Bull Volcanol (2011) 73:479–496 DOI 10.1007/s00445-010-0418-z RESEARCH ARTICLE Volcanology and petrology of Mathews Tuya, northern British Columbia, Canada: glaciovolcanic constraints on interpretations of the 0.730 Ma Cordilleran paleoclimate Benjamin R. Edwards & James K. Russell & Kirstie Simpson Received: 12 June 2009 / Accepted: 5 October 2010 / Published online: 11 November 2010 # Springer-Verlag 2010 Abstract Petrological, volcanological and geochronological data collected at Mathews Tuya together provide constraints on paleoclimate conditions during formation of the edifice. The basaltic tuya was produced via Pleistocene glaciovolcanism in northern British Columbia, Canada, and is located within the Tuya volcanic field (59.195°N/130.434°W), which is part of the northern Cordilleran volcanic province (NCVP). The edifice comprises a variety of lithofacies, including columnarjointed lava, pillow lava, massive dikes, and volcaniclastic rocks. Collectively these deposits record the transition from an explosive subaqueous to an effusive subaerial eruption environment dominated by Pleistocene ice. As is typical for tuyas, the volcaniclastic facies record multiple fragmentation processes including explosive, quench and mechanical fragmentation. All samples from Mathews Tuya are olivineplagioclase porphyritic alkali olivine basalts. They are mineralogically and geochemically similar to nearby glaciovolcanic centers from the southeastern part of the Tuya volcanic field Editorial responsibility: M.A. Clynne Electronic supplementary material The online version of this article (doi:10.1007/s00445-010-0418-z) contains supplementary material, which is available to authorized users. B. R. Edwards (*) Department of Earth Sciences, Dickinson College, Carlisle, PA 17013, USA e-mail: edwardsb@dickinson.edu J. K. Russell Volcanology and Petrology Laboratory, Earth & Ocean Sciences, University of British Columbia, Vancouver, BC, Canada K. Simpson Geoscience BC, #440-890 West Pender Street, Vancouver, BC V6C 1J9, Canada (e.g., Ash Mountain, South Tuya, Tuya Butte) as well as the dominant NCVP rock type. Crystallization scenarios calculated with MELTS account for variations between whole rock and glass compositions via low pressure fractionation. The presence of olivine microphenocrysts and the absence of pyroxene phenocrysts constrain initial crystallization pressures to less than 0.6 GPa. The eruption of Mathews Tuya occurred between 0.718±0.054 Ma and 0.742±0.081 Ma based on 40 Ar/39Ar geochronology (weighted mean age of 0.730 Ma). The age determinations provide the first firm documentation for large (>700 m thick), pre-Fraser/Wisconsin glaciers in north-central British Columbia ~0.730 Ma, and correlate in age with glaciovolcanic deposits in Russia (e.g., Komatsu et al. Geomorph 88: 352-366, 2007) and with marine isotopic evidence for large global ice volumes ~0.730 Ma. Keywords Mathews . Tuya . Cordilleran . Glaciation . Pleistocene . NCVP . AOB Introduction Volcanoes that erupt in glacial environments produce unique features that can be used to constrain paleo-environmental conditions at the time of eruption. Such glaciovolcanic products have been documented worldwide, but are especially prevalent in Iceland (e.g., Kjartsansson 1943; van Bemmelen and Rutten 1955; Sigvaldason 1968; Jones 1969; Tuffen et al. 2002; Hoskuldsson et al. 2006; Schopka et al. 2006; Jakobsson and Guðmundsson 2008; Skilling 2009), western North America (e.g., Mathews 1947; Hoare and Coonrad 1978; Allen et al. 1982; Moore et al. 1995; Hickson 2000; Lescinsky and Fink 2000; Dixon et al. 2002; Edwards et al. 2002, 2006, 2009; Kelman et al. 2002; Bacon and Lanphere 2006), and Antarctica (e.g., Skilling 1994; Smellie and 480 Skilling 1994; Wilch and McIntosh 2007; Smellie et al. 2008; Smellie 2009). Tuyas, also referred to as ‘table mountains’ (e.g. Mathews 1947; van Bemmelen and Rutten 1955), represent one of two uniquely distinctive glaciovolcanic landforms. The term ‘tuya’ was coined 60 years ago by W.H. Mathews, based on his landmark work describing the stratigraphy and morphology of basaltic volcanoes in the Tuya-Teslin region of northwestern British Columbia (Mathews 1947). There, he encountered numerous, small, apparently young, volcanic edifices hosting a variety of enigmatic features. Most of the volcanoes are basaltic in composition, are steep-sided and many have “flat” tops. Mathews recognized that these volcanic edifices shared common stratigraphic elements, including: pillow lavas and breccias, massive to bedded deposits of fragmented glassy basalt (‘hyaloclastite’), and capping, massive basaltic lava. He proposed the term ‘tuya’ for these volcanoes and interpreted their morphology and attendant volcanic lithofacies as indicative of volcanic eruptions from beneath and within Pleistocene ice sheets. He also recognized that the transition from pillow lava and volcanic breccia to subaerial lava flows was an intrinsically important marker horizon for establishing the minimum thickness of the confining ice, thus providing critical information about paleo-environmental conditions extant during the eruptions. Jones (1969) named these transitions ‘passage zones’, which have recently been described in detail by Smellie (2006). Relatively few studies subsequent to Mathews (1947) have examined the formation of basaltic tuyas in detail (e. g., Smellie and Skilling 1994; Moore et al. 1995; Werner and Schmincke 1999; Skilling 2009), and even fewer have attempted to integrate stratigraphic, petrological, and geochronologic data (Werner and Schmincke 1999). Stratigraphic studies of flat-topped volcanoes formed by glaciovolcanism derive mainly from work in Iceland (van Bemmelen and Rutten 1955; Sigvaldason 1968; Jones 1969; Werner and Schmincke 1999; Tuffen et al. 2002; Skilling 2009), Antarctica (e.g., Smellie and Skilling 1994; Skilling 1994; Smellie et al. 2008), and British Columbia, Canada (e.g., Mathews 1947; Allen et al. 1982; Moore et al. 1995; Dixon et al. 2002). Tuyas likely formed in other glacially covered, volcanically active regions of Earth in the past (e.g. Russia; Komatsu et al. 2007), and are also thought to be present on Mars (e.g., Allen 1979; Chapman et al. 2000); their presence and stratigraphy can be used to constrain planetary paleoclimates (e.g., Smellie 2009). Here we present an integrated study of the formation of Mathews Tuya, which is located in the Tuya volcanic field of northern British Columbia (59.195°N/130.434°W; Fig. 1; Mathews 1947; Allen et al. 1982; Moore et al. 1995). The purpose of this paper is threefold. First, we describe the geology and petrology of Mathews Tuya, including descriptions of the critical lithofacies and measurements of chemical Bull Volcanol (2011) 73:479–496 compositions of whole rock and glass samples. Most of the field-based observations were made in July/Aug 1995, with a brief reconnaissance visit in 2009. Secondly, we present a model for the physical and chemical evolution of the volcano that integrates the observed stratigraphic relationships and the petrological character of the volcanic rocks. Lastly, we use new 40Ar/39Ar geochronometry to constrain the regional paleoclimatic conditions in the area surrounding Mathews Tuya and, in conjunction with previously published data, to provide a preliminary view from glaciovolcanic constraints for the distribution of Pleistocene glaciers in the Canadian Cordillera. Geological setting The Tuya volcanic field of the northern Cordilleran volcanic province (NCVP) is an extensive area of Neogene to Recent alkaline volcanism formed from transtensional stresses concentrated within the western Canadian Cordillera after subduction of the Farallon and Nazca plates (Fig. 1; Edwards and Russell 1999, 2000; Madsen et al. 2006). Due to the spatial and temporal coincidence of NCVP volcanism and Pleistocene glaciations, including the Cordilleran Ice Sheet (CIS), a diverse range of glaciovolcanic landforms and deposits have been documented within the NCVP (e.g., Allen et al. 1982; Souther 1992; Moore et al. 1995; Hickson 2000; Dixon et al. 2002; Edwards et al. 2002, 2006, 2008). More than 30 individual volcanic centers/deposits are mapped as part of the Tuya Formation in the Jennings River 1:250,000 map sheet (Fig. 1b; Watson and Mathews 1944; Gabrielse 1970); at least 20 of those deposits show evidence for glaciovolcanism. Mathews (1947) gave brief descriptions of the petrology and volcanology of six tuyas, including what has been informally referred to as ‘Mathews Tuya’. Several studies have subsequently been published on the volcanology, petrology and geochemistry of the volcanic centers that form part of the Tuya Formation (Allen et al. 1982; Moore et al. 1995; Simpson 1996; Dixon et al. 2002; Wetherell et al. 2006; Simpson et al. 2006), but none have done more than briefly mention ‘Mathews Tuya’. Work by Allen et al. (1982) and Moore et al. (1995) gave brief field and geochemical descriptions of Tuya Butte, Ash Mountain and South Tuya (Fig. 1c; Table 1). Dixon et al. (2002) presented data on volatile behavior and geochemistry of Tanzilla Butte, a glaciovolcanic edifice immediately southeast of Tuya Lake; they concluded that ice was up 1 km thick at the onset of eruption. Wetherell et al. (2006) and Simpson et al. (2006) documented subaerial components of the Tuya Formation, which appear to be less common than glaciovolcanic deposits. Gabrielse (1970) inferred that the area underlying the Tuya Formation had been affected by regional ice sheets, Bull Volcanol (2011) 73:479–496 Fig. 1 Maps showing the location of Mathews Tuya. a Digital elevation model (DEM) of the Canadian Cordillera showing the location of the Tuya volcanic field in the northern Cordilleran volcanic province (NCVP; Edwards and Russell 2000). The NCVP comprises predominantly mafic, pre-Holocene volcanic centers (red dots), with minor Holocene activity (yellow dots) and relatively few centers with intermediate to felsic lavas (green dots). Also shown are other major Neogene to Recent volcanic provinces (e.g., Wrangell, Anahim, Wells Grey, Chilcotin and Cascade) situated in the Canadian Cordillera. b Distribution of the Quaternary Tuya Formation (orange) in the Jennings River 1:250,000 map sheet (NTS 104O; Gabrielse 1970), including Mathews Tuya. Abbreviations demarcate selected volcanic centers near Mathews Tuya, including Mount Josephine (MJ), Tuya Butte (TB), South Tuya (ST), Caribou Tindar (CT), and Ash Mountain (AM). c DEM of the region surrounding Tuya Lake, showing the locations of volcanic features mentioned in the text. Stars and numbers indicate peak elevations for centers discussed in the text 481 a Nome 20km Lake 0 Jennings Lakes b 30 Gabrielse Cone AM ST TB West Tuya Lava Field 30 c Ash Mountain 15 High Tuya Lake CT Mathews Tuya MJ Tuya Lake 131 00 59 00 N 130 00 W 30 2100m N Caribou Tindar 1850m 1650m Tuya Mount Butte Josephine NW Mathews Tuya 1775m South Tuya SE 1120m 0 and found evidence of tuyas to the south that have been glaciated, but which appear to have formed on top of glaciated bedrock, implying that the Tuya Formation could span more than one glacial episode (Gabrielse 1998). As glacial erratics, eskers, kame and kettle topography, moraines and glacial lake deposits are widespread throughout the area, at least one ice sheet (i.e. the Last Glacial Maximum CIS) probably covered all of the peaks in the area at some point during the Pleistocene, followed by potentially multiple episodes of alpine and valley glaciation during and after retreat of the ice sheets (Gabrielse 1998). Simpson (1996) presented the first detailed petrological examination of Mathews Tuya and a preliminary analysis of its stratigraphy and physical evolution. This work builds on that study, reassesses its main conclusions, and aims to place the detailed knowledge of the physical and chemical 5km evolution of Mathews Tuya into a regional framework in order to provide constraints for interpretation of paleoclimate conditions during formation of the tuya. Physical and petrological characteristics of Mathews Tuya Mathews Tuya rises to an elevation of 1780 m above sea level, with a relief of ~330 m, and has the characteristic flat top that distinguishes tuyas from most other volcanic landforms (Figs. 2 and 3). It is ~3 km long, elongated northeastsouthwest, and has a maximum exposed width of ~1.5 km. The edifice is bounded on the south by a large (4.5 km wide), northeast-trending U-shaped valley, which extends for several kilometers northeast into the Cassiar Ranges and 482 Bull Volcanol (2011) 73:479–496 Table 1 Whole rock geochemical compositions (weight percent) and normative mineralogy for samples from Mathews Tuyaa Sample KAS2 KAS3A KAS3B KAS11 KAS12A KAS12B KAS14A KAS14B SiO2 TiO2 Al2O3 FeO(T) MnO MgO CaO Na2O 45.55 3.25 14.28 13.28 0.16 7.14 8.05 3.85 47.32 2.34 14.32 12.55 0.17 8.53 8.90 2.98 47.33 2.35 14.36 12.37 0.17 8.39 8.88 3.09 45.45 3.25 14.34 13.32 0.16 6.77 7.98 3.95 45.39 3.24 14.30 13.34 0.16 6.97 7.83 3.95 46.06 3.26 14.40 13.39 0.16 6.87 7.79 4.03 47.03 2.42 14.34 12.60 0.17 8.39 8.66 3.33 46.97 2.48 14.36 12.56 0.17 8.20 8.79 3.15 0.055 0.01 0.045 0.058 0.002 0.038 0.032 0.040 1.14 0.47 98.73 b.d. 1.18 0.47 98.59 b.d. 2.01 0.80 98.03 0.43 2.01 0.80 97.98 0.40 2.04 0.78 98.78 b.d. 1.29 0.52 98.75 b.d. 1.35 0.53 98.57 b.d. 0.010 0.003 6.74 23.24 22.33 1.07 15.46 24.37 4.44 1.12 6.97 23.06 21.83 1.67 15.79 23.74 4.46 1.12 11.88 17.06 15.47 8.86 15.74 21.01 6.18 1.88 11.88 17.12 15.36 8.83 15.20 21.63 6.15 1.88 12.06 18.24 15.18 8.59 15.27 21.46 6.19 1.85 7.62 21.68 20.37 3.52 15.82 23.95 4.60 1.24 7.98 21.62 21.06 2.73 15.74 23.52 4.71 1.26 K2O 1.81 P2O5 0.78 Total 98.14 LOI 0.61 Normative Mineralogyb Or 10.70 Ab 18.25 An 16.34 Ne 7.76 Di 15.38 Ol 21.78 Il 6.16 Ap 1.84 1σ a analytical work was done at McGill University Geochemical Laboratories; b normative mineralogies are in weight percent and were calculated using an Fe2+ /Fe3+ ratio constrained by fO2 =QFM southwest into the Kawdy Plateau. The north side of the edifice hosts a small cirque, and opens northward to a smaller (1.5 km wide) U-shaped valley. The top of the edifice is buttressed part way up on its south side by the Parallel Creek batholith (Fig. 2b), which comprises biotite granite and quartz monzonite (Fig. 2; Gabrielse 1970). Lithofacies Mathews Tuya is a basaltic volcano that comprises coherent and fragmental lithofacies including: massive and jointed lavas and dikes, pillow lava, and associated volcaniclastic rocks (Figs. 2b, 3 and 4a–g). Outcrops at lower elevations are sparse and are restricted to stream cuts on the north, south and lower west faces, and sporadic outcrops elsewhere (Fig. 2). Much of the low-lying landscape surrounding the tuya is basaltic rubble; however, the stratigraphy in these areas has likely been significantly disrupted by permafrost, which is evident on the north and northeast slopes. At higher elevations outcrop is more abundant and forms prominent cliffs. Granitic cobbles and boulders occur locally on most of the upper surfaces of the edifice (Fig. 4h). All of the lithofacies comprise black, variably vesicular (0– 30% vesicles), fine-grained, and olivine-phyric basaltic rocks and clasts. Olivine microphenocrysts are up to 2 mm in maximum dimension and comprise between 10 and 25% of the rock; they are dominantly skeletal with some perfect euhedral edges and locally contain melt inclusions (Figs. 5a, c, g). Plagioclase laths are generally less than 1 mm long and comprise 15 to 20% of the groundmass, which also contains olivine, titanaugite and variable amounts of glass. Plagioclase laths are typically randomly oriented but locally form trachytic textures (e.g., Figs. 5a and c). Oxides occur in all of the samples, and are predominantly contained within olivine microphenocrysts. Rare crustal xenoliths up to 1 cm are present and locally show incipient melting. Coherent Flat-lying, columnar jointed basaltic lavas cap the edifice (Figs. 2 and 4a). At least three distinct, stacked lava flows are present and combine to form a total thickness that ranges between ~20 and >80 m. The west side of the tuya is ~40 m higher in elevation than the eastern side and the lavas are also thicker on the west side. Columnar jointing is typically fine (<0.5 m), well developed, and locally highly irregular in orientation (Fig. 4a). Columnar jointed lavas are also found as isolated structures extending down the slopes of the northwest, northeast and south central flanks, locally Bull Volcanol (2011) 73:479–496 Fig. 2 Aerial view and simplified geology of Mathews Tuya. a Aerial photograph showing relatively flat-topped, high standing, oval shape of Mathews Tuya (MT). Dashed white line delineates the presumed original extent of MT volcanic deposits. b Map showing the general distribution of coherent and volcaniclastic lithofacies at Mathews Tuya. Solid line denotes trace of cross-section (A-A′; see Fig. 9b) through the edifice. The locations of samples described in the text are denoted with black stars and field sample numbers 483 a 0 1.5km N b 1700 KAS12a,b A Undifferentiated colluvium KAS11 KAS9,10 KAS2 KAS7 KAS3a,b KAS4 KAS5 KAS6 Undifferentiated basaltic colluvium Coherent Ol-phyric basaltic facies KAS8a,b Volcaniclastic facies KAS14a,b Interbedded coherent and volcaniclastic facies A’ Parallel Creek Batholith granitoids Oblique Creek Formation, undifferentiated gneiss and schist 1300 0 defined contact approximate contact 1.5km Contour interval = 20 m with radial joint orientations perpendicular to inferred flow directions (Fig. 4b, d). The eastern contact between coherent basalt and granitic basement is distinct, sharp and clearly visible on aerial photography, as a southwest trending lineament. Two 60 cm wide, south trending, steeply dipping, massive dikes (200°/86°E, 180°/88°E) intrude coarse volcanic breccia in the lower section of the north flank, and locally show glassy margins (Fig. 4c). Dikes may also be present in the upper wall of the north-facing cirque. Exposures of pillow lava are most abundant on the northwestern flank (Figs. 3a and 4d) where they commonly occur with associated, interstitial volcanic breccia. Individ- N ual pillows range from 0.5 to ~1 m in diameter, up to 3 m in length, and generally plunge moderately to steeply to the northwest downslope. Pillows of similar size with no interstitial volcaniclastic deposits are locally present lower on the northwest flank. The coherent lithofacies are interpreted to include subaerial and ice-confined columnar jointed lavas, subaqueous pillow lava, and syn-eruption dikes. The variably oriented and finely columnar-jointed lavas are consistent with irregular cooling surfaces and rapid cooling. The radial jointing displayed by some of the lava lobes is consistent with lava tubes or emplacement into ice-confined tunnels. In addition, the lavas do not extend great lateral distances 484 Bull Volcanol (2011) 73:479–496 a b c d Fig. 3 Morphology of Mathews Tuya. a View looking to the south at the northern side of the tuya. Note the flat top on the northern side of the edifice. b Traced line-diagram of a, with approximate boundaries of geological units. See the legend in Fig. 2 for color code of specific units for b and d. c Aerial view looking to the north showing the south side of the edifice, with the Cassiar Mountains in the background. d Traced line-diagram of c, with approximate boundaries of geological units from the main volcanic edifice, which further supports a hypothesis of ice confinement. The flat-lying, capping columnar-jointed lavas are interpreted to have erupted subaerially. The presence of pillow lava is indicative of subaqueous deposition (e.g., Moore 1975; Walker 1992). The dipping geometry of the pillow lava tubes and association with pillow-fragment breccia is consistent with formation of a lava-fed delta (e.g., Swanson 1970; Skilling 2002) that was prograding to the northwest. The massive basaltic dikes crosscut the stratigraphy in the lower part of the edifice and their exposure at the surface confirms that an undetermined amount of the tuya has been eroded locally. highly vesicular (scoriaceous) lava. The mineralogy of the clasts is the same as that of the coherent facies, except that the groundmass has more glass, and the vitric clasts are variably palagonitized (e.g., Fig. 5c and f). The coarsegrained lithofacies is poorly-sorted, matrix-supported and contains breccia-sized fragments from 2 to 120 cm in maximum dimension (Figs. 4e and f). The scoriaceous clasts are subrounded to angular and the non-vesicular/ poorly vesicular clasts are typically blocky, angular and commonly have curviplanar clast margins. Rare granitic xenoliths up to 5 cm in size occur within some clasts, and microlites in some clasts terminate at clast margins. The matrix consists of angular, less than 2 mm, variably vesicular glassy fragments and olivine crystal fragments. Well-preserved bubble wall shards are common (Fig. 5d). The coarse-grained lithofacies is massive to very crudely bedded and locally occurs as lenses within the fine-grained lithofacies (Figs. 4f and g). The fine-grained lithofacies has identical components to the coarse-grained lithofacies except that fragments are sand-sized (<2 mm). This lithofacies is also thickly laminated to thinly bedded (Fig. 4g). The pillow-fragment breccia also has the same components as the coarse-grained lithofacies with the addition of pillow fragments and locally this unit can contain angular granite clasts (Fig. 4d). This lithofacies is Volcaniclastic Volcaniclastic lithofacies, defined in the general sense of Fisher (1961) to include all clastic materials derived from dominantly volcanic sources without implications for fragmentation mechanisms, are generally orange-brown in colour, monomictic, and basaltic. The volcaniclastic lithofacies are subdivided into three distinct units: 1) coarsegrained; 2) fine-grained; and 3) pillow-fragment breccia. All three lithofacies comprise fragments of non-vesicular to Bull Volcanol (2011) 73:479–496 Fig. 4 Field photographs showing large-scale deposit geometry and lithofacies. a Finely jointed, massive lava flow exposed on the north-central flank of Mathews Tuya. b Highly jointed lava lobe on the northwestern flank of Mathews Tuya. c Basal lithofacies comprising dikes and coarse basaltic breccia. The dike is ~1.6 m wide for scale. d Outcroppings at western end of the tuya contain crudely dipping beds of coarse and fine-grained lithofacies interbedded with pillow lava, capped by multiple subaerial lava flows. e Close-up view of matrix-poor, poorly-sorted coarse-grained lithofacies from base of the northern side of the edifice. f Close-up view of talus boulder comprising matrix-rich, palagonitized, poorly sorted fine-grained lithofacies from near the top of the south side of the edifice. Lens cap is 6 cm is diameter. g Outcrop view of crude bedding and sorting in the fine-grained lithofacies near the upper south side of the edifice. Field notebook is 19 cm long. h Granitic glacial erratic sitting on the flank of the edifice 485 a b g h associated with intact, moderately dipping pillow lobes on the northwest flank of the edifice. Within all three lithofacies the non- to poorly vesicular, blocky, angular clasts with curviplanar clast margins are interpreted to have formed by autoclastic processes (quench fragmentation and autobrecciation; Figs. 5b, c, g, h). The bubble wall shards and scoriaceous clasts, which are dominant throughout most of the sampled sections, are interpreted to have formed by explosive fragmentation (Fig. 5d and e). Attrition of larger clasts during transport and deposition also likely contributed to the generation of clasts, although no evidence for significant transport (e.g. rounding or sorting) was observed. The pillow-fragment breccia contains fragments derived from the disintegration of pillow lobes. The lack of jigsaw-fit textures, mixing of variably vesicular clasts and the bedding within some units supports a syn-eruptive origin involving non-explosive and explosive magma-water interaction. Thus the volcaniclastic deposits are interpreted to include fragments produced by autoclastic (hyaloclastite +/- autobreccia) and pyroclastic processes, which is typical of many glaciovolcanic deposits (e.g. Werner and Schmincke 1999). The angular granite clasts locally found within the pillow-fragment breccia occur on the northwestern flank 486 Bull Volcanol (2011) 73:479–496 Fig. 5 Photomicrographs of lithofacies from Mathews Tuya, all taken in plane-polarized light. a Trachytic, vitrophyric basalt with olivine microphenocrysts and plagioclase groundmass. b Fluidally-shaped, vesiculated, pyroclast of vitrophyric olivine basalt in a matrix of finer vitroclastic material (pore space is filled by secondary cement). c Blocky-shaped, non-vesicular pyroclast of trachytic, vitrophyric olivine basalt with incipient palagonitization along the clast rim. d Ash fraction of vesicular basaltic pyroclastic material with bubble-rich, shard-like pyroclasts. e Moderately sorted, clast-supported, highly porous deposit of highly vesicular basaltic tephra. f Close up view of pyroclast in deposits shown in e, showing relatively thicker areas of palagonitization on smaller clasts. g Fluidually-shaped, glass-jacketed phenocrysts of olivine. h Fluidally-shaped pyroclast with vesicles that range from equant (bottom center) to highly stretched (upper edge of clast) of the edifice and appear to be locally derived from the Parallel Creek batholith. The origins of the granitic clasts are enigmatic but could include: 1) dropstones melted out of surrounding ice during the course of the eruption; 2) syn-eruption mixing of pre-existing glacial sediment with volcaniclastic materials; or 3) blocks ejected during the establishment of the volcanic conduit. The angular clast shapes are most consistent with the last hypothesis. Geochronometry Two samples of coherent lithofacies were analyzed using 40 Ar/39Ar geochronometry to constrain interpretations of Bull Volcanol (2011) 73:479–496 the time of eruption and to enable correlation with the global climate record. Previous workers have assumed that much of the Tuya volcanic field formed during the Fraser/ Wisconsin glaciation (e.g., Mathews 1947; Moore et al. 1995; Dixon et al. 2002), although to our knowledge this inference is not constrained by geochronometry. 40 487 two outermost steps on a plateau are not significantly different from the weighted-mean plateau age (at 2 σ, six or more steps only); (5) the outermost two steps on either side of a plateau must not have nonzero slopes with the same sign (at 2 σ, nine or more steps only). All analytical data are included in Supplementary Tables 2 (KAS3a) and 3 (KAS14b). Ar/39Ar methodology Geochemistry Bulk separates from two samples (KAS3a and KAS14b) were washed in acetone, dried, wrapped in aluminum foil and stacked in an irradiation capsule with similar-aged samples and neutron flux monitors (Fish Canyon Tuff sanidine, 28.02 Ma; Renne et al. 1998). The samples were irradiated on July 4 through July 6, 2006 at the McMaster Nuclear Reactor in Hamilton, Ontario, for 90 MWH, with a neutron flux of approximately 3 × 1016 neutrons/cm2. Analyses (n=57) of 19 neutron flux monitor positions produced errors of <0.5% in the J value. The samples were analyzed on August 2 and 15, 2006, at the Noble Gas Laboratory, Pacific Center for Isotopic and Geochemical Research, University of British Columbia, Vancouver, BC, Canada. Samples were step-heated at incrementally higher powers in the defocused beam of a 10 W CO2 laser (New Wave Research MIR10) until fused. The gas evolved from each step was analyzed by a VG5400 mass spectrometer equipped with an ion-counting electron multiplier. All measurements were corrected for total system blank, mass spectrometer sensitivity, mass discrimination, radioactive decay during and subsequent to irradiation, as well as interfering Ar from atmospheric contamination and the irradiation of Ca, Cl and K (isotope production ratios: ð 40 Ar = 39 Ar ÞK ¼ 0:0302 0:00006, 37 Ar=39 Ar ¼ Ca 39 36 1416:4 0:5, Ar= Ar ¼ 0:3952 0:0004, Ca=K ¼ Ca 1:83 0:01 37 ArCa =39 ArK ). 40 Ar/39Ar results Results of the analyses give crystallization ages of 0.718± 54 Ma (KAS3a; initial 40 Ar=39 Ar ¼ 296:5 8:7) and 0.742±81 Ma (KAS14b; initial 40 Ar=39 Ar ¼ 302 34), for a weighted mean age of 0.730 Ma (Fig. 6). The plateau and correlation ages were calculated using Isoplot ver.3.09 (Ludwig 2003). Errors are quoted at the 2 σ (95% confidence) level and are propagated from all sources except mass spectrometer sensitivity and age of the flux monitor. The best statistically-justified plateau and plateau age were picked based on the following criteria: (1) three or more contiguous steps comprising more than 50% of the 39 Ar; (2) probability of fit of the weighted mean age greater than 5% (3) slope of the error-weighted line through the plateau ages equals zero at 5% confidence; (4) ages of the Analytical methods Major element concentrations for all samples of lava were analyzed by X-ray fluorescence at Geochemical Laboratories, McGill University, Quebec. Sample preparation followed the methods described by Cui and Russell (1995). Major element compositions were used to calculate normative mineralogy for whole-rock samples (Table 1). Estimates of analytical uncertainty derive from replicate analysis of blind samples (Table 1). Compositions of volcanic glasses were analyzed using a Cameca SX-50 electron microprobe at the University of British Columbia (cf. Russell and Hauksdottir (2001) for methods). Microprobe work was performed to determine the composition of volcanic glass within clastic samples and the composition of a glassy rind from one of the two dikes (see Table 2 for averages; a full set of analyses are available in electronic format from the authors). Replicate analyses were used to estimate analytical uncertainty. Major elements Samples of coherent lithofacies from Mathews Tuya all plot as basalt, basanite (greater than 10% normative ol), hawaiite and trachybasalt, above the alkaline-subalkaline divide of Irvine and Baragar (1971; Fig. 7a). Whole-rock samples are nepheline normative (Table 1) and plot in two distinct groups (Figs. 7a and b). The first group plots on the hawaiite-basanite boundary, and comprises samples from lower in the stratigraphic section. The second group comprises olivine basalt samples from higher in the section that plot well into the basalt field, as well as a dike that crosscuts the lower stratigraphy and may be a feeder dike for units higher in the section. Analyses of glass samples from volcaniclastic lithofacies (samples KAS 8a, 8b, 15a) and a dike margin also plot in two clusters (Fig. 7a). Clastic facies from relatively low in the section plot as hawaiites/basanites, while the glass rim of a feeder dike plots in the alkali basalt field. Glasses from both clusters have lower Mg # than accompanying whole rock analyses (Fig. 7b); however even though the wholerock Mg # differs by five units, the glasses from both clusters have overlapping Mg #. The two clusters also have 488 a b 1.6 0.0038 σ 0.0034 0.0030 40 0.8 0.0026 0.4 0.0022 KAS3a KAS3a 0.0 0 20 40 60 80 0.0 100 0.2 0.0018 40 d σ 1.2 0.004 40 Ar/ Ar 0.003 0.8 36 Age (Ma) 0.6 Ar/ Ar Cumulative Ar Percent c 0.4 39 39 0.002 0.4 KAS14b 0.0 Ar/ Ar Age (Ma) 1.2 36 Fig. 6 40Ar/39Ar geochronometry for samples from Mathews Tuya. Analytical data for both samples is included in Supplementary Tables 2 and 3. a Plateau diagram for sample KAS3a, a largely holocrystalline basaltic dike (0.742±0.081 Ma). Note that the first step (less than ~0.5% of cumulative 39Ar) is not shown for clarity, and height of individual boxes equals 2 σ errors. b Inverse isochron plot for KAS3a showing all heating steps. Ellipses show 2 σ errors. c Plateau diagram for sample KAS14b, a largely holocrystalline subaerial lava flow (0.718± 0.054 Ma). Note that the first step (less than ~0.5% of cumulative 39Ar) is not shown for clarity, and height of individual boxes equals 2 σ errors. d Inverse isochron plot for KAS14b showing all heating steps. Ellipses show 2 σ errors Bull Volcanol (2011) 73:479–496 0 20 40 60 80 39 Cumulative Ar Percent distinctive Ca/Al ratios (Fig. 7b). Thus the glass and rock analyses show the parallel relationships between units lower and higher in the section. Previously published data from nearby glaciovolcanic edifices (Ash Mountain, South Tuya, Tuya Butte; Moore et al. 1995) show similar general trends between whole-rock and glass analyses (Fig. 7a), and in general parallel trends for the stratigraphically higher group from Mathews Tuya (Fig. 7c). Although Moore et al. (1995) postulated the existence of two distinct geochemical groups at Ash Mountain, South Tuya, and Tuya Butte, the amount of geochemical separation of the two groups at those three volcanoes is minimal in comparison to the compositional variation at Mathews tuya (Fig. 7b versus c). Phase saturation diagrams Phase saturation diagrams for each of three samples (KAS 2 [WR group 1], KAS 3a [WR group 2], KAS8a [glass]) were calculated using MELTS (Ghiorso and Sack 1995; Asimow and Ghiorso 1998) and are used to constrain interpretations of the conditions attending crystallization of the microphenocryst assemblage (Fig. 8). The saturation calculations show the relative stability of major phases for a fixed melt composition. The saturation diagrams are not true phase diagrams, as the calculations to do not take into account changes in liquid compositions resulting from crystallization. Although Opx is never seen as a phenocryst or groundmass 100 KAS14b 0.0 0.2 0.4 39 0.6 0.8 0.001 1.0 40 Ar/ Ar phase in the samples, Ol is present as microphenocrysts and Ol, Pl and Cpx are ubiquitous in the groundmass of all nonvitrophyric samples (Simpson 1996). Calculations using whole-rock analyses as liquid compositions compare favorably to crystallization sequences inferred from petrography (Ol > Ol+Pl > Ol+Pl+Cpx), with Ol being the liquidus phase down to mid- to lower crustal pressures (0.4 to 0.6 GPa). The observed compositional differences between the two groups only slightly alter the estimated phase stabilities as a function of pressure, with the high SiO2 group losing Ol as the liquidus phase at slightly lower pressures than the low SiO2 group. The addition of one weight percent H2O enlarges the stability field of Ol, making it the liquidus phase to even greater depths (0.6 to 0.8 GPa) for both groups. Calculations indicate that the minimum liquidus temperatures for the magmas were greater than 1200°C. Computations using the glass composition yield significantly different results. For low pressure, anhydrous conditions plagioclase is predicted as the stable liquidus phase, followed by Cpx at pressures greater than ~0.35 GPa. However, the addition of one weight percent H2O destabilizes Pl, so that Ol followed closely by Cpx become the predicted low pressure, liquidus phases. The predicted liquidus temperatures as a function of pressure for the glass sample are taken to indicate that the lava erupted at a minimum temperature of ~1100°C. Bull Volcanol (2011) 73:479–496 489 Table 2 Average rock and glass compositions with standard deviations and computed mineral saturation temperatures for anhydrous and hydrous conditions Sample KAS3aa (n=10) 47.26 SiO2 TiO2 3.42 Al2O3 16.18 Cr2O3 0.02 FeO(T) 12.45 MnO 0.15 MgO 4.44 CaO 8.33 Na2O 4.56 K2O 2.25 P2O5 0.93 Totalf 100.00 Calculated Parameters Tliq (dry)g Phase Tliq (wet)h Phase Fe2O3i FeOi 1139 Pl (An64) 1113 Ol (Fo73) 2.297 10.382 1σ KAS8ab (n=10) 0.18 0.06 0.15 0.01 0.12 0.03 0.07 0.07 0.12 0.05 0.07 48.77 3.08 14.58 0.04 12.85 0.19 4.86 9.48 3.91 1.56 0.68 100.00 1σ 0.13 0.05 0.18 0.02 0.19 0.03 0.07 0.08 0.05 0.02 0.05 1152 Pl (An65) 1118 Cpx (Di46) 2.326 10.756 KAS8bc (n=5) 48.01 3.21 15.72 0.01 12.32 0.15 4.47 8.62 4.57 2.08 0.84 100.00 1143 Pl (An64) 1111 Ol (Fo73) 2.290 10.258 1σ 0.36 0.18 0.15 0.01 0.19 0.04 0.21 0.41 0.24 0.19 0.10 KAS15d (n=10) 47.86 3.14 15.96 0.02 12.30 0.15 4.70 8.53 4.48 2.03 0.83 100.00 1145 Pl (An65) 1120 Ol (Fo74) 2.280 10.247 1σ 0.25 0.06 0.15 0.02 0.14 0.03 0.07 0.08 0.10 0.05 0.15 WRe (n=8) 47.12 2.87 14.56 nd 13.13 0.17 7.78 8.49 3.60 1.63 0.65 100.00 1σ 0.75 0.47 0.04 0.48 0.01 0.78 0.48 0.46 0.41 0.16 1224 Ol (Fo81) 1216 Ol (Fo81) 2.187 11.162 a hyaloclastite; b dike selvage; c dike selvage; d hyaloclastite; e average of whole rock analyses from Table 1; f average analyses normalized to 100 weight percent; g all calculations done at P=1 MPa using MELTS (Ghiorso and Sack 1995; Asimow and Ghiorso 1998); h ‘wet’ = 0.5 wt% H2O based on estimates for Ash Mountain from Moore et al. (1995); i all calculations done at fO2=QFM Discussion Chemical evolution of Mathews Tuya We infer, based on the compositional similarities with alkaline basalts from throughout the northern Cordilleran volcanic province (NCVP) and calculated liquidus temperatures, that the formation of Mathews Tuya was initiated by partial melting in the asthenosphere (e.g., Edwards and Russell 2000; Dixon et al. 2002). Edwards and Russell (1999) suggested that the NCVP results from far-field plate tectonic forces that, combined with access to nonsubduction-modified mantle via slab windows (Madsen et al. 2006), produced a magma-charged lithosphere susceptible to periodic tapping caused by fluctuations in the local stress field driven by ice loading and unloading (e.g. Edwards et al. 2002). Other workers (e.g., Jull and McKenzie 1996; MacIennan et al. 2002; Sigvaldason et al. 1992) have suggested that isostatic changes caused by formation/degradation of ice sheets in Iceland led to increased eruption frequencies. While testing such a hypothesis in the Tuya volcanic field is not possible with present datasets, the dominance of glaciovolcanic products in a volcanic field that also has subaerial volcanism (e.g. Simpson et al. 2006; Wetherell et al. 2006) is consistent with causal linkages between ice sheet dynamics and volcanism. Work to test the hypothesis more rigorously by determining eruption ages for 30 of the centers in the volcanic field is presently in progress. Phase equilibrium modeling via MELTS (Fig. 8) indicates that the onset of crystal growth in the parental melt took place at less than 18 km depth based on the observation of Ol as the dominant microphenocryst. The lack of associated peridotite xenoliths, which are relatively common in NCVP lavas (cf. Edwards and Russell 2000; Harder and Russell 2005; Edwards et al. 2006), and the relatively low Mg Numbers for lava samples are both consistent with the parental magma having ponded temporarily within the crust and fractionating slightly prior to eruption; this hypothesis is similar to that of Moore et al. (1995). However, Moore et al. (1995) suggested that chemical differences between what they termed ‘tholeiitic’ and ‘alkalic’ rock types at three volcanoes adjacent to Mathews Tuya (Ash Mountain, Tuya Butte and South Tuya; Fig. 1) resulted from eruption of magmas from two different source regions during the course of a single glaciovolcanic eruption, both of which had been stored at shallow depths. In their model, initial eruption of overlying ‘tholeiitic’ magma allowed for vesiculation and eruption of the ‘deeper’ alkalic magma. We disagree with their model 490 Bull Volcanol (2011) 73:479–496 from two perspectives. Firstly, although the samples from Mathews Tuya also show two slightly different chemical compositions (e.g. Fig. 7b), the mineralogy of the samples is the same, and can be related to low pressure fractionation accompanying changes in activity of H2O; the geochemical variations seen at Mathews Tuya are far greater than those reported by Moore et al. (1995). Secondly, we do not see the predicted rapid change to dominantly magmatic fragmentation that would result from sudden depressurization of a deeper magma body. The transition from quench to magmatic fragmentation in volcaniclastic lithofacies does not appear to be abrupt at Mathews Tuya. a 2 Weight percent Na O + K O 7 2 6 5 4 3 2 44 46 48 50 52 Weight percent SiO2 54 Physical evolution of Mathews Tuya b 1kb dry 0.70 MT WR Molar Ca/Al MT GL 0.60 0.50 1 kb 'wet' 0.40 30 35 40 45 50 Mg Number 55 60 c Molar Ca/Al 0.70 AM WR AM GL ST WR ST GL 1kb dry 0.60 0.50 TB WR TB GL 1 kb 'wet' 0.40 30 40 50 Mg Number 60 70 Fig. 7 Geochemical characteristics for volcanic rocks and glasses from Mathews Tuya and surrounding volcanic centers. a TAS diagram (after LeMaitre 2002) showing published rock (WR) and glass (GL) compositions from edifices within the Tuya volcanic field: Mathews Tuya (MT, this study), Ash Mountain (AM, Allen et al. 1982; Moore et al. 1995), South Tuya (ST, Allen et al. 1982; Moore et al. 1995), and Tuya Butte (TB, Allen et al. 1982; Moore et al. 1995). Small gray symbols show the range of compositions from samples throughout the NCVP (cf. Edwards and Russell 2000). Alkaline-subalkaline division (solid black line) from Irvine and Baragar (1971). b Compositions of rocks and glasses from Mathews Tuya (MT) are plotted as ratios of molar Ca/Al versus Mg# and compared against model liquid lines of descent for low pressure crystallization of anhydrous and hydrous melts (see Tables 1 and 2 for compositions; LLD calculations from MELTS for b and c). c Compositions of rocks and glasses from Ash Mountain (AM), South Tuya (ST), and Tuya Butte (TB) are plotted as ratios of Ca/Al versus Mg# and compared against model liquid lines of descent for low pressure crystallization of anhydrous and hydrous melts Mathews Tuya erupted along the crest of a ridge separating a small U-shaped, glacier-filled valley to the north of the tuya from a much larger U-shaped, ice-filled valley to the south ~0.730 Ma (Fig. 9a). Thus, the volcano has an asymmetric appearance, with the south wall of the valley acting as a buttress along the south side of the edifice (Fig. 9b). Initial venting of the tuya melted a cavity in the overlying ice and produced an ice-confined, water-filled chamber (englacial lake) beneath at least 500 m of ice (e.g., Tuffen 2007). Evidence for the production of a lava-fed delta is consistent with eruption in an ice-dammed lake, which is more likely to form and stabilize during an eruption beneath relatively ‘thick’ ice (e.g. Smellie and Skilling 1994). The eruption appears to have followed the ‘classic’ tuya development model that has been described in detail by a number of previous workers (e.g. Jones 1969; Skilling 1994; Werner and Schmincke 1999; Fig. 9c): initial eruption of coherent pillow lava, followed by increasingly more-explosive eruptions as the volcanic pile grew with respect to the confining water, until the vent was sealed from water and effusion of coherent lava into the iceconfined lake built a lava delta, separated from capping subaerial lava flows by a passage zone (Mathews 1947; Jones 1969; Smellie 2006). The basal succession is overlain by coarse and fine clastic lithofacies that contain dominantly vesicular clasts (Fig. 9c). Several hypotheses might explain the transition from quench to magmatic/phreatomagmatic fragmentation: (1) if the water level in the subglacial cavity remained constant, the hydrostatic pressure overlying the active part of the edifice would decrease as the edifice grew in height; (2) as the eruption changed from initially effusion dominated to explosion dominated, the increased efficiency of heat transfer (e.g., Guðmundsson 2003) could cause an increase in melting, leading to increasing cavity underpressures and higher explosivity (e.g., Tuffen 2007); (3) buildup of meltwater in the sub-ice cavity could have led to catastrophic drainage of the cavity, causing a rapid pressure decrease. Bull Volcanol (2011) 73:479–496 a 1400 1400 Temperature (oC) KAS3a dry KAS3a 1wt% H2O OPX OPX 1300 1300 OL OL CPX CPX 1200 1200 PL PL 1100 1100 1000 1000 0.0 b 0.2 0.4 0.6 Pressure (GPa) 1.0 0.0 0.8 0.2 0.4 0.6 0.8 1.0 Pressure (GPa) 1400 1400 KAS2 1wt% H2O KAS2 dry OPX 1300 1300 OPX OL CPX OL CPX 1200 1200 PL 1100 1100 Temperature (oC) Temperature (oC) Temperature (oC) Fig. 8 Liquidus and pseudoliquidus pressure-temperature relationships calculated for three rock compositions from Mathews Tuya at anhydrous and hydrous (1 weight percent H2O) conditions: a Sample KAS3a; b Sample KAS2; c Sample KAS8a. The curves are consistent with a sequence of crystallization of Ol > Cpx >> Pl at high pressures, and Ol > Cpx ~ Pl at lower pressures. Orthopyroxene is predicted to be stable at the base of the crust but would not crystallize at lower pressures because of its reaction relationship with olivine. The main effect of water is to depress the saturation temperature of plagioclase relative to all other phases 491 PL 1000 1000 0.0 c 0.2 0.4 0.6 Pressure (GPa) 1.0 0.0 0.8 0.4 0.6 0.8 1.0 Pressure (GPa) 1400 1400 KAS8a 1wt% H2O KAS8a dry 1300 1300 CPX CPX OPX 1200 PL OL OPX 1200 PL 1100 OL 1100 1000 1000 0.0 Fig. 9 Schematic regional and local sections for Mathews Tuya. a Schematic regional topographic profile NW-SE showing the position of Mathews Tuya with respect to a smaller U-shaped valley to the north and a much larger U-shaped valley to the south (see Fig. 1). b Schematic cross-section NW-SE (see Fig. 2) illustrating the relationship between volcanic stratigraphy and underlying basement rocks as well as variations in volcanic lithofacies Temperature (oC) Temperature (oC) 0.2 0.2 a 0.4 0.6 Pressure (GPa) 1.0 0.0 0.8 0.2 0.4 0.6 0.8 1.0 Pressure (GPa) Mathews Tuya NW SE 1800 m 1800 m 1600 m 1600 m 1400 m 1400 m 1200 m 1200 m 0 km b 1 km NW 2 km 3 km 4 km 5 km 6 km 7 km 8 km SE 492 Bull Volcanol (2011) 73:479–496 Transition zone from subaqueous to likely subaerial eruption As the edifice grew above the level of the lake the eruption changed from subaqueous to subaerial. Lavas erupted subaerially flowed off the emergent portion of the volcano, entered the englacial lake and formed a pillow-lava delta comprising intact pillow lobes and pillow breccia (e.g., Skilling 2002). Exposures of the pillow-lava delta are restricted to the westnorthwest flank of the volcano so the true extent and geometry of this lava delta is not known. Continued magmatic fragmentation may also have been intermittent or synchronous with effusive eruptions during this time, but was likely subordinate. Subaerially erupted lavas advanced over the deltaic deposits, producing a relatively flat-lying passage zone capped by subhorizontal, subaerial lava. On the northwestern flanks, a series of radially jointed lava mounds outcrop midway down the slope. The origin of these features and timing relative to the other eruptive deposits remains uncertain. However, radial jointing, concave geometries, and apparent downslope dips are consistent with formation as lava tubes within the delta or as lavas emplaced into ice-bounded cavities along the volcano-ice contact (e.g., Loughlin 2002). At present no pillow lava has been found associated with these lavas, so they may have formed after the bounding englacial lake drained. Based on edifice morphology, its eruption age of ~0.730 Ma, and the presence of glacial erratics on the top and flanks of the edifice, it seems likely that glacial erosion has significantly modified the original form of Mathews Tuya. In all of northern British Columbia, extensive cirque glaciation is evident on most north-facing slopes. Mathews Tuya also has a north-facing cirque that has almost bisected Ash Mountain 2100 m 2000 m 1900 m 1800 m 1700 m 1300 m 1200 m 1200 m 1500 m 1400 m Regional volcanological comparisons As many as 20 volcanoes in the Tuya volcanic field may be glaciovolcanic in origin; however, only three other edifices South Tuya Unconsolidated 2100 m volcaniclastic facies comprising scoriaceous ash, 2000 m lapilli and rare bombs (up to 2 m).1900 m Cross-cutting dikes are locally bulbous 1800 m and pillow-like. 1700 m Pillow lava with minor 1600 m interlayered volcaniclastic facies. Upsection1500 m clastic facies is ? more abundant 1400 m and pillows are more vesicular. 1300 m 1600 m the edifice lava cap, and which still contains the remnants of what appears to be a small rock glacier. The extent of erosion at the tuya is consistent with it having experienced prolonged periods of glacial erosion since ~0.730 Ma. We can infer the presence and minimum thickness of ice extant at ~0.730 Ma surrounding Mathews Tuya from the height of the passage zone and the local bedrock topography (Fig. 9a). The passage zone occurs ~300 m above the inferred base of the edifice on the north side, and ~600 m above the valley floor on the south side. Smellie (2006) suggested that passage zones may demarcate the ice-firn transition in glaciers; thus the minimum ice thickness to the north of the vent location was ~400 m, while the minimum ice thickness to the south was ~700 m. Given the geometry of the deeper valley on the south side of the tuya, we would infer, based on a parabolic ice thickness model (Equation 5, p. 242 of Paterson 1994), that the eruption which formed Mathews Tuya occurred within a regionally extensive glacier or ice sheet. However, at present we cannot say with certainly if the enclosing ice mass was a ~0.730 Ma manifestation of the Cordilleran Ice Sheet, which, during the Last Glacial Maximum, is inferred to have been 2–3 km in maximum thickness. We can only say with certainty that the region surrounding Mathews Tuya was partly ice covered ~0.730 Ma. ? Mathews Tuya Tuya Butte 2100 m 2100 m Consolidated volcaniclastic facies comprising scoriaceous ash, lapilli and pillow fragments. Local lenses of pillow lava, dikes, and layers of volcanic bombs. 2000 m 2000 m 1900 m 1900 m Subaerial basaltic lava flows with 1800 m vertical to radial columnar jointing. 1700 m Pillow lava with minor interlayered volcaniclastic facies. 1500 m Fig. 10 Comparative stratigraphic sections for glaciovolcanic edifices in the Tuya volcanic field. Sections are drawn relative to their present day elevations. Shaded field denotes the inferred transition from subaqueous to subaerial facies as marked by the highest elevation of pillowed lavas or deposits containing pillow fragments or hyaloclas- 1800 m 1700 m 1600 m 1400 m 1300 m 1200 m Consolidated massive to bedded volcaniclastic facies. 1600 m Local lenses of pillow lava, dikes, and lava tubes/sills. 1500 m Pillow lava and massive lava(?) with ? minor interlayered volcaniclastic facies, locally cross-cut by dikes. 1400 m 1300 m 1200 m Subaerial basaltic lava flows with vertical to radial columnar jointing. Foreset bedded volcaniclastic facies containing broken and intact isolated pillows and massive(?) lava. Pillow lava with minor interlayered volcaniclastic ? facies locally cross-cut by dikes. tite. General stratigraphic information for Ash Mountain, South Tuya and Tuya Butte was derived from Mathews (1947), Allen et al. (1982), and especially Moore et al. (1995) as well as reconnaissance by the authors. Lithofacies colors same as in Fig. 2 Bull Volcanol (2011) 73:479–496 Fig. 11 Summary of geochronometric constraints on timing of North American glaciation and NCVP glaciovolcanism. Data for approximate relative global ice volumes are derived from 18O/16O for benthic foraminifera from Shackleton et al. (1990). Information on the North American ice record are derived from Bowen et al. (1986), and includes data interpreted as indicating mountain glaciation (MTN), Cordilleran ice sheet (CIS) and Laurentide ice sheet (LIS) deposits. Geochronometry for NCVP volcanic centers is from Souther (1992; Edziza), Edwards et al. (2002; Hoodoo), Edwards et al. (2006; BellIrving), and this study have been previously described in any detail (Fig. 1): Tuya Butte (Mathews 1947; Allen et al. 1982; Moore et al. 1995), South Tuya (Moore et al. 1995), and Ash Mountain (Mathews 1947; Allen et al. 1982; Moore et al. 1995). We use the published stratigraphic information on Tuya Butte, Ash Mountain, South Tuya in conjunction with our stratigraphic description of Mathews Tuya and our own reconnaissance work at Ash Mountain and South Tuya to give a stratigraphic comparison of glaciovolcanic deposits within this region of the Canadian Cordillera (Fig. 10). All four of the volcanoes are inferred to have 200–300 m thick successions of pillow lava at their bases (Mathews 1947; Moore et al. 1995). At South Tuya and Ash Mountain, basal platforms of pillow lava are well exposed, while at Tuya Butte and Mathews Tuya basal exposures are limited. Overlying the pillow lava facies are unconsolidated, massive to bedded volcaniclastic facies. The volcaniclastic facies are monomictic (basaltic), containing scoriaceous 493 lapilli and ash +/- broken pillows and rare intact pillows. At South Tuya and Ash Mountain some volcaniclastic facies contain distinctive fluidally-shaped clasts or bombs (Moore et al. 1995). Basaltic dikes cross-cut the stratigraphy at all centers, and appear to uphold ridges emanating radially from the summit of Ash Mountain. Mathews Tuya and Tuya Butte have characteristic flat tops defined by capping subaerial lava flows that overlie lava-fed deltas, while Ash Mountain and South Tuya are more conical in shape with the highest stratigraphic units comprising poorly characterized volcaniclastic deposits. The varied morphology of the volcanoes within the area suggests that they do not all share the same eruption histories. Mathews Tuya and Tuya Butte have capping lava flows; South Tuya and Ash Mountain do not. Neither Mathews (1947) nor Moore et al. (1995) speculated as to why capping flows were not erupted on South Tuya and Ash Mountain, but at least three plausible explanations exist: (1) the two eruptions may have ended before building above the level of an englacial lake; (2) the bounding ice might have been too thick to form an open cavity; or (3) the capping lava flows may have been removed by erosion, although this is considered least likely. The absence of a capping basalt flow, and presence of an upper conical edifice of scoriaceous lapilli and ash, including fluidal bombs on South Tuya and Ash Mountain suggest subaerial fire fountaining was the main late-stage eruptive style. Tuya Butte and Mathews Tuya are capped by subaerial lavas, which is consistent with effusive eruptions being dominant in the final stages of eruptive activity as well. Implications for pleistocene cordilleran paleoclimate Glaciovolcanism is critically important for recording changes in Pleistocene paleoclimate conditions, and glaciovolcanic products provide a means for further documenting the location and timing of continental ice, which can be compared with paleoclimate proxies from the marine isotopic record and the continental glaciological record (Fig. 11). Detailed volcanological/geochronological studies in Antarctica (e.g. Smellie et al. 2008) show local increases in maximum ice sheet thicknesses through time. In northern British Columbia, the eruption ages for a number of glaciovolcanic deposits are now known and can be used to further constrain interpretations of the Cordilleran paleoclimate, although distinguishing between local and regional glacial events can be problematic (e.g., Edwards et al. 2009). The glaciovolcanic origins of Mathews Tuya confirm the existence of pre-Last Glacial Maximum (LGM) glaciation at ~0.730 Ma, during a period of high ice volume as implied by the marine record. Geochronological evidence of tuya formation in the Tuva Republic, Russia, appears to corroborate an expansion of northern hemisphere 494 glaciers ~0.740 Ma (Yarmolyuk et al. 2001 as reported in Komatsu et al. 2007). The location of the Tuya volcanic field also corresponds with one of the two inferred areas of maximum thickness for the CIS during the LGM (Peltier 1994). However, few deposits remain in this area to provide pre-LGM evidence for regionally extensive glaciation, other than glaciovolcanic deposits such as those exposed at Mathews Tuya. Although previous workers inferred that Tuya area glaciovolcanism occurred during the LGM, our work clearly documents the existence of earlier glaciovolcanic activity. Stratigraphic comparisons of glaciovolcanic deposits in the Tuya volcanic field combined with detailed geochronologic studies currently in progress for other locations within the Tuya volcanic field will soon allow for much better correlations between North American continental and marine climate records. Conclusions Mathews Tuya records continuous volcano-ice interactions starting from initially sub-ice/subaqueous conditions to subaerial conditions. Textural analysis of volcaniclastic deposits show changes in proportions of clasts derived from quench versus explosive fragmentation processes and provides key information on the transitions between effusive and explosive activity in glaciovolcanic eruptions. Although geochemically similar to nearby volcanoes, Mathews Tuya shows the most extreme compositional diversity yet found in the Tuya volcanic field, which appears to be explained by lowpressure crystallization. Its eruption age of ~0.730 Ma means that it provides the first record of Cordilleran ice in northern British Columbia at that time and appears to correlate well with marine proxies indicative of relatively high ice volumes as well as ~0.740 Ma glaciovolcanic deposits in Russia. Acknowledgments We thank several people for general assistance with fieldwork in the Tuya area, including Jim Reed, Chris Price, Blake Parker and Tark Hamilton. Funding for initial fieldwork in 1995 was from LITHOPROBE. During the preparation of the manuscript BRE was supported in part by NSF-EAR 0439707, and a 2009 spot check was funded in part by NSF-EAR 0910712; JKR was supported by the NSERC Discovery Grants program. Tom Ullrich of the Pacific Center for Isotopic & Geochemistry Research at UBC made the 40Ar/39Ar determinations and interpretations. Helpful comments by C. Bacon and M.T. 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