International Journal of Engineering Trends and Technology (IJETT) – Volume 27 Number 1- September 2015 Investigating the Quality of Koya City Drinking Water Fakhri H. Ibraheem, Fyrad M Shareef, **Rostam S. Aziz, Galawesh B. Bapeer, Faculty of Engineering, Koya University, Koya, Kurdistan Region – Iraq *Koya Water Directorate, Koya, Kurdistan Region – Iraq. **Faculty of Education, Koya University, Koya, Kurdistan Region – Iraq Abstract— This project is based on the investigation of drinking water parameters at the city of Koya in Kurdistan Region. Group of researchers at the Faculty of Engineering, Koya University are participated in this study. Water are supplied to houses from two sources ground and surface water, these are the sources of drinking water in the majority of countries in the middle east. Therefore the paper can help the researchers in the region to use it as reference for their works. As field survey mass number of samples were collected from water stores and householders taps. Chemical and physical properties of water were tested for each sample. The results show that the surface water is more contaminated than the ground water due to waste disposal to the rivers. The lack for safe drinking water in Koya city and the instability of its physical, chemicals and microbiological aspects is the main reason for implementing this research. This study show us clearly the location and how much big is this problem. Keywords— Drinking water, water quality control, water standard specifications, Koya city. I. INTRODUCTION The tap water in Koya University, Kurdistan region - Iraq is suffering an acute shortage of drinking water that meets international standards specifications. Consequently, the provision of drinking water for Koya City people and the University students and staff is an immediate priority. EPA defines a water contaminant as any physical chemical, biological, or radiological substance or matter in water. EPA sets legal limits on the levels of certain contaminants in drinking water. The legal limits reflect both the level that protects human health and the level that water systems can achieve using the best available technology [1]. Contaminated water serves as a mechanism to transmit communicable diseases such as diarrhoea, cholera, dysentery, typhoid and guinea worm infection. WHO estimates that in 2008 diarrhoeal disease claimed the lives of 2.5 million people [2]. The quality of available water sources vary widely on the location regardless of being sourced from rivers or ground water. The project aims is to make survey on the quality of drinking water in all Koya city strips and how much it is far from standard specifications and is it suitable for human consumption. So it is important to identify actual ISSN: 2231-5381 production amount of drinking water and its qualities in different locations throughout Koya city. There are five drinking water resources in Koya city, Figure 1. Two of them are surface water from Al-zabe River, Kilesa and Taqtaq and the others from wells, Haibat-Sultan, Topzawa, and Hamamook. Figure 2 shows the distribution of ground water wells in the city. (78) Laboratory water testing was done from different locations for drinking water samples during the period from 1st Nov. - 10 Dec. / 2014. The samples were taken from main storage tanks and from all Koyas strips tap water. The tests are including microbiological, chemical and physical tests. It is shown from the testing results that there are no microbiological contaminations in all drinking water points, tanks and taps and fulfill Iraqi Standard Specification IQS 2270/14/2006. The chemical and physical test shows bad drinking water quality for some places and out of IQS 417/ 1974 – 2001. For drinking water storage tanks, two of them are within standard specification and two out of standard. Topzawa is out of standard due to increase TDS value by 13%. Taqtaq is out of standard due to increase turbidity by 330%. Generally the water specifications in tap water are higher than resources tanks especially in TDS, pH and turbidity. The searching for the reasons of that deviation is a part of future work in addition to searching for the suitable technology to overcome this deviation and improve Koya drinking water. The pH of Koya city drinking water is alkanet and it is higher for tap water than resources tanks. The drinking tap water specifications for eleven strips are out of standard due to increase turbidity. The Koya strips can be classified into three sectors. The 1st one is the strips which represent 25% of Koya city that suffering from severe effect of turbidity by about 267% from the standard level. The 2nd one is the strips which represent 30% of Koya city that are out of standard by about 50%. The 3rd one is the strips which represent 45% of Koya city and it is within high level of turbidity standard specification. The conclusion of that research is that eleven strips in Koya city have a drinking water not suitable for human consumption. Eight strips have a drinking water within the high level of turbidity so it is not safe. Hamammok strip only has the better water quality specification and suitable for human consumptions. http://www.ijettjournal.org Page 1 International Journal of Engineering Trends and Technology (IJETT) – Volume 27 Number 1- September 2015 Fig. 1 Koya city drinking water resources Fig. 2 Koya city with drinking water wells distribution ISSN: 2231-5381 http://www.ijettjournal.org Page 2 International Journal of Engineering Trends and Technology (IJETT) – Volume 27 Number 1- September 2015 II. STANDARD SPECIFICATIONS OF DRINKING WATER The drinking water is very important food especially for children due to its highly constituent of valuable elements and the ability to be modified to better quality with reference to the human body lack i.e can be supported by Florien element for tooth buildings or by iron and so on. The limits of the elements and compound should be controlled carefully. The monitoring of microbiological effect is also very important in order to let water far from pathogenic bacteria. The Iraqi Standard Specification (IQS) number 2270/14/2006 shows clearly the allowed limits of microbial in drinking water [3]. The (IQS) 417/ 1974 – 2001 shows the allowable level for drinking water physical and chemical specifications and classified the limits in to two regions, the first one represent the maximum acceptable limits for drinking water in the existence of suitable technology for water industry, and the second for maximum allowable limits when there is a lack of suitable water sources and technology. The most important chemicals figure to be concentrated on in koya city is TDS (Total Dissolved Salts), turbidity, and the water acidity PH number. With reference to the first region specifications, TDS should be not more than 500 ppm, turbidity below 5 NTU, and the acidity PH limits is (7 - 8.5) [4]. III. THE PRACTICAL WORK An effective cooperation occurred between Faculty of Engineering (FoE) – Koya University researchers and Koya drinking water directorate. The FoE nominates a research group for that purpose. The research group held seven meetings, ten visits and 78 laboratory tests. This work includes the surveying on the water resources, storage tanks, and all Koyas city strips for tap water samples. This is done through two months from 16 oct. – 14 Dec. 2014. The practical work going on into the following directions: a) The drinking water resources types and locations with reference to Koya city. b) The clarification process of each types of drinking water. c) The metal and concrete drinking water storage tanks situation and locations. d) The tap water net pipes classified with reference to Koya city sectors. ISSN: 2231-5381 e) The Microbiological tests for each source of drinking water in two labs, the 1st one in Koya Hospital and the 2nd in the Quality Control Labs (QCL) in Sustainable Industrial Development Directorate (SIDD) – Ministry of Trade and Industries (MTI). f) Primary chemical and physical tests for each source of drinking water represented by electrical conductivity, TDS, minerals,and turbidity. IV. WATER RESOURCES The Koya Drinking Water (KDW) amount from multi sources equal to 38400 m3/day. The source of KDW either surface water (Klesa new Project and Taq taq Koya project) which represent about 60 % from total amount (38400 m3/day) while the other source is under ground water which represent 40% of the total amount. i.e the underground water has more effect on overall KDW specifications. In the existence of Drinking Water Directorate Representative (DWDR), the research group gets samples from drinking water multi sources. It is shown from the visits and available information and drawings that there is interactions and connections between the multi drinking water sources pipes nets that feed Koyas cities. It is also important to get tap water samples from all Koyas city strips. V. LABORATORIES TESTS A. Microbiological Tests It was done for (28) samples in two labs. Four samples tested in QCL and (24) samples in Koya hospital. Eight of these samples are for water from drinking water resources tanks. ( 20 ) of these samples are for Koyas strips tap water. Tables 1, 2 show the microbiological tests for drinking water resources tanks and tap water respectively. B. Chemical Tests It was done for (24) samples in the research center lab in the faculty of Engineering (FoE)-Koya University and (18) samples in the college of education labs. The chemical testes concentrated on a) Total Dissolved Salts (TDS) ppm. b) Water acidity pH. c) Dissolved elements. TDS or Total Dissolved Solids is a measure of the total ions in solution. EC is actually a measure of the ionic activity of a solution in term of its capacity to transmit current. In dilute solution, TDS and EC are http://www.ijettjournal.org Page 3 International Journal of Engineering Trends and Technology (IJETT) – Volume 27 Number 1- September 2015 reasonably comparable. The TDS of a water sample are determined by measuring Electrical Conductivity EC. To convert the electric conductivity of a water sample (mS/cm) into the approximate concentration of total dissolved solids (ppm), the mS/cm is multiplied by a conversion factor. The conversion factor depends on the chemical composition of the TDS and can very between 0.54 – 0.96. A value of 0.67 is commonly used as an approximation if the actual factor is not known (TDS)ppm = Conductivity µS/cm x 0.67. [5]. Table (4) shows details of the elements detected by Atomic Absorption Spectrophotometry (AAS) equipment. It has highly accuracy. C. Physical Tests It is done for (24) samples in the research center lab in the faculty of Engineering (FoE)-Koya University. The Physical testes concentrated on the turbidity. Table (4) the turbidity values of raw water resources tanks. Table (5) shows turbidity values for Koya different places tap water. Table 3 shows TDS and pH testing results. Table 4: shows Dissolve elements. It was done for drinking water resources tanks by a previous research work. TABLE 1 MICROBIOLOGICAL TESTS RESULTS FOR KOYA DRINKING WATER RESOURCES TANKS AT 12-18 NOV. 2014 Raw Water Resource GPS XYZ) UTM location 462677× 3992674 × 666 Topzawa Taqtaq Klesa Haibatsultan 465538 × 3993953 × 677 470365 × 3994148 × 725 468471 × 3995538 × 727 ISSN: 2231-5381 Hospital Lab QCL lab M.P.N. Coli after 48 hrs < 2.2 --- M.P.N Fecal Coli 48 hrs < 2.2 --- Items (ISS) 2270/14/ 2006 E. Coli CFU/250 ml --- Zero Zero Total Coliforms Bacteria CFU/250 ml --- 1 2 Pseudomonas aerugenosa CFU/250 ml --- Zero 2 Fecal streptococcus CFU/250 ml --- Zero 2 M.P.N. Coli after 48 hrs < 2.2 --- M.P.N Fecal Coli 48 hrs < 2.2 --- E. Coli CFU/250 ml --- Zero Zero Total Coliforms Bacteria CFU/250 ml --- 1 2 Pseudomonas aerugenosa CFU/250 ml --- Zero 2 Fecal streptococcus CFU/250 ml --- Zero 2 M.P.N. Coli after 48 hrs < 2.2 --- M.P.N Fecal Coli 48 hrs < 2.2 --- E. Coli CFU/250 ml --- Zero Zero Total Coliforms Bacteria CFU/250 ml --- Zero 2 Pseudomonas aerugenosa CFU/250 ml --- Zero 2 Fecal streptococcus CFU/250 ml --- Zero 2 M.P.N. Coli after 48 hrs < 2.2 --- M.P.N Fecal Coli 48 hrs < 2.2 --- E. Coli CFU/250 ml --- Zero Zero Total Coliforms Bacteria CFU/250 ml --- Zero 2 Pseudomonas aerugenosa CFU/250 ml --- Zero 2 Fecal streptococcus CFU/250 ml --- Zero 2 http://www.ijettjournal.org Page 4 International Journal of Engineering Trends and Technology (IJETT) – Volume 27 Number 1- September 2015 TABLE 2 MICROBIOLOGICAL TESTS RESULTS FOR ALL KOYA CITY SECTORS TAP WATER AT 25 NOV. – 10 DEC. Koya City Strip M.P.N. Coli after 48 hrs M.P.N Fecal Coli 48 hrs Results Alieawa < 2.2 < 2.2 Satisfactory Kurdi Arabiean < 2.2 < 2.2 Satisfactory Sarbag 1 < 2.2 < 2.2 Satisfactory Sarbag 2 < 2.2 < 2.2 Satisfactory Jamiea < 2.2 < 2.2 Satisfactory Hawawan < 2.2 < 2.2 Satisfactory gashtearie < 2.2 < 2.2 Satisfactory Haiebat Sultan < 2.2 < 2.2 Satisfactory kakoun < 2.2 < 2.2 Eskan < 2.2 < 2.2 Satisfactory Hammamook < 2.2 < 2.2 Satisfactory Hamoon < 2.2 < 2.2 Satisfactory Fiderally < 2.2 < 2.2 Satisfactory Zansite < 2.2 < 2.2 Satisfactory Qalat < 2.2 < 2.2 Satisfactory Baezhaga < 2.2 < 2.2 Satisfactory BafriQundi < 2.2 < 2.2 Satisfactory Qundeel < 2.2 < 2.2 Satisfactory Azadi < 2.2 < 2.2 Satisfactory Kosrat < 2.2 < 2.2 Satisfactory Satisfactory TABLE 3 CHEMICAL TESTS RESULTS FOR KOYA DRINKING WATER RESOURCES TANKS AT 12-18 NOV. 2014 Drinking water tanks locations Electrical Conductivity µS/cm Total Dissolved Salts TDS (ppm) Iraqi Standard Specifications 417 – 1974 pH TDS (ppm) Results pH Topzawa 840 563 7.8 500 7.0 – 8.5 Reject Taqtaq 285 191 8.09 500 7.0 – 8.5 Accepted Klesa 277 186 7.88 500 7.0 – 8.5 Accepted Haibat sultan 409 274 7.96 500 7.0 – 8.5 Accepted ISSN: 2231-5381 http://www.ijettjournal.org Page 5 International Journal of Engineering Trends and Technology (IJETT) – Volume 27 Number 1- September 2015 TABLE 4 CHEMICAL TESTS RESULTS FOR ALL KOYA CITY SECTORS TAP WATER 25 NOV 2014 - 8 DEC 2014 Electrical Conductivity µS/cm Koya City Strip Total Dissolved Salts TDS (ppm) Iraqi Standard Specifications pH Results 417–1974 TDS (ppm) pH Alibawa 740 496 7.84 500 7.0 – 8.5 Accepted (Higher Level) Kurdi Arabiean 654 438 8.37 500 7.0 – 8.5 Accepted Sarbag 1 561 376 8.41 500 7.0 – 8.5 Accepted (Higher Level) Sarbag 2 616 413 8.28 500 7.0 – 8.5 Accepted Jamiea 702 470 8.21 500 7.0 – 8.5 Accepted Hawawan 734 492 8.38 500 7.0 – 8.5 Accepted (Higher Level) gashtearie 607 407 8.36 500 7.0 – 8.5 Accepted Haiebat Sultan 981 657 8.28 500 7.0 – 8.5 Reject kakoun 603 404 8.07 500 7.0 – 8.5 Accepted Eskan 669 448 8.03 500 7.0 – 8.5 Accepted Hammamook 635 425 7.97 500 7.0 – 8.5 Accepted Hamoon 460 308 8.35 500 7.0 – 8.5 Accepted Fiderally 605 405 8.25 500 7.0 – 8.5 Accepted Zansite 565 379 8.09 500 7.0 – 8.5 Accepted Qalat 297 200 8.19 500 7.0 – 8.5 Accepted Baezhaga 317 212 8.09 500 7.0 – 8.5 Accepted BafriQundi 565 379 7.68 500 7.0 – 8.5 Accepted Qundeel 874 586 7.88 500 7.0 – 8.5 Reject Azadi 834 559 8.13 500 7.0 – 8.5 Reject Kosrat 895 600 7.92 500 7.0 – 8.5 Reject ISSN: 2231-5381 http://www.ijettjournal.org Page 6 International Journal of Engineering Trends and Technology (IJETT) – Volume 27 Number 1- September 2015 TABLE 5 DISSOLVED IONS TESTS RESULTS IN PPM FOR KOYA DRINKING WATER RESOURCES TANKS * Haibat sultan Iraqi Standard Specifications 417 – 1974 1 Results 44-59 58.06 75 Accepted 20.73 11.1-13.3 9.85 150 Accepted 4.38 2.48 7.9-8.6 10.6 200 Accepted K 0.85 0.40 0.9-1.2 2.73 12 WHO Accepted Fe 0.111 N. D. 0.24-0.27 0.11 0.3 Accepted Mn 0.01 N. D. 0.02-0.05 0.01 0.1 Accepted Ni N. D. N. D. 0.0040.005 N. D. 0.02 Accepted Cu 0.04 N. D. 0.007 0.05 1 Accepted Cr N. D. N. D. N. D. 0.05 Accepted Pb N. D. N. D. N. D. 0.01 Accepted Cd N. D. N. D. N. D. 0.003 Accepted Zn HCO3-1 as CaCO3 SO4-2 N. D. N. D. 0.02-0.05 N. D. 3 Accepted 130.8 130.80 139-183 134.70 ---- 52.03 68.85 45-51 11.6 200 Accepted Cl-1 10.14 8.45 12.9-14.1 13.52 200 Accepted NO3-1 1.02 1.21 1.7-5.6 0.08 50 Accepted N. D. N. D. --- N. D. Drinking water tanks locations Topzawa Taqtaq Ca 59.08 43.80 Mg 27.64 Na PO4-3 Total Hardness TH Klesa 0.0050.007 0.0040.007 0.0010.002 100-379 * Determination of K and Na are done by Flam Atomic Emission Photometric (F-AES) method. Determination of Ca, Mg, Cu, Cr, Cd, Pb, Zn, Ni, Mn, and Fe are done by Flam Atomic Absorption Spectrophotometer (F-AAS) methods (SP9-PYEUICAM). ISSN: 2231-5381 Accepted Accepted Cl-1, SO4-2, and HCO3-1 are done by ergonometric, turbidimetric and potentiometric methods respectively. PO4-3 is done by spectrophotometric method (JENWAY – 6300) Ascorbic acid method http://www.ijettjournal.org Page 7 International Journal of Engineering Trends and Technology (IJETT) – Volume 27 Number 1- September 2015 TABLE 6 PHYSICAL TESTS TURBIDITY RESULTS FOR KOYA RESOURCES DRINKING WATER FROM 25 NOV 2014 - 8 DEC 2014 Drinking water tanks locations Turbidity Iraqi Standard Specifications 417 – 1974 Results NTU Hamammok 0.88 5 Accepted Taqtaq 16.5 5 Reject Klesa 1.64 5 Accepted Haibat sultan 1.34 5 Accepted TABLE 7 PHYSICAL TESTS TURBIDITY RESULTS FOR ALL KOYA CITY SECTORS TAP WATER FROM 25 NOV 2014 - 8 DEC 2014 Drinking water tanks locations Turbidity NTU Iraqi Standard Specifications 417 – 1974 Alibawa 11.5 5 Reject Kurdi Arabiean 2.54 5 Accepted Sarbag 1 3.48 5 Accepted Sarbag 2 10.7 5 Reject Jamiea 13.3 5 Reject Hawawan 8.30 5 Reject gashtearie 8.66 5 Reject Haiebat Sultan 2.08 5 Accepted kakoun 14.1 5 Reject Eskan 6.91 5 Reject Hammamook 0.36 5 Accepted Hamoon 2.96 5 Accepted Fiderally 3.07 5 Accepted Zansite 8.23 5 Reject Qalat 4.21 5 Accepted Baezhaga 6.26 5 Reject BafriQundi 17.2 5 Reject Qundeel 2.35 5 Accepted Azadi 2.58 5 Accepted Kosrat 6.73 5 Reject ISSN: 2231-5381 Results http://www.ijettjournal.org Page 8 International Journal of Engineering Trends and Technology (IJETT) – Volume 27 Number 1- September 2015 a. VI. 1. DISCUSSION OF RESULTS Microbiological tests: Tables 1 and 2 shows that there are no microbiological contaminations in drinking water storage tanks or in the all Koya city strips tap water in this period of year (Nov. and Dec.). 2. Chemical tests: In order to get full idea about the drinking water chemical specifications in different locations, it is important to classified the water according to its location as follows: 2.1 Resources water storage tanks: a. Table 3: shows two drinking water resources tanks are satisfied ISS 417/ 1974 – 2001 but two sources are unsatisfied. The unsatisfied drinking water source is Topzawa due to increase TDS by 13% and Taqtaq due to increase turbidity by 267% . b. The best drinking water resource tank is klesa. Klesa project is new modern efficient technology. 2.2 Tap water for all Koya city strips: a. Table 4: Shows there are 20 strips in Koya city. The TDS tests for 16 strips are satisfied the ISS 417/ 1974 – 2001 but 4 strips are out of standard. b. There are 3 strips near high accepted level of TDS like Alibawa and Hawawan strips, and pH like Sarbag 1. c. The general pH of water in Koya is alkalinity, often more than 8 pH. d. Generally the TDS and pH for tap water is higher than resources tanks by about 25%. e. Table 5: shows there are no poisons in resource tank drinking water by any element. All the elements below the standard level. 3. The turbidity of three sources is satisfied and only Taqtaq source is out of standard by 300%. 3.2 Tap water for all Koya city strips: a. 11 Strips from total 20 strips in Koya city are out of standard in turbidity. b. 5 strips suffer from sever effect. The average turbidity is 13.4 which have 267% deviation from standard level 5. c. 6 Strips have 50% deviation from standard level. d. 9 Strips within the standard limit but its recognized as high limits. Its average value 2.63. e. Figure 3: shows the turbidity profile of tap water for different Koya strips through the period Nov. and Dec. 2014. Physical tests: The physical test includes the turbidity, color and taste. The turbidity is very important and has a direct effect on color and taste. It is classified into two locations: 3.1 Resources water storage tank ISSN: 2231-5381 VII. CONCLUSIONS In this study the following are concluded: a) The Turbidity of Koya drinking water is high and above standard specification. The microbiological tests of all Koyas cities are within standard specifications. b) Koya city divided into 20 strips. The drinking water of eleven strips is not suitable for human consumption due to increase turbidity. The other cities are within the high level of standard specification. Only Hammammok has the best quality. c) The turbidity of three resources drinking water tanks is within standard specifications only Taqtaq is out of standard by 300%. d) The general specification of resources drinking water tanks is better than tap water. There are two reasons for that deviate. It is either to higher turbidity in Taqtaq water resource or to a leakage in drinking water pipe lines net. e) There is no microbiological contamination in water resources tanks or in tap water. The free of microbiology is either because a high amount of chlorine used for sterilization or because the leakage occurred far from dirty area or both of them. http://www.ijettjournal.org Page 9 International Journal of Engineering Trends and Technology (IJETT) – Volume 27 Number 1- September 2015 f) There are no heavy elements poisons in Koya drinking water. Fig. 3 Turbidity in tap water for different Koya city strips through the period Nov. and Dec. 2014 REFERENCES [1] [2] [3] [4] [5] EPA, “Regulating Public Water Systems and Contaminants Under the Safe Drinking Water Act” Internet: http://water.epa.gov/lawsregs/rulesregs/regulatingcontamina nts/basicinformation.cfm, Sep. 11, 2013 [Jun. 10, 2015] WHO, “Consultation on the Development of a Strategy on Water Quality and Health” Internet: http://www.who.int/water_sanitation_health/dwq/en/. [Jun. 09,2015]. Central Organization for Standardization and Quality Control (COSQC), Microbiological limits of drinking water / Part 14, IQS 2270/14/2006. Baghdad – Iraq. Central Organization for Standardization and Quality Control (COSQC), Drinking water, IQS 417/1974 and 417/2001, 1st revision. Baghdad – Iraq. Steven Water, “Monitoring the Earth Water Resources” Internet: http://www.stevenswater.com/water _quality_sensors/conductivity_info.html, [May, 20, 2015]. 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