UNIVERSITY OF MALTA FACULTY OF MEDICINE & SURGERY PHARMACY DEPARTMENT MATERIAL SAFETY DATA SHEET LIGHT KAOLIN Table of Contents Ref. No. MSDS /PD/21_01 Valid for: 2 years from approval Page 1. Chemical Product 2. Composition and Information on Ingredients 3. Hazards Identification 4. First Aid Measures 5. Fire and Explosion Data 6. Accidental Release Measures 7. Handling and Storage 8. Exposure Controls/ Personal Protection 9. Physical and Chemical Properties 10. Stability and Reactivity Data 11. Toxicological Information 12. Ecological Information 13. Disposal Considerations 14. References 15. Appendices 16. Revision History Page 1 of 9 2 2 2 3 4 5 5 6 7 7 8 8 9 9 9 9 UNIVERSITY OF MALTA FACULTY OF MEDICINE & SURGERY PHARMACY DEPARTMENT MATERIAL SAFETY DATA SHEET LIGHT KAOLIN 1. Ref. No. MSDS /PD/21_01 Valid for: 2 years from approval Chemical Product Product Name: Kaolin Chemical name: Kaolin Synonyms: N/A Chemical Formula: H2Al2Si2OK8-H2O 2. Composition and Information on Ingredients Composition: Kaolin 100% by weight Toxicological Data on Ingredients: N/A 3. Hazards Identification Potential Acute Health Effects: Hazardous in case of inhalation (lung irritant). Slightly hazardous in case of skin contact (irritant), eye contact (irritant) and ingestion. Potential Chronic Health Effects: Slightly hazardous in case of ingestion. A4 (Not classifiable for human or animal) MUTAGENIC EFFECTS: N/A TERATOGENIC EFFECTS: N/A DEVELOPMENTAL TOXICITY: The substance may be toxic to upper respiratory tract and stomach. Repeated or prolonged exposure to the substance can produce target organs damage. CARCINOGENIC EFFECTS: Page 2 of 9 UNIVERSITY OF MALTA FACULTY OF MEDICINE & SURGERY PHARMACY DEPARTMENT MATERIAL SAFETY DATA SHEET LIGHT KAOLIN 4. Ref. No. MSDS /PD/21_01 Valid for: 2 years from approval First Aid Measures General measures: N/A Skin contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. Serious skin contact: N/A Eye contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Serious indigestion: N/A Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Serious inhalation: N/A Page 3 of 9 UNIVERSITY OF MALTA FACULTY OF MEDICINE & SURGERY PHARMACY DEPARTMENT MATERIAL SAFETY DATA SHEET LIGHT KAOLIN 5. Ref. No. MSDS /PD/21_01 Valid for: 2 years from approval Fire and Explosion Data Flammability of the Product: Non-flammable Auto-Ignition Temperature: N/A Flash points: N/A Flammable limits: N/A Products of Combustion: N/A Fire Hazards in Presence of Various Substances: N/A Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: N/A Risks of explosion of the product in presence of static discharge: N/A Fire fighting media and Instructions: N/A Special Remarks on Fire Hazards: N/A Special Remarks on Explosion Hazards: N/A Page 4 of 9 UNIVERSITY OF MALTA FACULTY OF MEDICINE & SURGERY PHARMACY DEPARTMENT MATERIAL SAFETY DATA SHEET LIGHT KAOLIN 6. Ref. No. MSDS /PD/21_01 Valid for: 2 years from approval Accidental Release Measures NB: Wear appropriate protective equipment/clothing including gloves before removing any spills. Small spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Large spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above the threshold limit value (TLV). Check TLV on the MSDS and with local authorities. 7. Handling and Storage Precautions: Do not breathe dust. Keep away from incompatibles such as oxidizing agents, acids, alkalis. Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 23°C (73.4°F). Page 5 of 9 UNIVERSITY OF MALTA FACULTY OF MEDICINE & SURGERY PHARMACY DEPARTMENT MATERIAL SAFETY DATA SHEET LIGHT KAOLIN Ref. No. MSDS /PD/21_01 Valid for: 2 years from approval 8. Exposure Controls/Personal Protection Airborne Exposure Limits: TWA: 2 (mg/m3) from ACGIH (TLV) [United States] [1999] Inhalation Respirable. TWA: 15 (mg/m3) from OSHA (PEL) [United States] Inhalation Total. TWA: 5 (mg/m3) from NIOSH Inhalation Respirable. TWA: 10 (mg/m3) from NIOSH [United States] Inhalation Total. TWA: 5 (mg/m3) from OSHA (PEL) [United States] Inhalation Respirable. Consult local authorities for acceptable exposure limits. Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal Protection: Safety glasses, gloves, lab coat, dust respirator, making sure to use an approved/certified respirator or equivalent. Page 6 of 9 UNIVERSITY OF MALTA FACULTY OF MEDICINE & SURGERY PHARMACY DEPARTMENT MATERIAL SAFETY DATA SHEET LIGHT KAOLIN 9. Ref. No. MSDS /PD/21_01 Valid for: 2 years from approval Physical and Chemical Properties Physical state and appearance: Off-white powdered solid. Odour: N/A Taste: N/A Molecular Weight: 258.2 g/mole pH (1% solution/water): N/A Boiling Point: N/A Melting Point: 1760°C (3200°F) Critical Temperature: N/A Specific Gravity (Water = 1): 2.2 Vapour Pressure (mmHg): N/A Vapour Density: N/A Volatility: N/A Odour Threshold: N/A Water/Oil Distribution Coefficient: N/A Ionicity (in Water): N/A Dispersion Properties: N/A Solubility: Insoluble in cold water, hot water, methanol, diethyl ether, n-octanol. 10. Stability and Reactivity Data Stability: The product is stable. Corrosivity: Non-corrosive in presence of glass Instability temperature: N/A Conditions of Instability: Excess dust generation, incompatible materials Incompatibles: Reactive with oxidizing agents, acids, alkalis Polymerization: Will not occur Page 7 of 9 UNIVERSITY OF MALTA FACULTY OF MEDICINE & SURGERY PHARMACY DEPARTMENT MATERIAL SAFETY DATA SHEET LIGHT KAOLIN 11. Ref. No. MSDS /PD/21_01 Valid for: 2 years from approval Toxicological Information Toxicity to animals: LD50: N/A LC50: N/A Effects on humans: Acute potential health effects: Skin: Dust may cause skin irritation Eyes: Dust may cause eye irritation Ingestion: May cause irritation of the digestive tract. Low hazard for usual industrial handling. Inhalation: Dust may cause respiratory tract irritation. Low hazard for usual industrial handling Chronic potential health effects: CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal) by ACGIH. May cause damage to the upper respiratory tract, stomach. Prolonged exposure may affect the stomach and respiratory system. The NIOSH Pocket Guide lists the respiratory system and stomach as target organs. Chronic inhalation may cause a particular type of pneumoconiosis called Kaolinosis. It is characterized by positive x-ray findings and mild reductions in pulmonary function. Pure Kaolin is apparently not fibrogenic and does not induce debilitating silicosis. However, if it is contaminated with crystalline silica it may produce severe lung effects, including emphysema and pulmonary fibrosis due to the contaminating silica. MUTAGENIC EFFECTS: N/A TERATOGENIC EFFECTS: N/A DEVELOPMENTAL TOXICITY: N/A Other information: Slightly hazardous in case of skin contact (irritant), ingestion and inhalation. 12. Ecological Information Ecotoxicity: N/A Page 8 of 9 UNIVERSITY OF MALTA FACULTY OF MEDICINE & SURGERY PHARMACY DEPARTMENT MATERIAL SAFETY DATA SHEET Valid for: 2 years from approval LIGHT KAOLIN 13. Ref. No. MSDS /PD/21_01 Disposal Considerations Waste Disposal: Waste must be disposed of in accordance with local environmental control regulations. 14. References Sciencelab.com. Material Safety Data Sheet; Light Kaolin, MSDS [Online] 2005 [cited 2012 Nov 6]. Available from: URL: http://www.sciencelab.com/msds.php?msdsId=9927200 Jmloveridge.com. Material Safety Data Sheet; Light Kaolin, MSDS [Online] 2012 [cited 2012 Nov 6]. Available from: URL: http://www.jmloveridge.com/cosh/Kaolin%20Light.pdf Clayton.edu. Material Safety Data Sheet; Light Kaolin, MSDS [Online] 2012 [cited 2012 Nov 6]. Available from: URL: http://www.clayton.edu/portals/690/chemistry/inventory/MSDS%20Kaolin.pdf 15. Appendices N/A 16. Revision History Version Number Amendments/ Reasons for change 01 Initial Release Page 9 of 9