Updated Weblinks – Higher Chemistry Periodicity, Polarity and Properties 1. Trends in the Periodic Table and Bonding (a) The arrangement of elements in the Periodic Table http://www.rsc.org/Education/Teachers/Resources/PeriodicTableOfData.asp (b) Bonding and Structure of the first 20 elements http://www.rsc.org/Education/Teachers/Resources/Books/BooksA-C.asp http://media.rsc.org/videoclips/demos/SiliconandSilanes.mpg http://www.periodicvideos.com/ (c) Periodic trends in ionisation energy and covalent radius http://www.rsc.org/Education/Teachers/Resources/PeriodicTableOfData.asp http://www.rsc.org/chemsoc/visualelements/pages/page2.html (d) Periodic trends in Electronegativity http://chemsite.lsrhs.net/ChemicalBonds/images/custom_dipole2.swf http://www.rsc.org/images/Linus_Pauling_tcm18-189059.pdf http://www.rsc.org/Education/Teachers/Resources/PeriodicTableOfData.asp (e) Polar Covalent Bonds http://www.chm.bris.ac.uk/teaching-labs/1AManual2005-6/Experiment1.pdf (f) Bonding Continuum http://www.rsc.org/education/chemistryteachers/Index_Results.asp?Page=1&ID=11311&Search= 2. Intermolecular Forces (a) Van der Waals Forces http://www.rsc.org/Education/Teachers/Resources/Books/Misconceptions.asp (b) London Dispersion Forces http://www.rsc.org/Education/Teachers/Resources/PeriodicTableOfData.asp (c) Permanent Dipole - Permanent Dipole Interactions None (d) Hydrogen Bonding http://www.rsc.org/education/chemistryteachers/Index_Results.asp?Page=1&ID=11460&Search= http://www.rsc.org/Education/Teachers/Resources/Inspirational/ (section4.4, Hydrogels) http://media.rsc.org/Classic%20Chem%20Demos/CCD-41.pdf (e) Relating Properties to Intermolecular Forces http://media.rsc.org/Classic%20Chem%20experiments/CCE-2.pdf (viscosity) http://media.rsc.org/Classic%20Chem%20Demos/CCD-41.pdf (density) http://www.chemistryvideos.org.uk/chem%20clips/PR%20Viscosity%20in%20alcohols/viscosity%20in%20alcohols.htm UPDATED WEBLINKS (H, CHEMISTRY) 1 © Learning and Teaching Scotland 2011 (f) Predicting solubility from solute and solvent polarities http://media.rsc.org/Classic%20Chem%20experiments/CCE-2.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-41.pdf http://www.chemistryvideos.org.uk/chem%20clips/PR%20Viscosity%20in%20alcohols/viscosity%20in%20alcohols.htm 3. Oxidising and Reducing Agents (a) Elements as oxidising or reducing agents http://media.rsc.org/Classic%20Chem%20experiments/CCE-19.pdf http://media.rsc.org/videoclips/clips/DisplacementHalF2.mpg http://www.chemistryvideos.org.uk/chem%20clips/KS3%20Halogen%20displacment/halogen%20displacement.html http://www.practicalchemistry.org/experiments/displacement-series-for-non-metals,259,EX.html http://media.rsc.org/Classic%20Chem%20experiments/CCE-97.pdf http://media.rsc.org/videoclips/demos/ThermitReaction.mpg (b) Molecules and group ions can act as oxidising and reducing agents http://www.rsc.org/Education/Teachers/Resources/Books/BooksA-C.asp http://media.rsc.org/Classic%20Chem%20experiments/CCE-83.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-29.pdf http://www.rsc.org/Education/Teachers/Resources/Contemporary/index.html (password RSC2004) http://media.rsc.org/Classic%20Chem%20Demos/CCD-53.pdf http://www.practicalchemistry.org/experiments/finding-the-formula-of-copper-oxide,210,EX.html (c) Everyday uses for strong oxidising agents http://www.rsc.org/Education/EiC/issues/2009Nov/SoundbiteMolecules.asp http://www.scienceinthebox.com/en_UK/glossary/bleaches_en.html (d) Ion-electron and redox equations http://www.ltscotland.org.uk/Images/3729chem2_tcm4-124438.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-59.pdf http://www.practicalchemistry.org/experiments/estimation-of-the-concentration-of-householdbleach,253,EX.html http://media.rsc.org/In%20Search%20of%20Solutions/ISOSacts50.pdf Consumer Chemistry 1. Alcohols (a) Ethanol Production http://media.rsc.org/Classic%20Chem%20experiments/CCE-86.pdf http://www.chemistry-react.org/go/Tutorial/Tutorial_4783.html (b) Alcohols http://www.bbc.co.uk/scotland/learning/bitesize/higher/chemistry/carbon/naming_rev3.shtml http://www.chemguide.co.uk/organicprops/alcohols/background.html (c) Uses of Alcohols http://www.practicalchemistry.org/experiments/the-whoosh-bottle-demonstration,240,EX.html http://media.rsc.org/Classic%20Chem%20Demos/CCD-28.pdf http://www.chem13news.uwaterloo.ca/issues/350/Page_4_5_Dec%202007_Number_352_final.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-30.pdf UPDATED WEBLINKS (H, CHEMISTRY) 1 © Learning and Teaching Scotland 2011 http://www.practicalchemistry.org/experiments/heat-energy-from-alcohols,113,EX.html http://www.practicalchemistry.org/experiments/measuring-heat-energy-of-fuels,21,EX.html 2. Carboxylic Acids (a) Carboxylic Acids http://www.rsc.org/education/chemistryteachers/Index_Results.asp?Page=1&ID=11389&Search= (b) Uses of Carboxylic Acids http://www.guardian.co.uk/lifeandstyle/2009/aug/23/how-to-remove-limescale http://www.vinegartips.com/scripts/pageViewSec.asp?id=7 http://www.foodreference.com/html/artvinegar.html 3. Fruit Flavours (a) Esters http://www.bbc.co.uk/scotland/learning/bitesize/higher/chemistry/carbon/naming_rev4.shtml (b) Making Esters http://www.ltscotland.org.uk/Images/3729chem2_tcm4-124438.pdf (c) Uses of Esters http://www.scribd.com/doc/24382589/Lab-08 (d) Hydrolysis of esters None 4. Fats and Oils (a) Edible fats and oils http://www.practicalchemistry.org/experiments/fat-pan-fire,228,EX.html (b) Melting Points of Fats and Oils http://media.rsc.org/Classic%20Chem%20experiments/CCE-9.pdf 5. Proteins (a) Function of Proteins http://moleculesinmotion.com/jmol/protein_intro/index.html (b) Amino Acids http://www.rsc.org/Education/Teachers/Curriculum/curriculuminscience.asp (c) Amide Links http://www.rsc.org/education/chemistryteachers/Index_Results.asp?Page=1&ID=11323&Search= (d) Hydrolysis of Proteins None UPDATED WEBLINKS (H, CHEMISTRY) 1 © Learning and Teaching Scotland 2011 6. Chemistry of Cooking (a) Flavour in Food http://www.rsc.org/Education/Teachers/Resources/kitchenchemistry/00_video.htm (V04) http://www.rsc.org/Education/Teachers/Resources/kitchenchemistry/00_video.htm (V08) http://antoine.frostburg.edu/chem/senese/101/features/capsaicin.shtml (b) Changes in Protein Structure upon heating http://www.rsc.org/Education/Teachers/Resources/kitchenchemistry/00_video.htm (V09) 7. Oxidation of food (a) Oxidation of Alcohols http://www.practicalchemistry.org/experiments/oxidation-of-ethanol,239,EX.html http://www.practicalchemistry.org/experiments/the-oxidation-of-alcohols,217,EX.html http://media.rsc.org/Microscale%20chemistry/Microscale%2050.pdf (b) Aldehydes and Ketones http://www.ltscotland.org.uk/Images/3729chem2_tcm4-124438.pdf http://media.rsc.org/videoclips/demos/Silvermirror.mpg (c) Antioxidants http://www.understandingfoodadditives.org/ http://www.rsc.org/Education/Teachers/Resources/Aflchem/(44) http://media.rsc.org/Microscale%20chemistry/Microscale%2036.pdf http://www.ltscotland.org.uk/Images/3729chem2_tcm4-124438.pdf 8. Soaps and Emulsions (a) Making Soaps http://www.practicalchemistry.org/experiments/enhancement/fun-experiments/making-soaps-anddetergents,300,EX.html (b) Cleansing Action of Soaps http://www.bing.com/search?q=cleansing+action+of+soaps&src=IE-SearchBox&FORM=IE8SRC (c) Emulsions in Foods http://www.practicalchemistry.org/experiments/emulsifiers,125,EX.html http://www.rsc.org/Education/Teachers/Resources/Inspirational/ (section3.2) 9. Fragrances (a) Essential Oils None (b) Terpenes None UPDATED WEBLINKS (H, CHEMISTRY) 1 © Learning and Teaching Scotland 2011 10. Skin Care Products (a) Effect of Ultraviolet Light http://www.skincarephysicians.com/agingskinnet/uv_photography.html http://www.nhs.uk/conditions/Sunburn/Pages/Introduction.aspx http://www.dermatology.ucsf.edu/skincancer/General/prevention/Sunscreen.aspx (b) Free Radical reactions http://media.rsc.org/Classic%20Chem%20Demos/CCD-47.pdf http://media.rsc.org/videoclips/clips/ReactionCl2H2.mpg (c)Free Radical Scavengers http://www.naturalremedies.org/edaravone/ Principles to Production 1. Getting the most from Costly Reactants (a) Factors influencing the design of an industrial process http://www.rsc.org/Education/Teachers/Resources/Alchemy/ http://media.rsc.org/nonRSC/GreenChemistryTeachersPack.pdf (b) Calculation of the mass or volume (for gases) of products, assuming complete conversion of reactant(s) http://www.rsc.org/education/chemistryteachers/Index_Results.asp?Page=1&ID=11790&Search http://media.rsc.org/Classic%20Chem%20Demos/CCD-53.pdf http://media.rsc.org/Classic%20Chem%20experiments/CCE-68.pdf (c) Calculations concerning reactions which involve solutions, assuming complete conversion of reactant(s) http://www.ltscotland.org.uk/nationalqualifications/resources/c/nqresource_tcm4228677.asp http://www.ltscotland.org.uk/nationalqualifications/resources/c/nqresource_tcm4230244.asp (d) Reversible reaction http://www.rsc.org/Education/EiC/issues/2006May/ExhibitionChemistry.asp http://www.practicalchemistry.org/experiments/advanced/equilibrium/a-reversible-reaction-involvinghydrated-copperii-sulfate-and-its-anhydrous-form,285,EX.html (e) Altering Equilibrium Position http://www.sserc.org.uk/members/SafetyNet/bulls/220/Chemistry_2.htm http://www.sserc.org.uk/members/SafetyNet/bulls/219/Equilibrium_LeChatelier.htm http://media.rsc.org/Classic%20Chem%20Demos/CCD-4.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-81.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-39.pdf http://www.rsc.org/Education/Teachers/Resources/Aflchem/ http://www.freezeray.com/flashFiles/theHaberProcess.htm (f) Percentage Yield and Atom Economy http://media.rsc.org/nonRSC/GreenChemistryTeachersPack.pdf http://www.ltscotland.org.uk/nationalqualifications/resources/p/nqresource_tcm4228669.asp?strRefer ringChannel=nq http://media.rsc.org/Microscale%20chemistry/Microscale%2053.pdf http://www.ltscotland.org.uk/Images/3729chem2_tcm4-124438.pdf UPDATED WEBLINKS (H, CHEMISTRY) 1 © Learning and Teaching Scotland 2011 (g) Excess http://phet.colorado.edu/en/simulation/reactants-products-and-leftovers 2. Controlling the Rate (a) Collision Theory http://www.creative-chemistry.org.uk/gcse/documents/Module7/N-m07-18.pdf http://www.practicalchemistry.org/experiments/rates-and-rhubarb,61,EX.html http://media.rsc.org/Classic%20Chem%20experiments/CCE-65.pdf http://media.rsc.org/Classic%20Chem%20experiments/CCE-29.pdf http://media.rsc.org/Classic%20Chem%20experiments/CCE-64.pdf http://myweb.tiscali.co.uk/chemteach/swf/ratesT.swf http://media.rsc.org/In%20Search%20of%20Solutions/ISOSact32.pdf http://phet.colorado.edu/en/simulation/reactions-and-rates (b) Reaction Profiles http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/activa2.swf http://phet.colorado.edu/en/simulation/reactions-and-rates (c) Temperature and Kinetic Energy http://www.ltscotland.org.uk/Images/3729chem2_tcm4-124438.pdf (d) Catalysts http://media.rsc.org/Classic%20Chem%20Demos/CCD-58.pdf http://media.rsc.org/Creative%20Problem%20Solving/CPS-17.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-12.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-83.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-1.pdf 3. Chemical Energy (a) Enthalpy http://media.rsc.org/Classic%20Chem%20experiments/CCE-84.pdf http://media.rsc.org/Classic%20Chem%20experiments/CCE-22.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-74.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-11.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-44.pdf (b) Enthalpies of combustion http://www.ltscotland.org.uk/Images/3729chem2_tcm4-124438.pdf http://www.rsc.org/Education/Teachers/Resources/Databook/ (c) Hess’ Law http://www.ltscotland.org.uk/Images/3729chem2_tcm4-124438.pdf http://www.rsc.org/Education/Teachers/Resources/Aflchem/ (no66) (d) Bond Enthalpies None 4. Chemical Analysis as part of Quality Control (a) Chromatography can be used to check the composition and purity of reactants and products UPDATED WEBLINKS (H, CHEMISTRY) 1 © Learning and Teaching Scotland 2011 http://media.rsc.org/Modern%20chemical%20techniques/MCT5%20Chromatography.pdf http://media.rsc.org/Classic%20Chem%20Demos/CCD-24.pdf http://www.rsc.org/education/chemistryteachers/Index_Results.asp?Page=1&ID=11361&Search=0 http://media.rsc.org/Chemistry%20at%20the%20races/RSC%20Horseracing%20Part%205.pdf http://www.rsc.org/education/chemistryteachers/Index_Results.asp?Page=1&ID=11440&Search=0 (b) Volumetric titration http://www.rsc.org/Education/Teachers/Resources/Books/Aspirin.asp http://www.rsc.org/Education/Teachers/Resources/Aflchem/ (no44) http://www.rsc.org/Education/Teachers/GCSEsandAlevels.asp http://media.rsc.org/In%20Search%20of%20Solutions/ISOSact8.pdf UPDATED WEBLINKS (H, CHEMISTRY) 1 © Learning and Teaching Scotland 2011