w w ap eP m e tr .X w UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS for the guidance of teachers 0654 CO-ORDINATED SCIENCES 0654/31 Paper 3 (Extended Theory), maximum raw mark 120 This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of the examination. It shows the basis on which Examiners were instructed to award marks. It does not indicate the details of the discussions that took place at an Examiners’ meeting before marking began, which would have considered the acceptability of alternative answers. Mark schemes must be read in conjunction with the question papers and the report on the examination. • Cambridge will not enter into discussions or correspondence in connection with these mark schemes. Cambridge is publishing the mark schemes for the May/June 2012 question papers for most IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses. om .c MARK SCHEME for the May/June 2012 question paper s er International General Certificate of Secondary Education Page 2 1 Mark Scheme: Teachers’ version IGCSE – May/June 2012 Syllabus 0654 (a) (i) (KE =) ½ mv2 ; = ½ × 30 000 × 0.5 × 0.5 = 3750 J ; Paper 31 [2] (ii) (work done =) force × distance = 1 000 000 × 1000= 1 000 000 000 J ; [2] (iii) (power =) work / time ; = 1 000 000 000 / 300 = 3 300 000 W ; [2] (b) (i) 300 J AND all potential energy will be converted into kinetic energy / energy is conserved ; (ii) (temperature change =) energy / mass × shc ; = 300 / 1 × 4200 ; = 0.07 °C ; [1] [3] [Total: 10] 2 (a) (i) three shared pairs ; one lone pair on both atoms ; [2] (ii) two shells showing 2,8 configuration ; [1] (iii) reference to positive protons and negative electrons ; reference to 7 protons and 10 electrons / 3 more electrons than protons ; [2] (iv) Mg3N2 ; working / statement to show need for charge balance ; [2] (b) (i) chlorine ; [1] (ii) hydrogen ; pops on ignition ; [2] [Total: 10] © University of Cambridge International Examinations 2012 Page 3 3 Mark Scheme: Teachers’ version IGCSE – May/June 2012 Syllabus 0654 (a) label to root hair cell ; (b) (i) osmosis ; water moves down water potential gradient ; through partially permeable cell membrane ; (ii) absorb, minerals / ions / named ion / salts ; (iii) large surface area ; so more, (water / ions), can be absorbed (at the same time) ; contain, cell sap / cytoplasm, that is more concentrated than water ; (c) (i) xylem ; Paper 31 [1] [max 2] [1] [max 2] [1] (ii) A in central area of root ; (iii) idea that red dye has mixed with water, not combined with it ; idea that water molecules and dye molecules behave separately ; (only) water evaporates / dye does not evaporate ; other valid point ; [1] [max 2] [Total: 10] 4 (a) (i) frequency – number of waves produced / passing a point per second ; wavelength – distance between, two consecutive peaks / troughs ; (ii) (v =) f × λ ; 212 000 × 0.0016 = 339.2 m / s ; (iii) compression – region of high pressure / lots of air particles ; rarefaction – region of low pressure / fewer air particles ; (b) (i) normal drawn ; angle of incidence labelled AND angle of refraction labelled ; [2] [2] [2] [2] (ii) angle of reflection drawn and labelled ; [1] (iii) optical fibres / reflectors / periscopes ; use described ; [2] [Total: 11] © University of Cambridge International Examinations 2012 Page 4 5 Mark Scheme: Teachers’ version IGCSE – May/June 2012 Syllabus 0654 Paper 31 (a) respiration ; glucose / carbohydrate ; combined with oxygen / oxidised ; energy released / heat produced ; [max 3] (b) (i) eat a lot ; eat more / take in more energy, than they use ; excess, carbohydrate / protein, converted to fat ; [max 2] (ii) the greater the body mass, the greater the chance of survival ; idea that effect is greater at lower body masses / levels off at higher body masses ; use of figures ; (iii) poor conductor / insulator ; (c) addition of carbon dioxide to the atmosphere ; deforestation + explanation ; addition of methane to the atmosphere ; one named source of methane, e.g. paddy field, cattle ; idea that (long wave) radiation is trapped by greenhouse gases ; (d) (i) (mean body) mass is increasing ; (ii) marmots have more time to feed (from spring onwards) ; marmots lose less weight during hibernation (as winters are shorter) ; more food available earlier ; [max 2] [1] [max 3] [1] [max 1] [Total: 13] 6 (a) temperature and surface area of magnesium ; [1] (b) (i) (B) higher concentration shown by higher rate / higher rate shown by steeper graph ; [1] (ii) (maximum volume of gas is) 40 cm3 AND (time of reaction is) 4.9 ± 0.1 minutes ; average rate = 40 ÷ 4.9 = 8.2 / 8.0 to 8.3 ; units: [cm3 / minute] / [cm3 / second] if consistent with calculation ; (c) (i) aqueous (solution) / dissolved in water / in solution ; (ii) Ar Mg = 24 ; moles Mg = 6 ÷ 24 / 0.25 ; [3] [1] [2] [Total: 8] © University of Cambridge International Examinations 2012 Page 5 7 Mark Scheme: Teachers’ version IGCSE – May/June 2012 Syllabus 0654 Paper 31 (a) split ; [1] (b) (i) electron ; [1] (ii) 51 neutrons ; 39 protons ; [2] (iii) ionisation occurs ; electron(s) lost ; [2] (c) (i) 47 ± 1 cps ; (ii) Z ; [1] [1] [Total: 8] 8 (a) (i) P Group 1 Q Group 0 R Group 7 ; outer electrons determine group number / answer based on identifying the elements and looking up on PT ; [2] (ii) (Q) it is a noble gas / references to full shells ; [1] (iii) (P) it is a metal ; [1] (b) (i) limestone / calcium carbonate ; forms slag / removes impurities / removes silicon dioxide ; (ii) iron oxide + carbon monoxide → iron + carbon dioxide ;; [LHS + RHS] (c) (i) question withdrawn (ii) zinc more reactive than iron ; so zinc reacts (with water / oxygen) before / instead of iron ; so zinc corrodes leaving the iron / steel unaffected / owtte ; [2] [2] [2] [max 2] [Total: 12] © University of Cambridge International Examinations 2012 Page 6 9 Mark Scheme: Teachers’ version IGCSE – May/June 2012 Syllabus 0654 (a) chemical ; produced by a gland ; carried by the blood ; affects (specific) target organs ; destroyed by the liver ; (b) (i) pancreas ; Paper 31 [max 3] [1] (ii) liver ; removes glucose from the blood / changes glucose to glycogen ; (c) increases blood glucose concentration ; more energy (for muscles) / more fuel for respiration (in muscles) ; increases pulse rate / makes heart beat faster ; more, oxygen / glucose, delivered to (muscles) ; [max 3 if muscles not mentioned] [2] [4] [Total: 10] 10 (a) (i) ammeter in series ; voltmeter in parallel ; means of varying p.d. ; [max 2 if not a usable circuit] (ii) (R =) V / I ; = 3 / 0.3 = 10 Ω ; (b) (i) D because it is longer / resistance proportional to length ; [3] [2] [1] (ii) A because it has a small cross-section area / it is thinner / resistance inversely proportional to cross-section area ; [1] (iii) C – 20 Ω and twice as long ; E – 5 Ω and double cross-section area ; [2] [Total: 9] © University of Cambridge International Examinations 2012 Page 7 Mark Scheme: Teachers’ version IGCSE – May/June 2012 Syllabus 0654 11 (a) produces four cells, not two cells ; produces genetic variation ; halves chromosome number / number of chromosomes in new cells is haploid / new cells have half the DNA ; (b) (i) 1 in 4 / one quarter / 0.25 ; (ii) (parents’ genotypes) both Ff ; gametes F and f from both parents ; offspring genotypes FF, Ff, Ff and ff ; ff identified as having cystic fibrosis ; (c) idea of greater distance between alveoli and, blood / red cell / capillary ; reference to diffusion ; will take longer for, gases / oxygen / carbon dioxide, to travel across ; Paper 31 [max 2] [1] [4] [max 2] [Total: 9] © University of Cambridge International Examinations 2012 Page 8 Mark Scheme: Teachers’ version IGCSE – May/June 2012 Syllabus 0654 Paper 31 12 (a) (i) H H H H C C C H H H H alkene H H H H C C C H H H alcohol H H C C H H alkane O H (all correct = 2 one correct = 1) ;; [2] (ii) H H H H H C C C C H H H (double bond could be in middle) ;; [credit cyclobutane with both marks] [2] (b) idea that electricity comes from, power station / burning fuel ; where greenhouse gases / carbon dioxide may still have to be produced / owtte ; [2] (c) (i) heated ; mixed / reacted with water ; requires catalyst ; [3] (ii) solvent / in foods / sterilisation ; [1] [Total: 10] © University of Cambridge International Examinations 2012