If we only consider advection and start with a "point" of material with Co=1000mg/l A point has no volume so can it have a concentration? So why do we say a “point”? K = 0.1 cm/sec dh = 10 cm dl = 100 cm φ = 0.2 How long will it take for the material to move 50cm? What will the concentration be at that location at that time? in the down gradient direction cm 0 .1 Kdh sec 10 cm = 0 .05 cm v= = φ dl 0 .2 100 cm sec d = vt d 50 cm t= = = 1000 sec = 0 .28 hr v 0 .05 cm sec mg C = C o = 1000 l Suppose that source enters the up gradient end of a column At a continuous concentration of Co=1000mg/l K = 0.1 cm/sec dh = 10 cm dl = 100 cm φ = 0.2 02 Dispersivity αx = 5 cm What will the concentration be at 50 cm after 1000sec? cm sec 10cm = 0.05 cm average linear velocity 0.2 100cm sec cm distance traveled in 1000sec? d = v t = 0.05 1000 sec = 50cm sec Kdh v= = φdl 0 .1 By inspection we know that the concentration should be 0.5*Co=500mg/l But let’s carry out the calculation 1 ALERT! ALERT! CORRECTION IN SUBSEQUENT LECTURE Experiment with the spreadsheet http://inside.mines.edu/~epoeter/_GW/22ContamTrans/C1d.xls http://inside.mines.edu/~epoeter/_GW/22ContamTrans/C1d.xls Note the values of C using only the first term and then both terms at times and locations where y your intutition allows y you to know the concentration. When is use of the second term important? When does excel cause it to be in error? Try x = 50, 49, 51, 0, 100 then 10, 30, 200 Consider other times TRY 10000sec x = 500, 490, 510, 0, 1000 then x = 100, 200, 300, 400, 450, compare 450 to 550 ?symmetrical? Where and when can you know the correct C? The second term is important for calculating C @ early times near the source. v = 0.05 cm sec x = 0.05 cm 1000sec = 50cm so X = Y = Z = 0 and we want Cmax sec cm m2 10000cm2 cm2 5cm + 1x10−10 0 . 25 = sec sec 1m2 sec 2 2 1 cm 1 m 10000cm cm2 Dy = v α x + D* = 0.05 5cm + 1x10−10 = 0 . 05 sec 5 sec 5 sec 1m2 2 2 1 1 cm m 10000cm cm2 5cm + 1x10−10 Dz = v α x + D* = 0.05 = 0 . 025 10 sec 10 sec 1m2 sec Dx = v α x + D* = 0.05 C= M 8(πt ) 3 2 Dx Dy Dz 1000mg C= 8(π 1000sec) C = 0.0402 3 2 0.25 cm2 cm2 cm2 0.05 0.025 sec sec sec mg 1000cm3 mg mg = 40.2 ~ 40 3 cm l l l 2