Quantizing Majorana fermions in a superconductor The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. Citation Chamon, C. et al. “Quantizing Majorana fermions in a superconductor.” Physical Review B 81.22 (2010): 224515. © 2010 The American Physical Society. As Published http://dx.doi.org/10.1103/PhysRevB.81.224515 Publisher American Physical Society Version Final published version Accessed Thu May 26 04:48:23 EDT 2016 Citable Link http://hdl.handle.net/1721.1/60849 Terms of Use Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. Detailed Terms PHYSICAL REVIEW B 81, 224515 共2010兲 Quantizing Majorana fermions in a superconductor C. Chamon,1 R. Jackiw,2 Y. Nishida,2 S.-Y. Pi,1 and L. Santos3 1Physics Department, Boston University, Boston, Massachusetts 02215, USA Department, MIT, Cambridge, Massachusetts 02139, USA 3Physics Department, Harvard University, Cambridge, Massachusetts 02138, USA 共Received 19 January 2010; revised manuscript received 7 May 2010; published 17 June 2010兲 2Physics A Dirac-type matrix equation governs surface excitations in a topological insulator in contact with an s-wave superconductor. The order parameter can be homogenous or vortex valued. In the homogenous case a winding number can be defined whose nonvanishing value signals topological effects. A vortex leads to a static, isolated, zero-energy solution. Its mode function is real and has been called “Majorana.” Here we demonstrate that the reality/Majorana feature is not confined to the zero-energy mode but characterizes the full quantum field. In a four-component description a change in basis for the relevant matrices renders the Hamiltonian imaginary and the full, space-time-dependent field is real, as is the case for the relativistic Majorana equation in the Majorana matrix representation. More broadly, we show that the Majorana quantization procedure is generic to superconductors, with or without the Dirac structure, and follows from the constraints of fermionic statistics on the symmetries of Bogoliubov-de Gennes Hamiltonians. The Hamiltonian can always be brought to an imaginary form, leading to equations of motion that are real with quantized real-field solutions. Also we examine the Fock space realization of the zero-mode algebra for the Dirac-type systems. We show that a two-dimensional representation is natural, in which fermion parity is preserved. DOI: 10.1103/PhysRevB.81.224515 PACS number共s兲: 74.20.⫺z I. INTRODUCTION Majorana bound states arise as zero-energy states in twodimensional 共2D兲 systems involving superconductors in the presence of vortices.1–4 These zero modes have attracted much attention recently, in part, because of the possibility that they can realize “half-qubits” within topological quantum computing schemes.3 The basic idea is that two far away Majorana bound states, real fermions, can be put together into a complex fermion acting on a two-dimensional Hilbert space spanned by the states 兩0典 and 兩1典. Hence, two Majorana fermions comprise one qubit, which is protected against the environment if the vortices binding the Majorana fermions are kept far away from each other. The first example of a zero mode in a two-dimensional superconductor was presented in Ref. 1. More recently it has been stated that the proximity effect at the interface between an s-wave superconductor and the surface of a topological insulator can be described by a planar Dirac equation,4 providing a physical realization of the mathematical structure of Ref. 1. Other examples of Majorana bound states arise in systems with a nonrelativistic kinetic term and a p⫾ ⬅ px ⫾ ipy interaction with a vortex order parameter 共i.e., p-wave superconductors兲.2,3 These types of bound states have been the subject of much recent interest.5–8 The focus of the discussions of Majorana fermions in superconductors have focused thus far on the zero modes. However, Majorana’s original work9 was actually quite more general and did not address a single mode but instead a whole field. What he showed was that it was possible to construct a representation of the Dirac equation that admits purely real solutions. The particles that follow from his construction are their own antiparticles and thus necessarily neutral. What was striking about Majorana’s proposal was that these particles were fermions—bosonic neutral particles rep1098-0121/2010/81共22兲/224515共10兲 resented by real fields are common, pions, and vector bosons, such as photons, being simple examples 共see Ref. 10 for a perspective on Majorana fermions兲. In this paper we look at three issues regarding the quantization of Majorana fermions, beyond simply the zero modes, in superconductors. First, we look specifically at the case of Dirac-type systems describing s-wave-induced superconductivity on the surface of topological insulators. There, we find that the entire field of the superconductor model 共and not merely particular modes兲 obeys equations that are analogous to the Majorana equations of particle physics. The equations of motion for the fields can be brought to a real form, and the fermionic solutions are real and therefore their own antiparticles. Indeed, other than the fact that surface states are 2D, the topological insulator-superconductor system can be brought to the exactly same form that was discussed in Majorana’s original formulation of real relativistic fermions. Second, we note various topological features of the Diractype model. We compute the Pontryagin index associated with the k-space dispersion, and find it to be ⫾1 / 2, which is an indication of the existence of zero modes in the presence of vortices. We then present the Fock space-level structures that accommodate an isolated, zero-energy state, which arises in the presence of a vortex. In particular, we show that fermion parity can be preserved, even with a single zeroenergy state. As we discussed above the Majorana zero modes are usually thought of “half” qubits, as two of them make up a complex fermion with a two-dimensional Hilbert space. Here we ruffle this simple view by quantizing the theory in the infinite plane in the presence of a single vortex. A sole Majorana zero mode exists but a two-dimensional Hilbert space remains. In a finite system, another zero mode would appear at the edge, which is however absent in the infinite plane. 224515-1 ©2010 The American Physical Society PHYSICAL REVIEW B 81, 224515 共2010兲 CHAMON et al. Third, we show that the Majorana quantization procedure that we discuss for the Dirac-type equations describing s-wave-induced superconductivity on the surface of topological insulators does extend, more broadly, to any superconductor. A description of Bogoliubov-de Gennes 共BdG兲 Hamiltonians using Majorana modes has been noted by Senthil and Fisher11 for systems where spin-rotational symmetry is broken 共classes D and DIII of Ref. 12兲. Here we show rather generically that lack of spin-rotation symmetry is not a necessity and thus classes C and CI of Ref. 12 also realize Majorana fermions. All one actually needs is to have fermions and hence these results hold for any superconducting system made of half-integer spin particles, regardless of the size of the spin. What we show is that the constraints imposed by fermionic statistics on the symmetries of Bogoliubov-de Gennes Hamiltonians always allow one to bring the Hamiltonian in the Nambu representation to an imaginary form. In turn, Schrödinger’s equation with this imaginary Hamiltonian leads to a real equation of motion for the fields, as in Majorana’s construction. The real-field solutions in the constrained doubled Nambu space can then be quantized as Majorana fields. II. QUANTUM STRUCTURE OF THE SUPERCONDUCTING MODEL Let us start by analyzing the planar Dirac-type systems realized on the surface of a topological insulator, placed in proximity to an s-wave superconductor. The Hamiltonian density for the model under discussion acts on two spatial dimensions.1,4 spin 1/2 fermions with “Majorana mass” 兩⌬兩.13 A static solution to Eq. 共3兲, equivalently Eq. 共4兲, with a vortex profile for ⌬, can be readily found. It corresponds to a zero-energy mode. With f and g real in the Ansatz ↑ = f共r兲exp兵− i/4 − V共r兲其, ↓ = g共r兲exp兵i共 + /4兲 − V共r兲其, V⬘共r兲 ⬅ v共r兲. Equation 共3兲 reduces to 共rg兲⬘ = rf , f ⬘ = − g. f共r兲 = NJ0共r兲, g共r兲 = NJ1共r兲 H= 1 1 · p − 兲ij j + ⌬ⴱi i2ijⴱj − ⌬ⴱii2ij j . 共2兲 2 2 = 共 ↑↓ 兲 2 and comprises the two Pauli matrices Now 共1 , 兲. The 共2 + 1兲-dimensional equations of motion for Eqs. 共1兲 and 共2兲 共3兲 can be presented in two-component matrix notation. it = 共 · p − 兲 + ⌬i2ⴱ . ⌿= 冢冣 ↑ ↓ ⴱ↓ = 冉 冊 . i 2 ⴱ 共8兲 − ⴱ↑ An extended Hamiltonian density H leads to equations for ⌿, which are just two copies of Eq. 共3兲 or 共4兲. 冉 冊 ·p− ⌬ 1 1 ⌿ ⬅ ⌿ⴱTh⌿. 共9兲 H = ⌿ⴱT ⴱ 2 2 −·p+ ⌬ Here T denotes transposition. Because the last two components of ⌿ are constrained by their relation to the first two, ⌿ satisfies the 共pseudo-兲 reality constraint C⌿ⴱ = ⌿ 共10兲 −i2 it↑ = p−↓ − ↑ + ⌬ⴱ↓ , it↓ = p+↑ − ↓ − ⌬ⴱ↑ 共7兲 with N as a real normalization constant.14 While the static, zero-energy mode is readily obtained from Eq. 共3兲, for the finite-energy modes, we must take account of the fact that ↑ , ↓ mix with their complex conjugates. Therefore, one cannot separate the time dependence with an energy phase. Correspondingly one cannot construct a Hamiltonian energy eigenvalue problem, which is the usual first step in the quantization procedure. Progress is achieved by doublings the system with a four-component spinor. 共1兲 ⴱi 共 共6兲 共Dash signifies r—differentiation兲. Regular solutions are Bessel functions H = ⴱ↑ p−↓ + ⴱ↓ p+↑ − 共ⴱ↑↑ + ⴱ↓↓兲 + ⌬ⴱ↑ⴱ↓ + ⌬ⴱ↓↑ . Here ↑,↓ are electron field amplitudes, p⫾ ⬅ −ix ⫾ y , is the chemical potential 共which was omitted in the Ref. 1兲 and ⌬共r兲 is the order parameter that is constant in the homogenous case or takes a vortex profile in the topologically interesting case: ⌬共r兲 = v共r兲ei, in circular coordinates. Equivalently, in a two-component notation 共5兲 with C = C−1 = Cⴱ = CT = C† ⬅ 共 0i2 0 兲. To proceed, one ignores the constraint in Eq. 共10兲 on ⌿ and works with an unconstrained four-spinor ⌽ = 共 兲. Time can now be separated with the usual phase Ansatz and the energy eigenvalue spectrum can be found. h⌽ = it⌽, 共4兲 When the chemical potential is absent, and ⌬ is constant, the above system is a 共2 + 1兲-dimensional version of the 共3 + 1兲-dimensional, two component Majorana equation, which in 共3 + 1兲-dimensional space-time describes chargeless ⌽ = e−iEt⌽E , h⌽E = E⌽E . 共11兲 These are the Bogoliubov-de Gennes equations for the superconductor problem. In the particle physics application, the 224515-2 PHYSICAL REVIEW B 81, 224515 共2010兲 QUANTIZING MAJORANA FERMIONS IN A SUPERCONDUCTOR unconstrained four-component equation is just the Dirac equation describing charged spin 1/2 fermions. When the 共pseudo-兲 reality constraint is imposed, one is dealing with the four-component version of the Majorana equation.13 Observe that h in Eq. 共9兲 possesses the conjugation symmetry C−1hC = − hⴱ , 共12兲 which has the consequence that to each positive-energy eigenmode there corresponds a negative-energy mode. ⴱ C⌽+E = ⌽−E . 冉 共,J兲 = ⌽ⴱi ⌽i,⌽ⴱi 共13兲 A quantum field may now be constructed by superposing the energy eigenmodes ⌽E with appropriate creation and annihilation quantum operators. It is here that we again encounter the Majorana construction: the unconstrained fermion four-spinor ⌽ is like a “Dirac” fermion spinor, governed by a Hamiltonian, which satisfies a conjugation symmetry in Eq. 共12兲 that leads to Eq. 共13兲. Then the spinor ⌿, which satisfies the 共pseudo-兲 reality constraint in Eq. 共10兲, is like a Majorana spinor, viz., a Dirac spinor obeying a 共pseudo-兲 reality condition. With the eigenmodes one can construct a quantum field ⌽̂. It can be an unconstrained Dirac field operator. ⌽̂ = † −iEt aEe−iEt⌽E + 兺 b−E e ⌽E 兺 E⬎0 E⬍0 = 兺 aEe−iEt⌽E + E⬎0 兺 bE† eiEtC⌽Eⴱ . E⬎0 共15a兲 兵⌽̂i共r兲,⌽̂†j 共r⬘兲其 = ␦ij␦共r − r⬘兲. 共15b兲 For the superconductor/topological insulator system under consideration ⌽ → ⌿ and the quantum field ⌿̂ satisfies the constraint 共16兲 This is achieved by setting b = a in Eq. 共14兲. 兺 共aEe−iEt⌽E + aE† eiEtC⌽Eⴱ 兲. E⬎0 冉 冋 册 共5,J5兲 = ⌽ⴱi 册 冊 ⌽j . 共19兲 ij 0 I 0 −I ⌽ j,⌽ⴱi ij 冋 册 冊 0 0 ⌽j . 共20兲 ij But with nonvanishing ⌬ this is not conserved. 冉 0 ⌬ 5 + · J5 = − 2i⌽ⴱi − ⌬ⴱ 0 t 冊 ⌽j . 共21兲 ij 共5,J5兲 ⇒ 2共ⴱT, ⴱT兲, 共22兲 5 + · J5 ⇒ 2⌬ⴱT2ⴱ + 2⌬ⴱT2 . t 共23兲 Thus no conserved current is present in the superconductor model in Eq. 共1兲. The Majorana/reality properties are obscured by the representation of the Dirac matrices employed in presenting the 4 ⫻ 4 Hamiltonian h in Eq. 共9兲. As written, the matrices in h are given in the Weyl representation. ␣= 兵⌿̂i共r兲,⌿̂ j共r⬘兲其 = Cij␦共r − r⬘兲, 共18a兲 兵⌿̂i共r兲,⌿̂†j 共r⬘兲其 = ␦ij␦共r − r⬘兲. 共18b兲 obeying conThese also follow from Eq. 共17兲 with aE , ventional anticommutators. We have ignored possible zero- 冉 0 0 − 冊 冉 冊 = 0 I ␥5 = I 0 冉 冊 I 0 0 −I h = ␣ · p − ␥5 + ⌬R − i␥5⌬I . , 共24兲 共25兲 ⌬R,I are the real and imaginary parts of the order parameter. One may pass to the Majorana representation by conjugating with the unitary matrix 共17兲 Owing to the constraint in Eq. 共16兲 the anticommutators take a Majorana form. aE† 0 0 − When the above is evaluated on the constrained field ⌿, all terms vanish. This is to be expected for a Majorana field which carries no charge. One may also consider a chiral current constructed with the Dirac field ⌽. 共14兲 兵⌽̂i共r兲,⌽̂ j共r⬘兲其 = 0, Cij⌿̂†j = ⌿̂i . 冋 These results persist when the constraint in Eq. 共16兲 is imposed on ⌽ → ⌿. Here the aE operator annihilates positive-energy excitations 共conduction band兲 and the bE† operator creates negativeenergy excitations 共valence band兲. Since ⌽̂ is unconstrained, a and b are independent operators. Their conventional anticommutators ensure that the unconstrained fields satisfy Dirac anticommutation relations. ⌿̂ = energy states; they will be discussed at length below. In the final result in Eq. 共17兲, ⌿̂ retains the Majorana feature of describing excitations that carry no charge. This is true for the entire quantum field ⌿̂, not only for its zeroenergy modes 共if any兲, which are emphasized in the condensed-matter literature. Explicitly we see this by examining the conserved current that is constructed with the unconstrained Dirac field ⌽. V= 冉 Q− Q+ 冊 Q+ ei/4, − Q− 1 Q⫾ ⬅ 共1 ⫾ 2兲. 2 Then h becomes V−1hV = 冉 − py px1 + i⌬I px1 − i⌬I py 冊冉 + 共26兲 冊 2 − ⌬ R 2 . − ⌬ R 2 − 2 共27兲 This is manifestly imaginary and the conjugation matrix C in Eq. 共10兲 becomes the identity so that the 共pseudo-兲 reality constraint on ⌿̂ becomes a reality condition.17 224515-3 PHYSICAL REVIEW B 81, 224515 共2010兲 CHAMON et al. III. HOMOGENOUS ORDER PARAMETER operator ⌿̂ is constructed as in Eq. 共17兲, which with notational changes 关aE → an共k兲 ; ⌽E → ⌽n共k兲 ; n = 共+ , −兲兴 reads explicitly i For constant ⌬ = me , we pass to momentum space with an eik·r Ansatz in Eq. 共11兲. The energy eigenvalue is E = ⫾ 冑共k ⫾ 兲2 + m2 ⌿̂共t,r兲 = 兺 共28兲 n with no correlation among the signs. For fixed k there are two 共⫾兲 positive-energy solutions and two negative-energy solutions. They become doubly degenerate at = 0. The degeneracy occurs because at = 0, h commutes with S i 3 = 共 e0−ie3 0 兲 when the phase of ⌬ is constant. The energy in Eq. 共28兲 is nonvanishing for all values of the parameters; there is no zero-energy state. The operators aE , aE† and the eigenmodes ⌽E, which are explicitly presented in Appendix A, are labeled by the momentum k and a further 共+ , −兲 variety describing the twofold dependence on of E⫾ ⬅ 冑共k ⫿ 兲2 + m2 ⱖ 兩m兩. The quantum 冉冊冕 冉 ˆ ↑ ˆ = ˆ ↓ + = 1 冑2E− d 2k 共2兲2 再 冉 1 冑2E+ a−共k兲e−i共E−t−k·r兲 a+共k兲e−i共E+t−k·r兲 ⌬ † † i共E−t−k·r兲 h ⬘ = ⌺ an a 共a = 1,2,3兲. ⌺i = 冉 Here ni = ki共i = 1 , 2兲 and n3 is ⌬e−i ⬅ m, i.e., the constant phase of ⌬ is removed so m is a real constant but of indefinite sign. The matrices ⌺a 冑E+ − k + e−i兩− 典 冊 共30兲 . − ieiij j 0 ie 冊冎 −i ij j 0 冊 , ⌺3 = 冉 3 0 0 3 冊 共32兲 satisfy the SU共2兲 algebra, as is explicitly recognized after a further unitary transformation. U−1⌺aU = U⬅ 冉 P+ e −i 冉 冊 冊 − e i P − P− P+ a 0 , 0 a , 1 P⫾ ⬅ 共I ⫾ 3兲. 2 共33兲 共34兲 When the Hamiltonian is of the form 共31兲, we can consider the topological current in momentum space.20 K = 共31兲 i共E+t−k·r兲 冑E− + k + e−i兩+ 典 IV. TOPOLOGICAL NUMBERS When is absent and S commutes with h, we may equivalently work with h⬘ ⬅ Sh, which possesses the same eigenvectors as h, common with the eigenvectors of S. However, h⬘ has the appealing form 共29兲 with positive-energy eigenfunction ⌽n共k兲 carrying energy eigenvalue En. The conjugation condition in Eq. 共13兲 now states that C⌽ⴱn共k兲 is a negative energy solution at 共−k兲. Actually we can suppress the lower two components of ⌽n共k兲 in Eq. 共29兲, because they repeat the information contained in the upper two components, owing to the subsidiary condition in Eq. 共16兲. In this way from the four-component spinors recorded in Appendix A, we arrive at a mode expansion for the electron field operators ˆ ↑,↓. 冑E− + k + 兩− 典 + a−共k兲e Here 兩 ⫾ 典 are the two-component eigenvectors of · k̂ : 兩+典 where arises as k̂ ⬅ 冑12 共 e1i 兲 , 兩−典 ⬅ 冑12 共 −e1i 兲, = 共cos , sin 兲. One verifies that Eq. 共30兲 satisfies Eq. 共3兲. The Majorana character of this expression manifests itself in that the particle annihilation operators a⫾, associated with the positive energy eigenvalues E⫾, are partnered with their † , which are associHermitian adjoint creation operators a⫾ ated with the negative-energy −E⫾ modes. By contrast, for a Dirac field the negative-energy modes are associated with the † , which anticommute with antiparticle creation operators b⫾ † a⫾ , a⫾. In other words, in the Majorana field operator in Eq. 共30兲 the antiparticle 共hole兲 states are identified with the particle states. d 2k 兵an共k兲e−i共Ent−k·r兲⌽n共k兲 共2兲2 + a†n共k兲ei共Ent−k·r兲C⌽ⴱn共k兲其 冑E+ − k + 兩+ 典 − a+共k兲e ⌬ 冕 1 ␣ abcn̂a␣n̂bn̂c共n̂ ⬅ n/兩n兩兲 8 共35兲 and evaluate the topological number by integrating over twodimensional k space. N= 冕 d2kK0共k兲 = 1 8 冕 d 2k m m = . 共36兲 共k2 + m2兲3/2 2兩m兩 The nonvanishing answer ⫾1 / 2, depending only on the sign of m, is evidence that the model belongs to a topologically nontrivial class. It is also a hint that topologically protected zero modes exist in the presence of a vortex. 共Although vortex-based zero modes are also present for ⫽ 0, we do 224515-4 PHYSICAL REVIEW B 81, 224515 共2010兲 QUANTIZING MAJORANA FERMIONS IN A SUPERCONDUCTOR Again there are two towers of states not know how to define a winding number in that case.兲 We can understand the fractional value for N. The unit vector n̂a = 共k cos ,k sin ,m兲/冑k2 + m2 共37兲 maps R共2兲共⫽S共2兲兲 to S共2兲. When k begins at k = 0, n̂a is at the north or south pole 共0 , 0 , ⫾ 1兲. As k ranges to ⬁, n̂a covers a hemisphere 共upper or lower兲 and ends at the equator of S共2兲. Thus only one half of S共2兲 is covered. † † aE† aE⬘aE⬙ . . . 兩f典, 兩0+典 = When ⌬ takes the vortex form, ⌬共r兲 = v共r兲ei, Eq. 共11兲 possesses an isolated zero-energy mode 冉 冊 0v i20vⴱ 共38兲 with 0v determined by Eqs. 共5兲 and 共7兲. Note that C⌿0vⴱ = ⌿0v . 共39兲 There are also continuum modes. The operator field ⌿̂ is now given by an expansion such as Eq. 共17兲, except there is an additional contribution due to the zero mode controlled by the operator A. ⌿̂ ⬅ 共aEe−iEt⌽E + aE† eiEtC⌽Eⴱ 兲 + A冑2⌿0v . 兺 E⬎0 共40兲 共The 冑2 factor will be explained later.兲 Due to Eqs. 共16兲 and 共39兲, A is Hermitian A = A†, anticommutes with 共aE , aE† 兲 and obeys 兵A,A其 = 2A2 = 1. 共41兲 The question arises: how is A realized on states? Two possibilities present themselves: two disconnected onedimensional representations or one two-dimensional representation. In the first instance, we take the ground state to be an eigenstate of A. The possible eigenvalues are ⫾ 冑12 , so there are two ground states, 兩0+典 with eigenvalue + 冑12 , and 兩0−典 with eigenvalue − 冑12 . No local operator connects the two and the two towers of states built upon them † † aE† aE⬘aE⬙ . . . 兩0⫾典 define two disconnected spaces of states. Moreover, one observes that A has a nonvanishing expectation value 具0⫾兩A兩0⫾典 = ⫾ 冑12 . Since A is a fermionic operator, fermion parity is lost.21 In the second possibility, with a two-dimensional realization, we suppose that the vacuum is doubly degenerate: call one “bosonic” 兩b典, the other “fermionic” 兩f典, and A connects the two 1 共42兲 1 共43兲 A兩f典 = 冑2 兩b典, A兩b典 = 冑2 兩f典. 共Phase choice does not loose generality.兲 † but now A connects them. With this realization, fermion parity is preserved when 兩b典 and 兩f典 are taken with opposite fermion parity. Of course since A is Hermitian, it can be diagonalized by the eigenstates. V. SINGLE-VORTEX ORDER PARAMETER ⌿0v = † aE† aE⬘aE⬙ . . . 兩b典 兩0−典 = 1 冑2 共兩b典 + 兩f典兲, 1 冑2 共兩b典 − 兩f典兲. 共44兲 This regains the two states of the two one-dimensional realizations. But the combination 兩b典 ⫾ 兩f典 violates fermion parity as it superposes states with opposite fermion parity. There does not seem to be a mathematical way to choose between the two possibilities. But physical arguments favor the fermion parity preserving realization. First of all, there is no reason to abandon fermion parity; if possible it should be preserved since it is a feature of the action. Also arguments against combining states of opposite fermion parity may be given: Since bosons and fermions transform differently under 2-spatial rotations; the 兩0⫾典 states in Eq. 共44兲 are not rotationally covariant but transform into each other. 关This argument is completely convincing in a 共3 + 1兲-dimensional theory. In 共2 + 1兲 dimensions the anyon possibility clouds the picture, and in 共1 + 1兲 dimensions the argument cannot be made, because spatial rotations do not occur.兴 Furthermore, time inversion transformations work differently on bosons and fermions: T2 is I for bosons and −I for spinning fermions. The superposed states in Eq. 共44兲 are not invariant under T2, rather they transform into each other. 关This argument can be made for 共2 + 1兲 dimensional models, but in 共1 + 1兲 dimensions spin is absent so the fermion parity violating option cannot be ruled out. Furthermore, the fermion-boson equivalence of 共1 + 1兲-dimensional models obscures the status of fermion-boson mixing. Indeed it is argued within supersymmetry that fermion parity is lost in the presence of solitons in 共1 + 1兲 dimensions “due to boundary effects.”22兴 关Any argument based on time inversion transformations requires viewing the complex valued vortex configuration as arising from the degrees of freedom of an enlarged model, in which the vortex emerges from the dynamics of the extended model 共Abrikosov, Ginzburg, and Landau兲. Otherwise, a vortex background is not T invariant.兴 In the next section we examine the vortex/antivortex background and argue that the two-state, two-dimensional, fermion parity preserving realization can be established. The physical picture that emerges is that there are two towers of states, one built on an “empty” zero-energy state 兩b典, the other on the “filled” zero-energy state 兩f典, and the A operator, which connects the two “vacua,” fills or empties the zeroenergy state. VI. VORTEX/ANTIVORTEX ORDER PARAMETER Insight on physical states in the presence of a vortex in a superconductor adjoined to a topological insulator can be 224515-5 PHYSICAL REVIEW B 81, 224515 共2010兲 CHAMON et al. gotten by considering a vortex/antivortex background. The zero-energy mode for an antivortex at the origin, ⌬共r兲 = v共r兲e−i, is given by ↓ = NJ0共r兲exp兵i/4 − V共r兲其, ↑ = NJ1共r兲exp兵− i共 + /4兲 − V共r兲其. 共45兲 To simplify the discussion, we omit the chemical potential and evaluate V共r兲 ⬅ 兰rdr⬘v共r⬘兲 with the asymptotic form of v共r兲 → m. Thus the zero-energy mode for the vortex be- a⑀†兩f典 = 0. can be built either on the The remaining states, created by vacuum 兩⍀典 : aE† aE† aE† . . . 兩⍀典 or on the low-lying state ⬘ ⬙ 兩f典 : a⑀†兩⍀典 : aE† aE† ⬘aE† ⬙ . . . 兩f典. Now let us remove the antivortex by passing R to infinity. vv̄ vv̄ v Both ⌿⫾ ⑀ collapse to their zero-mode limit, ⌿⫾⑀ → ⌿0, and the expansion in Eq. 共42兲 becomes ⌿̂ = ⌿̂cont + r→⬁ comes, approximately 0v ⬇ Ne −i/4 −mr e 冉冊 1 共46a兲 0 = Ne i/4 −m兩r−R兩 e 冉冊 0 1 The corresponding four spinors that solve Eq. 共11兲 at zero energy are 冢 冣 冢 冣 ⌿0v = Ne−i/4e−mr 0 0 共47a兲 , − Nei/4e−mr 0 ⌿0v̄ = Ne Ne i/4 −m兩r−R兩 e −i/4 −m兩r−R兩 e 0 . 共47b兲 Consider now a configuration with a vortex at the origin and an antivortex at R. No zero mode is present in the spectrum of h; rather there are two bound states, one with positive, exponentially small energy ⬇ e−mR and the other with equal magnitude, but opposite sign. The former, called ⌽⑀vv̄, consists of portions localized at the origin 共vortex兲 and at r = R 共antivortex兲. The latter is given by ⌽−vv̄⑀ = C⌽⑀vv̄ⴱ and has similar structure. Both contribute unambiguously to the expansion of the quantum field operator ⌿̂, the former with an annihilation operator, the latter with a creation operator. ⌿̂ ⬅ ⌿̂cont + a⑀e−it⌽⑀vv̄ + a⑀†eitC⌽⑀vv̄ⴱ . 共48兲 The first term on the right is the continuum contribution, as in Eq. 共40兲. The Fock space spectrum is clear. There is a vacuum state 兩⍀典 annihilated by a⑀ a⑀兩⍀典 = 0. a⑀†兩⍀典 = 兩f典, 共49b兲 a⑀兩f典 = 兩⍀典, 共49c兲 a⑀ + a⑀† 2 2⌿0v = ⌿̂cont + A冑2⌿0v . 共50兲 1 A兩b典 = 冑2 兩f典, A兩f典 = 冑2 兩b典 1 共51兲 and two towers of states are built upon 兩b典 and 兩f典. In this way we justify the two-dimensional, fermion parity preserving realization of the zero-mode algebra in a superconducting/topological insulator system. 关Note the occurrence of the factor 冑2 modifying ⌿0v. This explains its first appearance in Eq. 共40兲. This factor compensates in the completeness sum for the loss of the antivortex wave function.兴 Because no explicit solutions in a vortex/antivortex background are available, the argument in this section is qualitative, without explicit formulas. However, one may consider a one-dimensional example with Majorana fermions in the presence of a kink and/or a kink antikink pair.21 In that model one can solve equations explicitly and verify the behavior described here for the two-dimensional vortex case. In this way one also establishes that even in one spatial dimension 共in the absence of rotation and spin to enforce fermion parity兲 the two-dimensional realization of the zero-mode algebra is appropriate. In Appendix B we present an approximate determination of the low-energy eigenvalues in the presence of a vortex/ antivortex pair. The result supports the above qualitative argument: an exponentially small splitting of the zero-energy mode is established. Also in the appendix, we study the two vortex background, and find, within the same approximation that no energy splitting occurs; rather two zero modes persist as anticipated by index theorems. 共49a兲 A low-lying state is gotten by operating on 兩⍀典 with a⑀†. 冉 冑 冊冑 兵A,A其 = 1, 共46b兲 . ⑀→0 Moreover the action of A ⬅ 冑12 共a + a†兲 = A† may be read off Eq. 共49兲. Renaming 兩⍀典 as 兩b典, we find while the antivortex at r = R, in the same approximation leads to 0v̄ 共49d兲 aE† VII. QUANTIZING MAJORANAS FERMIONS IN GENERIC SUPERCONDUCTORS In the preceding sections we showed that Majorana’s quantization prescription of the Dirac equation directly applies to the full quantum field describing the proximity effect of an s-wave superconductor to surface states of a topologi- 224515-6 PHYSICAL REVIEW B 81, 224515 共2010兲 QUANTIZING MAJORANA FERMIONS IN A SUPERCONDUCTOR cal insulator. Below we shall show that Majorana’s quantization prescription of real neutral fermions is rather generic in superconductors with or without Dirac-type dispersions. The construction below is possible for any half-integer spin 共fermionic兲 particle. The reality conditions on the fermionic fields follow from symmetries of the BdG Hamiltonian for superconductors constructed in the Nambu basis. Let us consider a system with fermionic degrees of free† , where r labels position, n the possible dom r,n,s and r,n,s flavors 共bands, for instance兲, and s the spin 共half-integer兲 along a chosen quantization axis. For simplicity, we shall define an index ␣ ⬅ 共r , n , s兲 that encodes all these degrees of freedom. The Hamiltonian describing superconductivity in such a system can be written as − hⴱ = CⴱhC. We stress that fermionic statistics underlies this result, as it is the reason for the minus signs and the complex conjugation in both terms in the second row of Eq. 共55兲. It follows from this symmetry that positive and negative eigenmodes of h are paired h⌽E = E⌽E ⇒ h共C⌽Eⴱ 兲 = − E共C⌽Eⴱ 兲 ⴱ = ⌽−E . C⌽+E B. Generic Majorana basis and its real equation of motion we can write It follows that − h̃ⴱ = Vⴱ共− hⴱ兲Vⴱ† = Vⴱ共CⴱhC兲Vⴱ† = VⴱCⴱV†VhV†VCVⴱ† = 共VCVT兲ⴱh̃共VCVT兲 = C̃ⴱh̃C̃ 共52兲 共53兲 冊 共54兲 † H ⌬ 1 ⌿ ⬅ ⌿†h⌿. H = ⌿† † 2 ⌬ − Hⴱ That HT = Hⴱ follows from H = H†. Notice that ⌬ = −⌬T is enforced because of fermionic statistics and consequently we can also write h= 冉 冊 ⌬ 1 H . ⴱ 2 − ⌬ − Hⴱ 共55兲 冉 冊 共56兲 Let us define C= 0 I I 0 so that C = CT = Cⴱ = C† = C−1. The operators ⌿ must satisfy the constraint Cab⌿†b = ⌿a , so the transformation law of C is 共57兲 and 兵⌿a,⌿†b其 = ␦ab . 共t + ih̃兲⌿̃ = 0 One can easily check that any BdG-type h as in Eq. 共55兲 possesses the following conjugation symmetry 共65兲 so the equation of motion for the field is purely real and thus admits purely real solutions. Notice that this path mirrors Majorana’s formulation of the Dirac equation for spin 1/2 particles 共he constructed a purely imaginary representation of the Dirac matrices, obtaining an equation of motion that was real兲. Notice that in this basis the commutation relations become 兵⌿̃a,⌿̃b其 = C̃ab = ␦ab and 兵⌿̃a,⌿̃†b其 = ␦ab 共66兲 corresponding to real fermions ⌿̃a = ⌿̃†a . 共58兲 A. Conjugation symmetry 共64兲 共Notice that C̃C̃ⴱ = VCVTVⴱCⴱV† = I so C̃−1 = C̃ⴱ still.兲 We will construct below a unitary matrix V such that C̃ = I. This basis is the appropriate Majorana representation for the generic superconducting system of half-integer spin particles 共for any number of flavors兲. In this basis, one has h̃ = −h̃ⴱ so that h̃ is imaginary or equivalently ih̃ is real. It follows from Schrödinger’s equation that where the index a ⬅ 共␣ , p兲 with p = ⫾ the Nambu grading 共⌿␣,+ = ␣ and ⌿␣,− = ␣† 兲. The fermionic commutation relations of the fields , † translate into 兵⌿a,⌿b其 = Cab 共63兲 C → C̃ = VCVT . 冉 冊 冉 共62兲 h → h̃ = VhV† . 1 1 1 = 兺 ␣† H␣ + ␣共− HT兲␣† + ␣† ⌬␣† 2 2 ␣, 2 ⌿= 共61兲 Consider a unitary transformation V, under which 1 1 1 1 ⴱ = 兺 ␣† H␣ − H␣␣† + ␣† ⌬␣† + ⌬␣ ␣ 2 2 2 2 ␣, Defining 共60兲 or equivalently 1 1 ⴱ H = 兺 ␣† H␣ + ␣† ⌬␣† + ⌬␣ ␣ 2 2 ␣, 1 † + ␣⌬␣  . 2 共59兲 共67兲 C. Construction of V The appropriate unitary transformation V which makes C̃ = I is constructed as follows. Because of fermionic statistics, the time-reversal operator ⌰ squares to −1. One can y write ⌰ = TK, where K is complex conjugation and T = eiS , 224515-7 PHYSICAL REVIEW B 81, 224515 共2010兲 CHAMON et al. with Sy the y component of the angular-momentum operator 共in a representation such that Sy is a purely imaginary matrix兲. T is a real antisymmetric matrix 共T = Tⴱ and TT = −T兲 y with T2 = ei2S = −Ispin⫻flavor when spin is half-integer. For instance, for spin 1/2 particles T = i2. Consider the following transformation: V= 冉 Q− − iQ+ iQ+ − Q− 冊 ei/4, 1 Q⫾ ⬅ 共1 ⫿ iT兲 2 APPENDIX A We present the four-component, positive energy solutions to Eq. 共11兲. The eigenvalues E⫾ = 冑共k ⫿ 兲2 + 兩⌬兩2 are associated with the eigenvectors 共68兲 关compare with Eq. 共26兲.兴 Notice that Q⫾ are projectors 2 † = Q⫾兲, that Q⫾ = Q⫾, and that Q+2 + Q−2 = Ispin⫻flavor and 共Q⫾ ⴱ T = Q⫾ = Q⫿. One can Q+Q− = Q−Q+ = 0. Also notice that Q⫾ then easily check that the above defined V is such that C̃ = VCVT = I. 共69兲 1 ⌽+共k兲 = 冑E + ⌽−共k兲 = 1 冑E − 冢 冢 ⌬ 冑E+ − k + 兩+ 典 冑E+ − k + 兩+ 典 ⌬ 冑E− + k + 兩− 典 冑E− + k + 兩− 典 冣 冣 , . ⴱ 共−k兲. 兩 ⫾ 典 are The negative-energy spinors are given by C⌽⫾ defined in the text. VIII. SUMMARY In this paper we studied mainly three issues regarding the quantization of Majorana fermions in superconductors, following closely Majorana’s original definitions, and looked beyond just the Majorana zero-energy modes that are bound to topological defects such as vortices. We started by analyzing the specific case of Dirac-type systems describing s-wave-induced superconductivity on the surface of topological insulators. We showed that the entire field of the superconductor model 共and not merely particular modes兲 obeys equations that are analogous to the Majorana equations of particle physics. We then analyzed the quantization of the theory in the presence of vortices. We showed that fermion parity can be preserved even with a single zero-energy state. This quantization scheme shows that one can obtain a two-dimensional Hilbert in the presence of a single vortex in an infinite plane, presenting a case where each Majorana fermions can be, when present in odd numbers, more than half a qubit. Finally, we showed that the Majorana quantization procedure that we discussed for the Dirac-type equations describing s-wave-induced superconductivity on the surface of topological insulators does extend, more broadly, to any superconductor. The constraints imposed by fermionic statistics on the symmetries of Bogoliubov-de Gennes Hamiltonians are sufficient to allow real-field solutions in the constrained doubled Nambu space that can then be quantized as Majorana fields. This results follows simply from fermionic statistics plus superconductivity, irrespectively of the presence or absence of any other symmetries in the problem, such as spin-rotation invariance or time-reversal symmetry. APPENDIX B We study the low-lying energy levels of the Dirac-type Hamiltonian h in Eq. 共9兲 with set to zero and ⌬ chosen first in an approximate vortex/antivortex profile ⌬vv̄ = mei⍀共r−R/2兲e−i⍀共r+R/2兲 共B1兲 and then similarly with two vortices. 共B2兲 ⌬vv = mei⍀共r−R/2兲ei⍀共r+R/2兲 Here ⍀ is the argument of the appropriate vector x + iy = e i , r ei⍀共r兲 ⬅ ei⍀共⫾R兲 ⬅ ⫾ 共X + iY兲 = ⫾ ei⌰ R with x = r cos , y = r sin , X = R cos ⌰ , Y = R sin ⌰. One vertex is located at r ⬇ R / 2, the antivortex or the second vortex at r ⬇ −R / 2.23 1. Vortex/antivortex Near the vortex at r ⬇ R / 2 the order parameter ⌬vv̄ is approximated by ⌬vv̄ → ⌬v = mei⍀共r−R/2兲e−i⍀共R兲 = mei⍀共r−R/2兲e−i⌰ . 共B3兲 The zero mode in the presence of ⌬v differs from Eq. 共47a兲 by a phase due to the additional phase ei⌰ in ⌬v. Also the location is shifted by R / 2. ACKNOWLEDGMENTS 冢冣 v We thank V. Sanz, who participated in an early stage of this investigation, for useful discussions. N. Iqbal and D. Park evaluated numerically the integral in Eqs. 共B11兲 and 共B12兲. This research is supported by DOE under Grants No. DEF-06ER46316 共C.C.兲, No. 05ER41360 共R.J.兲, and No. 91ER40676 共S.-Y. P.兲. 0v = 0 0 − vⴱ , v⬅ m 冑 e −i共/4+⌰/2兲 −m兩r−R/2兩 e . 共B4兲 Similarly, with the order parameter near the antivortex at r ⬇ −R / 2 taken as 224515-8 PHYSICAL REVIEW B 81, 224515 共2010兲 QUANTIZING MAJORANA FERMIONS IN A SUPERCONDUCTOR ⌬v̄v → ⌬v̄ = mei⍀共−R兲e−i⍀共r+R/2兲 = − mei⌰e−i⍀共r+R/2兲 ⑀ = 4m2 共B5兲 冕 ⬁ dre−mr 0 1 冕 d关1 − rm共1 + cos 兲兴e−mD 0 共B11兲 the zero mode solution replacing Eq. 共47b兲 reads 冢冣 0 0v̄ = v̄ v̄ ⴱ m v̄ ⬅ , 冑 e i共3/4+⌰/2兲 −m兩r+R/2兩 e 共B6兲 . and the energy is shifted from zero by ⫾⑀. Numerical integration of Eq. 共B11兲 at large R yields a result consistent with ⑀→ 0 0v R→⬁ 0v̄ and of h Next we evaluate the matrix element between in Eq. 共9兲, with = 0 and order parameters as in Eq. 共B1兲. We find that the diagonal matrix elements vanish 具v兩h兩v典 = 具v̄兩h兩v̄典 = 0. The energy shift ⌬E, determined by the offdiagonal elements of h, is ⌬E = ⫾ 兩具v̄兩h兩v典兩, ⴱ 具v̄兩h兩v典 = 具v兩h兩v̄典 = 冕 共B7兲 d2rv̄ⴱ p+v = − i m3 冕 ⴱ d r共v̄ p+v + ⬁ rdre−mr 冕 − 0 A further shift of by ⌰ leaves d2rv̄ⴱ p+v = − i 2m3 ⴱ v̄⌬vv̄v兲 − H.c. 共B8兲 The order parameter in Eq. 共B2兲 describing two vortices located at r ⬇ ⫾ R / 2 reduces at r ⬇ R / 2 to 冕 ⬁ rdre−mr 0 冕 ⌬vv → ⌬v+ = mei⍀共r−R/2兲ei⍀共R兲 = mei⍀共r−R/2兲ei⌰ 共B13a兲 while the one at r ⬇ −R / 2 becomes dei共−⌰兲 exp − m关r2 ⌬vv → ⌬v− = mei⍀共−R兲ei⍀共r+R/2兲 = − mei⌰ei⍀共r+R/2兲 . 共B13b兲 共B9a兲 The corresponding zero modes differ by phases from the vortex solution in Eq. 共47a兲 or 共B4兲 but they retain their spinor structure. d cos e−mD , 0 共B9b兲 0v+ = For the second integrand, a similar shift, first by R / 2 and then by ⌰ gives d2rv̄⌬ⴱvv̄v = i 2m3 冕 ⬁ rdre−mr 0 冕 0 d r + R cos −mD e . D 冕 冕 ⬁ dr共1 − rm兲e−mr 0 冕 0 , v− We notice that the integrand may also be presented as − m1 r e−mD, thereby transforming Eq. 共B10a兲 after an integration by parts into 2m2 0 − v+ⴱ 0v− = 共B10a兲 d2rv̄⌬ⴱvv̄v = i 冢冣 冢冣 v+ D ⬅ 冑r2 + R2 + 2Rr cos 冕 共B12兲 2. Two vortices 2 + R2 + 2rR cos 共 − ⌰兲兴1/2 . 冕 8 m共mR兲1/2e−mR . This may be derived analytically with the following argument. We replace the upper limit 共⬁兲 of the r integral by R and approximate D by R + r cos . The integral now leads to modified Bessel functions I0 and I1, and we keep only their large argument, exponential asymptote. The remaining r integral yields Eq. 共B12兲. The evaluation of the first integrand proceeds by recalling that p+v = ⌬v共r − R / 2兲vⴱ and yields, after a shift of integration variable by R / 2 冕 冑 de−mD . 0 共B10b兲 0 0 . − v−ⴱ The explicit expressions for v+ and v− are not needed because the above form of the spinors guarantees that all matrix elements of h vanish. Thus, within our approximation, the two-vortex background retains its two zero modes. This is to be expected because asymptotically such a configuration is indistinguishable from a double vortex ⌬vv → mei⍀共r兲ei⍀共r兲 = me2i Thus we find that r+⬁ 具v̄兩h兩v典 = i⑀ , 共B14兲 and a double vortex possesses two zero modes.1 224515-9 共B15兲 PHYSICAL REVIEW B 81, 224515 共2010兲 CHAMON et al. R. Jackiw and P. Rossi, Nucl. Phys. B 190, 681 共1981兲. Read and D. Green, Phys. Rev. B 61, 10267 共2000兲. 3 D. A. Ivanov, Phys. Rev. Lett. 86, 268 共2001兲. 4 L. Fu and C. L. Kane, Phys. Rev. Lett. 100, 096407 共2008兲. 5 V. Gurarie and L. Radzihovsky, Phys. Rev. B 75, 212509 共2007兲. 6 S. Tewari, S. Das Sarma, and D.-H. Lee, Phys. Rev. Lett. 99, 037001 共2007兲. 7 P. Ghaemi and F. Wilczek, arXiv:0709.2626 共unpublished兲. 8 D. L. Bergman and K. Le Hur, Phys. Rev. B 79, 184520 共2009兲. 9 E. Majorana, Nuovo Cim. 14, 171 共1937兲. 10 F. Wilczek, Nat. Phys. 5, 614 共2009兲. 11 T. Senthil and M. P. A. Fisher, Phys. Rev. B 61, 9690 共2000兲. 12 A. Altland and M. R. Zirnbauer, Phys. Rev. B 55, 1142 共1997兲. 13 L. S. Brown, Quantum Field Theory 共Cambridge University Press, Cambridge, UK, 1995兲, p. 363; M. F. Peskin and D. V. Schroeder, An Introduction to Quantum Field Theory 共Perseus, Cambridge, MA, 1995兲, p. 73. 14 The same zero-energy mode with damped Bessel function oscillations occurs also in descriptions of bilayer graphene with the condensate ⌬ arising from states bound by interlayer Coulomb forces and the role of the chemical potential taken by an 1 2 N. external constant biasing voltage 共Refs. 15 and 16兲. Seradjeh, H. Weber, and M. Franz, Phys. Rev. Lett. 101, 246404 共2008兲. 16 R. Jackiw and S. Pi, Phys. Rev. B 78, 132104 共2008兲. 17 Note that the Hamiltonian h acting on an unconstrained Dirac field ⌽ also arises in a description of graphene. 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