Environmental Health and Safety Update Flammable Liquid Storage Limits and FDNY Permitting Requirements Overview The New York City Fire Department (FDNY) requires all work areas that store, handle and/or use combustible/flammable liquids to have a permit if the quantity is over the permit threshold set in the Fire Code. The FDNY also restricts the maximum amount of all combustible/flammable liquids that may be stored in any work area. Chemical Owners are responsible for maintaining their stocks of combustible/flammable liquids below their work area limit. This Update provides information on storage permit thresholds and limits for work areas. Applicability This procedure applies to all WCMC Chemical Owners who purchase and maintain combustible and flammable liquid inventories in their work area. Responsibilities Environmental Health and Safety provides guidance, training and assistance on flammable liquid storage issues as needed and assists chemical owners with obtaining FDNY permits where required. Chemical Owners are responsible for maintaining compliance with the FDNY combustible and flammable liquid storage limits and ensuring that the area where combustible/flammable liquids are stored, handled and/or used has a proper FDNY permit if those materials are over the permitting threshold. Procedure 1. Based on the fire rating and fire protection system of the work area, the FDNY restricts the amount of combustible/flammable liquids that may be stored or used. All Chemical Owners are required to determine the permit thresholds of their spaces. All Chemical Owners should utilize their chemical inventory to assist in calculating the inventory of combustible/flammable liquids that are stored or used in their spaces. For additional information on the chemical inventory, please visit the ChemTracker Chemical Inventory System EHS update. 2. In general, most work areas can be categorized as either a laboratory or a non-laboratory space. Below are the permit thresholds and storage limits for each category of space: Laboratory Units: All laboratory units will have an FDNY permit prior to occupancy. The laboratory permit type for each laboratory unit can be found on the Health and Safety Door Sign (HSDS) posted at the laboratory’s entrance. If the laboratory does not have an HSDS, follow these steps: 1. Contact EHS to determine flammable storage limits for the laboratory. 2. Submit a HSDS request via the EHS website at http://www.med.cornell.edu/ehs/forms_and_resources/door_sign_request_form.html. March 2013 Weill Medical College of Cornell University ▪ Environmental Health and Safety 402 East 67th Street, Room LA-0020 ▪ Phone 646-962-7233 ▪ FAX 646-962-0288 ehs@med.cornell.edu ▪ http://weill.cornell.edu/ehs EHS Update – Flammable Liquid Storage Limits and FDNY Permitting Requirements The table below lists the permit thresholds for different laboratory types, the maximum storage limits and the FDNY Certificate of Fitness that is required if the permit threshold is exceeded. Type Type I Type II Type III Type IV Permitting Threshold 1 gallon 1 gallon 1 gallon 1 gallon Maximum Storage Limits (with Permit) 30 gallons 25 gallons 20 gallons 15 gallons Certificate of Fitness C-14 (Supervising Chemical Laboratories) a. Non-Laboratory Units: For non-laboratory units, the permit threshold depends on the materials stored or used in the space. The table below lists the permit thresholds for various materials and the FDNY Certificate of Fitness that is required if the permit threshold is exceeded. Materials Class I Liquids (excluding laboratories, paints, varnishes, lacquers, gasoline and other petroleum-based Class I liquids) Gasoline and other petroleum-based Class I liquids (excluding laboratories, paints, varnishes, and lacquers) Rubbing alcohol Alcohol-based hand rubs/sanitizers (Class I) Alcohol-based hand rubs/sanitizers (Class II) Oil-based paints, varnishes, and lacquers Class III combustible liquids Permitting Threshold Maximum Storage Limits (with Permit) Certificate of Fitness 5 gallons 2½ gallons 5 gallons 5 gallons Determined by the FDNY Permit type issued C-98/C-26 (Storage And Use Of Flammable and/or Combustible Liquids) 10 gallons 20 gallons 70 gallons i. For all non-laboratories and non-permitted units, the Chemical Owners must ensure that combustible/flammable liquids are maintained below the permitting threshold. ii. If routine operations require that the unit maintain an inventory of combustible/flammable liquids in excess of the permitting threshold, the Chemical Owner of the unit must contact EHS for assistance in initiating the permitting process with the FDNY. The FDNY permit type issued will determine the maximum combustible/flammable liquids that can be stored/used in the unit. 3. For any unit/space that requires an FDNY permit, the unit must be under the personal supervision of a Certificate of Fitness holder. For laboratories, the FDNY requires a Certificate of Fitness for Supervising Chemical Laboratories (C-14). For non-laboratory units, the FDNY requires the Storage and Use of Flammable and/or Combustible Liquids (C-98/C-26) Certificate of Fitness. Page 2 of 3 EHS Update – Flammable Liquid Storage Limits and FDNY Permitting Requirements 4. If the amount of combustible/flammable liquids stored or used is over the storage limits, Chemical Owners must reduce the amount and modify purchasing practices in order to maintain compliance with FDNY regulations. Definitions Class I Flammable Liquids are liquid mixtures, substances or compounds which will emit a flammable vapor and have a closed cup flash point below 100°F (38°C). Examples include Acetone, Acetonitrile, Ethanol, Hexanes, Isopropanol, Methanol, N,N,N',N'-Tetramethylethylenediamine, and Xylene. To determine whether a chemical is flammable, refer to the manufacturer’s label or the Safety Data Sheet (SDS; formerly Material Safety Data Sheet, or MSDS). Combustible liquids are liquids which emit a flammable vapor at temperatures between 100 degrees Fahrenheit and 300 degrees Fahrenheit when tested in a Tangliabue open cup tester. Examples include Acetic acid, naphtha and Stoddard solvent. Combustible liquids are referred to as Class II or Class III liquids: Class II liquids - flash points at or above 100°F (37.8°C) and below 140°F (60°C). Class IIIA liquids - flash points at or above 140°F (60°C) and below 200°F (93.4°C). Class IIIB liquids - flash points at or above 200°F (93.4°C). Rubbing alcohol is a liquid that typically contains 70% of either ethyl or isopropyl alcohol. Rubbing alcohols are considered a Class I flammable liquid (flash point below 100°F). Alcohol-based hand rubs/sanitizers are defined by the New York City Fire Code as alcohol-containing preparations designed for application to the hands for anti micro-bacterial or other medicinal purpose. They usually contain ethanol or isopropanol in an amount not exceeding 70 percent by volume. They are typically classified as either a Class I flammable liquid (flash point below 100°F) or a Class II combustible liquid (flash point at or above 100°F and below 140°F). Laboratory Units are enclosed, fire-rated spaces used for testing, research, experimental or educational purposes. A laboratory unit may consist of a single room or an entire floor of a building depending on its construction. Safety Data Sheets (SDSs) are documents created by chemical manufacturers or suppliers which identify a chemical’s physical and health hazards, exposure limits, precautions, personal protective equipment required when handling the material, and procedures that should be followed in the case of an emergency. SDS’s are available from the manufacturer. Additional information can be found on the EHS MSDS website can provide assistance. Health and Safety Door Signs (HSDS) provide emergency contact and hazard information for laboratory spaces. Additionally, this sign identifies all areas included within that laboratory unit as well as the flammable liquid storage limit. Please visit EHS website to get more information or request a door sign at http://www.med.cornell.edu/ehs/forms_and_resources/door_sign_request_form.html. References FDNY: New York City Fire Code WCMC EHS: Laboratory Chemical Hygiene Plan WCMC EHS: ChemTracker Chemical Inventory System update WCMC EHS: Health and Safety Door Sign program Page 3 of 3