vη τ ) , (19) ϕ2η = A 2 expressed in terms of the velocities vξ and vη , respectively, for the right- and left-propagating soliton. This requires that vξ > 0 and vη > 0 and also indicates that the two interacting solitons have the same polarity, given by the sign of A. For A > 0 the solitons will have positive polarity, and for A < 0 negative polarity. To obtain the phase shifts after the head-on collision between the two solitons, we assume that Sξ and Sη are, asymptotically, far from each other at the initial time (t = −∞), i.e., Sξ is at ξ = 0, η = −∞ and Sη is at η = 0, ξ = +∞, respectively, as done in several of the cited papers, e.g., Ref. [12]. After the collision (t = +∞), Sξ is far to the right of Sη , i.e., Sξ is at ξ = 0, η = +∞ and Sη is at η = 0, ξ = −∞. The phase shifts expressed by P and Q are found from substitution of (19) into (18) and integration, yielding p r 3B 2vη vη P = tanh (η + vη τ ) + 1 , A 2 p r 3B 2vξ vξ Q= tanh (ξ − vξ τ ) − 1 . (20) A 2 Note that, although the stretching (4) uses opposing velocities c = 1 of equal magnitude, this does not hold FIG. 1. (Color online) Head-on collision for plasma composition with two positive ion species and Boltzmann electrons, for z1 = 4, z2 = 1/2, vξ = 0.05 and vη = 0.1. The values for z1 might refer to H+ and z2 to O+ . The solitons have positive polarity and are compressive in the densities. for the one-soliton solutions, which are superacoustic in their direction of propagation but can have quite different amplitudes. Increases in vξ entail increases in the amplitudes of Sξ as well as in the phase shift of Sη . Thus, the larger of the two solitons travels faster than the smaller one, but is less affected by the phase shift when emerging from the collision region. For the special case of a plasma with one species of ions only, besides the electrons, as usually treated in the literature,2 we adjust the normalization such that ρi0 = 1 and zi = 1 and find that A = 1 and B = 1/2, with corresponding simplifications in (14) and (18)–(20). We can illustrate the foregoing discussion with some graphs, for the case when there are two ion species. In Fig. 1 both ion species are positive, so that the solitons have the positive polarity given by the sign of A. The values for z1 might refer to hydrogen ions, H+ , and z2 to singly ionized oxygen, O+ . Furthermore, there is a general proof in Appendix B that when all ions are positive, A > 1 and B > 1/2. The phase shifts P and Q are then also positive, pointing to a delay in propagation occurring during the interaction, as compared to a single KdV soliton in the same physical system. When the ion mixture contains both positive and negative ions, either of the two cases may be obtained: the ratios z1 and z2 are then such that either both solitons are positive, or they are both negative. This is illustrated in Fig. 2 for z1 = 0.1 and z2 = −0.1, which leads to both solitons being negative. The charge-to-mass ratios have been taken equal in magnitude, which could cover the case of a fullerene (pair-ion) plasma,20,21 with an admixture of electrons. We note that these experiments were reported to involve only positive and negative fullerene ions,20,21 without any contamination. However, not all the observed wave dispersion could then be under- 5 ∂ϕ1η 1 ∂ 3 ϕ1η ∂ϕ1η = 0, − C ϕ21η − ∂τ ∂η 2 ∂η 3 (22) with C= 1 X 15 ρi0 zi4 − 1 . 4 i (23) The terms which contain both ξ and η, besides τ , allow for the determination of the phase shifts through ∂P = D ϕ21η , ∂η ∂Q = D ϕ21ξ , ∂ξ (24) where FIG. 2. (Color online) Head-on collision for plasma composition with positive and negative ion species, and Boltzmann electrons, for z1 = 0.1, z2 = −0.1, vξ = 0.01 and vη = 0.02. The underlying model is a fullerene (pair-ion) plasma with an admixture of electrons. The solitons have negative polarity and are rarefactive in the densities. stood. Hence, the presence of some electron admixture has been advocated in order to explain the wave dispersion diagrams.22 III. SOLITONS AND PHASE SHIFTS AT CRITICAL COMPOSITIONS In this section we take the ion densities to be critical, with A = 0, examples of which are discussed in Appendix A. The quadratic nonlinearity in the KdV equations (14) disappears, and in (10) we have to keep the contributions in ϕ1 . Without loss of generality, we can set ϕξ2 = 0 and ϕη2 = 0, but ϕ e2 6= 0, as shown by the simplified version of (13), 2 ∂2ϕ e2 1 ∂ ∂2 ∂2 + − − 2 ϕ1ξ ϕ1η = 0. (21) ∂ξ∂η 3 ∂ξ∂η ∂ξ 2 ∂η It is remarkable that, barring the coefficient in front of the parentheses, this equation is identical to what one obtains for quite different plasma models and waves, such as for ion-acoustic solitons in a mixture of cold ions with nonthermal electrons14 or for electron-acoustic solitary waves in a two-electron plasma with hot nonextensive and cool components, in the presence of a neutralizing ion background.13 At critical densities, the new contributions involving P and Q appear in the equations for the third order variables. Combining again the parts of these equations which contain terms that only depend on ξ or on η (besides τ ) yields the typical mKdV equations ∂ϕ1ξ ∂ϕ1ξ 1 ∂ 3 ϕ1ξ + C ϕ21ξ + = 0, ∂τ ∂ξ 2 ∂ξ 3 D= X 1 1− ρi0 zi4 . 8 i (25) Because mKdV equations like (22) are invariant for a sign inversion of ϕ1ξ or ϕ1η , the one-soliton solutions of (22) are r p 6vξ ϕ1ξ = ± sech 2vξ (ξ − vξ τ ) , C r p 6vη ϕ1η = ± sech 2vη (η + vη τ ) . (26) C Note that the respective ± signs are not coupled. Substitution of (26) into (24) and integration yields p 3D p 2vη tanh 2vη (η + vη τ ) + 1 , C p 3D p Q= 2vξ tanh 2vξ (ξ − vξ τ ) − 1 . (27) C P = P and Q are defined in terms of ϕ21η and ϕ21ξ , respectively, so that the polarity of the modes does not play a role in this aspect of the problem. However, D could be negative in certain parameter ranges. For counter-propagating solitons of the same polarity the graphs are qualitatively similar to those obtained in the generic case, as illustrated in Figs. 1 and 2. The characteristics are less steep, because one is now plotting “sech” rather than “sech squared” solutions. Interestingly, in the critical case the two mKdV equations (22) admit a combination of positive and negative modes. This is shown in Fig. 3 for a stronger right-propagating negative soliton and a weaker left-propagating positive soliton. In order to bring out more clearly the interaction around the time of the head-on collision, we present in Fig. 4 three snapshots of the combined soliton profile ϕ1 as function of x, for the plasma parameters used to generate Fig. 3. The times are chosen before (t = −5, dotted curve), during (t = 0, solid curve) and after (t = 5, dashed curve) the head-on collision. Although it is difficult to see in detail, the negative polarity contribution is for t = −5 at x = −5.573 but for t = 5 only at x = 5.564, 6 IV. FIG. 3. (Color online) Head-on collision between solitons of opposite polarities, for critical plasma composition, for z1 = 0.739, z2 = −1.552, vξ = 0.1 (negative polarity) and vη = 0.05 (positive polarity). This mimics a plasma with Ar+ and F− ions. j 0.3 0.2 0.1 -20 10 -10 20 x -0.1 -0.2 -0.3 CONCLUSIONS The head-on collision between two electrostatic solitons in a multi-ion plasma with Boltzmann electrons has been treated for a general model which can accommodate a number of cold ion species. For the more specific applications, we have illustrated the essential characteristics for different plasmas with two ion species, of the same or of the opposite sign. In the generic case, the solitons are governed by KdV equations, with a phase shift occurring during the interaction, which usually leads to a time delay compared to the trajectory of a single soliton in the same plasma. Both left- and right-propagating solitons must have the electrostatic polarity given by the sign of the coefficient, A, of the nonlinear term in the KdV equation. For plasmas with two positive ion species, the solitons have positive polarity, as in, e.g., a hydrogen-oxygen model. To obtain negative polarities, there should be at least one negative ion species, besides one or more positive ones, and this is shown for a fullerene (pair-ion) plasma with an admixture of electrons. When A vanishes, for critical plasma parameters, the KdV equation disappears and the scaling leads to an mKdV equation with cubic nonlinearity, a possibility not addressed earlier in the literature, except in our recent investigation of head-on collisions in nonthermal plasmas.14 As the mKdV equation is invariant for inversion of the electrostatic polarity, it allows for combinations of solitons of different polarities. We have chosen to discuss a negative right- and a positive left-propagating soliton, for a plasma in which the dominant ions are argon and fluorine, experimentally studied by Nakamura et al.23 -0.4 FIG. 4. (Color online) Graphs of ϕ1 as function of x for the plasma parameters used in Fig. 3, before (for t = −5, dotted curve), during (for t = 0, solid curve) and after (for t = 5, dashed curve) the head-on collision. indicating a delay in propagation time, compared to what a single soliton would do. Similarly, the positive polarity contribution is for t = −5 at x = 5.349 but for t = 5 only at x = −5.336, showing a similar delay. Moreover, the amplitudes for t = 5 are smaller (in absolute values) than their counterparts for t = −5. Solitary waves under critical conditions were studied in seminal experiments of Nakamura et al.23 They worked with a negative ion plasma, having argon (Ar+ ) and fluorine (F− ) ions as the dominant ion species. From a mass ratio of z1 /|z2 | = 0.476, they found that the coefficient of the KdV equation vanishes at a critical density ratio of 0.102. Our computations yield a critical density of n20 /n10 = 0.1024, and thus confirm the value found by Nakamura et al. Appendix A: TWO-ION PLASMAS AND CRITICAL DENSITIES The simplest example of a plasma exhibiting a critical composition is a two-ion model, for which the necessary conditions that ρ10 and ρ20 must obey are ρ10 z1 + ρ20 z2 = 1, ρ10 z12 + ρ20 z22 = 1, ρ10 z13 + ρ20 z23 = 31 . (A1) The first two equations determine ρ10 and ρ20 in terms of z1 and z2 , ρ10 = 1 − z2 , z1 (z1 − z2 ) ρ20 = z1 − 1 . z2 (z1 − z2 ) (A2) Since at least one ion species needs to be positive, we can assume, without loss of generality, that z1 > 0. In the case of two positive species, we take z1 > z2 > 0, and see that for the densities to be strictly positive, this condition is sharpened to z1 > 1 > z2 . When there is 7 a negative ion species, then z2 < 0, and one has to take z1 < 1, without any obvious restriction on z2 < 0. Using (A2) one can rewrite the third condition (A1) as (z1 − 1)(1 − z2 ) + 2 3 = 0. (A3) In the case of two positive ion species, for which z1 > 1 > z2 , this condition cannot hold, as the left-hand side of (A3) is larger than 2/3. For such plasmas A > 0, the solitons are always compressive, and hence there can be no critical parameters. As shown in Appendix B, this holds even for more than two ion species, provided all are positive. We thus return to the case of a positive and a negative ion species and hence assume that z2 < 0. Solving (A3) yields z2 = z1 − 1/3 < 0, z1 − 1 (A4) requiring that 1/3 < z1 < 1. This leads to 2 , − 6z1 + 1) 9(z1 − 1)3 = , (3z1 − 1)(3z12 − 6z1 + 1) ρ10 = − ρ20 z1 (3z12 (A5) and these densities are positive. Hence, critical densities can occur in a two-ion plasma only if there are both a positive and a negative ion species. This condition is also required for the presence of rarefactive solitons in the generic case, for A < 0. Appendix B: COEFFICIENTS OF QUADRATIC AND CUBIC NONLINEARITIES First, we shall prove that, when all ion species in a multi-ion plasma are positive (zi > 0), both the coefficient of the quadratic nonlinearity, A, and the sign of the phase shifts, B, are also positive. The two solitons must then have positive polarity and there can be no critical compositions. In Appendix A it was already shown that A > 0 for two ion species, but in fact it holds for any number of ion species, provided all arePpositive. i ρi0 zi = 1 and PWhen2 all zi > 0, the conditions ρ z = 1 are used to deduce a chain of (in)equalities, i0 i i !2 !2 X X 1/2 1/2 1/2 3/2 1= ρi0 zi2 = ρi0 zi · ρi0 zi i i ! 6 X i ρi0 zi ! X i ρi0 zi3 = X ρi0 zi3 , (B1) i with the help of the Cauchy-Schwarz inequality24 in the penultimate step. The proof of the Cauchy-Schwarz inequality is immediate for N -dimensional vectors, as P 2 (a · b)2 6 ||a||2 ||b||2 underPthe norm ||a||2 = i ai and the scalar product a·b = i ai bi . We thus find that ! X 1 3 A= 3 ρi0 zi − 1 > 1, 2 i ! 1 1 X 3 B= ρi0 zi + 1 > , (B2) 4 2 i for any number of cold positive ion species. The equality sign in (B2) holds for a single ion species, and only then. Next, we assume that the composition is critical, A = 0, for which a mix of positive and negative ion species is needed. Now we prove that the coefficient of the cubic nonlinearity in the mKdV equations (22), C,P cannot be P 2 zero under the conditions that ρ z = 1, i0 i i i ρi0 zi = P 3 1 and i ρi0 zi = 1/3. From A = 0 we deduce another chain of (in)equalities, !2 !2 X X 1/2 1 1/2 2 3 = ρi0 zi = ρi0 zi · ρi0 zi 9 i i ! ! X X X 2 4 < ρi0 zi ρi0 zi = ρi0 zi4 . (B3) i i i Hence we arrive at 1 C= 4 ! 15 X i ρi0 zi4 − 1 > 1 , 6 (B4) for any number of cold ion species, regardless of their charge signs. As in related investigations,25 there is no need to resort to higher-order KdV equations, which would then be nonintegrable. On the other hand, we see that ! X 1 1 D= 1− ρi0 zi4 < , (B5) 8 9 i indicating that D might be negative, depending on the values for the model parameters. ACKNOWLEDGMENTS M.A.H. acknowledges the support of the NRF of South Africa. The research was supported in part by the National Science Foundation (NSF) of the U.S.A. under Grant No. CCF-0830783. Any opinions, findings and conclusions or recommendations expressed in this material are those of the authors and therefore the NRF and NSF do not accept any liability in regard thereto. Jacob Rezac is thanked for verifying the computations and additional editing. 8 1 2 3 4 5 6 7 8 9 10 11 12 13 14 J. K. Xue, Phys. Rev. E 69, 016403 (2004). H. Demiray, J. Comput. Appl. Math. 206, 826 (2007). J. N. Han, S. C. Li, X. X. Yang, and W. S. Duan, Europ. Phys. J. D 47, 197 (2008). E. F. El-Shamy, R. Sabry, W. M. Moslem, and P. K. Shukla, Phys. Plasmas 17, 082311 (2010). P. Chatterjee, U. N. Ghosh, K. Roy, S. V. Muniandy, C. S. Wong, and B. Sahu, Phys. Plasmas 17, 122314 (2010). P. Eslami, M. Mottaghizadeh, and H. R. Pakzad, Physica Scripta 84, 015504 (2011). U. N. Ghosh, K. Roy, and P. Chatterjee, Phys. Plasmas 18, 103703 (2011). P. Chatterjee, M. Ghorui, and C. S. Wong, Phys. Plasmas 18, 103710 (2011). S. K. El-Labany, E. F. El-Shamy, and M. A. El-Eneen, Astrophys. Space Sci. 337, 275 (2012). U. N. Ghosh, P. Chatterjee, and R. Roychoudhury, Phys. Plasmas 19, 012113 (2012). P. Eslami, M. Mottaghizadeh, and H. R. Pakzad, Astrophys. Space Sci. 338, 271 (2012). S. K. El-Labany, E. F. El-Shamy, and M. G. El-Mahgoub, Astrophys. Space Sci. 339, 195 (2012). F. Verheest, Astrophys. Space Sci. 339, 203 (2012). F. Verheest, M. A. Hellberg, and W. A. Hereman, Phys. Rev. E 86, 036402 (2012). 15 16 17 18 19 20 21 22 23 24 25 C. H. Su and R. M. Mirie, J. Fluid Mech. 98, 509 (1980). M. Van Dyke, Perturbation Methods in Fluid Mechanics (2nd ed. Parabolic Press, Stanford, CA, 1975) pp. 108– 112. H. Washimi and T. Taniuti, Phys. Rev. Lett. 17, 996 (1966). C. S. Gardner, J. M. Greene, M. D. Kruskal, and R. M. Miura, Phys. Rev. Lett. 19, 1095 (1967). P. Harvey, C. Durniak, D. Samsonov, and G. Morfill, Phys. Rev. E 81, 057401 (2010). W. Oohara and R. Hatakeyama, Phys. Rev. Lett. 91, 205005 (2003). W. Oohara, D. Date and R. Hatakeyama, Phys. Rev. Lett. 95, 175003 (2005). H. Saleem, Phys. Plasmas 14, 014505 (2007). Y. Nakamura, J. L. Ferreira, and G. O. Ludwig, J. Plasma Phys. 33, 237 (1985). I. S. Gradshteyn and I. M. Ryzhik, Tables of Integrals, Series, and Products (6th ed., Academic Press, San Diego, CA, 2000) p. 1054. F. Verheest, J. Plasma Phys. 39, 71 (1988).