International Journal of Engineering Trends and Technology (IJETT) – Volume 29 Number 1 - November 2015 Generation of Mechanical Energy using a Nitinol Wire By S. Swaroop Kumar1, Dr.S.A.K.Jilani2 Student (M.Tech In Micro And Nano Electronics), Madanapalle, India 1 Professor, Department Of Electronics &Communication Engineering, Mits, Madanapalle, India 2 ABSTRACT: The main objective of this project is to develop an innovative technology in order to generate mechanical energy using simpler equipments and at low cost variations. In order to achieve the above objective we need to study about certain unique properties of SMA’s(Shape Memory Alloys) which have an emerging and evaluating applications in many fields such as Actuators, Couplings, Bio-medicals, Toys and novelties, Heat engines, Sensors, Lifting devices etc,. This data is extracted from a few journals and text books after the complete study of nitinol practically and experimentally under the guidance of a PhD., scholar. which are mentioned in the below references reveals the idealistic properties of the shape memory alloys. nitinol wire comes back to its straightened shape even if it is twisted into turns, when heat is applied from a lighter to the wire. This automatic shape transformation heat is applied is the unique property of nitinol. Even though the potential applications of nitinol were identified at that time, the practical implementation of these applications in commercialization of nitinol took upto 1990‟s as there were many practical obstacles regarding the identification, manufacturing, related machinery and creating awareness on that rare alloy combination. However all these challenges were overcame by early 1990‟s. Initially this shape memory effect was discovered early in the year 1932 by a Swedish scientist named Arne olander observed this effect in the alloy of gold and cadmium later in 1950‟s it was also observed in copper and zinc alloy. 1. INTRODUCTION: The entire description of the project can be given as, conversion of the nitinol properties in to mechanical energy without any external power supply in maximum cases. Hence we can create a renewable form of mechanical energy using these simpler equipments. The development of the project follows with the study of the following contents: 2. MECHANISM: 1.1 THE HISTORY OF NITINOL: T he term Nitinol is the one derived from the metallic composition that it exhibits and also the place where exactly it is discovered.(Ninickel, Ti-Titanium, N-Naval, O-Ordnance, LLaboratory. (nickel, titanium, Naval Ordnance Laboratory). Fortunately, William J.Buehler and Frederick Wang, were the scientists who revealed the properties of Nitinol in 1959. It was then when buehler was in trials to discover a newer element that could resist heat and some other impact forces, he discovered that the combination of nickel and titanium elements can give the expected solution. The equal proportionate of these two elements nickel and titanium forms into NITINOL. After discovering the nitinol in 1959, he carried out many experiments on its properties and exhibited a presentation at a summit of laboratory management. In that he demonstrated the shape memorizing effect of the nitinol. It was shown that a straight ended ISSN: 2231-5381 Figure 1-The 3D view of structures of Ni-Ti compound, Austenite and Martensite. This reformable solid state phase transformation which is also known as martensitic transformation is an unusual property of the Nitinol, between two different martensite crystal phases that require a mechanical stress of 10,000–20,000psi (69138 mpa). At high temperatures, nitinol acts as an interpenetrating primitive cubic crystal structure which is referred as austenite and also called as the parent phase. Now At low temperatures, the nitinol element transforms to the most complicated mono clinical crystal structure known as martensite spontaneously which is also called as sub-parental http://www.ijettjournal.org Page 23 International Journal of Engineering Trends and Technology (IJETT) – Volume 29 Number 1 - November 2015 phase (daughter phase). Generally, the temperature where the transformation occurs from the austenite stage to the martensite stage that particular temperature is called as transformation temperature. Further precisely, we can classify four transition temperatures Ms, Mf, As, and Af. When the nitinol is subjected to the cooled state austenite converts into martensitic stage and thus we can name it is as martensite start or Ms Temperature and the temperature at which the complete martensitic stage is formed is called as the martensite finish, or Mf temperature. Now austenite starts to form when the fully martensite is subjected to the heat and this temperature is known as As temperature, and which will be finished at the Af temperature. method of deformation can be called as twinning and hence this is also named as monoclinic structure. The original austenite structure can be regained from the martensite structure when heated whether the martensite is deformed or not. Hence this effect of memorizing the shape of austenite stage even if the alloy is twisted into different shapes is known as “shape memory effect” where the alloy memorizes the austenite stage even after subjected to many physical changes at low temperature. Figure 3-The behavior of nitinol's crystalline structure at different temperatures. The other outmost quality of the nitinol is that it is an intermetallic compound where the atoms in it have very specific lattice locations. Due to this it becomes more hard to change from austenite to the martensite stage which requires more force for the deformation. The prevention of converting the deformed martensite stage to the austenite stage produces an effective force of 34000psi to 100000psi in the maximum number of cases. Figure 2-Nitinol's phase transformation indicating thermal hysteresis. The cycle of heating/cooling shows the thermal hysteresis. In general the nitinol composition and the processing show their effect on the hysteresis width. Its common value of temperature ranges are 21-51k; 21-51 °c; 37-91 °f. Related to the phase transformation of nitinol their exists two important points. The first point is that the transformation is reversible which means the crystallined structure is reverted to the original austenite stage when heated above the transformation temperature. Secondly the transformation can be done instantaneously in both the directions. The Martensite's crystal structure exhibits a peculiar property at the time of its deformation. It deforms its crystal structure in such a manner that their would not be any breakage in its atomic bonding. This is helps in re arranging the atomic planes without any damage in maximum cases. If at all their exists any damage, it ranges only from 6-8% of the total. This ISSN: 2231-5381 2.1 Thermal shape memory effect: The alloy must be fixed in a particular desired position and subjected to heat ranging at nearly 500 °c or 932 °f in order to fix its memorizable shape. After affixing the alloy we can observe it trying to go back to its original shape. This is due to the super elastic property that it exhibits. The general elasticity of the nitinol is 15 -30 times greater than a normal spring. A small change in the composition of nickel in nitinol may bring the significant changes in the transition temperature of the alloy. Generally nitinol comprises of 50-51% of nickel in it atomically. So we can vary the percentage of nickel inorder to vary the Af temperature in nitinol to some extent, but the super elastic temperature usually ranges from 25°c to +60°c. http://www.ijettjournal.org Page 24 International Journal of Engineering Trends and Technology (IJETT) – Volume 29 Number 1 - November 2015 3. THE MANUFACTURING PROCESS: The fabrication of nitinol has become more difficult due to the tightly proportionate and accurate composition of nickel and titanium. At present two basic melting techniques are being implemented to fabricate the NiTi alloy. 3.1 Vacuum Induction Melting: This method follows the heating up of raw materials in the alternating magnetic fields in the presence of carbon or any other crucible 3.2 Vacuum Arc Remelting: In this method the raw material along with a water cooled copper strike plate are subjected to an electrical arc. This molten form of liquid is melted and molded in a high vacuum thus not introducing any carbon during its melting. Either of the methods are advantageous, there is no particular differential analysis in between these two techniques. The other methods used are physical vapor deposition, plasma arc melting, e-beam melting and induction skull melting. There are a few considerations to be noticed while fabricating the nitinol like heat treatment, temperature and aging time considerations and certain other parameters to maintain the properties of a genuine nitinol. We can say that the heat treatment of nitinol is a challenging task which is so delicate. The removal of heat becomes difficult as nitinol exhibits less thermal conductivity. For that matter the hot working of nitinol is easy when compared to the cold working as the super elastic nature of the nitinol gives the better frictional resistance. Grinding, laser cutting and electrical discharge cuttings are comparatively easier methods. However both the hot and cold treatments are highly essential for a nitinol to maintain its standard properties. 4. APPLICATIONS: 4.1 GENERAL APPLICATIONS: Generally there are four common fields that uses the applications of nitinol. 4.1.1 Free shape Recovery: A Nitinol material which is deformed to any irregular shape prior to its original shape can be rearranged or reformed back to its original shape by subjecting the material to any heat source. ISSN: 2231-5381 4.1.2 Pressurized Recovery: This can be obtained when the normal shape recovery of the nitinol is firmly subjected to some opposition. It recovers its shape by creating some solid pressure or stress. 4.1.3 Mechanical energy Production: This is the procedure where the shape recovery is allowed with a little or capable oppose. Thus the recovering process of the nitinol shows its impact on the opposing substances. 4.1.4 Super elasticity: This is the major beneficiary tool of the nitinol with extraordinary elastic properties such as a super spring. In the year 1989 there was a survey held at United States and Canada with the involvement of seven organizations. The idea of the survey was to predict the future scope in the technology, applications and market of SMA‟s. Finally the indulged companies have given the following areas where the nitinol usage can be implemented effectively: 1. LIFTING DEVICES 2. CRYOGENICALLY ACTIVATED DIE AND BUBBLE MEMORY SOCKETS C OUPLINGS 3. SENSORS 4. HEAT ENGINES 5. ACTUATORS 6. T OYS, DEMONSTRATION AND NOVELTY ITEMS 7. B IOMEDICAL AND MEDICAL AND 8. COUPLINGS Nitinol can also be utilized mechanically in some watch springs and resilient glass frames. Biomedical and medical applications: The Biocompatibility is also an unique feature of the Nitinol and hence this is also used in orthopedic implants. Due to certain other unique properties of the nitinol it posses a massive usage in the production of invasive devices. These invasive devices also include super elastic needles, catheters and stents. Nitinol wires are used in identifying the breast tumors very precisely. So that the related surgeries can be carried out more precisely. Actuators: A nitinol wire can be used as an actuator efficiently as we have already seen in the above example. This http://www.ijettjournal.org Page 25 International Journal of Engineering Trends and Technology (IJETT) – Volume 29 Number 1 - November 2015 can be mechanically actuated at the time of necessity. The above application shows the nitinol added to schraeder valve core with the addition of an actuator wire. The valve can very gradually close or open to produce a proportionate controlled air flow through the valve. Even this nitinol can be implemented in operating the electrical latch box as electronic locks. The nitinol wire contracts when heated electrically and frees the latch. Of course this is a one of the low cost implementing examples of many. There are even more possibilities that can be achieved using this nitinol as we know there are no limitations for innovative applications. Cryogenically activated die and bubble memory sockets couplings: The word „cryogenically‟ means the physical effects occurring at very low temperatures. Using the shape memory effect of the nitinol wire we can use this as sockets couplings which can be activated by heating the nitinol. Sensors: A Sensor is a device which transfers one form of data or energy into another form. The electrical and thermal properties of nitinol are so high these can be effectively used as a sensor which indicates the existence of thermal and electrical pulses through the material. A nitinol wire can also perform mechanical changes transforming from austenite to martensite stages. Nitinol is used as a temperature control system. It is possible to activate a variable resistor or a switch to control the temperature using its shape changing technique. Figure 4 :Lifting with nitinol wire The power supply connected to the nitinol wire can be used to operate it in lifting and releasing the certain weighted pendulum in the upward and downward directions by switching on and off respectively thus lifting the any other materials too. A wire with the diameter of 250 micro meters and length of one meter can pull a weight of 900 grams approximately. It can deform its shape by 3% to 5% of its original linear shape. Its activation temperature is nearly 90 degrees centigrade and the recommended current through the wire is 1050 mA. 5.2 As Heat engines: Due to its high flexible and mechanical memory properties it offers its service as a retractable antenna or even as the boom of a microphone in cellular technology. 5. PROPOSED, CONDUCTED OBSERVED APPLICATIONS: AND 5.1 As Lifting devices: As we know the unique property of nitinol, which can expand its length when electrically conducted, we can make use of this function in lifting and releasing the devices and materials. Figure 5: Nitinol Heat engine These heat engines make use of nitinol wire to create mechanical energy from the two neighbouring hot and cold compartments. The prototype of the first heat engine was developed in 1970‟s by Ridgway Banks at Lawrence Berkley National Laboratory and after his name that was named as the Bank‟s engine. However the above shown figure is the heat engine of latest version. We can demonstrate this functionality in the following diagram: ISSN: 2231-5381 http://www.ijettjournal.org Page 26 International Journal of Engineering Trends and Technology (IJETT) – Volume 29 Number 1 - November 2015 silent, variable movement cycle and can give us a realistic motion. 5.3 In Toys, Demonstrations and Novelty items: It is used in certain novelty products by the magicians to perform some „psychic‟ powers as a practical trick, such as automatically bending spoons when stirred in a hot cup of tea or coffee or any other hot liquid. Hardware description: In the following shown figure the nitinol wire is implemented in a robotic arm. The nitinol wire is placed in between the robotic fingers vertically and pasted at both the ends with glue. These two ends are connected to a power supply. Likewise all the five fingers are connected with the five different nitinol wires. We have constructed the below shown circuit board using two IC‟s-the 4022 counter and the 555 timer. We used the 555 timer as a bistable vibrator. Based on the timer period set by the values of capacitor C3 and the resistors R9 and R10, the 555 timer sends a pulse to pin 3.i.e., the output is connected to ground. This is known as „Logic Low‟. In this case we chose these values to give us a pulse approximately every second. Figure 8: Nitinol wire usage in Toys. Here we have designed a bipedal robot and a horse which can move forward based on the contraction and relaxation movements of the nitinol wire when electrically conducted. This movement can be varied in terms of number of cycles per second using the capacitor used in a simple oscillator circuit which we used.It is also used in the golf club inserts as it has the property of changing its shape. Nickel titanium is also used in the field of textile industry for building strong arm suits and other costume material. CONCLUSION: It is highly essential to continue the study of the characteristic features of SMA‟s for a large extent to extract the much more possible outcomes in generating mechanical and further forms of energy with less equipment. REFERENCES: 1) Figure 7: Nitinol Robotic arm. Another IC we used is the 4022 as a counter circuit. It has an input pin and each time the voltage on this pin is connected to ground for a brief fraction of a second, it adds one to whatever number it already had. It shows its current value by setting one of its output pins to logic low, and the others are held at logic high. After reaching the highest number that it can hold, it rests to zero and continues counting. In the same way, we can construct some other toys as shown in the below figure which are purely ISSN: 2231-5381 Shape Memory Alloys: Manufacture, Properties and Applications by H.R.Chen,ed.,Nova Science Publishers. 2) Shape Memory Materials and Its Applications by Y.Y. Chu & L.C. Zhao, eds., Trans Tech Publications Ltd., 3) Shape Memory Alloys by D.C. Lagoudas, ed.,Springer Science and Business Media LLC. 4) Shape Memory Materials, K. Otsuka & C.M. Wayman, eds.,Cambridge University Press. 5) Low Temperature Creep of Hot-extruded Nearstoichiometric NiTi Shape Memory Alloy, Sai V. Raj, National Aeronautics and Space Administration, Glenn Research Center. 6) "Effects of Low-Temperature Phase Changes on the 7) Mechanical Properties of Alloys Near Composition TiNi". By Buehler, W. J. Gilfrich, J. W. Wiley, R. C. (1963).Journal of Applied Physics. 8) "The Alloy That Remembers", Time, 1968-09-13 9) "Magnificent Molecules - Nitinol". The Mole (RSC) by Withers, N. (2014). 10) "Nitinol facts". In (Nitinol.com. 2013). http://www.ijettjournal.org Page 27 International Journal of Engineering Trends and Technology (IJETT) – Volume 29 Number 1 - November 2015 11) Shape memory alloys, by Funakubo, Hiroyasu (1984), University of Tokyo. 12) Pelton, A. Russell, S. DiCello, J.(2003). "The Physical Metallurgy of Nitinol for Medical Applications". 13) Miller, R. K. Walker, T.(1989). Survey on Shape Memory Alloys. Survey Reports 89. Future Technology Surveys. 14) Banks.R.(1975)."TheBanksEngine". ieNaturwissenschaften. 15) Vimeo posting of "The Individualist", documentary on Ridgway Banks 16) "Single wire nitinol engine" by Ridgway M. Banks, US Patent. 17) "Metals that Remember", Popular Science, January 1988. 18) "Engine Uses No Fuel", Milwaukee Journal, December 5, 1973 AUTHORS DESCRIPTION 1. S.Swaroop kumar is pursuing his M.Tech in the stream of Micro & Nano electronics from Madanapalle Institute of Technology and Sciences, Madanapalle. He completed his B.Tech in the stream of Electronics and communication, from Hasvitha institute of Engineering and technology, Hyderabad. His areas of interest are embedded systems, IC fabrication, and Micro & Nano electronics 2. Dr. S A K Jilani is working as the Professor and project coordinator in the department of ECE, Madanapalle Institute of Technology and Sciences, Madanapalle. He has the teaching experience of over twelve years. He also worked as an R&D Professional earlier in Electronics Industry. He obtained his PhD In the year 2002 and also published more than 35 papers in different national and international Journals. He has also guided more than 50 M.Tech, M.Sc, MCA, B.Tech Projects. His areas of interest are Artificial Intelligence, Computer Visions, Digital Signal Processing and Embedded Systems. 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