Upper Ocean Water Properties and Currents along Paired Sections in the Northern California Current, September 1999-2003 Jane H. Fleischbein Adriana Huyer P. Michael Kosro Robert L. Smith Jennifer J. Wetz and Patricia A. Wheeler College of Oceanic and Atmospheric Sciences Oregon State University Corvallis OR 97331-5003 Data Report 204 Reference 2006-1 January 2006 Table of Contents Introduction 1 Sampling 1 Vertical Distributions 2 Offshore Profiles 2 Characteristic Diagrams 2 Acknowledgements 2 References 2 List of Tables and Figures Table 1. CTD and biochemical (BC) sampling along paired NH- and CR-Lines, September 1999 to 2003. Figure 1. Shelf and coastline geometry in the region of the section pair, showing the standard CTD stations of each section, and the location of Cape Blanco, Columbia River estuary, and the 50, 200 and 2000 m isobaths. Figure 2. Six-hourly values of the coastal upwelling index at 45°N, 125°W (black) and 42°N, 125°W (red) in late summer and early autumn (15 August through 15 October) of 1999-2003. Long vertical lines indicate 1 September and 1 October. Short vertical lines indicate dates of hydrographic sampling on the NH-line (black) and the CRline (red). (Data from http://www.pfeg.noaa.gov.) Figure 3. Upper-ocean distributions of temperature (C). Figure 7. Upper-ocean distributions of geostrophic velocity (cm s-1, positive northward) relative to 500 dbar. Values inshore of the 500 m isobath were calculated by the method of Reid and Mantyla (1976). Figure 8. Upper-ocean distributions of northward (alongshore) component of ADCP velocity (cm s-1). Figure 9. Upper-ocean distributions of eastward (onshore) component of ADCP velocity (cm s-1). Figure 10. Upper-ocean distributions of Brunt-Vaisala frequency (cycles per hour); values were calculated at 10 m intervals as the least-squares fit over a 10-m centered bins; the shallowest value is at 9.5 m. Light contour is at 3 cph; heavy contours are at intervals of 6 cph. Figure 11. Upper-ocean distributions of spiciness (kg m-3), calculated from T-S characteristics following Flament (2002). Figure 4. Upper-ocean distributions of salinity (psu). Figure 5. Upper-ocean distributions of potential density anomaly (σθ, kg m-3). Figure 6. Upper-ocean distributions of geostrophic velocity (cm s-1, positive northward) relative to 150 dbar. Values inshore of the 150 m isobath were calculated by the method of Reid and Mantyla (1976). Figure 12. Upper-ocean distributions of oxygen saturation (%). Contour interval is 10 %; the 50 % and 100% contours are heavy and the 105% contour is dashed. Saturation percentage was calculated from CTD oxygen concentration data calibrated by Winkler-titrated samples from a few stations on each cruise, using the algorithm from the Scripps PACODF library. Figure 13. Upper-ocean distributions of fluorescence voltage (V). Contours: dashed at 0.5 V; thin at 1, 3; heavy at 2, 4; full scale is at 15 V in 2002 and at 5.0 V in other years. Fluorometer calibration is believed to remain about the same within each cruise though it may vary from cruise to cruise. Figure 14. Upper-ocean distributions of total nitrate (µmol/l). Figure 15. Upper-ocean distributions of phosphate (µmol/l). Figure 16. Upper-ocean distributions of silicate (µmol/l). Figure 17. Upper-ocean distributions of chlorophyll (mg/m ). Contours are at 0.5 (dashed), 1, and 2, 4, 8 (heavy), 12 and 3 16 mg/m . 3 Figure 18. Offshore profiles of surface temperature and salinity. Figure 19. Offshore profiles of steric height (J/kg) of the sea surface relative to 150 dbar and 500 dbar. Figure 20. Offshore profiles of surface density and of surface mixed layer depth, defined as the depth at which potential density exceeds the surface value by 0.01 kg m-3. Figure 21. Offshore profiles of surface density and of surface mixed layer depth, defined as the depth at which potential density exceeds the surface value by 0.1 kg m-3. Figure 22. T-S characteristics of all CTD stations. Shelf stations are plotted in red. Figure 23. Superimposed groups of T-S characteristics. Upper row: NH (black) on CR (red). Lower row: CR (red) on NH (black). Figure 24. Detail of T-S characteristics in the permanent halocline. Shelf stations are plotted in red. Figure 25. Oxygen-salinity characteristics of all CTD stations. Shelf stations are plotted in red. Figure 26. Detail of oxygen-salinity characteristics in and below the permanent halocline. Shelf stations are plotted in red. Figure 27. Nitrate-phosphate relations for all rosette samples. Shelf stations are plotted in red. Figure 28. Silicate-phosphate relations for all rosette samples. Shelf stations are plotted in red. Figure 29. Nitrate-salinity relations. Shelf stations are plotted in red. Figure 30. Nitrate-salinity relations for samples with salinities ≥ 32 psu. Shelf stations are plotted in red. Figure 31. Nitrate-salinity relations for samples with salinities ≥ 32 psu: CR data (red) superimposed on NH data (black). Figure 32. Phosphate-salinity relations. Shelf stations are plotted in red. Figure 35. Silicate-salinity relations. Shelf stations are plotted in red. Figure 33. Phosphate-salinity relations for samples with salinities ≥ 32 psu. Shelf stations are plotted in red. Figure 36. Silicate-salinity relations for samples with salinities ≥ 32 psu. Shelf stations are plotted in red. Figure 34. Phosphate-salinity relations for samples with salinities ≥ 32 psu: CR data (red) superimposed on NH data (black). Figure 37. Silicate-salinity relations for rosette samples with salinities ≥ 32 psu: CR data (red) superimposed on NH data (black). Upper Ocean Water Properties and Currents along Paired Sections in the Northern California Current, September 1999-2003 whose separation increases with distance from shore; the most offshore station, NH-85, is at 126.05ºW, 157 km from shore. The CR-line at 41.9ºN off Crescent City, California, lies 300 km farther south and spans a narrower shelf; this line was originally sampled during the 1981-1984 SuperCODE experiment (Huyer et al., 2002). The CR-line originally consisted of nine CTD stations with the most offshore at 125.3ºW. This section was extended in 2000 by adding two stations (at 125.7ºW and 126.0ºW). Beginning in September 2000, the station CR-9 at 125.3ºW was dropped in favor of CR-9a at 125.4ºW. Sampling along both sections included CTD/rosette casts at standard stations (Table 1), and continuous operation of an Acoustic Doppler Current Profiler; results of the concurrent zooplankton sampling are not included in this report. Details of CTD data collection, calibration and processing are available in a series of data reports (Fleischbein et al., 1999; 2001; 2002; 2003). Accuracy of the processed data is estimated to be better than ±0.01ºC for temperature, ±0.003 psu for salinity, ±1 dbar for pressure, and ±0.2 ml/l for dissolved oxygen. A SeaTech fluorometer was also mounted on the CTD/rosette frame. Biochemical sampling was conducted at most stations (Table 1). Water samples from the upper 150 m were analyzed to determine concentrations of inorganic nutrients (nitrate, phosphate, silicate, nitrite, ammonium), phytoplankton biomass (chlorophyll-a), particulate organic carbon and nitrogen, and dissolved organic carbon and nitrogen. Samples were collected with 5-L Niskin bottles on a 12-bottle rosette, with samples Introduction As part of the U. S. GLOBEC NorthEast Pacific Program we made repeated seasonal hydrographic surveys in the northern California Current system (Figure 1) between July 1997 and September 2003. These surveys included sampling along a pair of hydrographic sections, one north (at 44.6ºN) and one south (at 41.9ºN) of Cape Blanco (Figure 1) in September of five years (1999-2003). The coastal upwelling associated with the California Current experiences maximum upwelling during summer, and usually continues through much of September; upwelling is usually stronger at 42ºN than at 45ºN (Figure 2). One purpose of this report is to show differences and similarities between the coastal upwelling domains north and south of Cape Blanco. We present graphical summaries of the physical oceanographic and biochemical observations along both sections, principally in the form of zonal sections (0-160 km from shore, 0-150 m depth). We also show offshore profiles of a few selected properties, and some characteristic diagrams (T-S, oxygen-S, etc.). Similar reports showing results for mid-summer and for spring have already been published (Fleischbein et al., 2005a, b). Sampling The NH-line at 44.6ºN off Newport, Oregon, lies about 130 km south of the mouth of the Columbia River, and spans a relatively wide shelf. This line was sampled seasonally from 1961 to 1971 (Smith et al., 2001), and then sporadically until July 1997 when GLOBEC resumed sampling of the NH-line until the fall of 2003. The NH-line consists of 12 CTD stations -1- taken at about 150 m, 100 m, and at 10 m intervals in the upper 70 m. Analytical methods have been described by Corwith and Wheeler (2002) and by Hill and Wheeler (2002). The following plots in this data report include only nutrient and chl-a data. Sampling protocols, analytical information and tabulated values of nutrient and chl-a are available in the data report by Wetz et al. (2004). Upper-ocean currents were measured along each section by a shipborne acoustic Doppler current profiler (ADCP). On most cruises the ADCP system was narrowband, 150 kHz, with 8-m bins, manufactured by RD Instruments. ADCP data were collected in 2.5 min ensembles and processed using the University of Hawaii CODAS system (Firing, Ranada and Caldwell, 1995). Profiles were screened manually for bottom interference, corrected for gyrocompass errors with data from an Ashtech 3DF GPS-based system, calibrated for transducer and gyrocompass alignment, and processed to absolute currents by referring to differential GPS data. Kosro (2002) estimates high-frequency noise (due to tides and inertial currents) to be about ±8 cm/s. Offshore Profiles Offshore profiles (Figure 18-21) are shown for a few selected parameters: surface temperature and salinity, steric height, and mixed layer depth (determined from two separate criteria). Characteristic Diagrams T-S diagrams (Figures 22-24) include all available data, i.e., from depths below 150 m (to 1000 m) as well as above 150 m. To facilitate comparison and interpretation, we show the TS diagrams superimposed as well as separately. We also show oxygen-salinity (Figures 25-26), nutrient-phosphate (Figures 27-28) and nutrient-salinity diagrams (Figures 29-37). For most characteristic diagrams, we distinguish from “shelf” data (NH-1 to NH-15 and CR-1 to CR-3) from offshore data (all remaining stations). For some T-S and nutrientsalinity relations we show two versions: one with a wide salinity range (30-35 psu), and one with a narrow salinity range (32 to 34.5 psu). Acknowledgements We are grateful to all those who participated in collecting these data, including the captain, crew and especially the marine technicians of R/V Wecoma and R/V New Horizon. We are supported by the National Science Foundation through Grant OCE 0000733 and OCE 0434810. The LTOP hydrographic data collection and analysis are supported by the U.S. GLOBEC NorthEast Pacific Program, funded jointly by NSF and NOAA. Vertical Distributions The upper-ocean distributions (surface to 150 m depth) are shown for fifteen parameters: temperature, salinity, potential density, geostrophic velocity (relative to both 150 dbar and 500 dbar), ADCP measured current (northward and eastward components), buoyancy frequency, spiciness, dissolved oxygen saturation, fluorescence voltage, nitrate, phosphate, silicate, and chlorophyll (Figures 3-17). For each parameter, distributions are shown for both sections in each fall. References Corwith, H.L. and P.A. Wheeler. 2002. El Niño related variations in nutrient and chlorophyll distributions off Oregon. Progr. Oceanogr., 54, 361-380. -2- observation program off Oregon, 2001. College of Oceanic and Atmospheric Sciences, Oregon State University, Data Report 187, Ref. 2002-3, 168 pp. Fleischbein, J., A. Huyer, and R. L. Smith, 2003. Hydrographic data from the GLOBEC long-term observation program off Oregon, 2002 and 2003. College of Oceanic and Atmospheric Sciences, Oregon State University, Data Report 192, Ref. 2003-2, 296 pp. Hill, J.K. and P.A. Wheeler. 2002. Organic carbon and nitrogen in the northern California Current system during July 1997: comparison of offshore, river plume, and coastally upwelled water. Progr. Oceanogr., 53, 369-387. Kosro, P. M. 2002. A poleward jet and an equatorward undercurrent observed off Oregon and northern California during the 1997-98 El Niño, Progr. Oceanogr., 54, 343360. Reid, J. L., and A. W. Mantyla, 1976. The effect of geostrophic flow upon coastal sea elevations in the northern North Pacific Ocean. J. Geophys. Res., 81, 3100-3110. Smith, R. L., A. Huyer and J. Fleischbein. 2001. The coastal ocean off Oregon from 1961 to 2000: Is there evidence of climate change or only of Los Niños? Progr. Oceanography, 49, 63-93. Wetz, J. J., J. Hill, H. Corwith and P. A. Wheeler. 2004. Nutrient and extracted chlorophyll data from the GLOBEC Long-Term Observation Program, 1997-2004. Data Report 193, COAS Ref. 2004-1, 135 pp. Firing, E., J. Ranada and P. Caldwell. 1995. Processing ADCP data with the CODAS software system, version 3.1. Honolulu, HI: University of Hawaii. Flament, P. 2002. A state variable for characterizing water masses and their diffusive stability: spiciness. Progress in Oceanography, 54, 491-500. Fleischbein, J., A. Huyer, P. M. Kosro, R. L. Smith and P. A. Wheeler. 2005a. Upper ocean water properties and currents along paired sections in the northern California Current, summer 1998-2003. College of Oceanic and Atmospheric Sciences, Oregon State University, Data Report 201, Ref. 2005-4, 41 pp. Fleischbein, J.H., A. Huyer, P. M. Kosro, R. L. Smith, J. J. Wetz, and P. A. Wheeler. 2005b. Upper ocean water properties and currents along paired sections in the northern California Current, spring 1998-2003. College of Oceanic and Atmospheric Sciences, Oregon State University, Data Report 203, Ref. 2005-6, 42 pp. Fleischbein, J., J. Hill, A. Huyer, R. L. Smith and P. A. Wheeler. 1999. Hydrographic data from the GLOBEC long-term observation program off Oregon, 1997 and 1998. College of Oceanic and Atmospheric Sciences, Oregon State University, Data Report 172, Ref. 99-1, 288 pp. Fleischbein, J., A. Huyer, and R. L. Smith, 2001. Hydrographic data from the GLOBEC long-term observation program off Oregon, 1999 and 2000. College of Oceanic and Atmospheric Sciences, Oregon State University, Data Report 183, Ref. 2001-3, 290 pp. Fleischbein, J., A. Huyer, and R. L. Smith, 2002. Hydrographic data from the GLOBEC long-term -3- Table 1. CTD and biochemical (BC) sampling along paired NH- and CR-Lines, September 1999 to 2003. NH-1 NH-3 NH-5 NH-10 NH-15 NH-20 NH-25 NH-35 NH-45 NH-55 NH-65 NH-85 CR-1 CR-2 CR-3 CR-4 CR-5 CR-6 CR-7 CR-8 CR-9 CR-9a CR-10 CR-11 -124.100 -124.130 -124.177 -124.295 -124.412 -124.528 -124.650 -124.883 -125.117 -125.367 -125.600 -126.050 -124.300 -124.400 -124.500 -124.600 -124.700 -124.800 -125.000 -125.200 -125.333 -125.400 -125.667 -126.000 22-25 Sept 1999 Stn Max BC No Depth 1 20 2 46 3 57 x 4 76 5 86 x 6 136 7 285 x 8 426 x 9 694 x 10 1008 11 1008 x 12 1008 x 21 35 x 22 61 23 127 x 24 496 x 25 655 x 26 688 27 826 x 28 1006 29 1005 x 7-10 Sept 2000 Stn Max BC No Depth 1 24 2 43 3 52 x 4 76 5 90 x 6 139 7 280 x 8 430 x 9 680 x 10 1006 11 1005 x 12 1007 x 21 35 x 22 64 23 130 x 24 500 x 25 651 x 26 686 27 811 x 28 1006 29 1007 x 30 31 1006 1005 4-9 Sept 2001 Stn Max BC No Depth 1 25 2 44 3 56 x 4 78 5 88 x 6 138 7 281 x 8 426 x 9 696 x 10 1005 11 1006 x 12 1005 x 21 36 x 22 62 23 130 x 24 505 x 25 630 x 26 692 27 838 x 28 1006 29 30 x -4- 1005 1006 x x 28 Sept -1 Oct 2002 Stn Max BC No Depth 1 2 3 4 5 6 7 8 9 10 12 19 20 21 22 23 18 17 16 41 53 74 87 134 272 435 684 1005 1006 1014 35 63 132 495 646 689 802 1005 15 14 13 1002 1007 1006 x x x x x x x x x x x x x x 26-29 Sept 2003 Stn Max BC No Depth 1 26 2 44 3 55 x 4 77 5 87 x 6 136 7 280 x 9 430 x 10 680 x 11 1005 12 1006 x 13 1006 x 14 35 x 15 62 16 130 x 17 500 x 18 650 x 19 691 20 811 x 21 1005 22 23 24 1005 1005 1005 x x Columbia River m 46 200 45 Latitude (N) Newport 50 m NH 44 43 Cape Blanco 42 CR Crescent City 2000 m 41 127 126 125 124 Longitude (W) 123 122 Figure 1. Shelf and coastline geometry in the region of the section pair, showing the standard CTD stations of each section, and the location of Cape Blanco, Columbia River estuary, and the 50, 200 and 2000 m isobaths. -5- 42N 45N 300 0 1999 Offshore Ekman Transport (m 3/100 m) -300 300 0 2000 -300 300 0 2001 -300 300 0 2002 -300 300 0 2003 -300 15 15 1 August September 15 1 October Figure 2. Six-hourly values of the coastal upwelling index at 45°N, 125°W (black) and 42°N, 125°W (red) in late summer and early autumn (15 August through 15 October) of 1999-2003. Long vertical lines indicate 1 September and 1 October. Short vertical lines indicate dates of hydrographic sampling on the NH-line (black) and the CR-line (red). (Data from http://www.pfeg.noaa.gov.) -6- Sep 99 16 Depth (m) 0 50 Sep 00 Sep 01 15 15 16 Sep 03 10 17 14 16 15 9 10 8 NH 8.5 8.5 100 8 8 8 150 15 0 50 10 9.5 13 10 10 15 8.5 9 CR 8.5 -80 Distance (km) 8 11 12 10 9 8 150 -160 7.5 13 9 100 7.5 8 17 11 Depth (m) Sep 02 8 8 0 Figure 3. Upper-ocean distributions of temperature (C). -7- 8 Sep 99 32 31.6 0 Depth (m) Sep 00 31.6 32.2 Sep 02 32 32 Sep 03 33 33 32.2 32 32.8 50 32.8 NH 33 100 150 33.9 33.9 0 50 33.8 32.6 33 33 33 32.2 32.8 33 Depth (m)) Sep 01 33.4 CR 100 33.8 33 34 33.9 150 -160 -80 Distance (km) 33.9 34 33.9 0 Figure 4. Upper-ocean distributions of salinity (psu). -8- Sep 99 23 Depth (m) 0 24 Sep 00 Sep 01 24 25 25 Sep 02 24 Sep 03 25 24 25 50 NH 26 100 26.25 26.25 26.25 26.25 26.25 150 25 0 25 26 24 25 Depth (m) 25.25 25 50 26 26 26 100 26.25 26.25 150 -160 -80 Distance (km) 26 26.25 26.25 0 Figure 5. Upper-ocean distributions of potential density anomaly (σθ, kg m-3). -9- 26.25 CR Sep 99 0 20 Sep 00 -30 Sep 01 Sep 02 -10 -30 Sep 03 -30 -30 Depth (m) 0 50 0 0 0 100 NH 0 0 0 150 0 -10 20 -20 -10 -20 Depth (m) 0 -10 50 0 0 CR 0 0 100 0 0 150 -160 0 -80 0 Distance (km) Figure 6. Upper-ocean distributions of geostrophic velocity (cm s-1, positive northward) relative to 150 dbar. Values inshore of the 150 m isobath were calculated by the method of Reid and Mantyla (1976). -10- Sep 99 0 30 Sep 00 -30 -30 0 0 Depth (m) Sep 01 Sep 02 Sep 03 -20 -30 -10 -30 -10 50 0 0 0 0 100 NH 0 150 0 -10 30 -30 -20 -10 Depth (m) -20 50 CR 0 100 -10 0 0 0 0 0 0 150 -160 -80 0 Distance (km) Figure 7. Upper-ocean distributions of geostrophic velocity (cm s-1, positive northward) relative to 500 dbar. Values inshore of the 500 m isobath were calculated by the method of Reid and Mantyla (1976). -11- Sep 99 Sep 00 Sep 01 Sep 03 0 -10 Depth (m) 30 -20 0 0 10 0 150 0 0 0 0 0 -20 20 30 0 -10 0 -40 30 -20 10 50 0 CR 0 -20 0 0 0 0 150 -160 NH -10 0 100 0 Depth (m) 0 0 50 100 -30 0 -20 -80 Distance (km) 0 Figure 8. Upper-ocean distributions of northward (alongshore) component of ADCP velocity (cm s-1). -12- Sep 99 Sep 00 Sep 01 Sep 03 0 Depth (m) -10 -10 50 0 -10 -20 0 -10 0 0 0 NH 0 100 0 0 0 0 0 0 150 20 0 0 Depth (m) 10 50 30 0 0 0 -20 0 0 40 0 -10 30 100 0 0 150 -160 -80 Distance (km) 0 0 0 Figure 9. Upper-ocean distributions of eastward (onshore) component of ADCP velocity (cm s-1). -13- CR Sep 99 0 18 Sep 00 Sep 01 18 6 Sep 02 18 3 3 Depth (m) 6 3 6 12 12 50 NH 6 100 6 3 3 6 3 50 6 3 3 150 0 6 6 3 Depth (m) Sep 03 6 3 12 3 3 3 12 3 12 3 6 6 6 6 100 CR 6 6 3 150 -160 3 3 3 -80 0 Distance (km) Figure 10. Upper-ocean distributions of Brunt-Vaisala frequency (cycles per hour); values were calculated at 10 m intervals as the least-squares fit over a 10-m centered bins; the shallowest value is at 9.5 m. Light contour is at 3 cph; heavy contours are at intervals of 6 cph. -14- Sep 99 Depth (m) 0 -0.6 0 50 100 Sep 00 Sep 01 0.2 0 -1 -1 -1 NH -0.2 -0.2 -0.2 -0.2 0 150 0.4 0 0 0 0.4 -0.6 0 -0.4 -0.4 Depth (m) Sep 03 0 0.2 -0.8 -0.8 Sep 02 0 50 -0.6 -0.2 -0.2 0 100 0 150 -160 -120 -80 -40 Distance (km) -1 0 CR 0 -0.2 0 Figure 11. Upper-ocean distributions of spiciness (kg m-3), calculated from T-S characteristics following Flament (2002). -15- Apr 99 Depth (m) 0 Apr 00 100 Mar 01 50 100 90 90 90 Apr 03 110 100 NH 100 50 50 50 50 40 150 30 40 100 100 90 50 40 40 120 105 100 100 0 Depth (m) Apr 02 90 105 90 CR 90 100 50 50 50 50 40 50 40 40 150 -160 -80 0 Distance (km) Figure 12. Upper-ocean distributions of oxygen saturation (%). Contour interval is 10 %; the 50 % and 100% contours are heavy and the 105% contour is dashed. Saturation percentage was calculated from CTD oxygen concentration data calibrated by Winkler-titrated samples from a few stations on each cruise, using the algorithm from the Scripps PACODF library. -16- Sep 99 Depth (m) 0 Sep 00 1 1 1 50 Sep 02 Sep 03 2 4 0.5 Sep 01 0.5 0.5 0.5 0.5 NH 5 100 4 3 150 2 5 0 0.5 1 Depth (m) 0.5 4 2 1 1 0.5 50 2 0.5 0 0.5 CR 100 150 -160 -80 0 Distance (km) Figure 13. Upper-ocean distributions of fluorescence voltage (V). Contours: dashed at 0.5 V; thin at 1, 3; heavy at 2, 4; full scale is at 15 V in 2002 and at 5.0 V in other years. Fluorometer calibration is believed to remain about the same within each cruise though it may vary from cruise to cruise. -17- Sep 99 Sep 00 0.5 0 Depth (m) Sep 02 5 0.5 10 Sep 01 Sep 03 10 0.5 0.5 50 NH 100 30 30 30 30 30 150 0 5 5 10 Depth (m) 50 150 -160 5 10 20 100 10 5 10 0.5 CR 20 25 30 30 -80 Distance (km) 30 30 0 Figure 14. Upper-ocean distributions of total nitrate (µmol/l). -18- 30 0 Sep 99 Sep 00 0.5 0.5 Sep 01 Sep 02 0.5 Sep 03 1 0.5 Depth (m) 1 1 50 3 2 2 2 100 3 NH 2 2 2.5 2.5 150 0 0.5 1 1 Depth (m) 1 50 1 1 1.5 CR 1.5 100 150 -160 2 2 2 -80 Distance (km) 2 2 0 Figure 15. Upper-ocean distributions of phosphate (µmol/l). -19- Sep 99 Sep 00 0 Depth (m) 20 NH 30 30 50 40 40 10 30 40 10 5 10 5 20 20 30 30 -80 Distance (km) CR 10 30 40 150 -160 20 40 5 10 100 60 50 0 Depth (m) 5 20 30 150 50 10 10 20 40 Sep 03 5 10 50 100 Sep 02 5 5 10 Sep 01 40 40 40 0 Figure 16. Upper-ocean distributions of silicate (µmol/l). -20- 30 20 40 Sep 99 0 Sep 00 8 2 0.5 0.5 Depth (m) Sep 01 Sep 02 2 1 Sep 03 1 0.5 4 1 0.5 0.5 50 NH 100 20 16 12 150 0 0.5 1 8 8 1 Depth (m) >0.5 8 1 >0.5 2 8 4 1 0 50 0.5 0.5 100 150 -160 -80 Distance (km) 0 Figure 17. Upper-ocean distributions of chlorophyll (mg/m ). Contours are at 0.5 (dashed), 1, and 2, 4, 8 (heavy), 12 and 16 3 mg/m . 3 -21- CR Sep 99 Sep 00 Sep 01 Sep 02 Surface Salinity Surface Temperature 20 NH 16 12 CR 8 36 34 32 30 160 80 Distance (km) 0 Figure 18. Offshore profiles of surface temperature and salinity. -22- Sep 03 Sep 00 Sep 01 Sep 02 Sep 03 100 Geopot Anom (0/150) Geopot Anom (0/500) Sep 99 NH 80 CR 60 40 20 160 80 Distance (km) 0 Figure 19. Offshore profiles of steric height (J/kg) of the sea surface relative to 150 dbar and 500 dbar. -23- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Mixed Layer Depth (m) 60 40 CR 20 NH Surface σθ 0 27 24 21 160 80 Distance (km) 0 Figure 20. Offshore profiles of surface density and of surface mixed layer depth, defined as the depth at which potential density exceeds the surface value by 0.01 kg m-3. -24- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Mixed Layer Depth (m) 80 60 CR 40 NH 20 Surface σθ 0 27 24 21 160 80 Distance (km) 0 Figure 21. Offshore profiles of surface density and of surface mixed layer depth, defined as the depth at which potential density exceeds the surface value by 0.1 kg m-3. -25- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 18 NH 1-15 Temperature p (C) ( ) 15 12 9 NH 20-85 6 3 18 CR 1-3 Temperature p (C) ( ) 15 12 9 CR 4-11 6 3 31 32 33 34 Salinity (psu) 35 Figure 22. T-S characteristics of all CTD stations. Shelf stations are plotted in red. -26- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 18 NH Temperature p (C) ( ) 15 12 9 CR 6 3 18 NH Temperature p (C) ( ) 15 12 9 CR 6 3 31 32 33 34 Salinity (psu) 35 Figure 23. Superimposed groups of T-S characteristics. Upper row: NH (black) on CR (red). Lower row: CR (red) on NH (black). -27- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Temperature (C) 12 NH 1-15 9 NH 20-85 6 Temperature (C) 12 CR 1-3 9 CR 4-11 6 32 33 34 Salinity (psu) Figure 24. Detail of T-S characteristics in the permanent halocline. Shelf stations are plotted in red. -28- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Dissolved Oxygen yg (ml/l) ( ) 10 8 NH 6 1-15 4 NH 2 20-85 0 Dissolved Oxygen yg (ml/l) ( ) 10 8 CR 6 1-3 4 CR 2 4-11 0 31 32 33 34 Salinity (psu) 35 Figure 25. Oxygen-salinity characteristics of all CTD stations. Shelf stations are plotted in red. -29- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Dissolved Oxygen (ml/l) 10 8 NH 6 1-15 4 NH 2 20-85 0 Dissolved Oxygen (ml/l) 10 8 CR 6 1-3 4 CR 2 4-11 0 32 33 34 Salinity (psu) Figure 26. Detail of oxygen-salinity characteristics in and below the permanent halocline. Shelf stations are plotted in red. -30- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Nitrate (µM) 40 NH-5,15 20 NH-25 to -85 0 Nitrate (µM) 40 CR-1,3 20 CR-4 to -11 0 0 2 4 Phosphate (µM) Figure 27. Nitrate-phosphate relations for all rosette samples. Shelf stations are plotted in red. -31- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Silicate (µM) 150 100 NH-5,15 NH-25 to -85 50 0 Silicate (µM) 150 100 CR-1,3 CR-4 to -11 50 0 0 2 4 Phosphate (µM) Figure 28. Silicate-phosphate relations for all rosette samples. Shelf stations are plotted in red. -32- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Nitrate (µM) 40 NH-5,15 20 NH-25 to -85 0 Nitrate (µM) 40 CR-1,3 20 CR-4 to -11 0 30 32 34 Salinity (psu) Figure 29. Nitrate-salinity relations. Shelf stations are plotted in red. -33- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Nitrate (µM) 40 NH-5,15 20 NH-25 to -85 0 Nitrate (µM) 40 CR-1,3 20 CR-4 to -11 0 32 33 34 Salinity (psu) Figure 30. Nitrate-salinity relations for samples with salinities ≥ 32 psu. Shelf stations are plotted in red. -34- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Nitrate (µM) 40 NH CR 20 0 32 33 34 Salinity (psu) Figure 31. Nitrate-salinity relations for samples with salinities ≥ 32 psu: CR data (red) superimposed on NH data (black). -35- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 (µM) Phosphate (uM) 4 NH-5,15 2 NH-25 to -85 0 (µM) Phosphate (uM) 4 CR-1,3 2 CR-4 to -11 0 30 34 32 Salinity (psu) Figure 32. Phosphate-salinity relations. Shelf stations are plotted in red. -36- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Phosphate (µM) 4 NH-5,15 2 NH-25 to -85 0 Phosphate (µM) 4 CR-1,3 2 CR-4 to -11 0 32 34 Salinity (psu) Figure 33. Phosphate-salinity relations for samples with salinities ≥ 32 psu. Shelf stations are plotted in red. -37- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Phosphate (µM) 4 NH 2 CR 0 32 34 33 Salinity (psu) Figure 34. Phosphate-salinity relations for samples with salinities ≥ 32 psu: CR data (red) superimposed on NH data (black). -38- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Silicate (µM) 150 100 NH-5,15 NH-25 to -85 50 0 Silicate (µM) 150 100 CR-1,3 CR-4 to -11 50 0 30 32 34 Salinity (psu) Figure 35. Silicate-salinity relations. Shelf stations are plotted in red. -39- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Silicate (µM) 150 100 NH-5,15 NH-25 to -85 50 0 Silicate (µM) 150 100 CR-1,3 CR-4 to -11 50 0 32 33 34 Salinity (psu) Figure 36. Silicate-salinity relations for samples with salinities ≥ 32 psu. Shelf stations are plotted in red. -40- Sep 99 Sep 00 Sep 01 Sep 02 Sep 03 Silicate (µM) (uM) 150 100 NH CR 50 0 32 33 34 Salinity (psu) Figure 37. Silicate-salinity relations for rosette samples with salinities ≥ 32 psu: CR data (red) superimposed on NH data (black). -41-